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    • 8. 发明申请
    • MEMBRANE REACTOR WITH IN-SITU DEHYDRATION AND METHOD FOR USING THE SAME
    • 具有现场脱水的膜反应器及其使用方法
    • WO2009088785A1
    • 2009-07-16
    • PCT/US2008/088247
    • 2008-12-23
    • CHEVRON U.S.A. INC.FAYYAZ-NAJAFI, BabakKIBBY, Charles L.SONG, Steven X.CHINN, Daniel
    • FAYYAZ-NAJAFI, BabakKIBBY, Charles L.SONG, Steven X.CHINN, Daniel
    • B01J8/00B01J19/24C07C1/04
    • B01J8/009B01J8/0214B01J8/067B01J2208/00123B01J2208/00212B01J2208/0053C10G31/11
    • A fixed bed membrane reactor is disclosed. The reactor has a housing including an inlet for receiving reactants and an outlet for discharging retentate streams of reaction products. The inlet and outlet are in fluid communication with a reaction zone in which the reactants may pass downstream from the inlet to the outlet with the reactants reacting to produce reaction products including water. The reactor further includes a membrane assembly disposed in fluid communication with the reaction zone. The membrane assembly includes at least one porous support with a water permselective membrane affixed thereto. The membrane allows water produced in the reaction zone to be selectively removed from the reaction zone as a permeate stream while allowing retentate reaction products to remain in the reaction zone and be discharged as a retentate stream. Ideally, the membrane assembly locates most of the membrane proximate the downstream portion of the reaction zone where accumulated produced water may be selectively removed from the reaction product as opposed to the upstream portion where relatively little water accumulation has occurred. A method for using the reactor to perform in situ water dehydration of reactions, such as Fischer-Tropsch reaction, is also disclosed.
    • 公开了一种固定床膜反应器。 反应器具有壳体,其包括用于接收反应物的入口和用于排出反应产物的滞留物流的出口。 入口和出口与反应区流体连通,其中反应物可以从入口到出口下游,反应物反应以产生包括水的反应产物。 反应器还包括与反应区流体连通地设置的膜组件。 膜组件包括至少一个具有附着于其上的水渗透选择膜的多孔支撑体。 膜允许在反应区中产生的水作为渗透物流从反应区选择性地除去,同时允许滞留的反应产物保留在反应区中并作为滞留物流排出。 理想地,膜组件将大多数膜定位在反应区的下游部分附近,其中累积的产生的水可以从反应产物中选择性地除去,而不是发生相对少的积水的上游部分。 还公开了使用反应器进行原位水脱水反应的方法,例如费 - 托反应。