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    • 4. 发明申请
    • INTEGRATED HEAVY OIL UPGRADING PROCESS AND IN-LINE HYDROFINISHING PROCESS
    • 一体化重油加工工艺和在线加氢工艺
    • WO2007078622A2
    • 2007-07-12
    • PCT/US2006047007
    • 2006-12-08
    • CHEVRON USA INCFARSHID DARUSHREYNOLDS BRUCE
    • FARSHID DARUSHREYNOLDS BRUCE
    • C10G45/00
    • C10G65/02C10G47/14C10G47/26C10G65/04C10G65/10C10G65/12C10G2300/1022C10G2300/107C10G2300/1074C10G2300/1077C10G2300/202C10G2300/302C10G2300/4018C10G2300/4081
    • A new residuum full hydroconversion slurry reactor system has been developed that allows the catalyst, unconverted oil and converted oil to circulate in a continuous mixture throughout an entire reactor with no confinement of the mixture. The mixture is partially separated in between the reactors to remove only the converted oil while permitting the unconverted oil and the slurry catalyst to continue on into the next sequential reactor where a portion of the unconverted oil is converted to lower boiling point hydrocarbons, once again creating a mixture of unconverted oil, converted oil, and slurry catalyst. Further hydroprocessing may occur in additional reactors, fully converting the oil. The oil may alternately be partially converted, leaving a highly concentrated catalyst in unconverted oil which can be recycled directly to the first reactor. Fully converted oil can be subsequently hydrofinished for the nearly complete removal of hetoroatoms such as sulfur and nitrogen.
    • 已经开发了一种新的残渣全加氢转化淤浆反应器系统,其允许催化剂,未转化的油和转化的油在连续混合物中在整个反应器中循环,而不限制混合物。 混合物在反应器之间部分分离以除去仅转化的油,同时允许未转化的油和浆料催化剂继续进入下一个顺序的反应器,其中一部分未转化的油转化为低沸点烃,再次产生 未转化油,转化油和浆料催化剂的混合物。 进一步的加氢处理可能发生在额外的反应器中,完全转化油。 油可以部分地转化,留下高度浓缩的催化剂在未转化的油中,其可以直接再循环到第一反应器。 完全转化的油可以随后加氢处理,几乎完全除去诸如硫和氮的氢原子。
    • 5. 发明申请
    • INTEGRATED PROCESS FOR THE PRODUCTION OF LUBRICATING BASE OILS AND LIQUID FUELS FROM FISCHER-TROPSCH MATERIALS USING SPLIT FEED HYDROPROCESSING
    • 使用分离进料加氢技术从固定式运输材料生产润滑基础油和液体燃料的综合方法
    • WO2005047424A2
    • 2005-05-26
    • PCT/US2004035611
    • 2004-10-26
    • CHEVRON USA INCFARSHID DARUSHMOORE RICHARDO O JR
    • FARSHID DARUSHMOORE RICHARDO O JR
    • C10G2/00C10G65/16C10G
    • C10G2/30C10G65/16C10G2300/1022C10G2400/02C10G2400/04C10G2400/10Y10S208/95
    • An integrated process for producing Fischer-Tropsch derived products boiling in the range of liquid fuel and lubricating base oil which comprises (a) recovering separately from a Fischer-Tropsch synthesis reactor a Fischer-Tropsch wax and a Fischer-Tropsch condensate; (b) hydroprocessing the Fischer-Tropsch wax in a wax hydroprocessing zone by contacting the Fischer-Tropsch wax with a hydroprocessing catalyst in the presence of hydrogen under hydroprocessing conditions and recovering from the wax hydroprocessing zone a waxy intermediate and a hydrogen-rich normally liquid fraction; (c) mixing the Fischer-Tropsch condensate from step (a) and at least part of the hydrogen-rich normally liquid fraction from step (b) to form a Fischer-Tropsch condensate mixture; (d) hydrotreating the Fischer-Tropsch condensate mixture in a condensate hydrotreating zone by contacting the Fischer-Tropsch condensate mixture with a hydrotreating catalyst in the presence of hydrogen under hydrotreating conditions and recovering from the condensate hydrotreating zone a Fischer-Tropsch condensate product; (e) recovering from the Fischer-Tropsch condensate product a Fischer-Tropsch derived hydrocarbon boiling within the range of liquid fuel; (f) dewaxing the waxy intermediate from step (b) in a catalytic dewaxing zone by contacting the waxy intermediate with a dewaxing catalyst in the presence hydrogen under dewaxing conditions and recovering a base oil from the dewaxing zone; (g) hydrofinishing the base oil from step (f) in a hydrofinishing zone by contacting the base oil with a hydrofinishing catalyst in the presence of hydrogen under hydrofinishing conditions; (h) recovering from the hydrofinishing zone a UV stabilized lubricating base oil and a hydrogen-rich gas; and (i) recycling the hydrogen-rich gas from step (h) to the wax hydroprocessing zone of step (b) and wherein the total pressure in the hydrofinishing zone is at least as high as the total pressure in the wax hydroprocessing zone.
    • 一种用于生产在液体燃料和润滑基础油范围内沸腾的费 - 托衍生产物的综合方法,其包括(a)从费 - 托合成反应器中单独回收费 - 托蜡和费 - 托冷凝物; (b)通过在加氢处理条件下在氢存在下使费 - 托蜡与加氢处理催化剂接触,在蜡加氢处理区中加氢处理费 - 托蜡,并从蜡加氢处理区回收蜡状中间体和富氢正常液体 分数; (c)将来自步骤(a)的费 - 托冷凝物和来自步骤(b)的至少部分富氢正常液体馏分混合以形成费 - 托冷凝物混合物; (d)通过在加氢处理条件下在氢气存在下使费 - 托冷凝物混合物与加氢处理催化剂接触并在冷凝水加氢处理区中从费 - 托冷凝物产物中回收,在冷凝物加氢处理区中加氢处理费 - 托冷凝物混合物; (e)从费 - 托冷凝物中回收在液体燃料范围内沸腾的费 - 托衍生烃; (f)通过在脱蜡条件下在氢存在下使蜡状中间体与脱蜡催化剂接触并从脱蜡区回收基础油,在催化脱蜡区中脱蜡步骤(b)中的蜡状中间体; (g)在加氢精制区通过在加氢处理条件下在氢的存在下使基础油与加氢精制催化剂接触来加氢精制步骤(f)的基础油; (h)从加氢精制区回收UV稳定的润滑油基础油和富氢气体; 和(i)将来自步骤(h)的富氢气体再循环到步骤(b)的蜡加氢处理区,并且其中加氢精制区域中的总压力至少与蜡加氢处理区域中的总压力一样高。
    • 6. 发明专利
    • BRPI0619931A2
    • 2011-10-25
    • BRPI0619931
    • 2006-12-08
    • CHEVRON USA INC
    • FARSHID DARUSHREYNOLDS BRUCE E
    • C10G45/00
    • A new residuum full hydroconversion slurry reactor system has been developed that allows the catalyst, unconverted oil and converted oil to circulate in a continuous mixture throughout an entire reactor with no confinement of the mixture. The mixture is partially separated in between the reactors to remove only the converted oil while permitting the unconverted oil and the slurry catalyst to continue on into the next sequential reactor where a portion of the unconverted oil is converted to lower boiling point hydrocarbons, once again creating a mixture of unconverted oil, converted oil, and slurry catalyst. Further hydroprocessing may occur in additional reactors, fully converting the oil. The oil may alternately be partially converted, leaving a highly concentrated catalyst in unconverted oil which can be recycled directly to the first reactor. Fully converted oil is subsequently hydrofinished for the nearly complete removal of hetoroatoms such as sulfur and nitrogen.
    • 7. 发明专利
    • СПОСОБ ГИДРОПЕРЕРАБОТКИ СЫРОЙ НЕФТИ
    • EA013065B1
    • 2010-02-26
    • EA200870067
    • 2006-12-08
    • CHEVRON USA INC
    • FARSHID DARUSHMURPHY JAMESREYNOLDS BRUCE
    • C10G45/00
    • Предложенановаямазутнаяполностьюреакторнаясистемагидропереработкишлама, котораяпозволяеткатализатору, непреобразованнойнефтии преобразованнойнефтициркулироватьв непрерывнойсмесиповсемуреакторубеззастаиваниясмеси. Смесьразделяютвнутри, впределаходногоизреакторов, дляотделениятолькопреобразованнойнефтии водородав парообразныйпродукт, втожежевремяпозволяянепреобразованнойнефтии катализаторнойпульпепродолжатьпередвигатьсяв следующийпоследовательныйреакторв видежидкогопродукта. Частьнепреобразованнойнефтизатемпреобразуетсяв болеенизкокипящиеуглеводородыв следующемреакторе, вочереднойразсоздаваясмесьнепреобразованнойнефти, водорода, преобразованнойнефтии катализаторнойпульпы. Дополнительнаягидрообработкаможетпроисходитьв дополнительныхреакторах, полностьюпреобразовываянефть. Нефтьможетбытьпоочередночастичнопреобразована, оставляявысококонцентрированныйкатализаторв непреобразованнойнефти, котораяможетбытьповторнонаправленанапрямуюв первыйреактор.
    • 10. 发明专利
    • BRPI0416189A
    • 2007-01-23
    • BRPI0416189
    • 2004-10-26
    • CHEVRON USA INC
    • FARSHID DARUSHMOORE RICHARD O JR
    • C10G2/00C10G65/16C10G65/14C10G65/00
    • An integrated process for producing liquid fuel and lubricating base oil from Fischer-Tropsch derived products which comprises (a) recovering separately from a Fischer-Tropsch synthesis reactor a Fischer-Tropsch wax and condensate; (b) hydroprocessing the wax and recovering a waxy intermediate and a hydrogen-rich normally, liquid fraction; (c) mixing the condensate and at least part of the hydrogen-rich normally liquid fraction to form a Fischer-Tropsch condensate mixture; (d) hydrotreating the condensate mixture and recovering a Fischer-Tropsch condensate product; (e) recovering from the condensate product a liquid fuel; (f) separately dewaxing the waxy intermediate and recovering a base oil; (g) hydrofinishing the base oil; (h) recovering from the hydrofinishing zone a stabilized base oil and a hydrogen-rich gas; and (i) recycling the hydrogen-rich gas to the wax hydroprocessing zone wherein the total pressure in the hydrofinishing zone is at least as high as the total pressure in the wax hydroprocessing zone.