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1. 发明授权

US5389510A Photographic elements containing alkynylamine dopants 失效
标题翻译：含有炔基胺掺杂剂的摄影元素
公开(公告)号：US5389510A
公开(公告)日：1995-02-14
申请号：US169832
申请日：1993-12-16
申请人： Carl R. Preddy , Wai K. Lam , Roger Lok
发明人： Carl R. Preddy , Wai K. Lam , Roger Lok
IPC分类号： G03C7/392 , G03C1/005 , G03C1/015 , G03C1/10 , G03C1/34
CPC分类号： G03C1/34 , G03C1/0051 , G03C1/10 , G03C1/015
摘要： The present invention relates to a photographic element comprising a silver halide emulsion, the emulsion comprising silver halide grains which contain an alkynylamine dopant. The presence of the alkynylamine dopant imparts to the photographic element the advantageous characteristic of increased sensitivity.
摘要翻译：本发明涉及包含卤化银乳剂的照相元件，该乳液包含含有炔基胺掺杂剂的卤化银颗粒。炔基胺掺杂剂的存在赋予照相元件增加灵敏度的有利特征。

2. 发明授权

US5482825A Silver halide emulsions containing fused dihydropyrimidines 失效
标题翻译：含有熔融二氢嘧啶的卤化银乳剂
公开(公告)号：US5482825A
公开(公告)日：1996-01-09
申请号：US362726
申请日：1994-12-23
申请人： Roger Lok , Carl R. Preddy , Xin Wen
发明人： Roger Lok , Carl R. Preddy , Xin Wen
IPC分类号： G03C1/015 , G03C1/005 , G03C1/07 , G03C1/10 , G03C1/34 , G03C1/08
CPC分类号： G03C1/07 , G03C1/10 , G03C1/34 , G03C1/0051
摘要： A method of making a silver halide emulsion comprising precipitating and chemically sensitizing the emulsion and further comprising adding to the emulsion a fused dihydropyrimidine compound represented by the following formula: ##STR1## wherein X is O, S or Se; R is a substituted or unsubstituted alkyl or aryl group; andZ contains the atoms necessary to form an aromatic group, a heteroaromatic group or a heterocyclic group and a silver halide emulsion made by this method.
摘要翻译：一种制备卤化银乳剂的方法，其包括对所述乳液进行沉淀和化学增感，并且还包括向所述乳液中加入由下式表示的稠合二氢嘧啶化合物：其中X为O，S或Se; R是取代或未取代的烷基或芳基; Z包含形成芳族基团，杂芳族基团或杂环基团所需的原子和通过该方法制备的卤化银乳剂。

3. 发明授权

US5413905A Photographic sensitivity increasing alkynylamine compounds and photographic elements 失效
标题翻译：摄影灵敏度增加炔基胺化合物和摄影元素
公开(公告)号：US5413905A
公开(公告)日：1995-05-09
申请号：US169833
申请日：1993-12-16
申请人： Roger Lok , Carl R. Preddy , John W. Harder
发明人： Roger Lok , Carl R. Preddy , John W. Harder
IPC分类号： G03C1/015 , G03C1/06 , G03C1/07 , G03C1/10 , G03C5/50 , G03C1/005 , G03C1/08
CPC分类号： G03C1/10 , G03C1/07 , G03C5/50
摘要： The present invention relates to water soluble photographic sensitivity increasing alkynylamine compounds. It also relates to photographic elements containing such compounds.
摘要翻译：本发明涉及水溶性照相感光度增加的炔基胺化合物。它还涉及含有这些化合物的照相元件。

4. 发明授权

US06322961B1 Color reversal photographic element containing emulsion sensitized with organomercapto AU(1) complexes and rapid sulfiding agents 失效
标题翻译：含有有机巯基AU（1）络合物和快速硫化剂敏化的乳液的彩色反转照相元件
公开(公告)号：US06322961B1
公开(公告)日：2001-11-27
申请号：US09666268
申请日：2000-09-21
申请人： Wai K. Lam , Roger Lok , David W. Sandford
发明人： Wai K. Lam , Roger Lok , David W. Sandford
IPC分类号： G03C106
CPC分类号： G03C1/09 , G03C7/3022
摘要： A color reversal photographic element is disclosed comprising a support having coated thereon a silver halide emulsion layer comprising a silver halide emulsion chemically sensitized in the presence of an organomercapto Au(I) complex having the formula [L—Au—L]M wherein M is a cationic counter ion and each L is an organomercapto ligand which has antifogging, stabilizing or sensitizing properties, and a rapid sulfiding agent represented by structure SS-1 wherein each of the R1, R2, R3, and R4 groups independently represents an alkylene, cycloalkylene, carbocyclic arylene, heterocyclic arylene, alkarylene or aralkylene group; or taken together with the nitrogen atom to which they are attached, R1 and R2 or R3 and R4 can complete a 5- to 7-membered heterocyclic ring; and each of the B1, B2, B3, and B4 groups independently is hydrogen or represents a carboxylic, sulfinic, sulfonic, hydroxamic, mercapto, sulfonamido or primary or secondary amino nucleophilic group, with the proviso that at least one of the B1R1 to B4R4 groups contains the nucleophilic group bonded to a urea nitrogen atom through a 1- or 2-membered chain. The use of the combination of the two classes of sensitizers of the present invention makes it possible to sensitize the silver halide emulsions employed in color reversal elements at a wider range of temperature. This robustness to temperature translates to less variable performance of the silver halide emulsion. Additionally, the use of individual gold and sulfur sensitizers advantageously makes it possible to sensitize silver halide reversal photographic elements such that the sulfur to gold ratio can be varied independently.
摘要翻译：公开了一种彩色反转照相元件，其包括在其上涂覆有卤化银乳剂层的载体，所述卤化银乳剂层包含在具有所述形成结构的有机巯基Au（I）络合物的存在下化学增感的卤化银乳剂，M是阳离子抗衡离子，并且每个L是具有防雾，稳定或敏化性能的有机巯基配体和由结构SS-1表示的快速硫化剂，其中R1，R2，R3和R4各自独立地表示亚烷基，亚环烷基，碳环亚芳基，杂环亚芳基，亚烷基或亚芳基组; 或与它们所连接的氮原子一起取代，R1和R2或R3和R4可以完成5-至7-元杂环; B1，B2，B3和B4各自独立地为氢或表示羧基，亚磺酸，磺酸，异羟肟酸，巯基，亚磺酰氨基或伯或仲氨基亲核基团，条件是至少一个B1R1至B4R4 基团通过1-或2-元链包含与尿素氮原子键合的亲核基团。使用本发明的两类敏化剂的组合使得可以在更宽的温度范围内使用在彩色反转元件中的卤化银乳剂敏化。对于温度的这种鲁棒性意味着卤化银乳剂的可变性能变小。此外，使用单独的金和硫敏化剂有利地使得可以使卤化银反转照相元件敏化，使得硫与金的比率可以独立地变化。

5. 发明授权

US06573038B2 High chloride silver halide elements containing pyrimidine compounds 失效
标题翻译：含有嘧啶化合物的高氯化物卤化银元素
公开(公告)号：US06573038B2
公开(公告)日：2003-06-03
申请号：US09872669
申请日：2001-06-01
申请人： Shihua S. Chen , Roger Lok , Alberto M. Martinez , Dean H. Russell
发明人： Shihua S. Chen , Roger Lok , Alberto M. Martinez , Dean H. Russell
IPC分类号： G03C134
CPC分类号： G03C7/39252 , G03C1/34 , G03C7/3022 , G03C2001/03517
摘要： A silver halide photographic element comprising a silver halide emulsion which is greater than 50 mole % silver chloride and a pyrimidine compound represented by Formula I wherein R1, R2, and R3 are each independently a hydrogen atom or a hydroxy, alkoxy, amino, alkylamino, cyanoamino or alkyl group, and R4 is a hydroxy, alkoxy, amino, alkylamino, cyanoamino or alkyl group; provided that at least one of R1, R2, R3, and R4 is a hydroxy or an amino group.
摘要翻译：一种卤化银照相元件，其包含大于50摩尔％氯化银的卤化银乳剂和由式I表示的嘧啶化合物，其中R1，R2和R3各自独立地为氢原子或羟基，烷氧基，氨基，烷基氨基，氰基氨基或烷基，R4是羟基，烷氧基，氨基，烷基氨基，氰基氨基或烷基; 条件是R 1，R 2，R 3和R 4中的至少一个是羟基或氨基。

6. 发明授权

US6034249A Stable and water soluble bis Au(I) complexes and their synthesis 失效
标题翻译：稳定和水溶性双Au（I）配合物及其合成
公开(公告)号：US6034249A
公开(公告)日：2000-03-07
申请号：US964104
申请日：1997-11-06
申请人： Roger Lok , Weimar W. White , Brian P. Cleary
发明人： Roger Lok , Weimar W. White , Brian P. Cleary
IPC分类号： G03C1/09 , C07D233/84 , C07F1/00 , C07F1/12 , C07D257/04
CPC分类号： C07F1/005
摘要： This invention relates to an organomercapto Au(I) complex having the formula ##STR1## wherein M is a cationic counterion;SOL is a solubilizing group;A is a substituted or unsubstituted divalent organic linking group;and n is 1 to 4 and wherein the compound is symmetrical.It further relates to a method of manufacturing an organomercapto Au(I) complex comprising reacting an Au(I) complex with an organomercapto ligand and isolating the resulting organomercapto Au(I) complex from the reaction mixture.
摘要翻译：本发明涉及具有下式的有机巯基Au（I）配合物，其中M是阳离子抗衡离子; SOL是增溶基团; A是取代或未取代的二价有机连接基团; 且n为1至4，并且其中该化合物是对称的。本发明还涉及一种制备有机巯基Au（I）配合物的方法，包括使Au（I）配合物与有机巯基配体反应并从所述反应混合物中分离得到的有机巯基Au（I）配合物。

7. 发明授权

US5700631A Photographic element containing new gold(I) compounds 失效
标题翻译：含有新金（I）化合物的摄影元素
公开(公告)号：US5700631A
公开(公告)日：1997-12-23
申请号：US672254
申请日：1996-06-28
申请人： Roger Lok , Weimar Weatherly White
发明人： Roger Lok , Weimar Weatherly White
IPC分类号： C07F1/00 , G03C1/09 , C07F1/12
CPC分类号： C07F1/005 , G03C1/09
摘要： A photographic element is provided comprising a support having situated thereon a silver halide emulsion layer, the emulsion layer comprising a compound of the formula: Z--SO.sub.2 S--Au(I)--L (I) wherein Z represents an alkyl, aryl, or heterocyclic group; and L represents a thioether, selenoether or telluroether containing ligand.
摘要翻译：提供了一种照相元件，其中包括一个位于其上的卤化银乳剂层的载体，该乳剂层包含下式的化合物：Z-SO2S-Au（I）-L（Ⅰ），其中Z代表烷基，芳基或杂环组; L代表含硫醚，硒醚或含曙红醚的配体。

8. 发明授权

US5601970A Photographic elements exhibiting improved stability 失效
标题翻译：表现出改善的稳定性的照相元件
公开(公告)号：US5601970A
公开(公告)日：1997-02-11
申请号：US367961
申请日：1995-01-03
申请人： Roger Lok
发明人： Roger Lok
IPC分类号： G03C7/00 , G03C1/035 , G03C1/34 , G03C7/392
CPC分类号： G03C1/346 , G03C7/39288
摘要： This invention provides a photographic element comprising a support having thereon a silver halide emulsion layer which is greater than about 50 mole % silver chloride, wherein the emulsion layer contains a thiophosphate ester of the structure: ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 are independently selected from the group consisting of an aliphatic, carbocyclic or heterocyclic group.
摘要翻译：本发明提供了一种照相元件，其中包含一种其上具有大于约50％（摩尔）氯化银的卤化银乳剂层的载体，其中该乳剂层含有以下结构的硫代磷酸酯：其中R1，R2和R3独立地为选自脂族，碳环或杂环基。

9. 发明授权

US5536633A Heat stabilized silver chloride photographic emulsions containing sulfur donors and sulfinate compounds 失效
标题翻译：含硫供体和亚磺酸盐化合物的热稳定氯化银照相乳剂
公开(公告)号：US5536633A
公开(公告)日：1996-07-16
申请号：US384200
申请日：1995-02-06
申请人： Roger Lok
发明人： Roger Lok
IPC分类号： G03C7/00 , G03C1/015 , G03C1/035 , G03C1/09 , G03C1/34 , G03C7/392
CPC分类号： G03C7/39296 , G03C1/346 , G03C7/39236 , G03C1/035
摘要： A silver halide photographic element comprising a silver halide emulsion which is greater than 50 mole % silver chloride, said emulsion being in reactive association with a sulfur donating compound, and a sulfinate compound represented by Formula (I)Z--SO.sub.2 M.sup.1 (I)wherein Z is a non-metallic aryl, alkyl or heterocyclic group, and M is a cationic counter ion;and wherein the sulfur donor is not a thiosulfonate or a diamino disulfide; and a method of making the emulsion.
摘要翻译：一种卤化银照相元件，其包含大于50摩尔％氯化银的卤化银乳剂，所述乳液与供硫化合物反应结合，和由式（I）Z-SO 2 M 1（I）表示的亚磺酸盐化合物，其中Z 是非金属芳基，烷基或杂环基，M是阳离子抗衡离子; 并且其中所述硫供体不是硫代磺酸盐或二氨基二硫化物; 以及制造乳液的方法。

10. 发明授权

US5399479A Photographic element exhibiting improved speed and stability 失效
标题翻译：具有改善速度和稳定性的照相元件
公开(公告)号：US5399479A
公开(公告)日：1995-03-21
申请号：US168892
申请日：1993-12-16
申请人： Roger Lok
发明人： Roger Lok
IPC分类号： G03C7/392 , G03C1/035 , G03C1/08 , G03C1/09 , G03C1/34
CPC分类号： G03C1/08 , G03C1/09 , G03C1/34 , G03C1/346 , G03C1/035
摘要： The present invention provides a photographic element comprising a support having thereon a silver halide emulsion layer. The emulsion layer contains an organic compound having a thiosulfonic acid substituent, an organic compound having a sulfinic acid substituent, and an alkynylamine.
摘要翻译：本发明提供了一种照相元件，其包括其上具有卤化银乳剂层的载体。乳剂层含有具有硫代磺酸取代基的有机化合物，具有亚磺酸取代基的有机化合物和炔基胺。

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