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    • 4. 发明申请
    • ALKALI METAL ION BATTERY USING ALKALI METAL CONDUCTIVE CERAMIC SEPARATOR
    • 使用碱性金属导电陶瓷分离器的ALKALI金属离子电池
    • WO2012154750A3
    • 2013-02-28
    • PCT/US2012036959
    • 2012-05-08
    • CERAMATEC INCGORDON JOHNBHAVARAJU SAI
    • GORDON JOHNBHAVARAJU SAI
    • H01M10/24H01M2/16H01M4/24
    • H01M2/16H01M2/1646H01M4/38H01M4/381H01M4/463H01M4/466H01M10/05H01M10/36H01M2300/0045
    • A battery (100) having a first electrode (104) and a second electrode (108). The first electrode (104) is made of metal and the second electrode (108) is made of an oxidized material that is capable of being electrochemically reduced by the metal of the first electrode (104). An alkali-ion conductive, substantially non-porous separator (120) is disposed between the first (104) and second electrode (108). A first electrolyte (134) contacts the first electrode (104). The first electrolyte (134) includes a solvent (154) which is non-reactive with the metal, and a salt bearing an alkali ion that may be conducted through the separator (120), wherein the salt is at least partially soluble in the solvent (120). A second electrolyte (138) is also used. The second electrolyte (138) contacts the second electrode (108). The second electrolyte (138) at least partially dissolves the salt that forms upon the oxidized material being electrochemically reduced.
    • 一种具有第一电极(104)和第二电极(108)的电池(100)。 第一电极(104)由金属制成,第二电极(108)由能够被第一电极(104)的金属电化学还原的氧化材料制成。 在第一(104)和第二电极(108)之间设置有碱离子导电的基本上无孔隔离物(120)。 第一电解质(134)接触第一电极(104)。 第一电解质(134)包括与金属不反应的溶剂(154)和可以通过隔膜(120)传导的具有碱离子的盐,其中盐至少部分地可溶于溶剂 (120)。 还使用第二电解质(138)。 第二电解质(138)接触第二电极(108)。 第二电解质(138)至少部分地溶解在氧化物质上形成的盐被电化学还原。
    • 10. 发明申请
    • METHOD AND DEVICE FOR CARBOXYLIC ACID PRODUCTION
    • 羧酸生产的方法和装置
    • WO2012018418A3
    • 2012-03-29
    • PCT/US2011035782
    • 2011-05-09
    • CERAMATEC INCBHAVARAJU SAIDUFFEY KEAN
    • BHAVARAJU SAIDUFFEY KEAN
    • C25B3/02C07C51/42C07C59/08C12P7/40
    • C25B1/02B01D61/422C25B3/00
    • A method for producing and recovering a carboxylic acid in an electrolysis cell (104). The electrolysis cell (104) is a multi-compartment electrolysis cell (104). The multi-compartment electrolysis cell (104) includes an anodic compartment (206), a cathodic compartment (204), and a solid alkali ion transporting membrane (220) (such as a NaSICON membrane). An anolyte (230) is added to the anodic compartment (206). The anolyte (230) comprises an alkali salt of a carboxylic acid (112), a first solvent (234), and a second solvent (232). The alkali salt of the carboxylic acid (112) is partitioned into the first solvent (234). The anolyte (230) is then electrolyzed to produce a carboxylic acid (112), wherein the produced carboxylic acid (112) is partitioned into the second solvent (232). The second solvent (232) may then be separated from the first solvent (234) and the produced carboxylic acid (112) may be recovered from the second solvent (232). The first solvent (234) may be water and the second solvent (232) may be an organic solvent.
    • 一种在电解槽(104)中生产和回收羧酸的方法。 电解槽(104)是多室电解槽(104)。 多室电解槽(104)包括阳极室(206),阴极室(204)和固体碱离子迁移膜(220)(例如NaSICON膜)。 将阳极电解液(230)加入到阳极室(206)中。 阳极电解液(230)包含羧酸(112),第一溶剂(234)和第二溶剂(232)的碱金属盐。 将羧酸(112)的碱金属盐分隔成第一溶剂(234)。 然后电解阳极电解液(230)以产生羧酸(112),其中所产生的羧酸(112)被分配到第二溶剂(232)中。 然后可以将第二溶剂(232)与第一溶剂(234)分离,并且可以从第二溶剂(232)回收所产生的羧酸(112)。 第一溶剂(234)可以是水,第二溶剂(232)可以是有机溶剂。