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    • 2. 发明授权
    • Liquefied natural gas processing
    • 液化天然气加工
    • US5114451A
    • 1992-05-19
    • US492548
    • 1990-03-12
    • C. L. RamboJohn D. WilkinsonHank M. Hudson
    • C. L. RamboJohn D. WilkinsonHank M. Hudson
    • C10G5/04F25J3/02
    • C10G5/04F25J3/0214F25J3/0233F25J3/0238C10G2300/1025F25J2200/02F25J2230/08F25J2230/60F25J2290/12
    • A process for the recovery of ethane, ethylene, propane, propylene and heavier hydrocarbons from a liquefied natural gas (LNG) stream is disclosed. At least a portion of the LNG feed stream is directed in heat exchange relation with a compressed recycle portion of the fractionation tower overhead, with the warmed LNG stream thereafter supplied to the fractionation tower at a mid-column feed position. The recycle stream is cooled by the LNG stream sufficiently to substantially condense it, and the substantially condensed recycle stream is then supplied to the column at a top column feed position to serve as reflux for the tower. The pressure of the recycle stream and the quantities and temperatures of the feeds to the column are effective to maintain the column overhead temperature at a temperature whereby the major portion of said desired components is recovered in the bottom liquid product from the column.
    • 公开了从液化天然气(LNG)流中回收乙烷,乙烯,丙烷,丙烯和较重烃的方法。 LNG进料流的至少一部分与分馏塔顶部的压缩再循环部分以热交换关系的方式引导,随后将加热的LNG流在中间塔进料位置供给至分馏塔。 再循环物流被LNG流充分冷却以使其基本冷凝,然后将基本上冷凝的再循环物流在顶塔进料位置供应至柱,以作塔的回流。 再循环料流的压力以及进料塔的进料量和温度对塔顶温度的维持是有效的,在此温度下,所需组分的主要部分从塔中回收到底部液体产物中。
    • 5. 发明授权
    • Hydrocarbon gas processing
    • 烃类气体加工
    • US5555748A
    • 1996-09-17
    • US477444
    • 1995-06-07
    • Roy E. CampbellJohn D. WilkinsonHank M. HudsonMichael C. Pierce
    • Roy E. CampbellJohn D. WilkinsonHank M. HudsonMichael C. Pierce
    • F25J3/02
    • F25J3/0238F25J3/0209F25J3/0219F25J3/0233F25J3/0242F25J2200/02F25J2200/70F25J2205/04F25J2210/06F25J2210/12F25J2235/60F25J2240/02F25J2270/90
    • A process for the recovery of ethane, ethylene, propane, propylene and heavier hydrocarbon components from a hydrocarbon gas stream is disclosed. The stream is cooled to partially condense it, then separated to provide a first vapor stream and a first condensed stream. The first vapor stream is divided into first and second streams, then the first stream is combined with the first condensed stream. The combined stream is cooled and expanded to an intermediate pressure to partially condense it, then separated to provide a second vapor stream and a second condensed stream. The second vapor stream is cooled at the intermediate pressure to condense substantially all of it and is thereafter expanded to the fractionation tower pressure and supplied to the fractionation tower at a top feed position. The second condensed stream is subcooled at the intermediate pressure, expanded to the tower pressure, and is supplied to the column at a first mid-column feed position. The second stream is expanded to the tower pressure and is then supplied to the column at a second mid-column feed position. The quantities and temperatures of the feeds to the column are effective to maintain the column overhead temperature at a temperature whereby the major portion of the desired components is recovered. In an alternative embodiment, the combined stream is cooled at essentially inlet pressure to partially condense it, then separated at pressure to provide the second vapor stream and the second condensed stream.
    • 公开了从烃气流中回收乙烷,乙烯,丙烷,丙烯和较重烃组分的方法。 将物流冷却以部分地冷凝,然后分离以提供第一蒸气流和第一冷凝流。 将第一蒸汽流分成第一和第二流,然后将第一流与第一冷凝流组合。 将合并的流冷却并膨胀至中间压力以部分地冷凝,然后分离以提供第二蒸气流和第二冷凝流。 第二蒸气流在中间压力下冷却,以基本上将其全部冷凝,然后膨胀至分馏塔压力,并在顶部进料位置供应至分馏塔。 将第二冷凝物流在中间压力下过冷,膨胀至塔压力,并以第一中柱进料位置供应到塔中。 将第二流扩张到塔压力,然后在第二中柱进料位置处供给塔。 进料到塔的数量和温度对塔顶温度的维持是有效的,从而回收主要部分的所需组分。 在替代实施例中,组合的流在基本入口压力下冷却以部分地冷凝,然后在压力下分离以提供第二蒸气流和第二冷凝流。
    • 6. 发明授权
    • Hydrocarbon gas processing
    • 烃类气体加工
    • US06915662B2
    • 2005-07-12
    • US10003453
    • 2001-10-26
    • John D. WilkinsonHank M. HudsonMichael C. Pierce
    • John D. WilkinsonHank M. HudsonMichael C. Pierce
    • C07C7/00C10G5/06C10G70/04F25J3/02
    • C10G70/04C07C7/005C10G5/06F25J3/0209F25J3/0219F25J3/0233F25J3/0238F25J2200/02F25J2200/70F25J2200/74F25J2200/90F25J2205/04F25J2210/12F25J2220/66F25J2235/60F25J2240/02F25J2245/02F25J2270/02F25J2290/40Y02C10/12
    • A process for the recovery of ethane, ethylene, propane, propylene and heavier hydrocarbon components from a hydrocarbon gas stream is disclosed. In recent years, the preferred method of separating a hydrocarbon gas stream generally includes supplying at least portions of the gas stream to a fractionation tower having at least one reboiler, and often one or more side reboilers, to supply heat to the column by withdrawing and heating some of the tower liquids to produce stripping vapors that separate the more volatile components from the desired components. The reboiler and side reboilers (if any) are typically integrated into the feed stream cooling scheme to provide at least a portion of the refrigeration needed to condense the desired components for subsequent fractionation in the distillation column. In the process disclosed, the tower reboiling scheme is modified to use one or more tower liquid distillation streams from a point higher in the column than is used in the conventional reboiling scheme, providing colder stream(s) for the reboiler(s) that allow more effective cooling of the feed streams and thereby improve the efficiency with which the desired components are recovered. In addition, the tower liquid streams withdrawn from a higher point in the column contain larger quantities of the more volatile components, which when vaporized provide better stripping of undesirable components like carbon dioxide without reducing the recovery of the desired components. The heated distillation stream is returned to a lower point on the fractionation tower that is separated from the withdrawal point by at least one theoretical stage.
    • 公开了从烃气流中回收乙烷,乙烯,丙烷,丙烯和较重烃组分的方法。 近年来,分离烃气流的优选方法通常包括将气流的至少一部分供应至具有至少一个再沸器的分馏塔,并且通常是一个或多个侧再沸器,以通过抽出和 加热一些塔式液体以产生汽提蒸汽,其将更易挥发的组分与期望的组分分离。 再沸器和侧面再沸器(如果有的话)通常集成到进料流冷却方案中,以提供冷凝所需组分所需的至少一部分制冷剂用于随后在蒸馏塔中分馏。 在所公开的方法中,塔式再沸腾方案被修改为使用一种或多种塔式液体蒸馏物流,其比在常规再沸腾方案中使用的塔中高一点,为再沸器提供较冷的流,其允许 更有效地冷却进料流,从而提高回收所需组分的效率。 此外,从柱中较高点排出的塔液流含有较大量的挥发性较高的组分,当汽化时,会提供更好的汽提不需要的组分如二氧化碳,而不会降低所需组分的回收率。 加热的蒸馏物流返回到分离塔上的一个较低点,其从提取点离开至少一个理论阶段。
    • 7. 发明授权
    • Hydrocarbon gas processing
    • 烃类气体加工
    • US06182469B2
    • 2001-02-06
    • US09439508
    • 1999-11-12
    • Roy E. CampbellJohn D. WilkinsonHank M. HudsonMichael C. Pierce
    • Roy E. CampbellJohn D. WilkinsonHank M. HudsonMichael C. Pierce
    • F25J302
    • F25J3/0233F25J3/0209F25J3/0219F25J3/0238F25J2200/02F25J2200/30F25J2200/70F25J2200/76F25J2200/90F25J2205/04F25J2210/12F25J2220/66F25J2235/60F25J2240/02F25J2245/02F25J2290/40Y02C10/12
    • A process for the recovery of ethane, ethylene, propane, propylene and heavier hydrocarbon components from a hydrocarbon gas stream is disclosed. In recent years, the preferred method of separating a hydrocarbon gas stream generally includes supplying at least portions of the gas stream to a fractionation tower having at least one reboiler, and often one or more side reboilers, to supply heat to the column by withdrawing and heating some of the tower liquids to produce stripping vapors that separate the more volatile components from the desired components. The reboiler and side reboilers (if any) are typically integrated into the feed stream cooling scheme to provide at least a portion of the refrigeration needed to condense the desired components for subsequent fractionation in the distillation column. In the process disclosed, the tower reboiling scheme is modified to use one or more tower liquid distillation streams from a point higher in the column than is used in the conventional reboiling scheme, providing colder stream(s) for the reboiler(s) that allow more effective cooling of the feed streams and thereby improve the efficiency with which the desired components are recovered. In addition, the tower liquid streams withdrawn from a higher point in the column contain larger quantities of the more volatile components, which when vaporized provide better stripping of undesirable components like carbon dioxide without reducing the recovery of the desired components. The heated distillation stream is returned to a lower point on the fractionation tower that is separated from the withdrawal point by at least one theoretical stage.
    • 公开了从烃气流中回收乙烷,乙烯,丙烷,丙烯和较重烃组分的方法。 近年来,分离烃气流的优选方法通常包括将气流的至少一部分供应至具有至少一个再沸器的分馏塔,并且通常是一个或多个侧再沸器,以通过抽出和 加热一些塔式液体以产生汽提蒸汽,其将更易挥发的组分与期望的组分分离。 再沸器和侧面再沸器(如果有的话)通常集成到进料流冷却方案中,以提供冷凝所需组分所需的至少一部分制冷剂用于随后在蒸馏塔中分馏。 在所公开的方法中,塔式再沸腾方案被修改为使用一种或多种塔式液体蒸馏物流,其比在常规再沸腾方案中使用的塔中高一点,为再沸器提供较冷的流,其允许 更有效地冷却进料流,从而提高回收所需组分的效率。 此外,从柱中较高点排出的塔液流含有较大量的挥发性较高的组分,当汽化时,会提供更好的汽提不需要的组分如二氧化碳,而不会降低所需组分的回收率。 加热的蒸馏物流返回到分离塔上的一个较低点,其从提取点离开至少一个理论阶段。