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1. 发明申请

WO2005113661A1 FLAME RETARDANTS 审中-公开
标题翻译：阻燃剂
公开(公告)号：WO2005113661A1
公开(公告)日：2005-12-01
申请号：PCT/EP2005/052126
申请日：2005-05-11
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , ROTH, Michael , SIMON, Dirk
发明人： ROTH, Michael , SIMON, Dirk
IPC分类号： C08K5/00
CPC分类号： C08K5/5317 , C07F9/301 , C07F9/304 , C07F9/305 , C07F9/3882 , C07F9/4056 , C08K5/34 , C08K5/5205
摘要： Flame retardants are described, comprising A. at least one organic phosphonate of formula (I), wherein R is hydrogen, C 1 -C 20 alkyl, unsubstituted or C 1 -C 4 alkyl-substituted phenyl or naphthyl, R' is hydrogen, C 1 -C 20 alkyl, unsubstituted or C 1 -C 4 alkyl-substituted phenyl or naphthyl or M 1 r+ /r, n is an integer from 0 to 6, M 1 r+ is an r-valent metal ion or the ammonium ion, r is an integer from 1 to 4, R 13 is isopropyl, isobutyl, tert-butyl, cyclohexyl or is cycloalkyl substituted by from 1 to 3 C 1 -C 4 alkyl groups, R 14 is hydrogen, C 1 -C 4 alkyl, cycloalkyl or is cyclohexyl substituted by from 1 to 3 C 1 -C 4 alkyl groups, and R 15 is hydrogen, C 1 -C 18 alkyl, trimethylsilyl, benzyl, phenyl or sulfonyl; and B. at least one flame retardant component based on a nitrogen compound, and also the use thereof in synthetic polymers.
摘要翻译：描述了阻燃剂，其包含A.至少一种式（I）的有机膦酸酯，其中R是氢，C 1 -C 20烷基，未取代的或C 1 -C 4烷基取代的苯基或萘基，R'是氢，C 1 -C 20烷基，未取代的或未取代的 C1-C4烷基取代的苯基或萘基或M1 / r，n为0-6的整数，M1为r价金属离子或铵离子，r为1至4的整数， R 13是异丙基，异丁基，叔丁基，环己基或被1至3个C 1 -C 4烷基取代的环烷基，R 14是氢，C 1 -C 4烷基，环烷基或被1至3个C 1取代的环己基 C 1-4烷基，R 15是氢，C 1 -C 18烷基，三甲基甲硅烷基，苄基，苯基或磺酰基; 和B.至少一种基于氮化合物的阻燃组分，以及它们在合成聚合物中的用途。

2. 发明申请

WO2003029332A1 CROSSLINKING OF UNSATURATED POLYMERS BY THE USE OF HYDROXYLAMINE-ESTERS 审中-公开
标题翻译：不饱和聚合物通过使用羟基胺酯的交联
公开(公告)号：WO2003029332A1
公开(公告)日：2003-04-10
申请号：PCT/EP2002/010403
申请日：2002-09-17
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , ROTH, Michael , SIMON, Dirk
发明人： ROTH, Michael , SIMON, Dirk
IPC分类号： C08J3/24
CPC分类号： C08K5/3435 , Y10T428/10
摘要： The instant invention relates to a process for crosslinking unsaturated polymer resins as e.g. unsaturated polyesters using hydroxylamine esters as radical source. Further aspects of the invention are a composition comprising unsaturated polymer resins as e.g. unsaturated polyester resins and a hydroxylamine ester and the use of hydroxylamine esters for crosslinking unsaturated polymers.
摘要翻译：本发明涉及一种使不饱和聚合物树脂交联的方法。使用羟胺酯作为根源的不饱和聚酯。本发明的其它方面是包含不饱和聚合物树脂的组合物，例如，不饱和聚酯树脂和羟胺酯，以及使用羟胺酯交联不饱和聚合物。

3. 发明申请

WO2003087211A3 FLAME RETARDANT POLYMER COMPOSITIONS CONTAINING HYDROXYLAMINE ESTERS 审中-公开
公开(公告)号：WO2003087211A3
公开(公告)日：2003-10-23
申请号：PCT/EP2003/003726
申请日：2003-04-10
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , ROTH, Michael , SIMON, Dirk , LESLIE, Grant , NESVADBA, Peter , KING, Roswell, Easton , KAPRINIDIS, Nikolas
发明人： ROTH, Michael , SIMON, Dirk , LESLIE, Grant , NESVADBA, Peter , KING, Roswell, Easton , KAPRINIDIS, Nikolas
IPC分类号： C08K5/3435
摘要： The instant invention pertains to a thermoplastic organic polymer containing a conventional flame retardant and a hydroxylamine ester, in particular a tetraalkyl piperidine hydroxylamine ester. Further aspects of the invention are the use of hydroxylamine esters as flame retardants and a method for improving flame retardancy of a thermoplastic organic polymer.

4. 发明申请

WO2003087211A2 FLAME RETARDANT POLYMER COMPOSITIONS CONTAINING HYDROXYLAMINE ESTERS 审中-公开
标题翻译：阻燃聚合物组合物含羟基胺酯
公开(公告)号：WO2003087211A2
公开(公告)日：2003-10-23
申请号：PCT/EP2003/003726
申请日：2003-04-10
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , ROTH, Michael , SIMON, Dirk , LESLIE, Grant , NESVADBA, Peter , KING, Roswell, Easton , KAPRINIDIS, Nikolas
发明人： ROTH, Michael , SIMON, Dirk , LESLIE, Grant , NESVADBA, Peter , KING, Roswell, Easton , KAPRINIDIS, Nikolas
IPC分类号： C08K5/3435
CPC分类号： C08K5/3435
摘要： The instant invention pertains to a thermoplastic organic polymer containing a conventional flame retardant and a hydroxylamine ester, in particular a tetraalkyl piperidine hydroxylamine ester. Further aspects of the invention are the use of hydroxylamine esters as flame retardants and a method for improving flame retardancy of a thermoplastic organic polymer.
摘要翻译：本发明涉及含有常规阻燃剂和羟胺酯，特别是四烷基哌啶羟胺酯的热塑性有机聚合物。本发明的其它方面是使用羟胺酯作为阻燃剂和改进热塑性有机聚合物的阻燃性的方法。

5. 发明申请

WO2007128678A1 DERIVATIVES OF PYRIMIDINES AS FLAME RETARDANTS 审中-公开
标题翻译：吡啶类作为阻燃剂的衍生物
公开(公告)号：WO2007128678A1
公开(公告)日：2007-11-15
申请号：PCT/EP2007/053948
申请日：2007-04-23
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , ROTH, Michael
发明人： ROTH, Michael
IPC分类号： C08K5/3462
CPC分类号： C08K5/3462 , C08K5/5313
摘要： The present invention pertains to a composition comprising an organic polymer, a derivative of a pyrimidine and a further flame retardant. The present invention also pertains to a process for flame retarding an organic polymer by applying thereto or incorporating therein a derivative of a pyrimidine, optionally in combination with a further flame retardant.
摘要翻译：本发明涉及包含有机聚合物，嘧啶衍生物和另外的阻燃剂的组合物。本发明还涉及一种通过向其中施用或掺入其中的可选地与另外的阻燃剂组合的嘧啶衍生物来阻燃有机聚合物的方法。

6. 发明申请

WO2006106059A1 AZO COMPOUNDS FOR POLYPROPYLENE DEGRADATION 审中-公开
标题翻译：用于聚丙烯降解的AZO化合物
公开(公告)号：WO2006106059A1
公开(公告)日：2006-10-12
申请号：PCT/EP2006/061120
申请日：2006-03-29
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , ROTH, Michael , PFAENDNER, Rudolf , WILÉN, Carl-Eric, Magnus , RONAN, Nicolas
发明人： ROTH, Michael , PFAENDNER, Rudolf , WILÉN, Carl-Eric, Magnus , RONAN, Nicolas
IPC分类号： C08F8/50 , C08F4/04 , C08F10/06 , C08K5/23 , C08L23/10
CPC分类号： C08F8/50 , C08F110/06 , C08K5/0033 , C08K5/23 , C08F10/06 , C08L23/10 , C08F2500/12 , C08F2500/02
摘要： The invention relates to a process and compositions suitable for reducing by heat the molecular weight of polypropylene, propylene copolymers or polypropylene blends. Azo compounds bearing different substituents are added to the polymers.
摘要翻译：本发明涉及一种适于通过加热降低聚丙烯，丙烯共聚物或聚丙烯共混物的分子量的方法和组合物。将具有不同取代基的偶氮化合物加入到聚合物中。

7. 发明申请

WO2006027327A1 DEGRADATION OF POLYPROPYLENE WITH HYDROXYLAMINE ESTER COMPOSITIONS 审中-公开
标题翻译：聚丙烯与羟基胺组合物的降解
公开(公告)号：WO2006027327A1
公开(公告)日：2006-03-16
申请号：PCT/EP2005/054268
申请日：2005-08-31
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , ROTH, Michael , NESVADBA, Peter , HORST, David E.
发明人： ROTH, Michael , NESVADBA, Peter , HORST, David E.
IPC分类号： C08K5/3435
CPC分类号： C08J11/28 , C08J2323/10 , C08J2323/12 , Y02W30/706
摘要： The invention relates to novel composition comprising hydroxylamine esters and thio compounds, which are suitable for lowering the molecular weight of polypropylene, propylene copolymers or polypropylene blends and result in an excellent degradation performance at temperatures below 220°C.
摘要翻译：本发明涉及包含羟胺酯和硫代化合物的新型组合物，其适用于降低聚丙烯，丙烯共聚物或聚丙烯共混物的分子量，并在低于220℃的温度下导致优异的降解性能。

8. 发明申请

WO2005090419A1 METHOD OF PREPARING ETHYLENE POLYMERS BY CONTROLLED HIGH PRESSURE POLYMERIZATION 审中-公开
标题翻译：通过控制高压聚合制备乙烯聚合物的方法
公开(公告)号：WO2005090419A1
公开(公告)日：2005-09-29
申请号：PCT/EP2005/051130
申请日：2005-03-14
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , ROTH, Michael , PFAENDNER, Rudolf , LUFT, Gerhard , FREIDEL, Frank
发明人： ROTH, Michael , PFAENDNER, Rudolf , LUFT, Gerhard , FREIDEL, Frank
IPC分类号： C08F10/02
CPC分类号： C08F110/02 , C08F10/00 , C08F4/32 , C08F4/00 , C08F2/00 , C08F2500/12 , C08F2500/10
摘要： The present invention relates to a method for the radical polymerization or copolymerization of ethylene at high pressures using a hydroxylamine ester as radical initiator. The hydroxylamine esters according to the invention are suitable initiators for the high pressure polymerization of ethylene leading to high molecular weight polyethylenes with narrow molecular weight distributions (Poyldispersity Index PD = 1,2 - 4.5).
摘要翻译：本发明涉及使用羟胺作为自由基引发剂在高压下自由基聚合或共聚乙烯的方法。根据本发明的羟胺酯是用于乙烯的高压聚合的合适的引发剂，导致具有窄分子量分布（分散度指数PD = 1,2-4.5）的高分子量聚乙烯。

9. 发明申请

WO2004000890A2 GRAFTING OF NITROXYL TERMINATED OLIGOMERS OR POLYMERS ONTO THERMOPLASTIC POLYMERS 审中-公开
标题翻译：将硝基终止的低聚物或聚合物引入热塑性聚合物
公开(公告)号：WO2004000890A2
公开(公告)日：2003-12-31
申请号：PCT/EP2003/006165
申请日：2003-06-12
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , FINK, Jochen , ROTH, Michael , PFAENDNER, Rudolf
发明人： FINK, Jochen , ROTH, Michael , PFAENDNER, Rudolf
IPC分类号： C08F4/00
CPC分类号： C08F293/005 , C08F4/00 , C08F8/30 , C08F10/00 , C08F2438/02 , C08G81/021 , C08F2/38
摘要： The instant invention relates to a process for the preparation of grafted polymers wherein in a first step A) a oligomer or polymer is prepared by controlled radical polymerization in the presence of a stable free nitroxyl radical or a nitroxylether to obtain a nitroxyl terminated oligomer or polymer and in a second step B) the nitroxyl terminated oligomer or polymer is mixed and reacted with a thermoplastic or elastomeric polymer or copolymer in its molten state at a temperature at which cleavage of the nitroxyl-polymer/oligomer bond occurs, whereby the nitroxyl terminated oligomer or polymer is grafted onto the thermoplastic or elastomeric polymer. A further subject of the present invention is a grafted polymer prepared by said process.
摘要翻译：本发明涉及一种制备接枝聚合物的方法，其中在第一步骤A）中，通过在稳定的游离硝酰基或硝酰基醚的存在下通过可控自由基聚合制备低聚物或聚合物，得到硝酰基封端的低聚物或聚合物并且在第二步骤B）中，将硝酰基封端的低聚物或聚合物与其熔融状态下的热塑性或弹性体聚合物或共聚物在发生硝酰基聚合物/低聚物键断裂的温度下反应，由此将硝酰基封端的低聚物或聚合物接枝到热塑性或弹性聚合物上。本发明的另一个主题是通过所述方法制备的接枝聚合物。

10. 发明申请

WO2004069887A2 COMB COPOLYMERS WITH DEFINED SIDE CHAINS AND PROCESS FOR THEIR MANUFACTURE 审中-公开
标题翻译：具有定义的侧链的COMB共聚物及其制造方法
公开(公告)号：WO2004069887A2
公开(公告)日：2004-08-19
申请号：PCT/EP2004/050063
申请日：2004-02-02
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , FINK, Jochen , ROTH, Michael , PFAENDNER, Rudolf
发明人： FINK, Jochen , ROTH, Michael , PFAENDNER, Rudolf
IPC分类号： C08F291/00
CPC分类号： C08F255/023 , C08F255/02 , C08F257/02 , C08F265/00 , C08F285/00 , C08F287/00 , C08F291/00 , C08F293/005 , Y10T428/2978
摘要： The present invention relates to the modification of copolymers, in particular of grafted copolymers into comb copolymers. The modification comprises the steps (i) of controlled radical polymerization of a polymer or copolymer bearing a epoxide group at one end resulting from the initiation step, and (ii) a heating step of the polymer prepared under (i) and a copolymer bearing a functional group either in the backbone or attached to a side chain, which is able to react with the epxide group. The result is a comb copolymer with well controlled chain length of the grafted side arms expressed for example by a low polydispersity.
摘要翻译：本发明涉及共聚物，特别是将接枝共聚物改性成梳型共聚物。所述改性包括步骤（i）在起始步骤产生的一端承载环氧基的聚合物或共聚物的受控自由基聚合，和（ii）在（i）下制备的聚合物的加热步骤和带有官能团在骨架中或附着于侧链，其能够与表面活性剂基团反应。结果是具有良好控制的链接长度的梳状共聚物，例如通过低多分散性表示的接枝侧臂的链长度。

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