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1. 发明授权

US5698647A Preparation of polymers based on basic vinyl monomers 失效
标题翻译：基于乙烯基单体的聚合物的制备
公开(公告)号：US5698647A
公开(公告)日：1997-12-16
申请号：US697724
申请日：1996-08-29
申请人： Brigitta Huckestein , Volker Schehlmann , Axel Sanner , Rainer Blankenburg
发明人： Brigitta Huckestein , Volker Schehlmann , Axel Sanner , Rainer Blankenburg
IPC分类号： C08F2/10 , C08F4/04 , C08F20/34 , C08F26/00 , C08F2/16
CPC分类号： C08F26/00 , C08F2/10 , C08F20/34
摘要： A process for the preparation of low-hydrazine polymers based on basic vinyl monomers by free-radical solution polymerization in aqueous medium in the presence, as compound which forms free radicals, of an azo compound which has alkoxycarbonyl groups on the carbon atoms adjacent to the azo group.
摘要翻译：在水介质中通过自由基溶液聚合制备基于乙烯基单体的低肼聚合物的方法，作为形成自由基的化合物，在邻近碳原子上的碳原子上具有烷氧基羰基的偶氮化合物偶氮类。

2. 发明授权

US06482393B1 Hairsetting compositions 失效
标题翻译：发胶组合物
公开(公告)号：US06482393B1
公开(公告)日：2002-11-19
申请号：US08537908
申请日：1995-10-26
申请人： Volker Schehlmann , Karin Sperling-Vietmeier , Axel Sanner , Rainer Blankenburg
发明人： Volker Schehlmann , Karin Sperling-Vietmeier , Axel Sanner , Rainer Blankenburg
IPC分类号： A61K711
CPC分类号： A61Q5/06 , A61K8/8147
摘要： Hairsetting compositions comprise as film-formers copolymers based on tert-butyl acrylate or tert-butyl methacrylate having a K value of from 10 to 50 which are obtainable by free-radical polymerization of A) from 30 to 72% by weight of tert-butyl acrylate or tert-butyl methacrylate or a mixture thereof as monomer A, B) from 10 to 28% by weight of acrylic acid or methacrylic acid or a mixture thereof as monomer B, and C) from 0 to 60% by weight of a free-radically copolymerizable monomer or of a free-radically copolymerizable monomer mixture as monomers C, where at least one of the monomers C produces a homopolymer having a glass transition temperature of less than 30° C., the carboxyl groups of the copolymers being partially or completely neutralized.
摘要翻译：毛发组合物包含作为成膜剂的基于丙烯酸叔丁酯或甲基丙烯酸叔丁酯的共聚物，其K值为10至50，可通过A）的自由基聚合获得30至72重量％的丙烯酸叔丁酯或甲基丙烯酸叔丁酯或其混合物作为单体A，B）10-28重量％的丙烯酸或甲基丙烯酸或其作为单体B的混合物，和C）0至60重量％的自由基可共聚单体或可自由基共聚的单体混合物作为单体C，其中至少一种单体C产生玻璃化转变温度低于30℃的均聚物，共聚物的羧基被部分或完全中和。

3. 发明授权

US06403074B1 Use of polymers containing polysiloxane for cosmetic formulations 有权
标题翻译：含聚硅氧烷的聚合物用于化妆品配方
公开(公告)号：US06403074B1
公开(公告)日：2002-06-11
申请号：US09462609
申请日：2000-01-11
申请人： Rainer Blankenburg , Reinhold Dieing , Wolfgang Müller , Axel Sanner , Volker Schehlmann , Katrin Zeitz
发明人： Rainer Blankenburg , Reinhold Dieing , Wolfgang Müller , Axel Sanner , Volker Schehlmann , Katrin Zeitz
IPC分类号： A61K706
CPC分类号： A61K8/893 , A61Q5/04 , A61Q5/06 , A61Q5/12
摘要： Process for preparing polymers which are water-soluble or water-dispersible or which, if consisting of monomers with neutralizable radicals, are soluble in water or dispersible in water in neutralized form, by subjecting (a) ethylenically unsaturated monomers to free-radical polymerization in the presence of (b) polyalkylene oxide-containing silicone derivatives.
摘要翻译：制备水溶性或水分散性聚合物的方法，或者如果由具有可中和基团的单体组成的方法可溶于水或以中和形式分散在水中，则通过使（a）烯属不饱和单体进行自由基聚合（b）含聚环氧烷烃的有机硅衍生物的存在。

4. 发明授权

US5461159A Binding chemical impurities contained in crude N-vinylpyrrolid-2-one 失效
标题翻译：包含在粗N-乙烯基吡咯烷酮-2-酮中的化学杂质的结合
公开(公告)号：US5461159A
公开(公告)日：1995-10-24
申请号：US387569
申请日：1995-02-13
申请人： Brigitta Huckestein , Rainer Blankenburg , Herbert Helfert
发明人： Brigitta Huckestein , Rainer Blankenburg , Herbert Helfert
IPC分类号： C07D207/26 , C07D207/267 , C08F26/06
CPC分类号： C07D207/267 , C08F26/06
摘要： Chemical impurities contained in N-vinylpyrrolid-2-one are bound by a process in which the anhydride of an organic carboxylic acid is added to the crude N-vinylpyrrolid-2-one.
摘要翻译：包含在N-乙烯基吡咯烷-2-酮中的化学杂质通过将有机羧酸的酸酐加入到粗N-乙烯基吡咯烷-2-酮中的方法结合。

5. 发明授权

US6107397A Aqueous copolymer dispersions of water-soluble monomers with N-vinyl groups and hydrophobic monomers 失效
标题翻译：水溶性单体与N-乙烯基和疏水性单体的水共聚物分散体
公开(公告)号：US6107397A
公开(公告)日：2000-08-22
申请号：US42744
申请日：1998-03-17
申请人： Rainer Blankenburg , Volker Schehlmann , Karl Kolter
发明人： Rainer Blankenburg , Volker Schehlmann , Karl Kolter
IPC分类号： C08F2/22 , A61K9/50 , C08F4/04 , C08F4/28 , C08F4/30 , C08F226/00 , C08L39/04 , C08L39/06
CPC分类号： A61K9/5026 , C08F226/00
摘要： An aqueous copolymer dispersion is prepared by free-radical emulsion co-polymerization of a monomer mixture ofi) from 10 to 70% by weight of at least one nonionic monomer A having a water-solubility of more than 60 g/l at 25.degree. C., and being selected from the group consisting of N-vinyllactams having from 6 to 8 carbon atoms, N-vinylformamide and N-methyl-N-vinylacetamide,ii) from 30 to 90% by weight of at least one monoethylenically unsaturated hydrophobic monomer B having a water-solubility of less than 60 g/l at 25.degree. C.,and optionally further comprisingiii) up to 5% by weight of at least one monoethylenically unsaturated monomer C which has at least one ionic and/or ionizable functional group,iv) up to 10% by weight of at least one monomer D which has at least 2 ethylenically unsaturated bonds,v) up to 20% by weight of at least one further monoethylenically unsaturated monomer E, which is different from the monomers A and C, and has a water-solubility of >60 g/l at 25.degree. C.,in the presence of a water-soluble polymerization initiator in water or an aqueous solvent.
摘要翻译：通过自由基乳液共聚制备水性共聚物分散体，该单体混合物为i）10至70重量％的至少一种在25℃下具有大于60g / l的水溶性的非离子单体A 并且选自具有6至8个碳原子的N-乙烯基内酰胺，N-乙烯基甲酰胺和N-甲基-N-乙烯基乙酰胺，ii）30至90重量％的至少一种单烯属不饱和疏水性单体B在25℃具有小于60g / l的水溶性，并且任选地还包含iii）至多5重量％的至少一种具有至少一个离子和/或可离子化的单烯属不饱和单体C 官能团，iv）至多10重量％的至少一种具有至少2个烯键式不饱和键的单体D，v）至多20重量％的至少一种另外的单烯属不饱和单体E，其不同于单体 A和C，并且在25℃下的水溶解度> 60g / l 在水或水溶剂中存在水溶性聚合引发剂的情况下。

6. 发明授权

US5635169A Soluble copolymers for hair cosmetics 失效
标题翻译：头发化妆品的可溶性共聚物
公开(公告)号：US5635169A
公开(公告)日：1997-06-03
申请号：US548726
申请日：1995-10-26
申请人： Rainer Blankenburg , Axel Sanner
发明人： Rainer Blankenburg , Axel Sanner
IPC分类号： A61K8/00 , A61K8/81 , A61Q5/00 , C08F2/06 , C08F26/00 , C08F226/06 , A61K7/06
CPC分类号： C08F226/06 , A61K8/8182 , A61Q5/00
摘要： Copolymers which have K values of from 30 to 50 are obtainable by free radical solution polymerization ofA) from 15 to 84.99% by weight of at least one monomer selected from the group consisting of N-vinylpyrrolidone, N-vinylcaprolactam and N-vinylimidazole,B) from 15 to 84.99% by weight of further monoolefinically unsaturated monomers capable of free radical copolymerization andC) from 0.01 to 2% by weight of at least one monomer capable of free radical copolymerization and having at least two non-conjugated olefinic double bondsin alcoholic solution.
摘要翻译：具有30至50的K值的共聚物可以通过A）的自由基溶液聚合获得15至84.99重量％的至少一种选自N-乙烯基吡咯烷酮，N-乙烯基己内酰胺和N-乙烯基咪唑的单体， B）15至84.99重量％的能够进行自由基共聚的另外的单烯属不饱和单体，和C）0.01至2重量％的至少一种能够自由基共聚并具有至少两个非共轭烯属双键的单体在酒精溶液中。

7. 发明授权

US6153179A Hair setting lotions 失效
标题翻译：头发定型乳液
公开(公告)号：US6153179A
公开(公告)日：2000-11-28
申请号：US879775
申请日：1997-06-20
申请人： Rainer Blankenburg , Karin Sperling , Axel Sanner
发明人： Rainer Blankenburg , Karin Sperling , Axel Sanner
IPC分类号： A61K8/00 , A61K8/31 , A61K8/34 , A61K8/81 , A61K8/87 , A61K8/88 , A61Q5/06 , C08L31/02 , C08L31/04 , C08L33/04 , C08L39/00 , C08L39/04 , C08L75/00 , C08L75/04 , A61K7/11
CPC分类号： A61K8/8147 , A61K8/8152 , A61K8/8158 , A61K8/8164 , A61K8/817 , A61K8/8182 , A61K8/87 , A61K8/88 , A61Q5/06
摘要： Hair setting lotion which are not subject to hydrolysis and which are made up ofA) 0.5-20% by weight of a nonionic or anionic homo- or copolymer of at least 70% by weight of N-vinylcaprolactam (polymer A), andB) 0.5-20% by weight of a further film-forming polymer (polymer B), selected from the group consisting of polyamides, polyurethanes, and homo- and copolymers of monoolefinically unsaturated monomers.
摘要翻译：不经水解的头发定型洗剂，其由A）0.5-20重量％的至少70重量％的N-乙烯基己内酰胺（聚合物A）的非离子或阴离子均聚物或共聚物和B ）0.5-20重量％的另外的成膜聚合物（聚合物B），其选自聚酰胺，聚氨酯和单烯属不饱和单体的均聚物和共聚物。

8. 发明授权

US06187884B1 Preparation of low molecular mass homopolymers of N-vinylpyrrolidone 失效
标题翻译：低分子量N-乙烯基吡咯烷酮均聚物的制备
公开(公告)号：US06187884B1
公开(公告)日：2001-02-13
申请号：US09104174
申请日：1998-06-25
申请人： Stephan Kothrade , Rainer Blankenburg , Iris Peters , Axel Sanner
发明人： Stephan Kothrade , Rainer Blankenburg , Iris Peters , Axel Sanner
IPC分类号： C08F238
CPC分类号： C08F126/10
摘要： A process for preparing highly concentrated aqueous solutions of low molecular mass homopolymers of N-vinylpyrrolidone by free-radical solution polymerization in an aqueous medium with H2O2 as initiator comprises carrying out the polymerization in the presence of from 0.1 to 30% by weight, based on N-vinylpyrrolidone, of a polymerization regulator which is selected from the group consisting of C1-C6-alkanols, hydroxylamine salts and water-soluble compounds containing sulfur in bonded form.
摘要翻译：通过在具有H 2 O 2作为引发剂的水性介质中通过自由基溶液聚合制备N-乙烯基吡咯烷酮的低分子质量均聚物的高浓度水溶液的方法包括在0.1-30重量％的存在下进行聚合，基于聚合调节剂的N-乙烯基吡咯烷酮，其选自C1-C6-链烷醇，羟胺盐和含有键合形式的硫的水溶性化合物。

9. 发明授权

US6103820A Preparation of water-soluble copolymers of at least one water-soluble N-vinyllactam and at least one hydrophobic comonomer 失效
标题翻译：制备至少一种水溶性N-乙烯基内酰胺和至少一种疏水性共聚单体的水溶性共聚物
公开(公告)号：US6103820A
公开(公告)日：2000-08-15
申请号：US805547
申请日：1997-02-25
申请人： Rainer Blankenburg , Stephan Kothrade , Axel Sanner
发明人： Rainer Blankenburg , Stephan Kothrade , Axel Sanner
IPC分类号： A01N25/00 , A61K8/81 , A61K47/32 , A61Q5/06 , A61Q19/00 , C08F2/10 , C08F2/38 , C08F4/04 , C08F226/06 , C08K3/20
CPC分类号： A61Q5/06 , A61K47/32 , A61K8/817 , A61K8/8182 , A61Q19/00 , C08F226/06
摘要： The present invention relates to a novel process for preparing water-soluble copolymers of at least one water-soluble N-vinyllactam of the formula I ##STR1## where n=1 or 2, and at least one hydrophobic comonomer having a water-solubility of 1 to 85 g/l, by free-radical polymerization in aqueous solution.
摘要翻译：本发明涉及制备至少一种n = 1或2的式I的水溶性N-乙烯基内酰胺和至少一种水溶性为1至85的疏水性共聚单体的水溶性共聚物的新方法 g / l，通过在水溶液中的自由基聚合。

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