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    • 8. 发明申请
    • SEPARATION OF DIENES FROM OLEFINS USING IONIC LIQUIDS
    • 使用离子液体从烯烃中分离二氧化碳
    • WO2003059483A2
    • 2003-07-24
    • PCT/US2002/041739
    • 2002-12-31
    • CHEVRON U.S.A. INC.BOUDREAU, Laura, C.DRIVER, Michael, S.MUNSON, Curt, L.
    • BOUDREAU, Laura, C.DRIVER, Michael, S.MUNSON, Curt, L.
    • B01D
    • C10G29/06B01J2219/00308B01J2219/00313B01J2219/00756B01J2219/00759C07C7/152C07C7/156C40B60/14C07C11/00
    • Methods for separating di-olefins from mono-olefins, and olefins from non-olefins such as paraffins, oxygenates and aromatics, are provided. The methods use metal salts which complex both mono-olefins and di-olefins, but which selectively complex di-olefins in the presence of mono-olefins. The metal salts are dissolved or suspended in ionic liquids, which tend to have virtually no vapor pressure. Preferred salts are Group IB salts, more preferably silver and copper salts. A preferred silver salt is silver tetrafluoroborate. A preferred copper salt is silver CuOTf. Preferred ionic liquids are those which form stable solutions, suspensions or dispersions of the metal salts, which do not dissolve unwanted non-olefins, and which do not isomerize the mono- or di-olefins. The equivalents of the metal salt can be adjusted so that di-olefins are selectively adsorbed from mixtures of mono-and di-olefins. Alternatively, both mono- and di-olefins can be adsorbed, and the mono-olefins selectively desorbed. The latter approach can be preferred when non-olefins are also to be separated. The mono- and di-olefin-containing mixture can be in the gas phase or in the liquid phase. The flow of mono- and di-olefin-containing mixture over/through the ionic liquid can be, for example, co-current, counter-current, or staged in stirred tanks, with countercurrent being preferred.
    • 提供了从单烯烃分离二烯烃的方法,以及来自非烯烃如链烷烃,含氧化合物和芳烃的烯烃。 该方法使用复合单烯烃和二烯烃的金属盐,但是在单烯烃存在下选择性复合的二烯烃。 金属盐溶解或悬浮在离子液体中,其倾向于几乎不具有蒸气压。 优选的盐是IB族盐,更优选银和铜盐。 优选的银盐是四氟硼酸银。 优选的铜盐是银CuOTf。 优选的离子液体是形成不溶解不需要的非烯烃并且不使单烯烃或二烯烃异构化的金属盐的稳定溶液,悬浮液或分散体的离子液体。 可以调节金属盐的当量,使得二烯烃从单烯烃和二烯烃的混合物中选择性吸附。 或者,可以吸附单烯烃和二烯烃,并且单烯烃选择性解吸。 当非烯烃也被分离时,后一种方法可以是优选的。 含单烯烃和二烯烃的混合物可以处于气相或液相中。 通过离子液体流过单 - 和二烯烃混合物的流动可以是例如在搅拌釜中的并流,逆流或分级,优选逆流。
    • 9. 发明申请
    • HYDRODTREATING OF FISCHER-TROPSCH DERIVED FEEDS PRIOR TO OLIGOMERIZATION USING AN IONIC LIQUID CATALYST
    • 使用离子液体催化剂进行过渡化过程中FISCHER-TROPSCH衍生的进料的加氢
    • WO2005005353A1
    • 2005-01-20
    • PCT/US2004/017991
    • 2004-06-03
    • CHEVROU U.S.A. INC.JOHNSON, David, R.HARRIS, Thomas, V.DRIVER, Michael, S.
    • JOHNSON, David, R.HARRIS, Thomas, V.DRIVER, Michael, S.
    • C07C2/04
    • C10G45/02C10G2/32C10G9/00C10G45/58C10G50/02C10G57/02C10G69/06C10G69/12
    • A process for oligomerizing a Fischer-Tropsch derived feed containing oxygenates which comprises (a) reducing significantly the oxygenates present in the Fischer-Tropsch derived feed by contacting said feed with a hydrotreating catalyst under hydrotreating conditions in a hydrotreating zone (8) and recovering from the hydrotreating zone a Fischer-Tropsch derived hydrotreated feed (10) which contains a significantly reduced amount of oxygenates as compared to the Fischer-Tropsch derived feed and also a significant amount of paraffins; (b) pyrolyzing the Fischer-Tropsch derived hydrotreated feed in a thermal cracking zone (12) under thermal cracking conditions pre-selected to crack the paraffin molecules to form olefins and collecting an olefin-enriched Fischer-Tropsch feed (14) from the thermal cracking zone (14); (c) contacting the olefin-enriched Fischer-Tropsch feed with a Lewis acid ionic liquid catalyst in an oligomerization zone (16) under oligomerization reaction conditions; and (d) recovering from the oligomerization zone a Fischer-Tropsch derived product (18) having molecules characterized by a higher average molecular weight and increased branching as compared to the Fischer-Tropsch derived feed.
    • 一种使包含含氧化合物的费 - 托衍生的原料低聚的方法,其包括(a)通过在加氢处理区(8)中在加氢处理条件下使所述进料与加氢处理催化剂接触,显着地还原费 - 托衍生的进料中存在的含氧化合物,并从 加氢处理区是费 - 托衍生的加氢处理进料(10),其与费 - 托衍生的进料相比含有显着减少量的含氧化合物,并且还含有大量的链烷烃; (b)在预选择的热裂解条件下在热裂解区(12)中热解费 - 托衍生的加氢处理的进料,以裂解链烷烃分子以形成烯烃,并从热量收集富烯烃的费 - 托进料(14) 开裂区(14); (c)在低聚反应条件下使低聚区(16)中富含烯烃的费 - 托进料与路易斯酸离子液体催化剂接触; 和(d)与费 - 托衍生的产物(18)相比,从齐聚区回收具有较高平均分子量和增加支化的分子的费 - 托衍生产物(18)。