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1. 发明授权

US5278245A Thermoplastic elastomers 失效
标题翻译：热塑性弹性体
公开(公告)号：US5278245A
公开(公告)日：1994-01-11
申请号：US957494
申请日：1992-10-07
申请人： Donn A. DuBois , Carl L. Willis
发明人： Donn A. DuBois , Carl L. Willis
IPC分类号： C08F297/02 , C08F297/04
CPC分类号： C08F297/048
摘要： Block copolymers of particular structure comprising blocks of polymerized alkenyl aromatic compound and polymerized conjugated alkadiene, as well as selectively hydrogenated derivatives thereof, are functionalized by the presence of additional polar blocks of polymerized alkyl methacrylate.
摘要翻译：包含聚合的链烯基芳族化合物和聚合的共轭二烯嵌段的特定结构的嵌段共聚物以及其选择性氢化的衍生物通过存在其它聚合的甲基丙烯酸烷基酯的极性嵌段官能化。

2. 发明授权

US5194510A Thermoplastic elastomers 失效
标题翻译：热塑弹性体
公开(公告)号：US5194510A
公开(公告)日：1993-03-16
申请号：US525812
申请日：1990-05-21
申请人： Donn A. DuBois , Carl L. Willis
发明人： Donn A. DuBois , Carl L. Willis
IPC分类号： C08F297/02 , C08F297/04
CPC分类号： C08F297/048
摘要： Block copolymers useful in formulations of adhesives, coatings, and lubricating oils have a particular structure comprising blocks of a polymerized alkenyl aromatic compound such as styrene, an internal block of a polymerized conjugated alkadiene such as butadiene, as well as selectively hydrogenated derivatives thereof, and a polar block of a polymerized alkyl methacrylate such as t-butyl methacrylate.

3. 发明授权

US5002676A Block copolymers 失效
标题翻译：嵌段共聚物
公开(公告)号：US5002676A
公开(公告)日：1991-03-26
申请号：US446827
申请日：1989-12-06
申请人： Carl L. Willis , Donn A. DuBois
发明人： Carl L. Willis , Donn A. DuBois
IPC分类号： C08F8/04 , C08F297/02 , C10M145/14 , C10N30/02 , C10N30/04 , C10N60/02
CPC分类号： C10M145/14 , C08F8/04 , C10M2205/06 , C10M2209/084 , C10N2240/02 , C10N2240/08
摘要： Novel, selectively hyrogenated block compolymers, which compolymers comprise at least one block of polymerized alkyl methacrylate and one block of polymerized conjugated alkadiene, provide improved dispersant properties and viscosity index improvement to hydrocarbon lubricating oils.

4. 发明授权

US5073610A Polymers of alkoxystyrenes and a process to produce polymers of alkoxystyrenes 失效
标题翻译：烷氧基聚合物的聚合物和生产聚合物的方法
公开(公告)号：US5073610A
公开(公告)日：1991-12-17
申请号：US589364
申请日：1990-09-28
申请人： Donn A. DuBois
发明人： Donn A. DuBois
IPC分类号： C08F12/22
CPC分类号： C08F12/22
摘要： A process to polymerize alkoxystyrenes utilizing a zeolite as the initiator is provided. Polymers of p-methoxystyrene having number average molecular weights in excess of 1.times.10.sup.6 are prepared by room temperature polymerization. The invention also provides a high molecular weight polymer of alkoxystyrenes which has a broad molecular weight distribution.
摘要翻译：提供了使用沸石作为引发剂使烷氧基苯乙烯聚合的方法。通过室温聚合制备数均分子量超过1×10 6的对甲氧基苯乙烯的聚合物。本发明还提供具有宽分子量分布的高分子量聚合物的烷氧基苯乙烯。

5. 发明授权

US5618903A Anionically polymerized block copolymers of ethylene and cyclic siloxane monomers 失效
标题翻译：乙烯和环状硅氧烷单体的阴离子聚合嵌段共聚物
公开(公告)号：US5618903A
公开(公告)日：1997-04-08
申请号：US634078
申请日：1996-04-17
申请人： Ronald J. Hoxmeier , Donn A. DuBois , Jeffrey G. Southwick
发明人： Ronald J. Hoxmeier , Donn A. DuBois , Jeffrey G. Southwick
IPC分类号： C08G77/442
CPC分类号： C08G77/442
摘要： This invention relates to anionically polymerized block copolymers comprised of at least one block polyethylene and at least one block of a polymerized cyclic siloxane monomer, e.g., polydimethylsiloxane. Block copolymers with multiple "arms" may be formed by coupling these living diblocks with polyfunctional coupling agents. One copolymer for use in wax release coatings has an overall weight average molecular weight of 1500 to 100,000, a polyethylene block weight average molecular weight of less than 4100, and a polyethylene content of less than 55 percent by weight. Another copolymer for use in extruded release coating films prepared by blending the copolymer with a film grade polymer has an overall molecular weight of less than 20,000 and a polyethylene block molecular weight of less than 3700.
摘要翻译：本发明涉及由至少一个嵌段聚乙烯和至少一个聚合的环状硅氧烷单体例如聚二甲基硅氧烷组成的阴离子聚合嵌段共聚物。可以通过将这些活性二嵌段与多官能偶联剂偶联来形成具有多个“臂”的嵌段共聚物。用于蜡剥离涂料的一种共聚物的总重均分子量为1500-100,000，聚乙烯嵌段重均分子量小于4100，聚乙烯含量小于55重量％。通过将共聚物与膜级聚合物共混制备的用于挤出脱模涂膜的另一种共聚物的总分子量小于20,000，聚乙烯嵌段分子量小于3700。

6. 发明授权

US5543458A Process for making graft block copolymers by growing anionic polymer chains from functionalized polyolefin backbones 失效
标题翻译：通过从官能化聚烯烃骨架生长阴离子聚合物链来制备接枝嵌段共聚物的方法
公开(公告)号：US5543458A
公开(公告)日：1996-08-06
申请号：US381242
申请日：1995-01-31
申请人： Ronald J. Hoxmeier , Robert C. Job , Bridget A. Spence , Donn A. DuBois
发明人： Ronald J. Hoxmeier , Robert C. Job , Bridget A. Spence , Donn A. DuBois
IPC分类号： C08F8/42 , C08F255/00 , C08F275/00
CPC分类号： C08F275/00 , C08F255/00 , C08F8/42
摘要： A graft block copolymer is comprised of a completely saturated olefinic backbone with pendant anionic polymer side chains. The polymer is produced by copolymerizing an .alpha.-olefin with a monomer which contains a functional group which can be metallated so an anionic monomer can be polymerized therefrom, metallating the copolymer by reaction with metal alkyl or aryl compound and a metallation activator, and growing anionic polymer side chains from the copolymer backbone by reacting an anionically polymerized monomer with the metallated copolymer.
摘要翻译：接枝嵌段共聚物由具有侧阴离子聚合物侧链的完全饱和的烯属主链组成。该聚合物是通过使α-烯烃与含有可被金属化的官能团的单体共聚制备的，因此阴离子单体可从其中聚合，通过与金属烷基或芳基化合物和金属化活化剂的反应使共聚物金属化，并且阴离子生长聚合物侧链通过使阴离子聚合的单体与金属化共聚物反应而由共聚物主链形成。

7. 发明授权

US5272211A Block copolymers of dienes, vinylarenes, and alkylmethacrylates as modified viscosity index improvers 失效
标题翻译：二烯，乙烯基芳烃和甲基丙烯酸烷基酯的嵌段共聚物作为改性粘度指数改进剂
公开(公告)号：US5272211A
公开(公告)日：1993-12-21
申请号：US993739
申请日：1992-12-21
申请人： Robert J. Sutherland , Donn A. DuBois
发明人： Robert J. Sutherland , Donn A. DuBois
IPC分类号： C08F8/04 , C08F8/32 , C08F297/04 , C08L53/00 , C10M145/14 , C10M149/06 , C10M157/00 , C10M157/04 , C10M169/02 , C10N20/04 , C10N30/02 , C10N40/04 , C10N40/08 , C10N40/20 , C08F297/02 , C10M149/00
CPC分类号： C10M157/04 , C08F297/048 , C08F8/32 , C08L53/00 , C10M145/14 , C10M149/06 , C10M157/00 , C10M2205/04 , C10M2205/06 , C10M2209/084 , C10M2217/00 , C10M2217/02 , C10M2217/024 , C10M2217/04 , C10M2217/06 , Y10S525/94
摘要： Polymers comprising blocks of a hydrogenated conjugated diene (B), a vinylarene (A), and an alkyl methacrylate (M), are readily prepared as a mixture of molecules having the structures B-A-M and B-A-M-A-B wherein both structures are effective as viscosity index improvers for oil compositions. Reaction of the polymers with a primary or secondary amine results in a dispersant viscosity index improver.
摘要翻译：包含氢化共轭二烯（B），乙烯基芳烃（A）和甲基丙烯酸烷基酯（M）的嵌段的聚合物容易制备为具有结构BAM和BAMAB的分子的混合物，其中两种结构作为粘度指数改进剂是有效的油组成。聚合物与伯胺或仲胺反应得到分散剂粘度指数改进剂。

8. 发明授权

US5496898A Star polymers of dienes, vinylarenes and alkyl methacrylates as modified viscosity index improvers 失效
标题翻译：二烯，乙烯基芳烃和甲基丙烯酸烷基酯的星形聚合物作为改性粘度指数改进剂
公开(公告)号：US5496898A
公开(公告)日：1996-03-05
申请号：US219338
申请日：1994-03-29
申请人： Robert J. Sutherland , Donn A. DuBois
发明人： Robert J. Sutherland , Donn A. DuBois
IPC分类号： C08F279/02 , C08F8/04 , C08F8/32 , C08F279/00 , C08F297/02 , C10M145/14 , C10M149/02 , C10M149/06 , C10N20/04 , C10N30/02 , C10N30/08 , C10N40/04 , C10N40/08 , C10N40/20
CPC分类号： C10M149/02 , C08F297/023 , C08F8/04 , C08F8/32 , C10M145/14 , C10M2209/084 , C10M2217/00 , C10M2217/02 , C10M2217/04 , C10N2240/06 , C10N2240/08 , C10N2240/10 , C10N2240/101 , C10N2240/104 , C10N2240/106 , C10N2240/40 , C10N2270/02
摘要： Star polymers having first polymeric arms comprising a hydrogenated conjugated diene and smaller second polymeric arms of a methacrylate resist coupling of methacrylate blocks attached to different cores and have improved performance as viscosity index improvers. The polymerized methacrylate units are converted to amide or imide groups by reaction with a primary or secondary amine to give the viscosity index improver dispersant properties.
摘要翻译：具有第一聚合物臂的星形聚合物包含氢化共轭二烯和甲基丙烯酸酯的较小的第二聚合物臂，其连接到不同芯上的甲基丙烯酸酯嵌段的偶联，并具有改进的作为粘度指数改进剂的通过与伯胺或仲胺反应将聚合的甲基丙烯酸酯单元转化成酰胺或酰亚胺基，得到粘度指数改进剂分散剂性质。

9. 发明授权

US5397841A Grafted polymers having reactive groups at the base 失效
标题翻译：在基体上具有反应性基团的接枝聚合物
公开(公告)号：US5397841A
公开(公告)日：1995-03-14
申请号：US163809
申请日：1993-12-08
申请人： Donn A. DuBois , Robert J. Sutherland
发明人： Donn A. DuBois , Robert J. Sutherland
IPC分类号： C08G81/02 , C08L33/06 , C08L33/00
CPC分类号： C08G81/021
摘要： The present invention provides grafted polymers that have pendent functional groups on the core of the polymer wherein the core is a polymerized alkylmethacrylate having a number average molecular weight from 500 to 1,000,000. The arms of the grafted polymer comprise anionically polymerized segments that have number average molecular weights from 1,000 to 300,000.
摘要翻译：本发明提供了在聚合物芯上具有侧基官能团的接枝聚合物，其中核是聚合的数均分子量为500至1,000,000的甲基丙烯酸烷基酯。接枝聚合物的臂包含数均分子量为1,000至300,000的阴离子聚合的链段。

10. 发明授权

US5336726A Butadiene polymers having terminal silyl groups 失效
标题翻译：具有末端甲硅烷基的丁二烯聚合物
公开(公告)号：US5336726A
公开(公告)日：1994-08-09
申请号：US29866
申请日：1993-03-11
申请人： Donn A. DuBois
发明人： Donn A. DuBois
IPC分类号： C07F7/18 , C08C19/44 , C08F4/42 , C08F4/58 , C08F8/04 , C08F8/42 , C08F36/06 , C08F136/00 , C08F136/06 , C08G81/02 , C08F297/04
CPC分类号： C08G81/021 , C08C19/44 , C08F36/06
摘要： Hydrogenated butadiene polymers having terminal silyl groups are prepared from a (4-vinylphenylene)dimethyl(t-butyl)silyl ether which is added to the polymer chain as a silyl ether initiator or an endcapping agent, or both. The silyl groups are then converted to phenolic groups. The polymers are useful in making coatings, sealants, binders, and block copolymers with polyesters, polyamides, and polycarbonates.
摘要翻译：具有末端甲硅烷基的氢化丁二烯聚合物由作为甲硅烷基醚引发剂或封端剂加入到聚合物链中的（4-乙烯基亚苯基）二甲基（叔丁基）甲硅烷基醚或二者制备。然后将甲硅烷基转化为酚基。聚合物可用于制备涂料，密封剂，粘合剂和与聚酯，聚酰胺和聚碳酸酯的嵌段共聚物。

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