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    • 6. 发明申请
    • METHOD AND DEVICE FOR CARBOXYLIC ACID PRODUCTION
    • 羧酸生产方法和装置
    • WO2012018418A2
    • 2012-02-09
    • PCT/US2011/035782
    • 2011-05-09
    • CERAMATEC, INC.BHAVARAJU, SaiDUFFEY, Kean
    • BHAVARAJU, SaiDUFFEY, Kean
    • C25B3/02C07C51/42C07C59/08C12P7/40
    • C25B1/02B01D61/422C25B3/00
    • A method for producing and recovering a carboxylic acid in an electrolysis cell (104). The electrolysis cell (104) is a multi-compartment electrolysis cell (104). The multi-compartment electrolysis cell (104) includes an anodic compartment (206), a cathodic compartment (204), and a solid alkali ion transporting membrane (220) (such as a NaSICON membrane). An anolyte (230) is added to the anodic compartment (206). The anolyte (230) comprises an alkali salt of a carboxylic acid (112), a first solvent (234), and a second solvent (232). The alkali salt of the carboxylic acid (112) is partitioned into the first solvent (234). The anolyte (230) is then electrolyzed to produce a carboxylic acid (112), wherein the produced carboxylic acid (112) is partitioned into the second solvent (232). The second solvent (232) may then be separated from the first solvent (234) and the produced carboxylic acid (112) may be recovered from the second solvent (232). The first solvent (234) may be water and the second solvent (232) may be an organic solvent.
    • 在电解槽(104)中生产和回收羧酸的方法。 电解池(104)是多室电解池(104)。 多室电解池(104)包括阳极室(206),阴极室(204)和固体碱离子迁移膜(220)(例如NaSICON膜)。 阳极电解液(230)被添加到阳极室(206)。 阳极电解液(230)包含羧酸(112)的碱金属盐,第一溶剂(234)和第二溶剂(232)。 羧酸(112)的碱金属盐被分配到第一溶剂(234)中。 然后电解阳极电解液(230)以产生羧酸(112),其中产生的羧酸(112)分配到第二溶剂(232)中。 然后可以将第二溶剂(232)与第一溶剂(234)分离,并且可以从第二溶剂(232)中回收所产生的羧酸(112)。 第一溶剂(234)可以是水,第二溶剂(232)可以是有机溶剂。
    • 9. 发明申请
    • SENSOR TO MEASURE A CONCENTRATION OF ALKALI ALCOHOLATE
    • 传感器测量碱性酒精的浓度
    • WO2011022162A2
    • 2011-02-24
    • PCT/US2010/042940
    • 2010-07-22
    • CERAMATEC, INC.BHAVARAJU, SaiPENDLETON, JustinBALAGOPAL, ShekarWALL, Peter
    • BHAVARAJU, SaiPENDLETON, JustinBALAGOPAL, ShekarWALL, Peter
    • G01N27/31G01N27/49
    • G01N27/49
    • A sodium sensor to measure a concentration of sodium methylate in methanol. The sensor assembly includes a solid alkali ion conducting membrane (102), a reference electrode (110), and a measurement electrode (108). The solid alkali ion conducting membrane (102) transports ions between two alkali-containing solutions, including an aqueous solution (106) and a non-aqueous solution (104). The reference electrode (110) is at least partially within an alkali halide solution of a known alkali concentration on a first side of the solid alkali ion conducting membrane (102). The measurement electrode (108) is on a second side of the solid alkali ion conducting membrane (102). The measurement electrode (108) exhibits a measurable electrical characteristic corresponding to a measured alkali concentration within the non-aqueous solution (104), to which the measurement electrode (108) is exposed
    • 用于测量甲醇钠甲醇浓度的钠传感器。 传感器组件包括固体碱离子传导膜(102),参比电极(110)和测量电极(108)。 固体碱离子传导膜(102)在包含水溶液(106)和非水溶液(104)的两种含碱溶液之间输送离子。 参考电极(110)至少部分地位于固体碱离子传导膜(102)的第一侧上已知碱浓度的碱金属卤化物溶液中。 测量电极(108)位于固体碱离子传导膜(102)的第二侧上。 测量电极(108)显示对应于测量电极(108)暴露于非水溶液(104)内的测量的碱浓度的可测量电特性