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    • 5. 发明专利
    • DE10340711A1
    • 2005-04-07
    • DE10340711
    • 2003-09-04
    • COVION ORGANIC SEMICONDUCTORS
    • PARHAM AMIRFALCOU AURELIEHEUN SUSANNESTEIGER JUERGEN
    • H01L51/00H01L51/30H01L51/40H01L51/50H01L51/10
    • The invention relates to electronic devices whose electronic properties can surprisingly be improved to a significant degree by inserting at least one crosslinkable polymeric buffer layer, preferably a cationically crosslinkable polymeric buffer layer, between the conductive doped polymer and the organic semiconductor layer. Particularly good properties are obtained with a buffer layer in which crosslinking is thermally induced, i.e. by raising the temperature to 50 to 250° C. Alternatively, crosslinking can be radiation-induced by adding a photoacid. Moreover, such a buffer layer can be advantageously applied by means of printing techniques, especially inkjet printing, as the ideal temperature for the thermal treatment is independent of the glass transition temperature of the material. This avoids having to rely on material that has a low molecular weight, making it possible to apply the layer by means of printing techniques. The next layer (the organic semiconductor layer) can also be applied with the aid of different printing techniques, particularly inkjet printing, because the buffer layer is rendered insoluble by the crosslinking process, thus preventing the buffer layer from solubilizing thereafter.
    • 6. 发明专利
    • ELECTRONIC DEVICES
    • AU2003288571A1
    • 2004-07-14
    • AU2003288571
    • 2003-12-18
    • AVECIA LTD
    • BECKER HEINRICHVESTWEBER HORSTVERES JANOSSTEIGER JUERGENOGIER SIMON DOMINICHEUN SUSANESTOESSEL PHILIPPGERHARD ANJA
    • C09K11/06H05B33/14H05B44/00H05B33/08
    • An electroluminescent device having an anode and a cathode, one of which is transparent, and one or more organic layers between said anode and said cathode, at least one of said organic layers comprising an organic electroluminescent material, wherein at least one of said organic layers comprises a polymeric material having repeat units of Formula (1): wherein: Y 1 represents, independently if in different repeat units, N, P, S, As and/or Se, preferably N; Ar 1 and Ar 2 are aromatic groups and Ar 3 is present only if Y 1 is N, P, or As in which case it too is an aromatic group; wherein Ar 1 and Ar 2 are the same or different and represent, independently if in different repeat units, a multivalent (preferably bivalent) aromatic group (preferably mononuclear but optionally polynuclear) optionally substituted by at least one optionally substituted C 1-40 carbyl-derived groups and/or at least one other optional substituent; and Ar 3 represents, independently if in different repeat units, a mono or multivalent (preferably bivalent) aromatic group (preferably mononuclear but optionally polynuclear) optionally substituted by at least one optionally substituted C 1-40 carbyl-derived group and/or at least one other optional substituent, and wherein the average number, m, of said repeat units in the polymer is at least (35).