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1. 发明授权

US6103846A Process for making anionic polymeric di-and polyfunctional polymers using protected functional initiators 有权
标题翻译：使用保护的官能引发剂制备阴离子聚合二 - 和多官能聚合物的方法
公开(公告)号：US6103846A
公开(公告)日：2000-08-15
申请号：US305491
申请日：1999-05-05
申请人： Carl Lesley Willis , Robert Charles Bening , Michael Wayne Potter , Grant Wesley Haddix , David Karl Schisla , Thomas Carl Semple , Daniel Earl Goodwin
发明人： Carl Lesley Willis , Robert Charles Bening , Michael Wayne Potter , Grant Wesley Haddix , David Karl Schisla , Thomas Carl Semple , Daniel Earl Goodwin
IPC分类号： C08F2/00 , C08F4/46 , C08F4/58 , C08F4/72 , C08F36/04 , C08F36/06
CPC分类号： C08F4/72 , C08F36/04 , C08F4/58
摘要： The preparation of di- or polyfunctional polymers by anionic polymerization using functionalized initiators having the structure R.sup.1 R.sup.2 R.sup.3 Si--A--B, wherein each R is methyl and A is a hydrocarbon bridging group containing from 1 to 25 carbon atoms, and B is an alkali metal, is improved when polymerization occurs in the presence of a polymerization termination inhibitor which is a metal alkyl which has been added at a concentration to afford a molar ratio of the termination inhibitor to living polymer chain ends of about 0.1:1 to about 10:1.
摘要翻译：通过使用具有结构R1R2R3Si-AB的官能化引发剂通过阴离子聚合制备二官能或多官能聚合物，其中每个R是甲基，A是含有1至25个碳原子的烃桥联基团，B是碱金属，其被改进当在聚合终止抑制剂存在下进行聚合时，该聚合终止抑制剂是以浓度提供终止抑制剂与活性聚合物链末端的摩尔比为约0.1:1至约10:1的金属烷基。

2. 发明授权

US5681903A Process for the preparation of polymeric alpha, omega-dialdehydes and diacids 失效
标题翻译：制备聚合物α，ω-二醛和二酸的方法
公开(公告)号：US5681903A
公开(公告)日：1997-10-28
申请号：US575377
申请日：1995-12-20
申请人： Herbert Elliott Fried , Michael Wayne Potter
发明人： Herbert Elliott Fried , Michael Wayne Potter
IPC分类号： C08C19/38 , C08F8/30
CPC分类号： C08C19/38
摘要： A process for the preparation of polymeric alpha,omega-dialdehydes, diacids and mixtures thereof, which process comprises reacting a corresponding polymeric aliphatic alkanediol with a stable free radical nitroxide in the presence of a NO.sub.x -generating compound, an oxidant and, optionally, a solvent and/or a bromide-containing compound, and thereafter separating out the polymeric alpha,omega-dialdehyde and/or diacid.
摘要翻译：用于制备聚合α，ω-二醛，二酸及其混合物的方法，该方法包括使相应的聚合脂族链烷二醇与稳定的自由基氮氧化物在产生NO x的化合物，氧化剂和任选的溶剂和/或含溴化合物，然后分离聚合的α，ω-二醛和/或二酸。

3. 发明授权

US5948212A Titanium separation process 失效
标题翻译：钛分离工艺
公开(公告)号：US5948212A
公开(公告)日：1999-09-07
申请号：US734690
申请日：1996-10-21
申请人： Peter Anthony Kilty , Michael Philip Zum-Mallen , Michael Wayne Potter
发明人： Peter Anthony Kilty , Michael Philip Zum-Mallen , Michael Wayne Potter
IPC分类号： B01D3/14 , C01G23/02 , C08F4/64 , B01D3/10 , C07C17/383
CPC分类号： B01D3/146 , C01G23/022
摘要： A process for the separation of a mixture of a titanium tetrahalide, a reaction diluent of an intermediate boiling point and at least one of a titanium alkoxide, ester or complex thereof without the aid of a distinct separation solvent by subjecting the mixture to a first distillation step to separate the titanium tetrahalide as the lights component and subjecting the heavies product to a second distillation step to recover a portion of the reaction diluent as the lights component.
摘要翻译：一种将四卤化钛，中间沸点的反应稀释剂和至少一种烷醇钛，酯或其络合物的混合物在不借助不同分离溶剂的条件下分离的方法，该方法是使混合物进行第一次蒸馏分离四卤化钛作为灯组分，并使重质物产物进行第二蒸馏步骤以回收一部分反应稀释剂作为光组分。

4. 发明授权

US07041864B2 Linear and branched olefin production from cyclic olefin feedstocks 失效
标题翻译：来自环烯烃原料的直链和支链烯烃生产
公开(公告)号：US07041864B2
公开(公告)日：2006-05-09
申请号：US10316812
申请日：2002-12-11
申请人： Howard Lam-ho Fong , Michael Wayne Potter , David Stephen Brown
发明人： Howard Lam-ho Fong , Michael Wayne Potter , David Stephen Brown
IPC分类号： C07C6/00
CPC分类号： C07C6/06 , Y02P20/127
摘要： Ring opening cross metathesis of secondary non-cyclic hydrocarbons with cyclic unsaturated hydrocarbons having 8 carbon atoms or more to produce corresponding unsaturated product hydrocarbons having more than 8 carbon atoms.
摘要翻译：具有8个碳原子或更多个碳原子的环状不饱和烃的次级非环状烃的开环交叉复分解以产生具有多于8个碳原子的相应的不饱和产物烃。

5. 发明授权

US5663250A Deprotection with molten salt 失效
标题翻译：用熔盐脱保护
公开(公告)号：US5663250A
公开(公告)日：1997-09-02
申请号：US648947
申请日：1996-05-16
申请人： Michael Wayne Potter , William Charles Malven , Cary Alan Veith
发明人： Michael Wayne Potter , William Charles Malven , Cary Alan Veith
IPC分类号： C08F4/46 , C08F4/72 , C08F6/02 , C08F8/00 , C08F36/04
CPC分类号： C08F4/72 , C08F36/04 , C08F6/02
摘要： Protected functional initiator initiated elastomer solutions are deprotected and optionally ionic impurities removed by contact with a molten component such as sodium bisulphate monohydrate. This allows deprotection and removal of metal contaminants such as the initiator or residue from hydrogenation catalysts without the introduction of significant amounts of additional water which cause emulsion formation. In accordance with this invention, better metal removal is achieved and the process of metal removal operates more smoothly because of the absence of emulsion formation. Separation of the molten component containing the extracted metal contaminants can easily be carried out by simple liquid-liquid phase separation on either a continuous or batch basis.
摘要翻译：保护的官能引发剂引发的弹性体溶液被去保护，并且任选地通过与熔融组分如硫酸氢钠一水合物接触除去离子杂质。这允许金属污染物如氢化催化剂的引发剂或残余物的脱保护和去除，而不引入大量引起乳液形成的另外的水。根据本发明，实现了更好的金属去除，并且由于不存在乳液形成，金属去除工艺更顺利。含有提取的金属污染物的熔融组分的分离可以通过简单的液 - 液相分离在连续或间歇的基础上进行。

6. 发明授权

US06448436B1 Integrated process for the production of 2, 6-naphthalene dicarboxylic acid 失效
标题翻译：用于生产2,6-萘二羧酸的综合工艺
公开(公告)号：US06448436B1
公开(公告)日：2002-09-10
申请号：US09644003
申请日：2000-08-22
申请人： Keith Michael Kreitman , Steve Edward Brewer , John Bernard Rodden , Robert Lawrence Blackbourn , Thomas Fairchild Brownscombe , James Laurel Buechele , Ye-Mon Chen , Zaida Diaz , Donn Anthony DuBois , Raymond Lawrence June , Brendan Dermot Murray , Michael Wayne Potter
发明人： Keith Michael Kreitman , Steve Edward Brewer , John Bernard Rodden , Robert Lawrence Blackbourn , Thomas Fairchild Brownscombe , James Laurel Buechele , Ye-Mon Chen , Zaida Diaz , Donn Anthony DuBois , Raymond Lawrence June , Brendan Dermot Murray , Michael Wayne Potter
IPC分类号： C07C51265
CPC分类号： C08G63/189 , B01J27/232 , C07C51/02 , C07C51/15 , C07C51/265 , C07C51/412 , C07C51/416 , C07C51/42 , C07C51/43 , C07C51/47 , C07C51/487 , Y02P20/125 , C07C63/16 , C07C63/36 , C07C63/24 , C07C63/38 , C07C63/26 , C07C63/15 , C07C63/307
摘要： Disclosed is an integrated process for producing 2,6-naphthalene dicarboxylicacid comprising oxidizing a methylnaphthalene feedstock, hydrodebrominating the crude naphthoic acid product under conditions different from any work known in the art, forming a potassium salt of the acid; disproportionating the potassium salt to produce 2,6 potassium salts of NDA; selectively precipitating K2NDA; selectively precipitating the monopotassium salt of 2,6 NDA(KHNDA); disproportionating the KHNDA into 2,6 NDA and K2NDA; further reacting the 2,6 NDA in a pipe reactor; and drying the product 2,6 NDA by conventional means or directly slurrying directly into a PEN process. The process can tolerate impurities in the economical methylnaphthalene feed and the resulting 2,6 NDA is of high quality with
摘要翻译：公开了一种用于生产2,6-萘二羧酸的综合方法，包括氧化甲基萘原料，在与本领域已知的任何工作不同的条件下氢化溴化粗萘甲酸产物，形成酸的钾盐; 歧化钾盐生成2,6-二硝基苯胺钾盐; 选择性沉淀K2NDA; 选择性沉淀2,6 NDA（KHNDA）的单钾盐; 将KHNDA分解为2,6 NDA和K2NDA; 进一步使2,6 NDA在管式反应器中反应; 并通过常规方法干燥产品2,6NDA或直接浆化成PEN方法。该方法可以耐受经济的甲基萘进料中的杂质，并且所得的2,6 NDA是高质量的，具有<50ppm的钾。

7. 发明授权

US06153790A Method to produce aromatic dicarboxylic acids using cobalt and zirconium catalysts 失效
标题翻译：使用钴和锆催化剂生产芳族二羧酸的方法
公开(公告)号：US06153790A
公开(公告)日：2000-11-28
申请号：US201963
申请日：1998-12-01
申请人： Raymond Lawrence June , Michael Wayne Potter , Edward James Simpson , Charles Lee Edwards
发明人： Raymond Lawrence June , Michael Wayne Potter , Edward James Simpson , Charles Lee Edwards
IPC分类号： C07C51/255
CPC分类号： C07C51/255 , Y02P20/582
摘要： A process to produce terephthalic acid is provided, the process including the steps of: providing a feed stream comprising a dialkyl substituted aromatic and in an organic acid solvent: contacting the feed stream with an oxidant, the oxidant containing at least 50% by volume oxygen and at an oxygen partial pressure of at least 1 psia, at a temperature between about 80.degree. C. and about 130.degree. C., in the presence of a catalyst system comprising zirconium and cobalt, wherein the contacting is done in a stirred tank reactor; removing from the stirred tank reactor a vapor stream comprising the organic acid, water vapor and unreacted oxidant; condensing at least a portion of the organic acid and water from the vapor stream; separating at least a portion of the water from the organic acid back to the stirred tank reactor; returning at least a portion of the condensed organic acid back to the stirred tank reactor; continuously recovering from the stirred tank reactor a product comprising a diacid substituted aromatic; isolating solid crystals of diacid substituted aromatic from the reactor product; and recovering from the solid crystals a diacid substituted aromatic having a purity of preferably at least 97% by weight.
摘要翻译：提供了制备对苯二甲酸的方法，该方法包括以下步骤：提供包含二烷基取代的芳族化合物和在有机酸溶剂中的进料流：使进料流与氧化剂接触，氧化剂含有至少50体积％的氧在约80℃至约130℃的温度下，在包含锆和钴的催化剂体系的存在下，在至少1psia的氧分压下，在搅拌釜反应器中进行接触 ; 从搅拌釜反应器中除去包含有机酸，水蒸汽和未反应的氧化剂的蒸气流; 从蒸气流中冷凝至少一部分有机酸和水; 将至少一部分水与有机酸分离回搅拌釜反应器; 将至少一部分冷凝的有机酸返回到搅拌釜反应器中; 从搅拌釜反应器连续回收包含二酸取代的芳族化合物的产物; 从反应器产物中分离出二酸取代芳族化合物的固体晶体; 并从固体晶体中回收纯度优选至少97重量％的二酸取代芳族化合物。

8. 发明授权

US5866750A Method for removal of metal alkoxide compounds from liquid hydrocarbon 失效
标题翻译：从液态烃中除去金属醇盐化合物的方法
公开(公告)号：US5866750A
公开(公告)日：1999-02-02
申请号：US548291
申请日：1995-11-01
申请人： Robert Stephen Tomaskovic , Michael Wayne Potter , William Charles Malven
发明人： Robert Stephen Tomaskovic , Michael Wayne Potter , William Charles Malven
IPC分类号： B01D11/04 , C07C7/148 , C07C17/38 , C08F4/64 , C08F4/68 , C08F6/02 , C07C7/00 , B01D11/00 , C07C7/10 , C10G17/00
CPC分类号： C08F6/02 , C07C17/38 , C07C7/1485 , Y02P20/52
摘要： A method for recovering titanium and vanadium compounds, such as alkoxides, from a liquid hydrocarbon mixture by hydrolyzing the mixture with a base or acid wash having a sufficiently different density so that two liquid phases form, and separating the two liquid phases.
摘要翻译：通过用具有足够不同密度的碱或酸洗来水解混合物从液态烃混合物中回收钛和钒化合物如醇盐的方法，从而形成两个液相并分离两个液相。

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