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    • 1. 发明授权
    • Tungstate, molybdate, vanadate base glasses
    • 钨酸盐,钼酸盐,钒酸盐底层玻璃
    • US06376399B1
    • 2002-04-23
    • US09490653
    • 2000-01-24
    • Bruce G. AitkenMatthew J. Dejneka
    • Bruce G. AitkenMatthew J. Dejneka
    • C03C312
    • C03C13/048C03C3/122C03C4/0071
    • Alkali tungstate, molybdate and vanadate glasses, and telecommunications components embodying such glasses, the compositions of the glasses consisting essentially of 15-70 mol percent of at least one oxide selected from the group consisting of WO3, MoO3 and VO2.5, 0-35% CrO3, 0-15% UO3, the total WO3 plus MoO3 plus VO2.5 plus CrO3 plus UO3 being 50-70%, 20-50% R2O where R represents at least two elements selected from the group consisting of Li, Na, K, Rb, Cs, Ag and T1, and optionally containing 0-10% MO where M is selected from the groups of elements consisting of Ca, Ba, Sr, Mg, Cd, Pb, 0-5 % X2O3 where x is at least one element selected from the group consisting of Al, Ga, In and Bi, 0-5% of at least one transition metal oxide, 0-15% P2O5 and/or TeO2 and 0-5% of a rare earth oxide selected from the lanthanide series.
    • 碱钨酸盐,钼酸盐和钒酸盐玻璃以及体现这种玻璃的通讯组件,玻璃的组成基本上由15-70摩尔%的选自WO3,MoO3和VO2.5,0-35的至少一种氧化物组成 %CrO 3,0-15%UO 3,总WO 3加MoO 3加VO2.5加上CrO 3加UO 3为50-70%,20-50%R 20,其中R表示选自Li,Na, K,Rb,Cs,Ag和T1,并且任选地含有0-10%MO,其中M选自由Ca,Ba,Sr,Mg,Cd,Pb,0-5%X 2 O 3组成的元素,其中x在 选自Al,Ga,In和Bi中的至少一种元素,0-5%的至少一种过渡金属氧化物,0-15%P 2 O 5和/或TeO 2和0-5%的稀土氧化物,其选自 镧系列。
    • 2. 发明授权
    • Tantalum containing glasses and glass ceramics
    • 含钽的玻璃和玻璃陶瓷
    • US06268303B1
    • 2001-07-31
    • US09321035
    • 1999-05-27
    • Bruce G. AitkenGeorge H. BeallNicholas F. BorrelliMatthew J. Dejneka
    • Bruce G. AitkenGeorge H. BeallNicholas F. BorrelliMatthew J. Dejneka
    • C03C3097
    • C03C10/0009C03C3/062C03C3/097C03C10/0072
    • The present invention relates to a glass matrix which includes 4-70 wt. % SiO2, 0.5-20 wt. % Al2O3, 0-20 wt. % R2O, 0-30 wt. % R′O, 8-85 wt. % Ta2O5, 0-40 wt. % Nb2O5, and 0.01-1.0 wt. % R″2O3, where R2O+R″O is between about 2-35 wt. %, Ta2O5+Nb2O5 is between about 8-85 wt. %, R is selected from a group consisting of Li, Na, K, and combinations thereof, R′ is selected from a group consisting of Ba, Sr, Ca, Mg, Zn, Pb, and combinations thereof, and R″ is a rare earth element. The present invention also relates to use of the glass matrix in forming optic waveguides such as optic amplifiers. The present invention further relates to a transparent glass ceramic that contains pyrochlore, perovskite, or a combination thereof as its major crystal phase, and includes 4-40 wt. % SiO2, 1-15 wt. % Al2O3, 0-20 wt. % K2O, 0-12 wt. % Na2O, 0-5 wt. % Li2O, 8-85 wt. % Ta2O5, and 0-45 wt. % Nb2O5, wherein Ta2O5+Nb2O5 is at least about 20 wt. % and (K2O+Li2O+Na2O) is between about 5-20 wt. %. Also disclosed is a method of making the glass ceramic and use of the glass ceramic as a ferro-electric component in electro-optical devices or as a filtering core in an optical filtering device.
    • 本发明涉及一种玻璃基质,其包含4-70wt。 %SiO 2,0.5-20重量% %Al2O3,0-20wt。 %R 2 O,0-30重量% %R'O,8-85wt。 %Ta2O5,0-40wt。 %Nb2O5和0.01-1.0wt。 %R“2 O 3,其中R 20 + R”O为约2-35重量% %,Ta 2 O 5 + Nb 2 O 5为约8-85wt。 %,R选自Li,Na,K及其组合,R'选自Ba,Sr,Ca,Mg,Zn,Pb及其组合,R“为 稀土元素。 本发明还涉及玻璃基质在诸如光放大器之类的光波导中的应用。 本发明还涉及含有烧绿石,钙钛矿或其组合作为其主要结晶相的透明玻璃陶瓷,并且包括4-40重量% %SiO 2,1-15wt。 %Al2O3,0-20wt。 %K2O,0-12wt。 %Na 2 O,0-5wt。 %Li 2 O,8-85wt。 %Ta2O5和0-45wt。 %Nb 2 O 5,其中Ta 2 O 5 + Nb 2 O 5为至少约20wt。 %和(K 2 O + Li 2 O + Na 2 O)为约5-20wt。 %。 还公开了一种制造玻璃陶瓷的方法,并且将玻璃陶瓷用作电光器件中的铁电部件或光过滤装置中的滤芯。
    • 6. 发明授权
    • Molecular, inorganic glasses
    • 分子,无机眼镜
    • US06503859B1
    • 2003-01-07
    • US09894587
    • 2001-06-28
    • Bruce G. Aitken
    • Bruce G. Aitken
    • C03C332
    • C03C3/321C03C4/10
    • The invention resides in a molecular, inorganic glass and a method of making the glass, the glass being vitreous and resistant to devitrification, that is composed, in substantial part at least, of thermally-stable, zero-dimensional clusters or molecules, composed of four atoms of arsenic and three atoms of sulfur, the glass further containing up to 12 atomic percent of germanium, adjoining clusters being bonded to each other primarily by van der Waals forces, and at least 95% of the glass composition consisting of 42-60% arsenic, 37-48% sulfur plus selenium, the selenium being 0-14%.
    • 本发明在于一种分子,无机玻璃和一种制造玻璃,玻璃是玻璃体并且耐失透的方法,其至少部分地由热稳定的零维簇或分子组成,其由 四个原子的砷和三个原子的硫,玻璃还含有最多12原子%的锗,相邻的簇主要通过范德华力彼此结合,并且至少95%的玻璃组合物由42-60 %砷,37-48%硫加硒,硒为0-14%。