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1. 发明申请

WO2003033500A1 PHOTOACTIVABLE NITROGEN BASES 审中-公开
标题翻译：可摄氮
公开(公告)号：WO2003033500A1
公开(公告)日：2003-04-24
申请号：PCT/EP2002/011238
申请日：2002-10-08
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , BAUDIN, Gisèle , DIETLIKER, Kurt , JUNG, Tunja
发明人： BAUDIN, Gisèle , DIETLIKER, Kurt , JUNG, Tunja
IPC分类号： C07D487/04
CPC分类号： C07D487/04 , B33Y70/00 , G03F7/0045 , G03F7/0295 , G03F7/031
摘要： Compounds of the formula I R7"N-R6 RS-C,N-R4 H C, R'/ I R, 3 R 2 (I) in which R, is an aromatic or heteroaromatic radical which is capable of absorbing light in the wave-length range from 200 nm to 650 nm and which is unsubstituted or substituted one or more times by C,-C,8alkyl, C2-C,ealkenyl, C2-C,8alkynyl, C,-C,ehaloalkyl, N02, NR,OR , CN, OR,2, SR,2, C(O)R,3, C(O)OR,4, halogen or a radical of the formula II R∼-N' R6 1 R5-C,N.R4 H I C - R3 I R2 (II) and which on absorption brings about a photoelimination which leads to the generation of an amidine group, R2 and R3 independently of one another are hydrogen, C,-C,ealkyl or phenyl which is unsubstituted or is substituted one or more times by C,-C,8alkyl, CN, OR,2, SR,2, halogen or C,-C,ehaloalkyl; R5 is C,-C,ealkyl or NR8R9; R4, R6, R,, R8, R9, R,o and R inde-pendently of one another are hydrogen or C,-C,8alkyl; or R4 and R6 together form a C2-C,2alkylene bridge which is unsubstituted or is substituted by one or more C1-C4alkyl radicals; or R5 and R,, independently of R4 and R6, together form a C2-C,2alkylene bridge which is unsubstituted or is substituted by one or more C1-C4alkyl radicals; or, if R5 is a radi-cal NR8R9, R, and R9 together form a C2-C,2alkylene bridge which is unsubstituted or is sub-stituted by one or more C1-C4alkyl radicals; and R,2, R,3 and R,4 independently of one another are hydrogen or C,-C,ealkyl; are suitable as photoinitiators for compounds which react under base catalysis.
摘要翻译：式I R7“N-R6RS-C，N-R4H HC，R'/ IR，3R2（I）的化合物，其中R 1是能够吸收波浪中的光的芳族或杂芳族基团，长度范围为200nm至650nm，其未被取代或被C 1 -C 8烷基，C 2 -C 6烯基，C 2 -C 8炔基，C 1 -C 8卤代烷基，N 2 NR，OR ，CN，OR，2，SR，2，C（O）R，3，C（O）OR 4，卤素或式II的基团R 1 -C 6R 5 R 5 -C - R3 I R2（II），其吸收引起导致脒基的生成的光致游离，R 2和R 3彼此独立地是氢，C 1 -C 6烷基或未取代或被取代的苯基 C 1 -C 8烷基，CN，OR 2，SR 2，卤素或C 1 -C 6卤代烷基; R 5为C 1 -C 6烷基或NR 8 R 9; R 4，R 6， R 1，R 2，R 3和R 4彼此独立地是氢或C 1 -C 8烷基;或者R 4和R 6一起形成未被取代或被一个或多个C 1 -C 4烷基取代的C 2 -C 2亚烷基桥自由基; 或R 5和R 7独立于R 4和R 6一起形成未被取代或被一个或多个C 1 -C 4烷基取代的C 2 -C 2亚烷基桥; 或者如果R 5是辐射级NR 8 R 9，则R 3和R 9一起形成未被取代或由一个或多个C 1 -C 4烷基取代的C 2 -C 2亚烷基桥; 和R，2，R 3和R 4彼此独立地是氢或C 1 -C 6烷基; 适用于在碱催化下反应的化合物的光引发剂。

2. 发明申请

WO2004108799A1 NOVEL SURFACE-ACTIVE POLYSILOXANE PHOTOINITIATORS 审中-公开
标题翻译：新型表面活性聚硅氧烷光敏剂
公开(公告)号：WO2004108799A1
公开(公告)日：2004-12-16
申请号：PCT/EP2004/050952
申请日：2004-05-28
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , ROGERS, Jonathan , BAUDIN, Gisèle , JUNG, Tunja , ÖHRLEIN, Reinhold , BAISCH, Gabriele
发明人： ROGERS, Jonathan , BAUDIN, Gisèle , JUNG, Tunja , ÖHRLEIN, Reinhold , BAISCH, Gabriele
IPC分类号： C08G77/38
CPC分类号： G03F7/029 , C08F2/50 , C08G77/38 , G03F7/0007 , G03F7/001 , G03F7/0037 , G03F7/0757
摘要： Polymeric photoinitiators of the formula I or II wherein n and m independently of one another are 3-5; o is 10-16; p is 4-8; R is phenyl-CO-CO-O-; Y and Y' independently of one another are C 1 -C 10 alkylene or -[(CH 2 ) a -O-(CH 2 ) b ] c - wherein a is 2-10, b is 0-10, c is 1-3; with the proviso that they are, however, at least 1 if the methylene group in question is between two oxygen atoms.
摘要翻译：其中n和m彼此独立的式I或II的聚合物光引发剂为3-5; o是10-16; p为4-8; R是苯基-CO-CO-O-; Y和Y'彼此独立地是C 1 -C 10亚烷基或 - [（CH 2）a -O-（CH 2）b] c - ，其中a是2-10，b是0-10，c是1-3; 但是，如果所讨论的亚甲基在两个氧原子之间，则它们至少为1。

3. 发明申请

WO2003066693A1 FLUORINATED PHOTOINITIATORS IN HIGHLY FLUORINATED MONOMERS 审中-公开
标题翻译：高荧光单体中的荧光光敏元件
公开(公告)号：WO2003066693A1
公开(公告)日：2003-08-14
申请号：PCT/EP2003/000818
申请日：2003-01-28
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , BAUDIN, Gisèle , JUNG, Tunja
发明人： BAUDIN, Gisèle , JUNG, Tunja
IPC分类号： C08F220/24
CPC分类号： C08F20/24
摘要： The invention provides photopolymerizable compositions comprising (A) at least one ethylenically unsaturated photopolymerizable fluocarbon compound selected from polyfluoroalkyl monoacrylates, polyfluoroalkyl monomethacrylatesor polyfluoroalkyldiacrylates and (B) at least one photoinitiator of the formula (I) R is a radical of the formula (II) s is a number of 1 to 4, r is a number of 1 to 2; Y is a single bond or is a divalent linker group A if s is 1, is a radical A 0 , where A 0 is C 1 -C3oalkyl, C 1 -C 30 alkenyl, C 1 -C 30 alkynyl or C 1 -C 30 aralkyl the radicals being substituted by at least two fluorine atoms and optionally further substituted by OH-, C 1 -C 4 alkoxy-, phenyl-, naphthyl-, halogen-, CN-, SR 7 -, NR 8 R 9 - and/or -O(CO)R 10 -; and the radical A 0 is uninterrupted or interrupted by one or more -O-, -S- or -NR 12 -; A if s is > 1, is a radical A 1 ; where A 1 is C 1 -C 30 alkylene, C 1 -C 3 oalkenylene, C l -C 3 oalkynylene or C 1 -C 30 aralkylene, the radicals being substituted by at least two fluorine atoms and optionally further substituted by OH-, C 1 -C 4 alkoxy-, phenyl-, naphthyl-, halogen-, CN-, SR 7 -, NR 8 R 9 - and/or -O(CO)R 10 -; and the radical A 1 is uninterrupted or interrupted by one or more -0-, -S- or -NR 12 -.
摘要翻译：本发明提供了可光聚合组合物，其包含A至少一种选自多氟烷基单丙烯酸酯，多氟烷基单甲基丙烯酸酯或多氟烷基二丙烯酸酯和至少一种式IR的光引发剂的烯键式不饱和光聚合性氟化烃化合物，式II的基团是1至4的数，r 是1〜2的数，Y是单键，如果s是1，则为二价连接基团A，为基团A0，其中A0为C1-C3烷基，C1-C30烯基，C1-C30炔基或C1-C30芳烷基，基团为被至少两个氟原子取代并任选进一步被OH - ，C 1 -C 4烷氧基 - ，苯基 - ，萘基 - ，卤素 - ，CN-，SR 7 - ，NR 8 R 9 - 和/或-OCOR 10-取代，并且基团A 0不间断或如果s> 1，则被一个或多个-O - ， - S-或-NR 12 - A中断，是基团A1，其中A 1是C 1 -C 30亚烷基，C 1 -C 30亚烯基，C 1 -C 30亚炔基或C 1 -C 30亚烷基，该基团被取代通过至少两个氟原子和任选的f 还被OH-，C 1 -C 4烷氧基 - ，苯基 - ，萘基 - ，卤素 - ，CN-，SR 7 - ，NR 8 R 9 - 和/或-OCOR 10 - 取代，并且基团A1不间断或被一个或多个-O-， -S-或-NR 12 - 。

4. 发明申请

WO2003074718A1 ENZYMATIC PROCESS FOR PREPARING ORGANOSILICON GROUP CONTAINING PHOTOINITIATORS 审中-公开
标题翻译：用于制备含有光敏剂的有机硅基团的酶法
公开(公告)号：WO2003074718A1
公开(公告)日：2003-09-12
申请号：PCT/EP2003/001896
申请日：2003-02-25
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , ÖHRLEIN, Reinhold , SCHÖNING, Kai-Uwe , BAISCH, Gabriele , HARTWIG, Jemima , BAUDIN, Gisèle , JUNG, Tunja
发明人： ÖHRLEIN, Reinhold , SCHÖNING, Kai-Uwe , BAISCH, Gabriele , HARTWIG, Jemima , BAUDIN, Gisèle , JUNG, Tunja
IPC分类号： C12P9/00
CPC分类号： C07F7/0889 , C12P9/00
摘要： The invention relates to a process for preparing organosilicon group containing photoinitiators of the formula (I), wherein m is a number from 1 to 200; q is 0 or 1; A is IN-C(O)-O-CHR 3 -Y- or IN-C(O)-NH-CHR 3 -Y-; A’ is A or R 1 ’; R 1 and R 1 ’, R 2 and R 2 ’ are C 1 -C 18 alkyl or phenyl, or -(O) q -SiR 1 R 1 ’R2; R 3 is hydrogen or C 1 -C 6 alkyl, Y is a divalent group selected from C 1 -C 10 alkeylene, C 2 -C 10 alkenylene or -(CH 2 ) b -O-(CH 2 ) a -; and b are each independently of the other a number of 1 to 6; IN is a photolabile functional moiety of the formula (II) or (III), wherein R 4 is hydrogen or -C(O)-C(O)-OH or -C(O)-C(O)-OC 1 -C 6 alkyl and n is 1-3; R 5 and R 6 are C 1 -C 12 alkyl or together are cycloC 5 -C 7 alkyl; R 7 is hydroxy, C 1 -C 6 alkoxy or morpholinyl; X is -(CH 2 ) a -, -(CH 2 ) b -O-(CH 2 ) a - or -(CH 2 ) b -O-CO-(CH 2 ) a -; a and b are each independently of the other a number of 1 to 6; whereby the process is characterized in that a photolabile functional moiety containing a carboxy group (IN-COOH) or an alkoxycarbonyl group (IN-CO-OC 1 -C 6 alkyl) is reacted with a carbinol- or amino terminated organosilicon compound of the formula (IV), wherein m, R 1 and R 1 ’, R 2 and R 2 ’ are as defined above and B is -Y-CHR 3 -OH or -Y-CHR 3 -NH 2 ; B’ is B or R 1 ’, in the presence of an enzyme which catalyzes the esterification, transesterification or amidation reaction.
摘要翻译：本发明涉及一种制备含有式（I）的光引发剂的有机硅基团的方法，其中m为1至200的数; q为0或1; A是IN-C（O）-O-CHR 3 -Y-或IN-C（O）-NH-CHR 3 -Y-; A'是A或R1'; R1和R1'，R2和R2'是C1-C18烷基或苯基，或 - （O）q-SiR1R1'R2; R 3是氢或C 1 -C 6烷基，Y是选自C 1 -C 10亚乙烯基，C 2 -C 10亚烯基或 - （CH 2）b -O-（CH 2）a - 的二价基团。和b各自独立地为1至6的数; IN是式（II）或（III）的光不稳定官能部分，其中R4是氢或-C（O）-C（O）-OH或-C（O）-C（O）-OC1-C6烷基， n为1-3; R5和R6是C1-C12烷基或一起是环C 5 -C 7烷基; R7是羟基，C1-C6烷氧基或吗啉基; X是 - （CH 2）a - ， - （CH 2）b -O-（CH 2）a-或 - （CH 2）b -O-CO-（CH 2）a-; a和b各自独立地为1至6的数; 其特征在于含有羧基（IN-COOH）或烷氧基羰基（IN-CO-OC1-C6烷基）的光不稳定官能部分与式（IV）的甲醇或氨基封端的有机硅化合物反应，其中m，R1和R1'，R2和R2'如上所定义，B是-Y-CHR 3 -OH或-Y-CHR 3 -NH 2; 在催化酯化，酯交换反应或酰胺化反应的酶存在下，B'是B或R1'。

5. 发明申请

WO2003066688A1 SURFACE-ACTIVE SILOXANE PHOTOINITIATORS 审中-公开
标题翻译：表面活性硅氧烷光敏剂
公开(公告)号：WO2003066688A1
公开(公告)日：2003-08-14
申请号：PCT/EP2003/000820
申请日：2003-01-28
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , BAUDIN, Gisèle , JUNG, Tunja
发明人： BAUDIN, Gisèle , JUNG, Tunja
IPC分类号： C08F2/50
CPC分类号： C08F2/50 , B33Y70/00
摘要： Compounds of the formula (I) are suitable photoinitiators which accumulates at the surface of the formulation (I), in which R is for example phenyl and A is a surface-active radical of the formula (III), Y is a divalent group C 3 -C 12 cycloalkylene, C 6 -C 12 bicycloalkylene; C 1 -C 6 alkylene-C 3 -C 12 cycloalkylene, C 1 -C 6 alkylene-C 6 -C 12 bicycloalkylene or C 1 -C 10 alkylene interrupted by one or more non-consecutive C 3 -C 12 cycloalkylene, -U-C 3 -C 12 Cycloalkylene, C 6 -C 12 bicycloalkylene or -U-C 6 -C 12 bicycloalkylene; C 1 -C 10 alkylene interrupted by one or more non-consecutive O and C 3 -C 12 Cycloalkylene, -U-C 3 -C 12 cycloalkylene, C 6 -C 12 bicycloalkylene and/or -U-C 6 -C 12 bicycloalkylene; -(CH 2 ) a -CH-CH 2 -OH or -(CH 2 ) b -O-(CH 2 ) a -CH-CH 2 -OH; or -(CH 2 ) a -CH(OH)-CH 2 - or -(CH 2 ) b -O-(CH 2 ) a CH(OH)-CH 2 -. U is U' or U" U' is -(CH 2 ) a COO-; U" is -Si(CH 3 )(CH 3 )- or -(CH 2 ) a -Si(CH 3 )(CH 3 )- , a is a number from 1 to 10; b is a number from 0 to 10; with the proviso that they are, however, at least 1 if the methylene group in question is between two oxygen atoms .
摘要翻译：式I的化合物是在制剂I的表面积聚的合适的光引发剂，其中R是例如苯基，A是式III的表面活性基团，Y是二价基团C 3 -C 12亚环烷基，C 6 -C 12亚环烷基 C 1 -C 6亚烷基-C 3 -C 12亚环烷基，被一个或多个非连续C 3 -C 12亚环烷基断开的C 1 -C 6亚烷基-C 6 -C 12亚环烷基或C 1 -C 10亚烷基，-U-C 3 -C 12亚环烷基，C 6 -C 12二环
烃基或-U-C 6 -C 12二环烷基C1- -C 1 -C 10亚烷基被一个或多个不连续的O和C 3 -C 12亚环烷基，-U-C 3 -C 12亚环烷基，C 6 -C 12二环烷基和/或-U-C 6 -C 12二环
烃基-CH 2 a -CH-CH 2 -OH或-CH 2 b -O-CH 2 - CH-CH 2 -OH或-CH 2 a-CHOH -CH 2 - 或-CH 2 b -O-CH 2 CH CHOH-CH 2 - 。 U是U'或U“U'是-CH 2 aCOO-U”是-SiCH 3 CH 3 - 或-CH 2 a-SiCH 3 CH 3 - ，a是1至10 b的数字是0至10的数，条件是它们是如果所讨论的亚甲基在两个氧原子之间，则至少为1。

6. 发明申请

WO2003066687A3 SURFACE-ACTIVE PHOTOINITIATORS 审中-公开
公开(公告)号：WO2003066687A3
公开(公告)日：2003-08-14
申请号：PCT/EP2003/000819
申请日：2003-01-28
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , BAUDIN, Gisèle , JUNG, Tunja
发明人： BAUDIN, Gisèle , JUNG, Tunja
IPC分类号： C08F2/46
摘要： Compounds of the formula la, Ib and Ic are suitable photoinitiators which accumulate at the surface of the formulation (Ic), in which R, R 1 , and R 2 a are e.g.phenyl substituted by at least one siloxane group A-X-, R a and R are e.g. phenylene is a surface-active radical of the formula III A 3 is a radical of the formula III in which n is from 2 to 1000; X and X 1 are -U-C 3 -C 12 cycloalkylene, -U-C 6 -C 12 bicycloalkylene, U-C 3 -C 12 cyclo-alkylene-C l -C 6 alkylene, U-C 6 - C 12 bicycloalkylene-C,-C 6 alkylene;- - or a group selected from -(CH 2 ) a CH-CH 2 -OH or -(CH 2 ) a O-(CH 2 ) b -CH-CH 2 -OH; I I O-CO-(CH 2 ) b - O-CO-(CH 2 ) c or -(CH 2 ) a .-CH(OH)-CH 2 -O-CO-(CH 2 ) b - or -(CH 2 ) b -O-(CH 2 ) a CH(OH)-CH 2 -O-CO-(CH 2 ) c ; and U is e.g. -COO-, -(CH 2 ) a C00-; Y is hydrogen; unsubstituted C 1 -C 20 alkyl or C 1 -C 20 alkyl substituted by A-X-.; Y 1 is e.g. C 1 -C 12 -alkylene.

7. 发明申请

WO2009050115A1 PHOTOLATENT CATALYSTS BASED ON ORGANOMETALLIC COMPOUNDS 审中-公开
标题翻译：基于有机化合物的光催化剂催化剂
公开(公告)号：WO2009050115A1
公开(公告)日：2009-04-23
申请号：PCT/EP2008/063608
申请日：2008-10-10
申请人： CIBA HOLDING INC. , KOHLI STECK, Rachel , LORDELOT, Caroline , VOGEL, Thomas , BAUDIN, Gisèle , BROWN, Paul , DIETLIKER, Kurt , HÜSLER, Rinaldo , JUNG, Tunja , SIMMENDINGER, Peter , STUDER, Katia , CARROY, Antoine
发明人： KOHLI STECK, Rachel , LORDELOT, Caroline , VOGEL, Thomas , BAUDIN, Gisèle , BROWN, Paul , DIETLIKER, Kurt , HÜSLER, Rinaldo , JUNG, Tunja , SIMMENDINGER, Peter , STUDER, Katia , CARROY, Antoine
IPC分类号： C08G18/22 , C08G18/24 , C08G18/62 , C08G18/79 , C09D175/04 , C08G18/42 , C08G18/80
CPC分类号： C08G18/227 , B33Y70/00 , C08G18/222 , C08G18/24 , C08G18/42 , C08G18/6216 , C08G18/792 , C08G18/80 , C09D175/04
摘要： The present invention provides organometallic latent catalyst compounds, which aresuitable as catalysts in polyaddition or polycondensation reactions which are catalysed by a Lewis acid type catalyst, in particular for the crosslinking of a blocked or unblocked isocyanate or isothiocyanate component with a polyol or polythiolto form a polyurethane (PU).
摘要翻译：本发明提供了有机金属潜催化剂化合物，它们可作为催化剂在催化剂加成或缩聚反应中被路易斯酸型催化剂催化，特别是用于使多元醇或多硫醇与封端或未封端异氰酸酯或异硫氰酸酯组分交联形成聚氨酯（PU）。

8. 发明申请

WO2007090765A2 HIGH CAPACITY OPTICAL STORAGE MEDIA COMPRISING ORGANOMETALLIC ION PAIRS 审中-公开
标题翻译：包含有机离子对的高容量光存储介质
公开(公告)号：WO2007090765A2
公开(公告)日：2007-08-16
申请号：PCT/EP2007/050922
申请日：2007-01-31
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , WENDEBORN, Frédérique , ADAM, Jean-Marie , BACHER, Jean-Pierre , BAUDIN, Gisèle , BIRBAUM, Jean-Luc , BUDRY, Jean-Luc , HINTERMANN, Tobias , NISHIMAE, Yuichi , BRYNJOLFFSSEN, Jitka , LIU, Suyou
发明人： WENDEBORN, Frédérique , ADAM, Jean-Marie , BACHER, Jean-Pierre , BAUDIN, Gisèle , BIRBAUM, Jean-Luc , BUDRY, Jean-Luc , HINTERMANN, Tobias , NISHIMAE, Yuichi , BRYNJOLFFSSEN, Jitka , LIU, Suyou
IPC分类号： G11B7/246 , G11B7/2467 , G11B7/249 , G11B7/2495 , G11B7/2498 , G11B7/253 , G11B7/2531 , G11B7/2534 , G11B7/2535 , G11B7/254 , G11B7/257 , G11B7/2575
CPC分类号： G11B7/2498 , C09B69/02 , C09B69/045 , G11B7/246 , G11B7/2467 , G11B7/2495 , G11B7/2531 , G11B7/2534 , G11B7/2535 , G11B7/254 , G11B7/256 , G11B7/2575 , G11B2007/25706 , G11B2007/2571
摘要： The invention , wherein the recording track comprises a compound of formula (I) or a mesomeric or tautomeric form thereof and are each independently of the other, or ; is or C 2 -C 8 heteroaryl unsubstituted or mono- or poly-substituted by R 47 , R 48 , R 49 and/or R 50 ; Q 1 and Q 6 are each independently of the other O or S; Q 2 and Q 4 are each independently of the other O, S or NR 51 ; Q 3 is N or CR 52 ; Q 5 is N, or is CR 14 when Q 4 is O or S; Q 7 is O, S, CR 22 R 23 or NR 35 ; Q 8 and Q 10 are each independently of the other CR 53 R 54 , O, S or NR 55 ; Q 9 is CR 43 or N; Q 11 is CR 56 or N; Q 12 , Q 14 and Q 16 are each independently of the other CR 57 R 58 , O, S or NR 51 ; Q 13 and Q 15 are each independently of the other CR 59 or N. The structures of the cations and the substituents are defined in the description. The invention also pertains to the use of compounds of the formula (I) in optical recording with a blue laser as well as to optical recording processes wherein pits of either lower or higher reflecticity are written on a track comprising compounds of the formula (I). Hence, the invention finally also relates to an optical recording medium comprising a recording dye which is bathochromic as compared with the laser wavelength, on which medium pits of lower reflectivity are written on a higher reflectivity track.
摘要翻译：本发明，其中记录轨道包含式（I）化合物或其互变异构体或互变异构体形式，各自独立地为或是未取代的或被R 47，R 48取代的单或多取代的C 1 -C 6烷基或C 2 -C 8 - R 49和/或R 50; Q 1和Q 6各自独立地为O或S; Q 2和Q 4各自独立地为另一个O，S或NR 51; Q 3是N或CR 52; 当Q 4是O或S时，Q 5是N，或者是CR 14; Q 7是O，S，CR 22 R 23或NR 35; Q 8和Q 10各自独立于另一个CR 53 R 54，O，S或NR 6， SUB> 55 ; Q 9是CR 43或N; Q 11是CR 56或N; Q 12，Q 14和Q 16各自独立于另一个CR 57 R 58， / SUB，O，S或NR 51; Q 13和Q 15各自独立于另一个CR 59或N.阳离子和取代基的结构在说明书中定义。本发明还涉及式（I）化合物在具有蓝色激光的光学记录中的用途以及光学记录方法，其中将低或高反射性的凹坑写在包含式（I）化合物的轨道上，。因此，本发明最终还涉及一种光记录介质，其包括与激光波长相比是红色的记录染料，其中较低反射率的中等凹坑被写在较高反射率轨道上。

9. 发明申请

WO2006018352A1 HIGH-CAPACITY OPTICAL STORAGE MEDIA 审中-公开
标题翻译：高容量光存储介质
公开(公告)号：WO2006018352A1
公开(公告)日：2006-02-23
申请号：PCT/EP2005/053215
申请日：2005-07-06
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , BACHER, Jean-Pierre , BAUDIN, Gisèle , WENDEBORN, Frédérique , ADAM, Jean-Marie , LEHMANN, Urs , BIRBAUM, Jean-Luc
发明人： BACHER, Jean-Pierre , BAUDIN, Gisèle , WENDEBORN, Frédérique , ADAM, Jean-Marie , LEHMANN, Urs , BIRBAUM, Jean-Luc
IPC分类号： C09B69/02 , C09B45/34 , G11B7/24
CPC分类号： G11B7/2467 , C09B45/20 , C09B45/34 , C09B69/045 , G11B7/246 , G11B7/247 , G11B7/2472 , G11B7/2492 , G11B7/2495 , G11B7/2498 , G11B7/2531 , G11B7/2533 , G11B7/2534 , G11B7/2535 , G11B7/256 , G11B7/2575 , G11B7/259 , G11B2007/25706 , G11B2007/2571 , G11B2007/25713 , G11B2007/25715 , G11B2007/25716
摘要： The invention accordingly relates to an optical recording medium comprising a substrate, a reflecting layer and a recording layer, wherein the recording layer comprises a compound of formula (I) or a mesomeric or tautomeric form thereof, wherein M 1 is a metal cation in the oxidation state +3, a hydroxy or halogeno metal group wherein the metal is in the oxidation state +4, or an oxo metal group wherein the metal is in the oxidation state +5; (III) and (IV) are each independently of the other (V), (VI) or (VII); (VIII) is (IX), (X), (XI), (XII), (XIII) or (XIV); (XV) is (XVI) or C 2 - C8 heteroaryl unsubstituted or mono- or poly-substituted by R 10 , R 11 , R 12 and/or R 13 ; Q 1 is N or CR 18 , Q 2 is N or CR 19 , Q 3 , Q 5 and Q 7 are each independently of the other CR 20 R 21, O, S or NR 22 , Q 4 is CR 16 or N and Q 6 is CR 17 or N ; and R 2 and/or R 6 are O, S or NR 33 . Please see the disclosure for the other substituents which are less relevant. The compounds of formula (I) are novel and also claimed, as well as the compound of formula (II), or a mesomer or tautomer thereof, wherein R38 is halogen, CF 3 , NO 2 , CN, COR 22 , COOR 23 , SO 3 R 23 , NCO or SCN, G 1 , G 2 , M 1 , R 1 , R 2 , R 4 , R 5 , R 6 , R 8 , R 22 and R 23 are as defined in formula (I), M 2 m+ is a cation with m positive charges, and m is an integer 1, 2 or 3. The optical recording media are remarkably suitable for DVD±R (658 nm), especially at high recording speeds.
摘要翻译：因此，本发明涉及一种包括基底，反射层和记录层的光学记录介质，其中记录层包含式（I）化合物或其互变异构体或互变异构体形式，其中M +

10. 发明申请

WO2008101842A1 ELECTROLUMINESCENT METAL COMPLEXES WITH BENZOTRIAZOLES 审中-公开
标题翻译：电致发光金属复合物与苯甲酸酯
公开(公告)号：WO2008101842A1
公开(公告)日：2008-08-28
申请号：PCT/EP2008/051702
申请日：2008-02-13
申请人： CIBA HOLDING INC. , SCHÄFER, Thomas , MURER, Peter , BAUDIN, Gisèle , KOCHER, Manuela , MAIKE, François , ALLENBACH, Stephan , SIFT, Rosemarie , SCHMIDHALTER, Beat
发明人： SCHÄFER, Thomas , MURER, Peter , BAUDIN, Gisèle , KOCHER, Manuela , MAIKE, François , ALLENBACH, Stephan , SIFT, Rosemarie , SCHMIDHALTER, Beat
IPC分类号： C07F15/00
CPC分类号： H01L51/0085 , C07F15/0033 , C07F15/0086 , C09K11/06 , C09K2211/1059 , C09K2211/185 , H01L51/006 , H01L51/0081 , H01L51/0087 , H01L51/5016
摘要： This invention relates to electroluminescent metal complexes with benzotriazoles of the formula (I), a process for their preparation, electronic devices comprising the metal complexes and their use in electronic devices, especially organic light emitting diodes (OLEDs), as oxygen sensitive indicators, as phosphorescent indicators in bioassays, and as catalysts.
摘要翻译：本发明涉及具有式（I）的苯并三唑的电致发光金属络合物，其制备方法，包含金属络合物的电子器件及其在电子器件中的用途，特别是有机发光二极管（OLED），作为氧敏感指示剂，如生物测定中的磷光指标，以及催化剂。

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