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1. 发明授权

US07160833B2 Spray-dried polymerization catalyst and polymerization process employing same 失效
标题翻译：喷雾干燥聚合催化剂和采用其的聚合方法
公开(公告)号：US07160833B2
公开(公告)日：2007-01-09
申请号：US10889813
申请日：2004-07-13
申请人： Burkhard Eric Wagner , Mark Wilton Smale , Robert James Jorgensen
发明人： Burkhard Eric Wagner , Mark Wilton Smale , Robert James Jorgensen
IPC分类号： C08F4/02 , B01J31/00
CPC分类号： C08F10/02 , C08F110/02 , C08F2410/01 , Y02P20/582 , C08F4/6367 , C08F2500/12 , C08F2500/18 , C08F2500/24
摘要： A spray-dried composition comprising the reaction product of a magnesium halide, a solvent, an electron donor compound, and a transition metal compound and an inert filler comprising substantially spherical particles having an average particle size ranging from about 1 μm to about 12 μm, and a polymerization process using the same.
摘要翻译：一种喷雾干燥的组合物，其包含卤化镁，溶剂，电子给体化合物和过渡金属化合物的反应产物和包含平均粒度范围为约1μm至约12μm的基本上为球形的颗粒的惰性填料，和使用其的聚合方法。

2. 发明授权

US06806221B2 Method for preparing a spray-dried composition for use as a polymerization catalyst 失效
标题翻译：制备用作聚合催化剂的喷雾干燥组合物的方法
公开(公告)号：US06806221B2
公开(公告)日：2004-10-19
申请号：US10196663
申请日：2002-07-15
申请人： Burkhard Eric Wagner , Robert James Jorgensen , Mark Wilton Smale
发明人： Burkhard Eric Wagner , Robert James Jorgensen , Mark Wilton Smale
IPC分类号： B01J3100
CPC分类号： C08F10/02 , C08F110/02 , C08F2410/01 , Y02P20/582 , C08F4/6367 , C08F2500/12 , C08F2500/18 , C08F2500/24
摘要： A method of making a spray-dried composition using a solution or mixture comprising the reaction product of a magnesium halide, a solvent, an electron donor compound, and a transition metal compound and an inert filler comprising substantially spherical particles having an average particle size ranging from 1 &mgr;m to about 12 &mgr;m.
摘要翻译：使用包含卤化镁，溶剂，电子给体化合物和过渡金属化合物的反应产物的溶液或混合物和包含平均粒度范围的基本上为球形的颗粒的惰性填料制备喷雾干燥组合物的方法从1毫米到约12个妈妈。

3. 发明授权

US06982237B2 Spray-dried polymerization catalyst and polymerization processes employing same 失效
标题翻译：喷雾干燥聚合催化剂和采用其的聚合方法
公开(公告)号：US06982237B2
公开(公告)日：2006-01-03
申请号：US10196705
申请日：2002-07-15
申请人： Burkhard Eric Wagner , Robert James Jorgensen
发明人： Burkhard Eric Wagner , Robert James Jorgensen
IPC分类号： B01J31/00 , B01J37/00 , C08F4/02 , C08F4/60 , C08F4/44
CPC分类号： C08F10/00 , C08F110/02 , C08F2410/01 , C08F4/651 , C08F4/6555 , C08F4/6543 , C08F2500/12 , C08F2500/07 , C08F2500/18 , C08F2500/24
摘要： A spray-dried catalyst precursor composition and method of making a spray-dried catalyst precursor composition with an inert filler, magnesium, a transition metal, solvent, and one electron donor compound. The catalyst precursor composition is substantially free of other electron donor compounds, the molar ratio of the electron donor compound to magnesium is less than or equal to 1.9, and comprises spherical or substantially spherical particles having a particle size of from about 10 to about 200 μm. Catalysts made from the spray-dried catalyst precursors and polymerization methods using such catalysts are disclosed.
摘要翻译：喷雾干燥的催化剂前体组合物和用惰性填料，镁，过渡金属，溶剂和一种电子给体化合物制备喷雾干燥的催化剂前体组合物的方法。催化剂前体组合物基本上不含其它电子给体化合物，电子给体化合物与镁的摩尔比小于或等于1.9，并且包含粒度为约10至约200μm的球形或基本上为球形的颗粒。公开了由喷雾干燥的催化剂前体制备的催化剂和使用这种催化剂的聚合方法。

4. 发明授权

US5652314A Shape-shifted magnesium alkoxide component for polymerizing olefins 失效
公开(公告)号：US5652314A
公开(公告)日：1997-07-29
申请号：US701805
申请日：1996-08-21
申请人： Burkhard Eric Wagner , Daniel Paul Zilker, Jr. , Robert James Jorgensen
发明人： Burkhard Eric Wagner , Daniel Paul Zilker, Jr. , Robert James Jorgensen
IPC分类号： B01J21/10 , B01J37/08 , C07C29/68 , C07C31/30 , C08F4/656 , C08F10/00 , C08F210/06 , C08F210/16
CPC分类号： C07C31/30 , B01J21/10 , B01J37/088 , C07C29/68 , C08F10/00 , C08F210/06 , C08F210/16 , Y10S526/908
摘要： A process is provided for preparing a shape-shifted catalyst component comprising (1) contacting a dihydrocarbyloxide magnesium compound with carbon dioxide in the presence of a slurrying agent to form a slurry of a carboxylated dihydrocarbyloxide magnesium compound; (2) adding a filler to the slurry either before or after the carboxylation of step (1); (3) spray drying the slurry of step (2) to evaporate the slurrying agent and to produce solid particles of the carboxylated dihydrocarbyloxide magnesium compound incorporating the filler; and, optionally, (4) heating the solid particles to remove carbon dioxide to produce a shape-shifted dihydrocarbyloxide magnesium compound component. A catalyst system using the component and a polymerization process employing the catalyst system are also provided.

5. 发明授权

US06780808B2 Enhanced solubility of magnesium halides and catalysts and polymerization process using same 失效
标题翻译：提高卤化镁和催化剂的溶解度和使用相同的聚合方法
公开(公告)号：US06780808B2
公开(公告)日：2004-08-24
申请号：US10196704
申请日：2002-07-15
申请人： Burkhard Eric Wagner , Robert James Jorgensen , Cynthia Anne Hepburn
发明人： Burkhard Eric Wagner , Robert James Jorgensen , Cynthia Anne Hepburn
IPC分类号： B01J3100
CPC分类号： C07F3/003 , C07F7/003 , C08F110/02 , C08F4/651 , C08F4/6543 , C08F2500/12
摘要： A magnesium halide composition comprising and/or made from a magnesium halide, a solvent suitable for an electron donor compound and an electron donor compound. The composition is characterized by enhanced solubility whereby it has a solubility in the solvent that does not decrease as a function of temperature up to the boiling point of the solvent and the solubility of the magnesium halide in the solvent is greater than 0.7 mol/liter. A polymerization catalyst precursor composition can be made from magnesium halide composition by mixing the magnesium halide composition with a transition metal compound.
摘要翻译：包含卤化镁和/或由卤化镁制成的卤化镁组合物，适用于电子给体化合物的溶剂和电子给体化合物。该组合物的特征在于增加的溶解度，由此其在溶剂中的溶解度不随温度升高到溶剂的沸点而降低，并且卤化镁在溶剂中的溶解度大于0.7mol /升。聚合催化剂前体组合物可以由卤化镁组合物通过混合卤化镁组合物与过渡金属化合物制成。

6. 发明授权

US6117399A Fluidized bed polymerization reactor with multiple fluidization grids 失效
公开(公告)号：US6117399A
公开(公告)日：2000-09-12
申请号：US842395
申请日：1997-04-23
申请人： Robert James Jorgensen , Steven Paul Sawin
发明人： Robert James Jorgensen , Steven Paul Sawin
IPC分类号： B01J8/24 , B01J8/28 , B01J8/44 , C08F2/34 , C08F10/00 , B01J8/18
CPC分类号： C08F10/00 , B01J8/1872 , B01J8/28 , B01J8/44 , B01J2208/00044 , B01J2208/00256 , B01J2208/00274 , Y02P20/582
摘要： The invention teaches a novel design for a fluidized bed polymerization reactor which utilizes a primary fluidization grid to provide mixing and fluidization of the polymer and at least one secondary distribution plate located above the first distribution plate to promote segregation of polymer particles by size, the larger particles falling into the lower fluidization zone and the smaller particles being entrained up from the primary fluidization grid and through the secondary distribution grid into an upper reaction zone.

7. 发明授权

US6113862A Fluidized bed polymerization reactor with multiple fluidization grids 失效
标题翻译：具有多个流化床的流化床聚合反应器
公开(公告)号：US6113862A
公开(公告)日：2000-09-05
申请号：US892019
申请日：1997-07-14
申请人： Robert James Jorgensen , Steven Paul Sawin
发明人： Robert James Jorgensen , Steven Paul Sawin
IPC分类号： B01J8/24 , B01J8/28 , B01J8/44 , C08F2/34 , C08F10/00 , B01J8/18
CPC分类号： B01J8/1872 , B01J8/28 , B01J8/44 , C08F10/00 , B01J2208/00044 , B01J2208/00256 , B01J2208/00274 , Y02P20/582
摘要： The invention teaches a novel design for a fluidized bed polymerization reactor which utilizes a primary fluidization grid to provide mixing and fluidization of the polymer and at least one secondary distribution plate located above the first distribution plate to promote segregation of polymer particles by size, the larger particles falling into the lower fluidization zone and the smaller particles being entrained up from the primary fluidization grid and through the secondary distribution grid into an upper reaction zone.
摘要翻译：本发明教导了流化床聚合反应器的新颖设计，该反应器利用初级流化网格来提供聚合物和位于第一分配板上方的至少一个次级分布板的混合和流化，以促进聚合物颗粒按尺寸分离，较大的颗粒落入下部流化区，较小的颗粒从初级流化栅格夹带并通过二次分配网格进入上部反应区。

8. 发明授权

US08653208B2 Process for preparing catalysts and catalysts made thereby 失效
标题翻译：制备催化剂和催化剂的方法
公开(公告)号：US08653208B2
公开(公告)日：2014-02-18
申请号：US13475611
申请日：2012-05-18
申请人： Robert James Jorgensen
发明人： Robert James Jorgensen
IPC分类号： C08F4/24 , B01J23/00
CPC分类号： C08F4/69 , B01J23/26 , B01J31/2295 , B01J35/023 , B01J35/1014 , B01J35/1042 , B01J37/0045 , B01J37/0201 , B01J37/04 , B01J37/12 , C08F4/63912 , C08F4/63925 , C08F4/659 , C08F10/02 , C08F10/00 , C08F4/64148 , C08F4/65925 , C08F4/63904 , C08F4/025
摘要： A process for preparing a catalyst, and catalysts prepared thereby. The process includes selecting a catalyst support and mixing it with one or more chromium containing compounds oxidizable to a Cr+6 state or already in a Cr+6 state, and with one or more transition metal catalyst component, and calcining the catalyst support while oxidizing any chromium containing compound to a Cr+6 state, and spray drying the catalyst support to form catalyst particles. The catalyst supports are characterized by a surface area greater than 50 m2/gram and a pore volume greater than 0.5 cc/gram at the time of mixing the catalyst support with the chromium containing compound.
摘要翻译：制备催化剂的方法和由此制备的催化剂。该方法包括选择催化剂载体并将其与一种或多种可氧化成Cr + 6状态或已经处于Cr + 6状态的含铬化合物和一种或多种过渡金属催化剂组分混合，并在氧化时煅烧催化剂载体任何含铬化合物处于Cr + 6状态，并喷雾干燥催化剂载体以形成催化剂颗粒。在将催化剂载体与含铬化合物混合时，催化剂载体的特征在于表面积大于50m 2 / g，孔体积大于0.5cc / g。

9. 发明授权

US06617405B1 Process for the preparation of polyethylene 失效
标题翻译：制备聚乙烯的方法
公开(公告)号：US06617405B1
公开(公告)日：2003-09-09
申请号：US09353207
申请日：1999-07-14
申请人： Robert James Jorgensen
发明人： Robert James Jorgensen
IPC分类号： C08F444
CPC分类号： C08F10/02 , C08F210/16 , Y02P20/52 , C08F4/6425 , C08F4/6543 , C08F2/34 , C08F210/14 , C08F2500/12 , C08F2500/18 , C08F2500/24 , C08F210/08
摘要： A process of polymerizing ethylene or ethylene and one or more comonomers in one or more fluidized bed reactors with a catalyst system comprising (i) a supported or unsupported magnesium/titanium based precursor in slurry form, said precursor containing an electron donor; and (ii) an activator containing aluminum in an amount sufficient to essentially complete the activation of the precursor is disclosed. In the process, the precursor and the activator are mixed prior to introduction into the reactor in at least one mixing procedure, and then the mixture is contacted again with additional activator to essentially complete activation of the precursor. In the method, the atomic ratio of aluminum to titanium is in the range of about 1:1 to about 15:1 and the mole ratio of activator to electron donor is about 1:1 to about 2:1, and no additional activator is introduced into the reactor(s).
摘要翻译：一种在一个或多个流化床反应器中用催化剂体系聚合乙烯或乙烯和一种或多种共聚单体的方法，所述催化剂体系包括（i）以浆料形式的负载或未负载的镁/钛基前体，所述前体含有电子给体; 并且（ii）含有足以基本上完成前体活化的量的含铝的活化剂被公开。在该方法中，在将至少一种混合程序引入反应器之前将前体和活化剂混合，然后将混合物再与另外的活化剂接触以基本上完全活化前体。在该方法中，铝与钛的原子比在约1:1至约15:1的范围内，活化剂与电子给体的摩尔比为约1:1至约2:1，并且不另外的活化剂为引入反应器中。

10. 发明授权

US06187866B1 Staged reactor process 有权
标题翻译：分阶段反应器工艺
公开(公告)号：US06187866B1
公开(公告)日：2001-02-13
申请号：US09326083
申请日：1999-06-04
申请人： Robert James Jorgensen , Stephanie Marie Upham , James Daniel Madden , William James Michie, Jr.
发明人： Robert James Jorgensen , Stephanie Marie Upham , James Daniel Madden , William James Michie, Jr.
IPC分类号： C08F800
CPC分类号： C08F210/16 , C08F2/001
摘要： In a process for the in situ blending of polymers comprising contacting ethylene and one or more comonomers in two or more fluidized bed reactors with a catalyst system comprising (i) a magnesium/titanium based precursor containing an electron donor and (ii) a hydrocarbyl aluminum cocatalyst, the improvement comprising (A) increasing or decreasing the melt flow ratio and/or molecular weight of the blend by, respectively, decreasing or increasing the mole ratio of a precursor activator compound to the electron donor or (B) increasing or decreasing the bulk density of the blend by, respectively, increasing or decreasing the mole ratio of a precursor activator compound to the electron donor, both (A) and (B) subject to defined provisos including partial pre-activation of the precursor.
摘要翻译：在一种用于原位共混聚合物的方法中，包括使两个或多个流化床反应器中的乙烯和一种或多种共聚单体与催化剂体系接触，所述催化剂体系包含（i）含有电子给体的基于镁/钛的前体和（ii）烃基铝助催化剂，其改进包括（A）通过分别降低或增加前体活化剂化合物与电子给体的摩尔比来增加或降低共混物的熔体流动比和/或分子量，或（B）增加或减少通过分别增加或降低前体活化剂化合物与电子给体的摩尔比（A）和（B），共混物的体积密度均受制于包括部分预活化前体的限定条件。

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