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1. 发明授权

US4093651A Production of perchloromethyl mercaptan 失效
标题翻译：全氯甲基硫醇的生产
公开(公告)号：US4093651A
公开(公告)日：1978-06-06
申请号：US753119
申请日：1976-12-22
申请人： Milton L. Honig , Carl C. Greco , Edward N. Walsh
发明人： Milton L. Honig , Carl C. Greco , Edward N. Walsh
IPC分类号： C07C313/08 , C07C145/00
CPC分类号： C07C313/08
摘要： A method for improving the yield of perchloromethyl mercaptan by including in the reaction mixture phosphonates or phosphonites, in amounts effective to suppress the formation of undesirable byproducts, such as carbon tetrachloride and sulfur monochloride.
摘要翻译：通过在反应混合物中包含膦酸盐或亚膦酸盐来提高全氯甲基硫醇的产率的方法，其用量有效地抑制不希望的副产物如四氯化碳和一氯化硫的形成。

2. 发明授权

US4092357A Production of perchloromethyl mercaptan 失效
标题翻译：全氯甲基硫醇的生产
公开(公告)号：US4092357A
公开(公告)日：1978-05-30
申请号：US753133
申请日：1976-12-22
申请人： Carl C. Greco , Edward N. Walsh
发明人： Carl C. Greco , Edward N. Walsh
IPC分类号： C07C319/02 , C07C321/04 , C07C145/00
CPC分类号： C07C313/08
摘要： A method for improving the yield of perchloromethyl mercaptan by including in the reaction mixture amounts of difunctional carbonyl compounds effective to suppress the formation of undesirable byproducts, such as carbon tetrachloride and sulfur monochloride.
摘要翻译：通过在反应混合物中包含有效抑制不希望的副产物（如四氯化碳和一氯化硫）形成的双官能羰基化合物的量来提高全氯甲基硫醇的产率的方法。

3. 发明授权

US4886895A Phosphate-containing and phosphonate-containing phosphate esters 失效
标题翻译：含磷酸盐和膦酸酯的磷酸酯
公开(公告)号：US4886895A
公开(公告)日：1989-12-12
申请号：US306113
申请日：1989-02-06
申请人： Thomas A. Hardy , Edward N. Walsh
发明人： Thomas A. Hardy , Edward N. Walsh
IPC分类号： C07F9/09 , C07F9/40 , C08K5/521 , C08K5/5333 , D06M13/292
CPC分类号： D06M13/292 , C07F9/091 , C07F9/093 , C07F9/4006 , C08K5/521 , C08K5/5333 , C23F11/1673
摘要： There are disclosed multiphosphorus-containing compounds comprising phosphonate-containing or phosphate-containing phosphate esters. The compounds can be prepared by: (a) reacting a phosphonate-containing or phosphate-containing alcohol with phosphorus pentoxide following by reaction with an epoxide, (b) reacting a phosphonate-containing or phosphate-containing alcohol with a phosphorus oxyhalide, hydrolyzing any phosphorus halogen bonds and then reacting the resulting phosphoric acid derivative with an epoxide, (c) transesterifying a phosphonate-containing or phosphate-containing alcohol with a dialkyl phosphite, oxidizing the resulting compound to yield a phosphoric acid derivative and reacting the phosphoric acid derivative with an epoxide. The compounds are useful as flame retardant additives for polyurethanes and textiles.
摘要翻译：公开了包含含膦酸酯或磷酸酯的磷酸酯的含有多磷的化合物。化合物可以通过以下方法制备：（a）通过与环氧化物反应，使含膦酸酯或含磷酸酯的醇与五氧化二磷反应，（b）使含膦酸酯或含磷酸盐的醇与磷酰卤反应，将任何磷卤素键，然后使所得磷酸衍生物与环氧化物反应，（c）将含膦酸酯或含磷酸酯的醇与亚磷酸二烷基酯酯交换，氧化所得化合物以产生磷酸衍生物，并使磷酸衍生物与环氧化物。该化合物可用作聚氨酯和纺织品的阻燃添加剂。

4. 发明授权

US4044074A Flame retardant polycarboxy alkyl and aryl phosphonates 失效
标题翻译：阻燃聚羧基烷基和芳基膦酸酯
公开(公告)号：US4044074A
公开(公告)日：1977-08-23
申请号：US669004
申请日：1976-03-22
申请人： Edward N. Walsh , Milton L. Honig
发明人： Edward N. Walsh , Milton L. Honig
IPC分类号： C07F9/40 , C08G63/692 , C08G79/04 , C08K5/51 , C08L101/00
CPC分类号： C08L101/00 , C07F9/4075 , C08G63/6924 , C08G79/04 , C08K5/51
摘要： Flame retardant polycarboxy alkyl and aryl phosphonates having the structural formula: ##STR1## ARE PREPARED, WHEREIN R is hydrocarbyl consisting of hydrogen and carbon and substituted hydrocarbyl including C.sub.2 -C.sub.10 alkylene, arylene, C.sub.7 -C.sub.20 alkylene substituted arylene, C.sub.3 -C.sub.20 cycloalkylene, C.sub.4 -C.sub.20 vinylene and derivatives of the foregoing containing non-labile pendant halogens, C.sub.1 -C.sub.6 alkyls, C.sub.1 -C.sub.6 haloalkyls, vinyls, ethers or C.sub.1 -C.sub.6 alkyl alcohol functions. R.sup.1 is hydrocarbyl consisting of hydrogen and carbon and substituted hydrocarbyl including C.sub.1 -C.sub.10 alkyl, aryl, C.sub.7 -C.sub.20 alkyl substituted aryl, C.sub.2 -C.sub.10 alkenyl, phenoxy, C.sub.1 -C.sub.10 alkoxy, aryloxy, or C.sub.3 -C.sub.20 cycloalkyl, and derivatives thereof containing non-liabile pendant halogens, C.sub.1 -C.sub.6 alkyls, C.sub.1 -C.sub.6 haloalkyls, vinyls, ethers, or C.sub.1 -C.sub.6 alkyl alcohol functions. R.sup.1 can also be: ##STR2## or OR.sup.4 H wherein R.sup.4 has the same definition as R, and R.sup.4 and R can be the same or different. R.sup.2, R.sup.3 and R.sup.5 are straight or branched C.sub.1 -C.sub.10 alkylene and can be the same or different. The integer represented by i is from about 2 to about 20 and the integers represented by m and n are different and are 0 or 1.The monomers are prepared by catalyzed transalkylation and the polymers are prepared by polycondensation of the monomers with diols or by polymeric transalkylation.
摘要翻译：具有以下结构式的阻燃聚羧基烷基和芳基膦酸酯：（I）制备，其中R是由氢和碳组成的烃基和包括C 2 -C 10亚烷基，亚芳基，C 7 -C 20亚烷基取代的亚芳基，C 3 -C 20亚烷基取代的亚芳基的取代的烃基， C 20 -C 20亚环烷基，C 4 -C 20亚乙烯基和前述的衍生物包含非不稳定的侧挂卤素，C 1 -C 6烷基，C 1 -C 6卤代烷基，乙烯基，醚或C 1 -C 6烷基醇官能团。 R 1是由氢和碳组成的烃基和包括C 1 -C 10烷基，芳基，C 7 -C 20烷基取代的芳基，C 2 -C 10烯基，苯氧基，C 1 -C 10烷氧基，芳氧基或C 3 -C 20环烷基的取代的烃基，及其衍生物 C1-C6烷基，C1-C6卤代烷基，乙烯基，醚或C1-C6烷基醇官能团。 R1也可以是：其中R 4具有与R相同的定义，且R 4和R可以相同或不同。 R2，R3和R5是直链或支链C1-C10亚烷基，可以相同或不同。由i表示的整数为约2至约20，由m和n表示的整数不同，为0或1。

5. 发明授权

US3965217A Method of preparing stable condensation products and products formed by the process 失效
标题翻译：通过该方法制备稳定的缩合产物和产物的方法
公开(公告)号：US3965217A
公开(公告)日：1976-06-22
申请号：US494444
申请日：1974-08-05
申请人： Kyung S. Shim , Edward N. Walsh
发明人： Kyung S. Shim , Edward N. Walsh
IPC分类号： C07F9/09 , C08J9/00 , C07F9/40
CPC分类号： C08J9/0061 , C07F9/09 , C08J2375/04 , C08J2485/00
摘要： Stabilized products which are phosphorus containing oligomers having ##EQU1## linkages between phosphorus atoms and which are obtained by the self-condensation of .beta.-haloalkyl esters of pentavalent phosphorus acids or the condensation products of these esters with an alkyl ester of a pentavalent phosphorus acid are formed by terminating the condensation reaction when it is about 35-75% complete, said condensation being performed in the absence of a nucleophilic initiator, such as a sodium salt initiator. The lower degree of condensation in the product and the absence of the nucleophilic initiator during the condensation reaction, is responsible for the lesser degree of scorching in a polyurethane foam containing the product as compared to one which is formed by allowing the condensation reaction go to completion or by use of a nucleophilic initiator during the condensation. If desired, the final product can be post-treated with an alkylene oxide and/or water or alcohol or by extraction with an inert organic solvent.
摘要翻译：具有磷原子之间具有|| -OCCO- |键的含磷低聚物的稳定化产物，其通过五价磷酸的β-卤代烷基酯的自缩合或这些酯与烷基酯的缩合产物当其完全约35-75％时终止缩合反应形成五价磷酸，所述缩合在不存在亲核引发剂如钠盐引发剂的情况下进行。与缩合反应中的亲核性引发剂相比，缩合反应中的缩合度低，不含亲核性引发剂，与通过使缩合反应完成而形成的聚氨酯泡沫体相比，含有该产品的聚氨酯泡沫体的焦烧程度较小或在冷凝期间使用亲核引发剂。如果需要，最终产物可用环氧烷和/或水或醇进行后处理，或用惰性有机溶剂萃取。

6. 发明授权

US4622276A Fuel cell electrolyte 失效
标题翻译：燃料电池电解液
公开(公告)号：US4622276A
公开(公告)日：1986-11-11
申请号：US751119
申请日：1985-07-02
申请人： Edward N. Walsh
发明人： Edward N. Walsh
IPC分类号： H01M8/08 , H01M8/00
CPC分类号： H01M8/08
摘要： This invention relates to a novel intermediate temperature fuel cell electrolyte, fuel cells containing this electrolyte and a process for operating these fuel cells.The fuel cell electrolyte composition comprises one or more phosphonic acids. Typical phosphonic acids are compounds of the formula ##STR1## wherein R is a moiety derived from hydroxyalkyl, alkyl, phenyl, alkylphenyl, vinyl, haloalkyl, halophenyl, halomethylphenyl, vinyl, amine, ammonia and ##STR2## and m represents an integer from 1 to 3 and n represents 0 (zero) or the integer 1. This electrolyte composition can further comprise phosphoric acid.The fuel cell electrolyte composition can include a gelling agent and can be effectively used in fuel cells wherein the fuel is hydrogen, the oxidizer is oxygen and the operating temperature is between about 100.degree. C. and 250.degree. C.
摘要翻译：本发明涉及一种新型的中温燃料电池电解质，含有该电解质的燃料电池和这些燃料电池的操作方法。燃料电池电解质组合物包含一种或多种膦酸。典型的膦酸是下式的化合物，其中R是衍生自羟基烷基，烷基，苯基，烷基苯基，乙烯基，卤代烷基，卤代苯基，卤代甲基苯基，乙烯基，胺，氨的部分，m表示1的整数至3，n表示0（零）或整数1.该电解质组合物可进一步包含磷酸。燃料电池电解质组合物可以包括胶凝剂，并且可以有效地用于燃料为氢的燃料电池中，氧化剂为氧，工作温度为约100℃至250℃。

7. 发明授权

US4292036A Process for imparting flame retardance to textile materials 失效
标题翻译：赋予纺织材料阻燃性的方法
公开(公告)号：US4292036A
公开(公告)日：1981-09-29
申请号：US146582
申请日：1980-05-05
申请人： Edward N. Walsh , Thomas A. Hardy
发明人： Edward N. Walsh , Thomas A. Hardy
IPC分类号： C07F9/09 , D06M13/292 , C07F9/11 , C07F9/40 , D06M1/00 , D06M13/34
CPC分类号： D06M13/292 , C07F9/091
摘要： Flame retardance is imparted to textile materials by impregnating them with a flame retardant composition comprising(a) at least one compound represented by the formula ##STR1## wherein R.sup.1 and R.sup.2 are each independently selected from the group consisting of aryl, arylalkyl, alkylaryl, alkenyl and alkyl having from 1 to about 6 carbon atoms and ##STR2## R.sup.3 represents an alkylene group having from 1 to about 5 carbon atoms, and R.sup.4 and R.sup.5 are each independently selected from the group consisting of hydrogen, ##STR3## wherein R.sup.6 represents an alkyl group having from 1 to about 4 carbon atoms; provided that not all of said R.sup.4 's and R.sup.5 's are --CH.sub.3 at the same time:(b) an aminoplast; and(c) an acid catalyst; and heating the impregnated textile material sufficiently to cure said flame retardant composition.
摘要翻译：通过用阻燃组合物浸渍它们来赋予纺织材料阻燃性，所述阻燃组合物包含（a）至少一种由下式表示的化合物：其中R 1和R 2各自独立地选自芳基，芳基烷基，烷基芳基，烯基和具有1至约6个碳原子的烷基，并且R 3代表具有1至约5个碳原子的亚烷基，且R 4和R 5各自独立地选自氢，其中R 6表示具有1至约4个碳原子的烷基; 条件是并不是所有的R 4和R 5都是同时的-CH 3：（b）氨基塑料; 和（c）酸催化剂; 并充分加热浸渍的纺织材料以固化所述阻燃组合物。

8. 发明授权

US4162279A Phosphonoxycarboxamides 失效
标题翻译：膦氧基酰胺
公开(公告)号：US4162279A
公开(公告)日：1979-07-24
申请号：US837072
申请日：1977-09-28
申请人： Edward N. Walsh , Ralph B. Fearing
发明人： Edward N. Walsh , Ralph B. Fearing
IPC分类号： C07F9/40 , D06M13/447 , C07F9/11
CPC分类号： D06M13/447 , C07F9/4075
摘要： Novel phosphonoxycarboxamides of the formula: ##STR1## WHEREIN R.sup.1 and R.sup.2 are selected from the group consisting of aryl and alkyl having from 1-6 carbon atoms and may be the same or different; R.sup.3 represents hydrogen or --CH.sub.2 OH; R.sup.4 represents hydrogen, --CH.sub.3, --CH.sub.2 OH, or --C.sub.2 H.sub.4 OH, R.sup.5 represents an alkyl group having from 1-5 carbon atoms; and n represents 1 or 2 are useful as flame retardant agents for textile materials.
摘要翻译：下式的新型膦酰氧甲酰胺：其中R 1和R 2选自芳基和具有1-6个碳原子的烷基，可以相同或不同; R3代表氢或-CH2OH; R 4表示氢，-CH 3，-CH 2 OH或-C 2 H 4 OH，R 5表示具有1-5个碳原子的烷基; n表示1或2可用作纺织材料的阻燃剂。

9. 发明授权

US3959415A Methods of preparing stable condensation products and products therefrom using an alkylene oxide treatment 失效
标题翻译：使用环氧烷处理制备稳定的缩合产物及其制品的方法
公开(公告)号：US3959415A
公开(公告)日：1976-05-25
申请号：US473469
申请日：1974-05-28
申请人： Kyung S. Shim , Edward N. Walsh
发明人： Kyung S. Shim , Edward N. Walsh
IPC分类号： C08G18/00 , C07F9/02 , C07F9/09 , C08G65/26 , C08G79/04 , C08J9/00 , C08K5/52 , C07F9/08
CPC分类号： C08J9/0061 , C08G65/2639 , C08G79/04 , C08J2375/04 , C08J2485/00
摘要： Products which are phosphorus containing oligomers having ##EQU1## linkages between phosphorus atoms and which are obtained by the self-condensation of .beta.-haloalkyl esters of pentavalent phosphorus acids or by condensation of these esters with an alkyl ester of a pentavalent phosphorus acid are treated after residual acidity has been neutralized with an alkylene oxide for a period of time which is sufficient to enable the alkylene oxide to act upon labile groups contained in the condensed product, i.e., cyclic, pyro and bridged groups, and to neutralize any further acidity generated by the opening of such groups. The stabilized products formed by this process when incorporated in a polyurethane foam formulation produce a foam having superior green strength to a foam containing such products which have not been treated in accordance with this invention.
摘要翻译：作为磷原子的磷键的低聚物的产物，它们是通过五价磷酸的β-卤代烷基酯的自缩合得到的，或通过这些酯与五价磷的烷基酯的缩合得到的在用烯化氧中和残余酸度后，将其酸处理一段时间，其足以使环氧烷能够作用于缩合产物中所含的不稳定基团，即环状，热解和桥连基团，并中和任何由这些群体的开放产生的进一步的酸度。通过该方法形成的稳定化产品在掺入聚氨酯泡沫配方中时，会产生具有优良生坯强度的泡沫，而泡沫体含有本发明未经处理过的这类产品。

10. 发明授权

US4604330A Fuel cell electrolyte 失效
公开(公告)号：US4604330A
公开(公告)日：1986-08-05
申请号：US562319
申请日：1983-12-16
申请人： Edward N. Walsh
发明人： Edward N. Walsh
IPC分类号： H01M8/08
CPC分类号： H01M8/08
摘要： This invention relates to a novel intermediate temperature fuel cell electrolyte, fuel cells containing this electrolyte and a process for operating these fuel cells.The fuel cell electrolyte composition comprises one or more phosphonic acids. Typical phosphonic acids are compounds of the formula ##STR1## wherein R is a moiety derived from hydroxyalkyl, alkyl, phenyl, alkylphenyl, vinyl, haloalkyl, halophenyl, halomethylphenyl, vinyl, amine, ammonia and ##STR2## and m represents an integer from 1 to 3 and n represents 0 (zero) or the integer 1. This electrolyte composition can further comprise phosphoric acid.The fuel cell electrolyte composition can include a gelling agent and can be effectively used in fuel cells wherein the fuel is hydrogen, the oxidizer is oxygen and the operating temperature is between about 100.degree. C. and 250.degree. C.

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