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    • 2. 发明申请
    • OXIME ESTER PHOTOINITIATORS
    • OXIME ESTER照相机
    • WO2008138732A1
    • 2008-11-20
    • PCT/EP2008/055126
    • 2008-04-28
    • CIBA HOLDING INC.MATSUMOTO, AkiraTANABE, JunichiKURA, HisatoshiOHWA, Masaki
    • MATSUMOTO, AkiraTANABE, JunichiKURA, HisatoshiOHWA, Masaki
    • C07D409/06C07D409/14
    • C07D409/06B33Y70/00C07D209/86C07D335/16C07D405/12C07D409/14C07D417/12
    • Compounds of the formula (I) and (II) M 1 , M 2 and M 3 independently of one another are no bond, a direct bond, CO, O, S, SO, SO 2 or NR 14 ; provided that at least one of M 1 , M 2 or M 3 is a direct bond, CO, O, S, SO, SO 2 or NR 14 ; M 4 is a direct bond, CR" 3 R" 4 , CS, O, S, SO, or SO 2 ; Y is S or NR 18 ; R 1 for example is hydrogen, C 3 -C 8 cycloalkyl, phenyl or naphthyl, both of which are optionally substituted; R 2 for example is C 1 -C 20 alkyl; R" 2 has one of the meanings given for R 2 ; R 3 and R 4 are for example hydrogen, halogen, C 1 -C 20 alkyl; R' 3 , R' 4 , R" 3 and R" 4 indepedently of one another have one of the meanings given for R 3 and R 4 ; and R 5 is for example hydrogen, halogen, C 1 -C 20 alkyl; provided that in the compounds of the formula (I) at least two oxime ester groups are present and provided that at least one specified substituent R 2 or R" 2 is present; exhibit an unexpectedly good performance in photopolymerization reactions.
    • 式(I)和(II)M 1,M 2和M 3 - 彼此独立的化合物不是键,直接 键,CO,O,S,SO,SO 2或NR 14; 条件是M 1,M 2或M 3 3中的至少一个是直接键,CO,O,S,SO,SO, SUB> 2或NR 14; M 4是直接键合,CR“3 R”4,CS,O,S,SO或SO 2, / SUB>; Y是S或NR 18; R 1例如是氢,C 3 -C 8环烷基,苯基或萘基,它们都是任选取代的; R 2例如是C 1 -C 20烷基; R“2具有对R 2 2给出的含义之一; R 3和R 4是例如氢 ,卤素,C 1 -C 20烷基; R'3,R'4,R“,SUB > 3个和R“4个彼此独立地具有对R 3和R 4给出的含义之一; R 5是例如氢,卤素,C 1 -C 20烷基;条件是在式(I)的化合物中至少有两个 存在肟酯基团,并且条件是存在至少一个特定的取代基R 2或R“2个<! - SIPO < 在光聚合反应中表现出出人意料的良好性能。
    • 5. 发明申请
    • OXIME ESTER PHOTOINITIATORS
    • OXIME ESTER照相机
    • WO2007071497A1
    • 2007-06-28
    • PCT/EP2006/068254
    • 2006-11-09
    • CIBA SPECIALTY CHEMICALS HOLDING INC.MATSUMOTO, AkiraTANABE, JunichiKURA, HisatoshiOHWA, Masaki
    • MATSUMOTO, AkiraTANABE, JunichiKURA, HisatoshiOHWA, Masaki
    • C08F2/50C07C251/66G03F7/031
    • G03F7/031B33Y70/00C07D209/86C07D409/06C08F2/50G03F7/0007G03F7/001
    • Compounds of the Formula (I) and (II) wherein M 1 , M 2 and M 3 independently of one another are no bond, a direct bond, CO, O, S, SO, SO 2 or NR 14 ; provided that at least one of M 1 , M 2 or M 3 is a direct bond, CO, O, S, SO, SO 2 or NR 14 ; M 4 is a direct bond, CR" 3 R" 4 , CS, O, S, SO, or SO 2 ; Y is S or NR 18 ; R 1 for example is hydrogen, C 3 -C 8 cycloalkyl, phenyl or naphthyl, both of which are optionally substituted; R 2 for example is C 1 -C 20 alkyl; R" 2 has one of the meanings given for R 2 ; R 3 and R 4 are for example hydrogen, halogen, C 1 -C 20 alkyl; R' 3 , R' 4 , R" 3 and R" 4 indepedently of one another have one of the meanings given for R 3 and R 4 ; and R 5 is for example hydrogen, halogen, C 1 -C 20 alkyl; provided that in the compounds of the Formula (I) at least two oxime ester groups are present; exhibit an unexpectedly good performance in photopolymerization reactions.
    • 式(I)和(II)的化合物(其中M 1,M 2和M 3)彼此独立地不具有键, 直接键合,CO,O,S,SO,SO 2或NR 14; 条件是M 1,M 2或M 3 3中的至少一个是直接键,CO,O,S,SO,SO, SUB> 2 或NR 14; M 4是直接键合,CR“3”R“4,CS,O,S,SO或SO 2, / SUB>; Y是S或NR 18; R 1例如是氢,C 3 -C 8环烷基,苯基或萘基,它们都是任选取代的; R 2是例如C 1 -C 20烷基; R“2具有对R 2 2给出的含义之一; R 3和R 4是例如氢 ,卤素,C 1 -C 20烷基; R'3,R'4,R“,SUB > 3个和R“4个独立地具有对R 3和R 4给出的含义之一; R 式(I)的化合物中至少有两个是氢,卤素,C 1 -C 20烷基, 存在肟酯基团;在光聚合反应中表现出意想不到的良好性能。
    • 8. 发明申请
    • OXIME ESTER PHOTOINITIATORS HAVING A COMBINED STRUCTURE
    • 具有组合结构的OXIME ESTER光敏元件
    • WO2002100903A1
    • 2002-12-19
    • PCT/EP2002/006107
    • 2002-06-04
    • CIBA SPECIALTY CHEMICALS HOLDING INC.KUNIMOTO, KazuhikoTANABE, JunichiKURA, HisatoshiOKA, HidetakaOHWA, Masaki
    • KUNIMOTO, KazuhikoTANABE, JunichiKURA, HisatoshiOKA, HidetakaOHWA, Masaki
    • C08F2/50
    • C08F2/50B33Y70/00C07C251/66G03F7/031
    • Compounds of the formulae I, II, and III wherein R 1 is for example hydrogen, C 3 -C 8 cycloalkyl, C 1 -C 12 alkyl, phenyl unsubstituted or substituted; R 2 and R 2 ' for example are hydrogen, C 1 -C 20 alkyl, C 3 -C 8 cycloalkyl or phenyl, unsubstituted or substituted, or are (I) (I) or (I); Ar 1 is for example phenyl, optionally substituted by e.g. (CO)R 7 , (I)(D), (I)(E) and/or(I)(F); Ar 2 is for example phenylene, optionally substituted e.g. by (CO)R 7 , (D), (E)or (F); Ar 3 is for example phenyl; M 1 ,M 2 and M 3 are, for example, C 1 -C 20 alkylene; M 4 is for example direct bond, -O-, -S-, -Y-(C 1 -C 10 alkylene)-Y'-, optionally substituted;Y and Y' are for example a direct bond or O; R 7 is for example hydrogen, C 1 -C 20 alkyl or phenyl, optionally substituted; R 8 , R 9 , R 8 'and R 9 ' are for example hydrogen or C 1 -C 12 alkyl, exhibit an unexpectedly good performance in photopolymerization reactions.
    • 式I,II和III的化合物,其中R 1是例如氢,C 3 -C 8环烷基,C 1 -C 12烷基,未取代或取代的苯基; R 2和R 2'例如是氢,C 1 -C 20烷基,C 3 -C 8环烷基或未取代或取代的苯基,或者是(I)(I)或(I); Ar 1是例如苯基,任选地被例如苯基取代。 (CO)R7,(I)(D),(I)(E)和/或(I)(F); Ar 2是例如亚苯基,任选被取代的例如亚苯基。 (CO)R7,(D),(E)或(F); Ar 3例如是苯基; M1,M2和M3是例如C1-C20亚烷基; M4例如直接键合,-O - , - S-,-Y-(C 1 -C 10亚烷基)-Y'-,任意取代; Y和Y'例如是直接键或O; R 7为例如氢,C 1 -C 20烷基或苯基,任选取代; R 8,R 9,R 8'和R 9'例如为氢或C 1 -C 12烷基,在光聚合反应中表现出出乎意料的良好性能。