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1. 发明授权

US5319101A Reactive imide monomers and radiation curable polymers derived therefrom 失效
标题翻译：活性酰亚胺单体和由其衍生的可辐射固化的聚合物
公开(公告)号：US5319101A
公开(公告)日：1994-06-07
申请号：US906715
申请日：1992-06-30
申请人： Carl J. Long, II , William F. Masler, III , William R. Wilber , Gary L. Julian
发明人： Carl J. Long, II , William F. Masler, III , William R. Wilber , Gary L. Julian
IPC分类号： C08F220/36 , C08F8/30 , C08F20/10 , C08G18/78 , C08G18/79 , C08G69/00 , C07D207/40
CPC分类号： C08G69/00 , C08F8/30
摘要： Reactive multifunctional imide monomers have been discovered from which radiation curable oligomers and polymers may be derived. The reactive imide monomers have at least one functional group which is polymerizable under free radical or ionic polymerization conditions with other similar functional groups. However, the same functional group and reaction product derived therefrom is substantially not subject to cleavage by oxidation or hydrolysis. The reactive imide monomer also contains at least one other functional group which remains intact under the above-described polymerization conditions to form a part of a side chain of the resultant polymer and will cross-link or cure by 2+2 cyclo-addition with other like functional groups upon irradiation.
摘要翻译：已经发现了可以衍生可辐射固化的低聚物和聚合物的反应性多官能酰亚胺单体。反应性酰亚胺单体具有至少一个在自由基或离子聚合条件下与其它类似官能团聚合的官能团。然而，相同的官能团和由其衍生的反应产物基本上不会被氧化或水解而被切割。反应性酰亚胺单体还含有至少一种在上述聚合条件下保持完整的其它官能团，以形成所得聚合物的侧链的一部分，并且通过与其它的2 + 2环加成交联或固化类似官能团。

2. 发明授权

US5212268A Multifunctional reactive polymeric diluent and method relating thereto 失效
标题翻译：多功能反应性聚合物稀释剂及其相关方法
公开(公告)号：US5212268A
公开(公告)日：1993-05-18
申请号：US965631
申请日：1992-10-23
申请人： Carl J. Long, II , William F. Masler, III , William R. Wilbur , Gary L. Julian , Julius Farkas
发明人： Carl J. Long, II , William F. Masler, III , William R. Wilbur , Gary L. Julian , Julius Farkas
IPC分类号： C08F8/30 , C08G69/00
CPC分类号： C08F8/30 , C08G69/00
摘要： The present invention is directed to a reactive diluent comprising a backbone portion and a pendant group portion. The backbone portion comprises at least two polymerizable sites, and the pendant group portion comprising a functional group having the following formula: ##STR1## wherein Z is an ethylenically unsaturated hydrocarbyl or substituted hydrocarbyl group containing from 2 to about 12 carbon atoms and wherein said pendant group is capable of a (2+2) cyclo-addition with another like pendant group of the above formula. The chain extending reaction site is preferably used in a polymerization reaction to provide a polymeric material, and the cross-linking reactive site is preferably used to create cross-linking as needed or desired.
摘要翻译：本发明涉及包含主链部分和侧基部分的反应性稀释剂。骨架部分包含至少两个可聚合位点，并且侧基部分包含具有下式的官能团：其中Z是含有2至约12个碳原子的烯键式不饱和烃基或取代烃基，其中所述垂饰基团能与（2 + 2）环加成与上述式的另一个相似的侧基。扩链反应位点优选用于聚合反应以提供聚合物材料，并且交联反应位点优选用于根据需要或需要产生交联。

3. 发明授权

US5349030A Easy to disperse polycarboxylic acid thickeners 失效
标题翻译：易分散多元羧酸增稠剂
公开(公告)号：US5349030A
公开(公告)日：1994-09-20
申请号：US156158
申请日：1993-11-23
申请人： Carl J. Long, II , Zahid Amjad , William F. Masler, III , William H. Wingo
发明人： Carl J. Long, II , Zahid Amjad , William F. Masler, III , William H. Wingo
IPC分类号： C08F283/06 , C08F2/26 , C08F220/04 , C08F283/12 , C08F287/00 , C09K3/00 , C08F2/08
CPC分类号： C08F220/04
摘要： An interpolymer of at least one olefinically unsaturated carboxylic acid containing at least one activated carbon-to-carbon olefinic double bond and at least one carboxyl group, in an amount of more than 15% by weight based upon the weight of the interpolymer, and at least one steric stabilizer surfactant having at least one hydrophilic moiety and at least one hydrophobic moiety and a linear block or a random comb configuration, or mixtures thereof, made by polymerizing olefinically unsaturated carboxylic acid monomers in an organic media, in the presence of free a radical forming catalyst, and the steric stabilizer.
摘要翻译：至少一种含有至少一种活性碳 - 碳烯属双键和至少一个羧基的烯属不饱和羧酸的互聚物，其量相对于互聚物的重量为大于15重量％，并且在至少一种空间稳定剂表面活性剂，其具有至少一个亲水部分和至少一个疏水部分和线性嵌段或无规梳形结构，或其混合物，其通过在有机介质中在烯属不饱和羧酸单体的存在下，在游离a 自由基形成催化剂和空间稳定剂。

4. 发明授权

US5288814A Easy to disperse polycarboxylic acid thickeners 失效
公开(公告)号：US5288814A
公开(公告)日：1994-02-22
申请号：US935616
申请日：1992-08-26
申请人： Carl J. Long, II , Zahid Amjad , William F. Masler, III , William H. Wingo
发明人： Carl J. Long, II , Zahid Amjad , William F. Masler, III , William H. Wingo
IPC分类号： C08F283/06 , C08F2/26 , C08F220/04 , C08F283/12 , C08F287/00 , C09K3/00 , C08F2/08
CPC分类号： C08F220/04
摘要： An interpolymer of at least one olefinically unsaturated carboxylic acid containing at least one activated carbon-to-carbon olefinic double bond and at least one carboxyl group, in an amount of more than 15% by weight based upon the weight of the interpolymer, and at least one steric stabilizer surfactant having at least one hydrophilic moiety and at least one hydrophobic moiety and a linear block or a random comb configuration, or mixtures thereof, made by polymerizing olefinically unsaturated carboxylic acid monomers in an organic media, in the presence of free a radical forming catalyst, and the steric stabilizer.

5. 发明授权

US5196550A Maleimido group containing monomers 失效
标题翻译：包含MONOMERS的MALEIMIDO GROUP
公开(公告)号：US5196550A
公开(公告)日：1993-03-23
申请号：US516409
申请日：1990-04-30
申请人： Carl J. Long, II , William F. Masler , William R. Wilbur , Gary L. Julian , Julius Farkas
发明人： Carl J. Long, II , William F. Masler , William R. Wilbur , Gary L. Julian , Julius Farkas
IPC分类号： C08F220/36 , C08F8/30 , C08F20/10 , C08G18/78 , C08G18/79 , C08G69/00
CPC分类号： C08G69/00 , C08F8/30
摘要： The present invention is directed to a reactive diluent comprising a backbone portion and a pendant group portion. The backbone portion comprises at least two polymerizable sites, and the pendant group portion comprising a functional group having the following formula: ##STR1## wherein Z is an ethylenically unsaturated hydrocarbyl or substituted hydrocarbyl group containing from 2 to about 12 carbon atoms and wherein said pendant group is capable of a (2+2) cyclo-addition with another like pendant group of the above formula. The chain extending reaction site is preferably used in a polymerization reaction to provide a polymeric material, and the cross-linking reactive site is preferably used to create cross-linking as needed or desired.

6. 发明授权

US5098982A Radiation curable thermoplastic polyurethanes 失效
标题翻译：辐射可固化热塑性聚氨酯
公开(公告)号：US5098982A
公开(公告)日：1992-03-24
申请号：US419236
申请日：1989-10-10
申请人： Carl J. Long, II
发明人： Carl J. Long, II
IPC分类号： C07D207/452 , C08G18/50 , C08G18/67 , C08G18/68
CPC分类号： C08G18/678 , C08G18/683
摘要： Radiation curable linear thermoplastic polyurethanes having imido pendent groups of the formula (A) ##STR1## wherein Z is an unsaturated C.sub.2-12 hydrocarbyl or substituted hydrocarbyl group (preferably H.sub.3 CC.dbd.CCH.sub.3) capable of undergoing photocrosslinking with another like group Z, are prepared by reaction of (a) a macroglycol of molecular weight 500-7,000, (b) one or more glycol chain extenders each having a molecular weight less than 500, which may include one or more low molecular weight aliphatic glycols (e.g., a C.sub.2-12 alkylene glycol or mixture thereof), and (c) an organic diisocyanate. Either a macroglycol or a chain extender must include a radiation sensitive pendent imido group of the above formula (A). The thermoplastic polyurethanes herein have hard and soft segments. Pendent groups (A) are present in the hard segments when a chain extender containing pendent group (A) is used, and are present in the soft segment when a macroglycol having pendent group (A) is used. The thermoplastic polyurethanes are useful for various purposes including coatings and magnetic recording media. Radiation curing gives a thermoset polyurethane having high hardness and good solvent resistance.

7. 发明授权

US5468797A Polycarboxylic acid thickeners, emulsifiers, and suspending aids having improved wettability characteristics 失效
标题翻译：聚羧酸增稠剂，乳化剂和悬浮助剂具有改善的润湿性能
公开(公告)号：US5468797A
公开(公告)日：1995-11-21
申请号：US346121
申请日：1994-11-29
申请人： Daniel J. Adams , Zahid Amjad , Solomon Lemma , Carl J. Long, II
发明人： Daniel J. Adams , Zahid Amjad , Solomon Lemma , Carl J. Long, II
IPC分类号： C08F283/06 , C08F2/26 , C08F220/04 , C08F283/12 , C08F287/00 , C09K3/00 , C08F2/08
CPC分类号： C08F220/04
摘要： A polymeric thickener, emulsifier or suspension aid having improved wettability which is an interpolymer of at least one olefinically unsaturated carboxylic acid containing at least one activated carbon-to-carbon olefinic double bond and at least one carboxyl group, in an amount of more than 15% by weight based upon the weight of the interpolymer, and at least one steric stabilizer surfactant having at least one hydrophilic moiety and at least one hydrophobic moiety and a linear block or a random comb configuration, or mixtures thereof, where the interpolymer has admixed therewith a wetting additive such as a low surface tension surfactant, a glycol, a polyhydric alcohol or mixtures thereof, and a process for dispersing the interpolymer by adding a low surface tension surfactant to the water into which the interpolymer is being dispersed.
摘要翻译：一种具有改善的润湿性的聚合物增稠剂，乳化剂或悬浮助剂，其是至少一种含有至少一种活性碳 - 碳烯属双键和至少一个羧基的烯属不饱和羧酸的互聚物，其量大于15 基于互聚物重量的重量％，以及至少一种具有至少一个亲水部分和至少一个疏水性部分的空间稳定剂表面活性剂和线性嵌段或无规梳形结构或其混合物，其中互聚物已与其混合润湿添加剂，例如低表面张力表面活性剂，二醇，多元醇或其混合物，以及通过向共聚物被分散的水中加入低表面张力表面活性剂来分散共聚体的方法。

8. 发明授权

US5373044A Polycarboxylic acid thickeners, emulsifiers, and suspending aids having improved wettability characteristics 失效
标题翻译：聚羧酸增稠剂，乳化剂和悬浮助剂具有改善的润湿性能
公开(公告)号：US5373044A
公开(公告)日：1994-12-13
申请号：US198007
申请日：1994-02-17
申请人： Daniel J. Adams , Zahid Amjad , Solomon Lemma , Carl J. Long, II
发明人： Daniel J. Adams , Zahid Amjad , Solomon Lemma , Carl J. Long, II
IPC分类号： C08F283/06 , C08F2/26 , C08F220/04 , C08F283/12 , C08F287/00 , C09K3/00 , C08F2/08
CPC分类号： C08F220/04
摘要： A polymeric thickener, emulsifier or suspension aid having improved wettability which is an interpolymer of at least one olefinically unsaturated carboxylic acid containing at least one activated carbon-to-carbon olefinic double bond and at least one carboxyl group, in an amount of more than 15% by weight based upon the weight of the interpolymer, and at least one steric stabilizer surfactant having at least one hydrophilic moiety and at least one hydrophobic moiety and a linear block or a random comb configuration, or mixtures thereof, where the interpolymer has admixed therewith a wetting additive such as a low surface tension surfactant, a glycol, a polyhydric alcohol or mixtures thereof, and a process for dispersing the interpolymer by adding a low surface tension surfactant to the water into which the interpolymer is being dispersed.
摘要翻译：一种具有改善的润湿性的聚合物增稠剂，乳化剂或悬浮助剂，其是至少一种含有至少一种活性碳 - 碳烯属双键和至少一个羧基的烯属不饱和羧酸的互聚物，其量大于15 基于互聚物重量的重量％，以及至少一种具有至少一个亲水部分和至少一个疏水性部分的空间稳定剂表面活性剂和线性嵌段或无规梳形结构或其混合物，其中互聚物已与其混合润湿添加剂，例如低表面张力表面活性剂，二醇，多元醇或其混合物，以及通过向共聚物被分散的水中加入低表面张力表面活性剂来分散共聚体的方法。

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