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1. 发明申请

WO2013016040A1 REDUCED OXIDES HAVING LARGE THERMOELECTRIC ZT VALUES 审中-公开
标题翻译：具有大量热电阻值的减少氧化物
公开(公告)号：WO2013016040A1
公开(公告)日：2013-01-31
申请号：PCT/US2012/046834
申请日：2012-07-16
申请人： CORNING INCORPORATED , BACKHAUS-RICOULT, Monika , SMITH, Charlene Marie , ST. CLAIR, Todd Parrish
发明人： BACKHAUS-RICOULT, Monika , SMITH, Charlene Marie , ST. CLAIR, Todd Parrish
IPC分类号： C04B35/47
CPC分类号： C04B35/47 , B82Y30/00 , C04B35/495 , C04B35/645 , C04B2235/3224 , C04B2235/3225 , C04B2235/3227 , C04B2235/3229 , C04B2235/3239 , C04B2235/3251 , C04B2235/3843 , C04B2235/5445 , C04B2235/5454 , C04B2235/652 , C04B2235/6587 , C04B2235/666 , C04B2235/77 , C04B2235/9669 , H01L35/22
摘要： Doped and partially-reduced oxide (e.g., SrTiO 3 -based) thermoelectric materials is provided. The thermoelectric materials can be single-doped or multi-doped (e.g., co-doped) and display a thermoelectric figure of merit (ZT) of 0.2 or higher at 1050K. Also provided are methods of forming the thermoelectric materials involve combining and reacting suitable raw materials and heating them in a graphite environment to at least partially reduce the resulting oxide. Optionally, a reducing agent such as titanium carbide can be incorporated into the starting materials prior to the reducing step in graphite. The reaction product can be sintered to form a dense thermoelectric material.
摘要翻译：提供掺杂和部分还原的氧化物（例如，基于SrTiO 3的）热电材料。热电材料可以是单掺杂或多掺杂（例如，共掺杂），并且在1050K下显示出0.2或更高的热电性能（ZT）。还提供形成热电材料的方法包括组合和反应合适的原料并在石墨环境中加热它们以至少部分地减少所得到的氧化物。任选地，还原剂如碳化钛可以在石墨中的还原步骤之前引入原料中。反应产物可以烧结以形成致密的热电材料。

2. 发明申请

WO2009148567A2 METHODS FOR DIMINISHING OR PREVENTING THE DEPOSITION OF A METAL OXIDE ON AN ELECTRODE SURFACE 审中-公开
标题翻译：用于在电极表面上划分或防止金属氧化物沉积的方法
公开(公告)号：WO2009148567A2
公开(公告)日：2009-12-10
申请号：PCT/US2009/003339
申请日：2009-06-02
申请人： CORNING INCORPORATED , BACKHAUS-RICOULT, Monika
发明人： BACKHAUS-RICOULT, Monika
IPC分类号： H01M4/86 , H01M8/12
CPC分类号： H01M4/8605 , H01M4/9033 , H01M8/1231 , H01M8/1253 , H01M2008/1293 , Y02E60/525 , Y02P70/56
摘要： Described herein are methods for diminishing or preventing in electrochemical operating systems the deposition of a metal oxide on an electrode surface. The metal oxide is formed by electrochemically assisted reduction of volatile metal oxides formed from a metallic component exposed to oxidative environments. In one example, described herein are methods for diminishing or preventing poisoning of a cathode by applying a negative protection potential to the metallic component. In another example, described herein are methods for diminishing or preventing the deposition of a metal oxide on a cathode surface by removing oxygen from the metallic component itself and thereby decreasing the amount of released volatile oxide from the metallic component by use of an auxiliary oxygen pump cell. In another example, described herein is a method for diminishing or preventing the formation of volatile suboxides formed from a component composed of an oxide species by reduction in a fuel chamber or reducing environment, which includes applying a positive protection potential to the component.
摘要翻译：这里描述的是在电化学操作系统中减少或防止金属氧化物沉积在电极表面上的方法。通过电化学辅助还原由暴露于氧化环境的金属组分形成的挥发性金属氧化物形成金属氧化物。在一个实例中，本文描述的是通过向金属部件施加负的保护电位来减少或防止阴极中毒的方法。在另一个实例中，本文描述的是通过从金属组分本身去除氧而减少或防止金属氧化物沉积在阴极表面上的方法，从而通过使用辅助氧气泵来减少从金属组分释放的挥发性氧化物的量细胞。在另一个实例中，本文描述了一种减少或防止由燃料室中的还原或还原环境由氧化物种组成的组分形成的挥发性低氧化物的方法，其包括对组分施加正的保护电位。

3. 发明申请

WO2009058211A2 SEGMENTED SOLID OXIDE FUEL CELL STACK AND METHODS FOR OPERATION AND USE THEREOF 审中-公开
标题翻译：分段的固体氧化物燃料电池堆和用于其操作和使用的方法
公开(公告)号：WO2009058211A2
公开(公告)日：2009-05-07
申请号：PCT/US2008/012036
申请日：2008-10-23
申请人： CORNING INCORPORATED , BADDING, Michael E , BACKHAUS-RICOULT, Monika , HARRIS, James M , MARX, Paul
发明人： BADDING, Michael E , BACKHAUS-RICOULT, Monika , HARRIS, James M , MARX, Paul
IPC分类号： H01M8/24 , H01M8/04 , H01M8/12
CPC分类号： H01M8/249 , H01M8/04223 , H01M8/04238 , H01M8/04268 , H01M8/04302 , H01M8/04388 , H01M8/04395 , H01M8/04559 , H01M8/04589 , H01M8/04753 , H01M8/04955 , H01M8/2425 , H01M2008/1293
摘要： Disclosed is a segmented modular solid oxide fuel cell device having a plurality of independently controllable electrical power producing segments disposed within a common thermal environment. Also disclosed are methods for selectively operating one or more segments of the disclosed segmented modular solid oxide fuel cell device. Also disclosed are methods for performing a maintenance process on one or more segments of a segmented modular fuel cell device during fuel cell operation.
摘要翻译：公开了一种分段式模块化固体氧化物燃料电池装置，其具有设置在公共热环境内的多个可独立控制的产生电能的区段。还公开了用于选择性地操作所公开的分段模块化固体氧化物燃料电池装置的一个或多个区段的方法。还公开了用于在燃料电池操作期间对分段模块化燃料电池装置的一个或多个区段执行维护过程的方法。

4. 发明公开

EP2412039A2 THERMOELECTRIC DEVICE, ELECTRODE MATERIALS AND METHOD FOR FABRICATING THEREOF 审中-公开
标题翻译：热电装置材料，电极材料及其制造方法
公开(公告)号：EP2412039A2
公开(公告)日：2012-02-01
申请号：EP10725531.7
申请日：2010-03-25
申请人： Chen, Lidong , Corning Incorporated , Shanghai Institute Of Ceramics, Chinese Academy Of Sciences , Backhaus-Ricoult, Monika , He, Lin , Li, Xiaoya , Xia, Xugui , Zhao, Degang
发明人： CHEN, Lidong , BACKHAUS-RICOULT, Monika , HE, Lin , Li, Xiaoya , XIA, Xugui , ZHAO, Degang
IPC分类号： H01L35/32 , H01L35/34
CPC分类号： H01L35/34 , H01L35/08
摘要： A thermoelectric device, a method for fabricating a thermoelectric device and electrode materials applied to the thermoelectric device are provided according to the present invention. The present invention is characterized in arranging thermoelectric material power, interlayer materials and electrode materials in advance according to the structure of thermoelectric device; adopting one-step sintering method to make a process of forming bulked thermoelectric materials and a process of combining with electrodes on the devices to be completed simultaneously; and obtaining a π shape thermoelectric device finally. Electrode materials related to the present invention comprise binary or ternary alloys or composite materials, which comprise at least a first metal selected from Cu, Ag, Al or Au, and a second metal selected from Mo, W, Zr, Ta, Cr, Nb, V or Ti. The present invention simplifies fabricating procedures, reduces the cost and avoids adverse impacts due to exposing related elements to heat and pressure for a second time.

5. 发明申请

WO2013115888A2 NIOBIUM OXIDE-BASED THERMOELECTRIC COMPOSITES 审中-公开
标题翻译：氧化镍基热电复合材料
公开(公告)号：WO2013115888A2
公开(公告)日：2013-08-08
申请号：PCT/US2012/065453
申请日：2012-11-16
申请人： CORNING INCORPORATED , BACKHAUS-RICOULT, Monika
发明人： BACKHAUS-RICOULT, Monika
IPC分类号： H01B1/02 , H01B1/00
CPC分类号： C01G33/00 , B82Y30/00 , C01P2004/80 , C01P2006/40 , C04B35/495 , C04B35/62675 , C04B35/645 , C04B2235/3225 , C04B2235/3227 , C04B2235/3229 , C04B2235/3232 , C04B2235/3244 , C04B2235/3251 , C04B2235/3253 , C04B2235/3255 , C04B2235/3256 , C04B2235/3258 , C04B2235/3281 , C04B2235/3284 , C04B2235/3826 , C04B2235/3839 , C04B2235/3843 , C04B2235/3847 , C04B2235/3886 , C04B2235/404 , C04B2235/407 , C04B2235/422 , C04B2235/5436 , C04B2235/5454 , C04B2235/652 , C04B2235/6562 , C04B2235/6565 , C04B2235/6567 , C04B2235/6582 , C04B2235/6588 , C04B2235/666 , C04B2235/76 , C04B2235/77 , C04B2235/79 , C04B2235/80 , C04B2235/9615 , H01L35/22
摘要： A thermoelectric oxide material having at least one family of periodic planar crystallographic defects, where the planar defect interspacings match a significant fraction of the phonon dispersion (free path distribution) in the oxide material. As an example, a sub-stoichiometric, composite thermoelectric oxide material can be represented by the formula NbO 2.5-x :M, where 0
摘要翻译：具有至少一个周期性平面晶体缺陷系列的热电氧化物材料，其中平面缺陷间隔与氧化物材料中的声子分散（自由路径分布）的显着部分相匹配。作为示例，亚化学计量的复合热电氧化物材料可由式NbO 2·5-x：M表示，其中0

6. 发明申请

WO2012024120A1 P-TYPE SKUTTERUDITE MATERIAL AND METHOD OF MAKING THE SAME 审中-公开
标题翻译： P型球形材料及其制造方法
公开(公告)号：WO2012024120A1
公开(公告)日：2012-02-23
申请号：PCT/US2011/047172
申请日：2011-08-10
申请人： CORNING INCORPORATED , SHANGHAI INSTITUTE OF CERAMICS, CHINESE ACADEMY OF SCIENCES , BACKHAUS-RICOULT, Monika , CHEN, Lidong , HE, Lin , HUANG, Xiangyang , LIU, Ruiheng , QIU, Pengfei , YANG, Jiong , ZHANG, Wenqing
发明人： BACKHAUS-RICOULT, Monika , CHEN, Lidong , HE, Lin , HUANG, Xiangyang , LIU, Ruiheng , QIU, Pengfei , YANG, Jiong , ZHANG, Wenqing
IPC分类号： C22C12/00 , H01L35/18
CPC分类号： B22F3/10 , C22C12/00 , C22C30/00 , H01L35/18
摘要： The disclosure relates to a p-type skutterudite material and a method of making the same, comprising providing a p-type skutterudite material having a general formula: I y Fe 4-x M x Sb 12 /z(J) wherein I represents one or more filling atoms in a skutterudite phase, the total filling amount y satisfying 0.01≤y≤l; M represents one or more dopant atoms with the doping amount x satisfying 0≤x≤4; J represents one or more second phases with the molar ratio z satisfying 0≤z≤0.5; wherein second phase precipitates are dispersed throughout the skutterudite phase.
摘要翻译：本发明涉及一种p型方钴矿材料及其制备方法，包括提供具有以下通式的p型方钴矿材料：IyFe4-xMxSb12 / z（J）其中I表示方钴矿中的一个或多个填充原子总填充量y满足0.01 = y = 1; M表示掺杂量x满足0 = x = 4的一种或多种掺杂剂原子; J表示摩尔比z满足0 = z = 0.5的一个或多个第二相; 其中第二相沉淀分散在整个方钴矿相中。

7. 发明申请

WO2011066490A3 RETICULAR CORDIERITE COMPOSITION, ARTICLE AND MANUFACTURE THEREOF 审中-公开
公开(公告)号：WO2011066490A3
公开(公告)日：2011-06-03
申请号：PCT/US2010/058151
申请日：2010-11-29
申请人： CORNING INCORPORATED , BACKHAUS-RICOULT, Monika , GLOSE, Christopher R. , ZIMMERMANN, James W.
发明人： BACKHAUS-RICOULT, Monika , GLOSE, Christopher R. , ZIMMERMANN, James W.
IPC分类号： B01D46/24 , C04B38/00
摘要： A porous ceramic material is disclosed having a principal cordierite phase, the porous ceramic material exhibiting a normalized strength greater than 20 MPa. The cordierite phase has a reticular microstructure. A method for forming a porous ceramic body having a predominant phase of cordierite is provided which includes forming a body from a plasticized mixture of inorganic ceramic-forming ingredients that include a magnesia source, a silica source, and an alumina source, the alumina source including alumina-containing elongated particles, wherein at least 90 wt% of the alumina-containing elongated particles have a length of 50 to 150 ?m, and then firing the body.

8. 发明申请

WO2010068657A2 TITANIA-HALF METAL COMPOSITES AS HIGH-TEMPERATURE THERMOELECTRIC MATERIALS 审中-公开
标题翻译：钛金属高温金属复合材料作为高温热电材料
公开(公告)号：WO2010068657A2
公开(公告)日：2010-06-17
申请号：PCT/US2009/067297
申请日：2009-12-09
申请人： CORNING INCORPORATED , BACKHAUS-RICOULT, Monika
发明人： BACKHAUS-RICOULT, Monika
IPC分类号： C04B35/46 , C04B35/56 , C04B35/58 , C04B35/645 , C04B35/628 , C04B35/626
CPC分类号： C04B35/46 , B82Y30/00 , C04B35/56 , C04B35/5611 , C04B35/58 , C04B35/58014 , C04B35/5805 , C04B35/6265 , C04B35/62821 , C04B35/62831 , C04B35/645 , C04B2235/3232 , C04B2235/3237 , C04B2235/3826 , C04B2235/3843 , C04B2235/3886 , C04B2235/404 , C04B2235/5445 , C04B2235/5454 , C04B2235/549 , C04B2235/656 , C04B2235/6562 , C04B2235/6567 , C04B2235/6581 , C04B2235/6584 , C04B2235/664 , C04B2235/666 , C04B2235/781 , C04B2235/785 , C04B2235/80 , C04B2235/9607 , H01L35/22
摘要： A multiphase thermoelectric material includes a titania-based semiconducting phase and a half-metal conducting phase. The multiphase thermoelectric material is advantageously a nanocomposite material wherein the constituent phases are uniformly distributed and have crystallite sizes ranging from about 10 nm to 800 nm. The titania-based semiconducting phase can be a mixture of sub-stoichiometric phases of titanium oxide that has been partially reduced by the half-metal conducting phase. Methods of forming a multiphase thermoelectric material are also disclosed.
摘要翻译：多相热电材料包括基于二氧化钛的半导体相和半金属导电相。多相热电材料有利地是纳米复合材料，其中组成相均匀分布并且具有约10nm至800nm的微晶尺寸。基于二氧化钛的半导体相可以是由半金属导电相部分还原的氧化钛的亚化学计量相的混合物。还公开了形成多相热电材料的方法。

9. 发明申请

WO2009110974A1 DISPERSION-TOUGHENED CORDIERITE FOR FILTER AND SUBSTRATE APPLICATIONS 审中-公开
标题翻译：用于过滤器和基板应用的分散 - 增韧的腐蚀剂
公开(公告)号：WO2009110974A1
公开(公告)日：2009-09-11
申请号：PCT/US2009/001189
申请日：2009-02-26
申请人： CORNING INCORPORATED , BACKHAUS-RICOULT, Monika , GLOSE, Christopher R
发明人： BACKHAUS-RICOULT, Monika , GLOSE, Christopher R
IPC分类号： C04B35/195 , C04B38/00
CPC分类号： C04B35/195 , C04B38/0006 , C04B38/0009 , C04B2111/00793 , C04B2111/343 , Y10T428/24149 , Y10T428/249953 , C04B35/478 , C04B35/50 , C04B38/0054 , C04B38/0645
摘要： A porous ceramic substrate includes a first phase of microcracked cordierite ceramic material and a second phase of non-cordierite metal oxide particles dispersed in the cordierite ceramic, wherein at least a portion of the interface between the first and second phases is wetted by glass and the particles of the second phase have a size in the range of from about 0.1 to about 10 µm. A method for toughening a porous microcracked cordierite ceramic includes the steps of providing a cordierite batch composition; adding to the cordierite batch composition at least one non-cordierite forming metal oxide or metal oxide precursor; mixing the batch composition with a pore former, binder, and water into a paste; shaping the paste into a green body; firing the green body; and annealing the fired green body at a temperature below the firing temperature to form a toughened cordierite ceramic honeycomb having a second phase of crystallized non-cordierite particles dispersed within the cordierite ceramic, wherein at least a portion of the interface between the first and second phases is wetted by glass.
摘要翻译：多孔陶瓷衬底包括微裂纹堇青石陶瓷材料的第一相和分散在堇青石陶瓷中的非堇青石金属氧化物颗粒的第二相，其中第一相和第二相之间的界面的至少一部分被玻璃润湿，第二相的颗粒的尺寸在约0.1至约10μm的范围内。一种增韧多孔微裂纹堇青石陶瓷的方法包括提供堇青石批料组合物的步骤; 向所述堇青石批料组合物中加入至少一种形成非堇青石的金属氧化物或金属氧化物前体; 将分批组合物与成孔剂，粘合剂和水混合成糊状物; 将糊状物变成绿色的身体; 点燃绿色的身体以及在低于焙烧温度的温度下对烧制的生坯退火以形成具有分散在堇青石陶瓷内的结晶非堇青石颗粒的第二相的增韧堇青石陶瓷蜂窝体，其中第一相和第二相之间的界面的至少一部分被玻璃润湿。

10. 发明申请

WO2008066853A2 ACTIVATION OF SOLID OXIDE FUEL CELL ELECTRODE SURFACES 审中-公开
标题翻译：固体氧化物燃料电池电极表面的活化
公开(公告)号：WO2008066853A2
公开(公告)日：2008-06-05
申请号：PCT/US2007/024517
申请日：2007-11-28
申请人： CORNING INCORPORATED , BACKHAUS-RICOULT, Monika , WORK, Kimberley, L.
发明人： BACKHAUS-RICOULT, Monika , WORK, Kimberley, L.
IPC分类号： H01M8/12 , C04B41/91 , C04B35/486
CPC分类号： C04B41/91 , C04B35/486 , C04B41/009 , C04B41/5315 , C04B2111/00853 , C04B2235/3201 , C04B2235/3208 , C04B2235/3217 , C04B2235/3225 , C04B2235/3244 , C04B2235/3256 , C04B2235/3418 , C04B2235/72 , C04B2235/724 , C04B2235/727 , C11D7/08 , C11D11/0041 , H01M4/8621 , H01M8/1253 , H01M8/126 , H01M2300/0077 , Y02E60/525 , Y02P70/56 , C04B35/48 , C04B35/50
摘要： A solid oxide fuel cell that is capable of increased power density is disclosed. A ceramic electrolyte comprising at least one surface, wherein at least a portion of at least one surface is substantially free of segregated impurities is also disclosed. A solid oxide fuel cell comprising an anode and a cathode, each comprising an active surface, and an electrolyte having a surface, wherein at least a portion of each of the cathode active surface, the anode active surface, and the electrolyte surface are substantially free of segregated impurities is also disclosed. Methods for removing at least a portion of a segregated impurity from a solid oxide fuel cell either prior to or during assembly, or after a period of fuel cell operation are also disclosed.
摘要翻译：公开了一种能够提高功率密度的固体氧化物燃料电池。还公开了包含至少一个表面的陶瓷电解质，其中至少一个表面的至少一部分基本上没有分离的杂质。一种固体氧化物燃料电池，其包含阳极和阴极，每个阳极和阴极各自包含活性表面，以及具有表面的电解质，其中阴极活性表面，阳极活性表面和电解质表面中的每一个的至少一部分基本上不含还公开了分离的杂质。还公开了在组装之前或期间或在燃料电池操作一段时间之后从固体氧化物燃料电池去除至少一部分分离杂质的方法。

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