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    • 1. 发明授权
    • Process for separating 1-dodecene and 1-tetradecene from an aluminum
alkyl chain growth product
    • 从烷基链烷基铝生长产物中分离1-十二碳烯和1-十四碳烯的方法
    • US4929788A
    • 1990-05-29
    • US345699
    • 1989-05-01
    • C. S. Warren HuangKarl W. Meyer
    • C. S. Warren HuangKarl W. Meyer
    • C07C2/88C07C7/04C07C11/02
    • C07C11/02C07C2/88C07C7/04
    • Dodecene-1 and 1-tetradecene can be rectified from a mixture containing 1-dodecene and 1-tetradecene and triethylaluminum ("TEA") which has about the same normal boiling point as 1-dodecene and 1-tetradecene by feeding the above mixture to an intermediate point of a rectification column maintained under sufficient vacuum (e.g. 5-30 torr) such that the temperature at the intermediate feed point is about 250.degree.-260.degree. F. and the overhead distillation temperature is about 190.degree.-240.degree. F. The TEA which normally boils at about the same temperature as 1-dodecene and 1-tetradecene will exist as a dimer permitting part of the 1-dodecene and 1-tetradecene to distill overhead and most of the TEA to exit the bottom of the column.
    • 十二碳烯-1和1-十四碳烯可以从含有1-十二碳烯和1-十四碳烯和三乙基铝(“TEA”)的混合物中进行精馏,其通过将上述混合物加入到具有与1-十二碳烯和1-十四碳烯相同的标准沸点 精馏塔的中间点保持在足够的真空(例如5-30托),使得中间进料点的温度为约250°-260°F,塔顶馏出温度为约190°-240°F。 通常以与1-十二碳烯和1-十四碳烯相同的温度沸腾的TEA将作为二聚体存在,允许1-十二碳烯和1-十四碳烯的一部分蒸馏塔顶馏出物并且大部分TEA离开塔底。