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    • 5. 发明专利
    • DE69726544T2
    • 2004-09-30
    • DE69726544
    • 1997-10-06
    • CIBA SC HOLDING AG
    • KURATLI ROLFSCHMIDLIN ANITA
    • D06L3/12C11D1/72C11D1/722C11D1/825C11D3/28C11D3/34C11D3/42C11D3/20
    • The present invention provides a liquid fluorescent whitening agent formulation which is a solution having a viscosity of 50 to 5000 mPas, preferably 100 to 3500 mPas, especially 100 to 1000 mPas and which comprises: a) 10-25%, preferably 15-20% by weight of an anionic fluorescent whitening agent, based on the total weight of the formulation; b) 15-35%, preferably 20-30% by weight of a polar solvent, based on the total weight of the formulation; and c) 45-75%, preferably 50-70% by weight, based on the total weight of the formulation, of a nonionic surfactant having the formula: in which m is 1, 2, 3 or 4 and, when m is 1, R is a C8-C18-alkyl residue or a C8-C18-alkylcarboxy residue; when m is 2, R is a C2-C4alkylene glycol residue from which the two hydroxy groups have been removed; when m is 3, R is the residue of trimethylolpropane from which the three hydroxy groups have been removed; and when m is 4, R is the residue of pentaerythritol residue from which the four hydroxy groups have been removed; R1 is hydrogen, methyl or ethyl; and n is a number ranging from 1 to 40.
    • 6. 发明专利
    • ES2210486T3
    • 2004-07-01
    • ES97810741
    • 1997-10-06
    • CIBA SC HOLDING AG
    • KURATLI ROLFSCHMIDLIN ANITA
    • D06L3/12C11D1/72C11D1/722C11D1/825C11D3/28C11D3/34C11D3/42C11D3/20
    • The present invention provides a liquid fluorescent whitening agent formulation which is a solution having a viscosity of 50 to 5000 mPas, preferably 100 to 3500 mPas, especially 100 to 1000 mPas and which comprises: a) 10-25%, preferably 15-20% by weight of an anionic fluorescent whitening agent, based on the total weight of the formulation; b) 15-35%, preferably 20-30% by weight of a polar solvent, based on the total weight of the formulation; and c) 45-75%, preferably 50-70% by weight, based on the total weight of the formulation, of a nonionic surfactant having the formula: in which m is 1, 2, 3 or 4 and, when m is 1, R is a C8-C18-alkyl residue or a C8-C18-alkylcarboxy residue; when m is 2, R is a C2-C4alkylene glycol residue from which the two hydroxy groups have been removed; when m is 3, R is the residue of trimethylolpropane from which the three hydroxy groups have been removed; and when m is 4, R is the residue of pentaerythritol residue from which the four hydroxy groups have been removed; R1 is hydrogen, methyl or ethyl; and n is a number ranging from 1 to 40.
    • 9. 发明专利
    • GRANULOS SOLUBLES EN AGUA DE COMPLEJOS DE MANGANESO DEL TIPO SALEN.
    • ES2280237T3
    • 2007-09-16
    • ES00954542
    • 2000-07-20
    • CIBA SC HOLDING AG
    • HAZENKAMP MENNOBACHMANN FRANKMAKOWKA CORNELIAKVITA PETRKURATLI ROLFSCHMIDLIN ANITA
    • C11D3/39D06L1/12C11D3/00C11D3/395C11D17/06
    • Gránulos solubles en agua de complejos de manganeso del tipo salen, los cuales comprenden a) de un 1 a un 89%, en peso, de una forma preferible, de un 1 a un 30%, en peso, de un complejo de manganeso del tipo salen de la fórmula (1), en donde, m, n y p son, cada una de ellas, de una forma independiente, 0, 1, 2 ó 3, R, R1 y R1'' son, cada uno de ellas, de una forma independiente con respecto a las otras, ciano; halógeno; OR4 ó COOR4, en donde, R4, es hidrógeno o un alquilo C1-C4, lineal o ramificado; nitro; alquilo C1-C8, lineal o ramificado; alquilo C1-C8, lineal o purificado, parcialmente fluorado o perfluorado; ó NHR6, NR5R6, ó N+R5R6R7, en donde, R5, R6 y R7, son iguales o diferentes, y son, cada una de ellas, hidrógeno o alquilo C1-C12, lineal o ramificado, o en donde, R5 y R6, conjuntamente con el átomo de nitrógeno al cual éstas se encuentran unidas, forman un anillo de 5, de 6 ó de 7 miembros, el cual puede contener heteroátomos adicionales, o son alquilo C1-C8-R8, en donde, R8,es un radical OR4, COOR4 ó NR5R6, tal y como se ha definido anteriormente, arriba, ó es NH2 ó N+R5R6R7, en donde, R5, R6 y R7, son tal y como se ha definido anteriormente, arriba, b) de un 10 a un 95%, en peso, de un agente dispersante aniónico, un agente dispersante no iónico o un polímero orgánico soluble en agua, como retardante de disolución, c) de un 0 a un 20%, en peso, de un aditivo adicional, y d) de un 1 a 15%, en peso, de agua, en base al peso total de los gránulos.