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1. 发明申请

WO2009055037A1 THERMOCHEMICAL SYNTHESIS OF FUELS FOR STORING THERMAL ENERGY 审中-公开
标题翻译：用于储存热能的燃料的热化学合成
公开(公告)号：WO2009055037A1
公开(公告)日：2009-04-30
申请号：PCT/US2008/012125
申请日：2008-10-24
申请人： CALIFORNIA INSTITUTE OF TECHNOLOGY , HAILE, Sossina , CHUEH, William C.
发明人： HAILE, Sossina , CHUEH, William C.
IPC分类号： H01M8/10
CPC分类号： C01B13/0203 , C01B3/02 , Y02P20/134
摘要： The present invention provides a method for storing thermal energy, such as solar energy, as a fuel, by heating a reactive oxide substrate to a first temperature, such that the reactive oxide substrate is reduced, wherein the reactive oxide substrate includes a cerium oxide. The method also includes contacting the reduced reactive oxide substrate at a second temperature with a gas mixture including carbon dioxide, wherein the first temperature is greater than the second temperature, thereby preparing the fuel. The present invention also provides a method for preparing the reactive oxide substrates by heating a mixture including a doped cerium oxide and a pore-forming agent, such that pores are formed in the doped cerium oxide, thereby forming the reactive oxide substrate.
摘要翻译：本发明提供了一种通过将反应性氧化物衬底加热至第一温度来储存诸如太阳能之类的热能作为燃料的方法，使得反应性氧化物衬底减少，其中反应性氧化物衬底包括氧化铈。该方法还包括使第二温度下的还原反应性氧化物衬底与包括二氧化碳的气体混合物接触，其中第一温度大于第二温度，由此制备燃料。本发明还提供一种通过加热包含掺杂的氧化铈和成孔剂的混合物来制备活性氧化物衬底的方法，使得在掺杂的氧化铈中形成孔，从而形成反应性氧化物衬底。

2. 发明申请

WO2012178159A1 ISOTHERMAL SYNTHESIS OF FUELS WITH REACTIVE OXIDES 审中-公开
标题翻译：燃料与反应性氧化物的同位素合成
公开(公告)号：WO2012178159A1
公开(公告)日：2012-12-27
申请号：PCT/US2012/043991
申请日：2012-06-25
申请人： CALIFORNIA INSTITUTE OF TECHNOLOGY , HAO, Yong , CHUEH, William , HAILE, Sossina
发明人： HAO, Yong , CHUEH, William , HAILE, Sossina
IPC分类号： B01J23/00 , B01J23/10
CPC分类号： C01B3/063 , B01J23/002 , B01J23/464 , B01J23/63 , B01J35/002 , B01J35/1009 , B01J35/1014 , B01J37/0009 , B01J37/04 , B01J37/08 , C01B3/042 , C01B13/0207 , C01D1/02 , C01D17/003 , C01G25/02 , Y02E60/364
摘要： A method for converting thermal energy to chemical energy by reducing a reactive oxide substrate at a constant temperature under a first atmosphere with a lower oxygen partial pressure, and then contacting the reduced oxide at the same temperature with a second atmosphere with a higher oxygen partial pressure, during which oxygen is driven into the reduced oxide by the oxygen chemical potential difference between the two atmospheres, thereby leaving fuel behind, i.e. producing fuel. A method for preparing the reactive oxide substrate by using liquid media as a binder and pore former and heating the mixture of the reactive oxide and the liquid media, thereby forming the reactive oxide substrate.
摘要翻译：一种通过在低氧分压的第一气氛下在恒定温度下还原反应性氧化物衬底然后在相同温度下与还原氧化物与较高氧分压的第二气氛接触来将热能转化为化学能的方法在此期间，通过两个气氛之间的氧化学势差将氧气驱动到还原氧化物中，从而留下燃料，即产生燃料。通过使用液体介质作为粘合剂和成孔剂来制备活性氧化物基材的方法，并加热反应性氧化物和液体介质的混合物，由此形成反应性氧化物基材。

3. 发明公开

EP2723491A1 ISOTHERMAL SYNTHESIS OF FUELS WITH REACTIVE OXIDES 审中-公开
标题翻译：与活性氧化物燃料等温合成
公开(公告)号：EP2723491A1
公开(公告)日：2014-04-30
申请号：EP12803288.5
申请日：2012-06-25
申请人： California Institute of Technology
发明人： HAO, Yong , CHUEH, William , HAILE, Sossina
IPC分类号： B01J23/00 , B01J23/10
CPC分类号： C01B3/063 , B01J23/002 , B01J23/464 , B01J23/63 , B01J35/002 , B01J35/1009 , B01J35/1014 , B01J37/0009 , B01J37/04 , B01J37/08 , C01B3/042 , C01B13/0207 , C01D1/02 , C01D17/003 , C01G25/02 , Y02E60/364
摘要： A method for converting thermal energy to chemical energy by reducing a reactive oxide substrate at a constant temperature under a first atmosphere with a lower oxygen partial pressure, and then contacting the reduced oxide at the same temperature with a second atmosphere with a higher oxygen partial pressure, during which oxygen is driven into the reduced oxide by the oxygen chemical potential difference between the two atmospheres, thereby leaving fuel behind, i.e. producing fuel. A method for preparing the reactive oxide substrate by using liquid media as a binder and pore former and heating the mixture of the reactive oxide and the liquid media, thereby forming the reactive oxide substrate.

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