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1. 发明授权

US06596253B1 Regeneration of a desulfurizing catalytic solution by means of an ejector 有权
标题翻译：通过喷射器再生脱硫催化剂溶液
公开(公告)号：US06596253B1
公开(公告)日：2003-07-22
申请号：US09592425
申请日：2000-06-12
申请人： Cécile Barrere-Tricca , Christian Streicher , Jean-Charles Viltard
发明人： Cécile Barrere-Tricca , Christian Streicher , Jean-Charles Viltard
IPC分类号： C01B1704
CPC分类号： B01J31/2234 , B01D53/1425 , B01D53/1468 , B01D53/52 , B01J8/005 , B01J8/228 , B01J31/223 , B01J31/2243 , B01J31/4015 , B01J31/403 , B01J2231/70 , B01J2531/842 , B01J2531/96 , C01B17/05 , C10L3/10 , Y02P20/584
摘要： In the desulfurization of a gaseous feed containing hydrogen sulfide, comprising contacting the gaseous feed with a catalytic solution containing a chelated polyvalent metal under suitable conditions for oxidation of the hydrogen sulfide to elementary sulfur and concomitant reduction of the chelated polyvalent metal from a higher oxidation level to a lower oxidation level, recovering a gaseous effluent substantially freed from hydrogen sulfide, and a catalytic solution at least partly reduced and containing elementary sulfur, separating the solid elementary sulfur from the reduced catalytic solution, and regenerating the reduced catalytic solution by contacting the catalytic solution with a gas containing oxygen by means of an ejector.
摘要翻译：在含有硫化氢的气态原料的脱硫中，包括使气态进料与含有螯合多价金属的催化溶液在合适的条件下使硫化氢氧化为单质硫并伴随从较高氧化水平还原螯合多价金属回收基本上不含硫化氢的气态流出物，以及至少部分还原并含有元素硫的催化溶液，从还原的催化溶液中分离固体元素硫，并通过使催化剂接触再生还原的催化溶液溶液与含有氧的气体通过喷射器。

2. 发明授权

US06872367B2 Method and device for processing a gas containing hydrogen sulfide and sulfut dioxide comprising a stage of removal of solid by-products 失效
标题翻译：包含硫化氢和二氧化硫的气体的处理方法和装置，包括除去固体副产物的阶段
公开(公告)号：US06872367B2
公开(公告)日：2005-03-29
申请号：US09897464
申请日：2001-07-03
申请人： Fabrice Lecomte , Christian Streicher , Daniel Benayoun , Cécile Barrere-Tricca
发明人： Fabrice Lecomte , Christian Streicher , Daniel Benayoun , Cécile Barrere-Tricca
IPC分类号： B01D53/50 , B01D53/52 , B01D53/77 , B01D53/86 , C01B17/02 , C01B17/033 , C01B17/04 , C01B17/05 , B01J8/00
CPC分类号： B01D53/523 , B01D53/8615 , C01B17/0205 , C01B17/033 , C01B17/05
摘要： A method for processing a gas containing at least hydrogen sulfide (H2S) and at least sulfur dioxide (SO2), includes the following stages: contacting the gas with a liquid solvent containing at least one catalyst in a contacting stage, recovering a gaseous effluent substantially containing no hydrogen sulfide and no sulfur dioxide, and a mixture containing liquid sulfur, liquid solvent and solid by-products resulting from the degradation of the catalyst, separating the liquid sulfur from the liquid solvent in a decantation zone, extracting a liquid fraction F containing at least the solid by-products from a layer between the liquid solvent and the liquid sulfur in the decantation zone, sending the liquid fraction F to a processing stage distinct from the contacting stage, and recovering at least a stream F1 comprising most of the solid by-products and a stream F2 mostly comprising solvent nearly free of the solid by-products from the processing stage.
摘要翻译：一种用于处理至少包含硫化氢（H 2 S）和至少二氧化硫（SO 2）的气体的方法包括以下阶段：在接触阶段使气体与含有至少一种催化剂的液体溶剂接触，基本上回收气态流出物不含硫化氢和不含二氧化硫的混合物，以及含有液体硫，液体溶剂和由催化剂降解而产生的固体副产物的混合物的混合物，在倾析区中将液体硫与液体溶剂分离，提取含有至少来自液体溶剂和倾析区中的液体硫之间的层的固体副产物，将液体馏分F送至与接触阶段不同的处理阶段，并回收至少一种包含大部分固体的流F1 副产物和主要包含来自处理阶段的几乎不含固体副产物的溶剂的流F2。

3. 发明授权

US06872368B2 Method and device for processing a gas containing hydrogen sulfide and sulfur dioxide comprising a stage of removal of by-products 失效
标题翻译：用于处理含有硫化氢和二氧化硫的气体的方法和装置，包括除去副产物的阶段
公开(公告)号：US06872368B2
公开(公告)日：2005-03-29
申请号：US09902104
申请日：2001-07-11
申请人： Fabrice Lecomte , Christian Streicher , Cécile Barrere-Tricca
发明人： Fabrice Lecomte , Christian Streicher , Cécile Barrere-Tricca
IPC分类号： C01B17/04 , B01D53/86 , C01B17/05 , B01J8/00
CPC分类号： B01D53/8615 , C01B17/05
摘要： A method for processing a gas containing at least hydrogen sulfide (H2S) and at least sulfur dioxide (SO2), includes the steps of contacting the gas with a liquid solvent containing at least one catalyst in a contacting stage, recovering gaseous effluent substantially containing no hydrogen sulfide and no sulfur dioxide from the contacting stage, and separating liquid sulfur from liquid solvent in a decantation zone downstream of the contacting stage. In order to remove by-products resulting from degradation of the catalyst, a liquid fraction F containing at least solvent, catalyst, sulfur and the solid by-products resulting from degradation of the catalyst is extracted from after the contacting stage. The liquid fraction F is sent to a processing stage distinct from the contacting stage where the liquid fraction F is heated to a temperature at least partially crystallizing the by-products, and the at least partially crystallized by-products separated from the rest of the liquid fraction F containing at least solvent. At least a stream F1 comprising solvent, catalyst and sulfur and substantially free of the by-products and a stream F2 mostly comprising the by-products are recovered.
摘要翻译：一种用于处理至少包含硫化氢（H 2 S）和至少二氧化硫（SO 2）的气体的方法，包括以下步骤：在接触阶段使气体与含有至少一种催化剂的液体溶剂接触，回收基本上不含硫化氢和来自接触阶段的二氧化硫，并且在接触阶段下游的倾析区中将液体硫与液体溶剂分离。为了除去由催化剂的降解引起的副产物，从接触阶段后提取至少含有溶剂，催化剂，硫和由催化剂降解引起的固体副产物的液体馏分F. 液体馏分F被送至不同于液体馏分F被加热至至少部分使副产物结晶的温度的接触阶段的处理阶段，并且至少部分结晶的副产物与其余液体分离含有至少溶剂的馏分F. 回收至少包含溶剂，催化剂和硫并基本上不含副产物的流F1和主要包含副产物的料流F2。

4. 发明授权

US06589498B1 Process and device for treating a gas containing hydrogen sulfide, with recycling of the reduced catalytic solution 有权
标题翻译：通过再循环还原的催化溶液处理含硫化氢的气体的方法和装置
公开(公告)号：US06589498B1
公开(公告)日：2003-07-08
申请号：US09589744
申请日：2000-06-09
申请人： Cécile Barrere-Tricca , Thierry Huard , Christian Streicher
发明人： Cécile Barrere-Tricca , Thierry Huard , Christian Streicher
IPC分类号： C01B1704
CPC分类号： B01D53/1468
摘要： A process intended for desulfurization of a gaseous feed containing hydrogen sulfide, includes at least the following stages: a) contacting the gaseous feed with a catalytic solution containing at least one polyvalent metal chelated by at least one chelating agent, under suitable conditions for oxidation of the hydrogen sulfide to elemental sulfur and concomitant reduction of the polyvalent metal from a higher oxidation level to a lower oxidation level, b) recovering on the one hand a gaseous effluent substantially freed from hydrogen sulfide and, on the other hand, the catalytic solution at least reduced and containing elemental sulfur, and c) recycling at least a fraction F1 of the catalytic solution at least reduced and containing solid elemental sulfur to absorption stage a) so as to reduce the number of sulfur grains of very small size.
摘要翻译：用于含硫化氢气态进料脱硫的方法至少包括以下阶段：a）使气态进料与含有至少一种螯合剂螯合的至少一种多价金属的催化溶液在适合的条件下，硫化氢至元素硫，并将多价金属从较高的氧化水平降低至较低的氧化水平，b）一方面回收基本上不含硫化氢的气态流出物，另一方面，回收催化剂溶液在最少还原并含有元素硫，以及c）将至少一种至少还原并含有固体元素硫的催化剂溶液的馏分F1循环至吸收级a），以减少非常小尺寸的硫颗粒的数量。

5. 发明授权

US06280698B1 Removal of by-products in method for processing a gas containing hydrogen sulfide and sulfur dioxide 有权
标题翻译：在含有硫化氢和二氧化硫的气体的处理方法中除去副产物
公开(公告)号：US06280698B1
公开(公告)日：2001-08-28
申请号：US09444847
申请日：1999-11-22
申请人： Fabrice Lecomte , Christian Streicher , Cécile Barrere-Tricca
发明人： Fabrice Lecomte , Christian Streicher , Cécile Barrere-Tricca
IPC分类号： C01B1704
CPC分类号： B01D53/8615 , C01B17/05
摘要： A method for processing a gas, such as a Claus tail gas, containing at least hydrogen sulfide (H2S) and at least sulfur dioxide (SO2), includes the steps of contacting the gas with a liquid solvent, such as polyethylene glycol, containing at least one catalyst, such as sodium salicylate, in a contacting stage, recovering gaseous effluent substantially containing no hydrogen sulfide and no sulfur dioxide from the contacting stage, and separating liquid sulfur from liquid solvent in a decantation zone beneath the contacting stage. In order to remove by-products, such as sulfate and thiosulfate salts, resulting from degradation of the catalyst, a liquid fraction F containing at least solvent, catalyst, sulfur and the solid by-products resulting from degradation of the catalyst is extracted from the contacting stage and sent to a processing stage distinct from the contacting stage where the liquid fraction F is heated to a temperature sufficient to at least partially crystallize the by-products, and the crystallized by-products are separated from the rest of the liquid fraction F containing at least solvent. At least a stream F1 comprising solvent, catalyst and sulfur and substantially free of the by-products and a stream F2 mostly comprising the by-products are recovered.
摘要翻译：至少含有硫化氢（H2S）和至少二氧化硫（SO2）的克劳斯尾气处理气体的方法包括以下步骤：使气体与液体溶剂如聚乙二醇接触，至少一种催化剂，如水杨酸钠，在接触阶段，从接触阶段回收基本上不含硫化氢并且不含二氧化硫的气态流出物，以及在接触阶段下方的倾析区域中将液体硫与液体溶剂分离。为了除去由催化剂降解而产生的副产物如硫酸盐和硫代硫酸盐，至少含有溶剂，催化剂，硫和由催化剂降解引起的固体副产物的液体馏分F从接触阶段并送到与将液体馏分F加热至足以至少部分地使副产物结晶的温度的接触阶段不同的处理阶段，并且将结晶的副产物与液体馏分F的其余部分分离至少含有溶剂。回收至少包含溶剂，催化剂和硫并基本上不含副产物的流F1和主要包含副产物的料流F2。

6. 发明授权

US06669921B2 Process for regenerating a catalytic redox solution, to include measuring the oxygen dissolved in the regeneration effluent and its application to desulfurization 有权
标题翻译：用于再生催化氧化还原溶液的方法，包括测量溶解在再生流出物中的氧气及其在脱硫中的应用
公开(公告)号：US06669921B2
公开(公告)日：2003-12-30
申请号：US10023765
申请日：2001-12-21
申请人： Thierry Huard , Christian Streicher
发明人： Thierry Huard , Christian Streicher
IPC分类号： C01B1705
CPC分类号： B01J31/403 , B01D53/8612 , B01J31/223 , B01J31/2234 , B01J31/2243 , B01J31/226 , B01J31/4015 , B01J38/48 , B01J2231/70 , B01J2531/56 , B01J2531/842 , B01J2531/96 , C01B17/05 , Y02P20/584
摘要： The present invention relates to a process for regenerating an at least partly reduced catalytic redox solution. The solution includes at least one polyvalent metal chelated by a chelating agent and is circulated in at least one regeneration zone while an oxygen-containing gas is injected into the regeneration zone. The process includes measuring a concentration of oxygen dissolved in a regeneration zone effluent. The process also includes adjusting a flow rate of the at least partly reduce catalytic redox solution entering the at least one regeneration zone and/or an oxygen-containing gas entering the regeneration zone in response to a measured concentration of oxygen, until a concentration of oxygen in the regeneration zone effluent is less than 20% of an amount of oxygen dissolved in water saturated with oxygen. Thus, degradation of the chelating agent in the catalytic redox solution is minimized.
摘要翻译：本发明涉及一种再生至少部分还原的催化氧化还原溶液的方法。该溶液包含至少一种螯合剂螯合的多价金属，并且在含氧气体注入到再生区中的同时在至少一个再生区中循环。该方法包括测量溶解在再生区流出物中的氧浓度。该方法还包括响应于测量的氧浓度调节进入至少一个再生区的至少部分还原催化氧化还原溶液的流速和/或进入再生区的含氧气体，直到氧气浓度在再生区中，流出物的溶解度低于氧气饱和的水中的氧气的20％。因此，催化氧化还原溶液中的螯合剂的降解最小化。

7. 发明授权

US5609734A Combined distillation and permeation process for the separation of oxygenated compounds from hydrocarbons and use thereof in etherification 失效
标题翻译：用于将含氧化合物与烃分离的联合蒸馏和渗透方法以及其在醚化中的用途
公开(公告)号：US5609734A
公开(公告)日：1997-03-11
申请号：US336222
申请日：1994-11-07
申请人： Christian Streicher , Lionel Asselineau
发明人： Christian Streicher , Lionel Asselineau
IPC分类号： B01D53/22 , B01D3/14 , C07C7/00 , C07C41/06 , C07C41/42 , C07C43/04 , B01D3/36
CPC分类号： C07C7/005 , C07C41/42
摘要： A process for the separation of oxygenated compounds, containing mainly methanol and possibly a minor amount of water and/or dimethyl ether, from a mixture of hydrocarbons containing 3 to 8 carbon atoms containing said oxygenated compounds. The mixture is distilled in a distillation zone (D). A gaseous distillate (line 2) is taken overhead which contains methanol, possibly water, possibly dimethyl ether, and hydrocarbons. The gaseous distillate is separated in a separator (B) and at least one organic liquid phase is recovered (line 6) and sent as a reflux to the head of distillation zone D. An aqueous liquid phase (line 5) may possibly be recovered, also a gaseous phase (line 4). A phase (line 8) is extracted as a side stream from the distillation zone and sent to a permeation zone (PV) comprising at least one membrane which is selectively permeable to methanol; a permeation step is carried out on said phase. At least one methanol-enriched permeate (line 14) is recovered downstream of the permeation zone, preferably as a vapor, and at least one residue (line 11) is recovered upstream which is optionally recycled to the distillation zone. The purified hydrocarbon mixture is extracted (line 16) from the bottom of the distillation column.
摘要翻译：从含有含氧化合物的含有3至8个碳原子的烃的混合物中分离含氧化合物的方法，该化合物主要含有甲醇和可能少量的水和/或二甲醚。将混合物在蒸馏区（D）中蒸馏。塔顶馏出气态馏分（管线2），其中含有甲醇，可能是水，可能是二甲醚和烃。将气态馏出物在分离器（B）中分离并回收至少一个有机液相（管线6）并作为回流送至蒸馏区D的头部。可能回收含水液相（管线5）也是气相（管线4）。 A相（管线8）作为来自蒸馏区的侧流提取并送至包含至少一个选择性可渗透甲醇的膜的渗透区（PV）; 对所述相进行渗透步骤。至少一个甲醇富集的渗透物（管线14）在渗透区的下游，优选蒸气回收，并且至少一个残余物（管线11）被回收到上游，任选地再循环到蒸馏区。从蒸馏塔的底部萃取纯化的烃混合物（管线16）。

8. 发明授权

US06780396B2 Process for the production of a gas that contains hydrogen from hydrogen sulfide 有权
标题翻译：用于从硫化氢生产含氢气的方法
公开(公告)号：US06780396B2
公开(公告)日：2004-08-24
申请号：US10134646
申请日：2002-04-30
申请人： Christian Streicher
发明人： Christian Streicher
IPC分类号： C01B304
CPC分类号： C01B3/04 , C01B17/0495 , Y02E60/364
摘要： A process for the production of hydrogen from a hydrogen sulfide feedstock, comprising a stage for heating feedstock (1) in a heating zone (2, 5) to a suitable temperature so as to produce a hot gas (6) that contains hydrogen and elementary sulfur, whereby this heating is carried out at least in part by an external heat source and a stage for rapid cooling of the hot gas thus obtained, by mixing with a fluid (8) by means of at least one mixer (7), preferably an ejector, so as to obtain a gaseous effluent (9). The mixing time is less than 20 milliseconds. Elementary sulfur (11) is separated from this effluent and the hydrogen is recovered. Application for the elimination of hydrogen sulfide and the production of hydrogen.
摘要翻译：一种用于从硫化氢原料生产氢气的方法，包括用于将加热区（2,5）中的原料（1）加热至合适温度的阶段，以产生含有氢气和基体的热气体（6）硫，由此这种加热至少部分地通过外部热源和用于通过至少一个混合器（7）与流体（8）混合而快速冷却所获得的热气体的阶段，优选地喷射器，以获得气态流出物（9）。混合时间小于20毫秒。将基本硫（11）与该流出物分离，并回收氢。应用于消除硫化氢和产生氢气。

9. 发明授权

US06277352B1 Method and device for processing a gas containing hydrogen sulfide and sulfur dioxide, comprising a stage of removal of solid by-products 有权
标题翻译：用于处理含有硫化氢和二氧化硫的气体的方法和装置，包括除去固体副产物的阶段
公开(公告)号：US06277352B1
公开(公告)日：2001-08-21
申请号：US09413889
申请日：1999-10-07
申请人： Fabrice Lecomte , Christian Streicher , Daniel Benayoun , Cecile Barrere-Tricca
发明人： Fabrice Lecomte , Christian Streicher , Daniel Benayoun , Cecile Barrere-Tricca
IPC分类号： B01D5350
CPC分类号： B01D53/523 , B01D53/8615 , C01B17/0205 , C01B17/033 , C01B17/05
摘要： A method for processing a gas containing at least hydrogen sulfide (H2S) and at least sulfur dioxide (SO2), includes the following stages: contacting the gas with a liquid solvent, such as polyethylene glycol, containing at least one catalyst, such as sodium salicylate, in a contacting stage, recovering a gaseous effluent substantially containing no hydrogen sulfide and no sulfur dioxide, and a mixture containing liquid sulfur, liquid solvent and solid by-products such as alkali metal or alkaline earth metal sulfates or thiosulfates, resulting from the degradation of the catalyst, separating the liquid sulfur from the liquid solvent in a decantation zone, extracting a liquid fraction F containing at least the solid by-products from a layer between the liquid solvent and the liquid sulfur in the decantation zone, sending the liquid fraction F to a processing stage distinct from the contacting stage, and recovering at least a stream F, comprising most of the solid by-products and a stream F2 mostly comprising solvent nearly free of the solid by-products from the processing stage.
摘要翻译：至少包含硫化氢（H 2 S）和至少二氧化硫（SO 2）的气体的处理方法包括以下阶段：将气体与液体溶剂如聚乙二醇接触，所述液体溶剂含有至少一种催化剂，例如钠水杨酸盐在接触阶段回收基本上不含硫化氢和二氧化硫的气态流出物，以及含有液体硫，液体溶剂和固体副产物如碱金属或碱土金属硫酸盐或硫代硫酸盐的混合物，由催化剂降解，在倾析区中将液态硫与液体溶剂分离，从倾析区内的液体溶剂和液态硫之间的层中提取至少含有固体副产物的液体馏分F，将液体馏分F到与接触阶段不同的处理阶段，并且回收至少一个流F，其包含大部分固体副产物和流浆 m F2主要包括几乎不含处理阶段固体副产物的溶剂。

10. 发明授权

US6096195A Process and unit for hydrotreating a petroleum feedstock that comprises the cracking of ammonia and the recycling of hydrogen in the unit 失效
标题翻译：用于加氢处理石油原料的方法和单元，其包括氨的裂解和氢气在单元中的再循环
公开(公告)号：US6096195A
公开(公告)日：2000-08-01
申请号：US138547
申请日：1998-08-24
申请人： Christian Streicher , Fabrice Lecomte , Christian Busson
发明人： Christian Streicher , Fabrice Lecomte , Christian Busson
IPC分类号： C10G49/00 , C10G49/22 , C10G45/02
CPC分类号： C10G49/007 , C10G49/22
摘要： Described in a process for hydrotreating (HDT) a petroleum feedstock (1) that contains sulfur and nitrogen are the catalytic cracking of the ammonia, produced by the hydrotreating process, in a catalytic cracking furnace (F), the cooling (E2) and separating of the cracking effluent to produce an H.sub.2 S containing gas phase, the extraction of the hydrogen sulfide from said gas phase and from the hydrotreating purge gas in an amine washing unit (20), and the separation (SM) of the hydrogen from the resultant effluent. The recovered hydrogen is recycled to hydrotreating unit (HDT) via a pipe (17).
摘要翻译：在加氢处理（HDT）的方法中，含有硫和氮的石油原料（1）是在催化裂化炉（F），冷却（E2）和分离中由加氢处理方法产生的氨的催化裂化的裂解流出物以产生含H 2 S的气相，从胺洗涤单元（20）中从所述气相和加氢处理净化气体中提取硫化氢以及从所得流出物中分离（SM）氢。回收的氢气通过管道（17）再循环到加氢处理装置（HDT）中。

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