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1. 发明申请

US20070078249A1 Polymerisation catalysts 有权
标题翻译：聚合催化剂
公开(公告)号：US20070078249A1
公开(公告)日：2007-04-05
申请号：US11601739
申请日：2006-11-20
申请人： Brian Kimberley , Peter Maddox , Stephen Partington
发明人： Brian Kimberley , Peter Maddox , Stephen Partington
IPC分类号： C08F210/00
CPC分类号： C07D213/53 , C07F13/005 , C07F15/0053 , C07F15/025 , C07F15/065 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C08F2410/04 , Y10S526/943 , C08F4/61904 , C08F4/60089 , C08F4/6541 , C08F4/025 , C08F2500/04 , C08F2500/07 , C08F2500/12 , C08F210/14 , C08F2500/10 , C08F2500/26 , C08F2500/03 , C08F4/7042
摘要： A catalyst for the polymerisation of 1-olefins is disclosed, which comprises (1) a compound of Fotmula B wherein M is Fe[II], Fe[III], Co[I], Co[II], Co[III], Mn[I], Mn[II], Mn[III], Mn[IV], Ru[II], Ru[III] or Ru[IV]; X represents an atom or group covalently or ionically bonded to the transition metal M; T is the oxidation state of the transition metal M and b is the valency of the atom or group X; R1, R2, R3, R4, R5, R6 and R7 are independently selected from hydrogen, halogen, hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl or substituted heterohydrocarbyl; and when any two or more of R1-R7 are hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl or substituted heterohydrocarbyl, said two or more can be linked to form one or more cyclic substituents; and (2) a further catalyst. Copolymers made using the catalyst having specific physical properties arm also disclosed.
摘要翻译：公开了用于1-烯烃聚合的催化剂，其包括（1）Fotmula B的化合物，其中M是Fe [II]，Fe [III]，Co [I]，Co [II]，Co [III] Mn [I]，Mn [II]，Mn [III]，Mn [IV]，Ru [II]，Ru [III]或Ru [IV] X表示与过渡金属M共价或离子键合的原子或基团; T是过渡金属M的氧化态，b是原子或基团X的化合价; R 1，R 2，R 3，R 4，R 5， R 6和R 7独立地选自氢，卤素，烃基，取代的烃基，杂烃基或取代的杂烃基; 当R 1〜R 2中的任意两个以上为烃基，取代烃基，杂烃基或取代的杂烃基时，所述两个或多个可以连接形成一个或多个环状取代基; 和（2）另外的催化剂。还公开了使用具有特定物理性能的催化剂制备的共聚物。

2. 发明申请

US20050227860A1 Polymerisation catalyst 审中-公开
标题翻译：聚合催化剂
公开(公告)号：US20050227860A1
公开(公告)日：2005-10-13
申请号：US10512282
申请日：2003-04-17
申请人： Simon Green , Hoyt Griffin , Brian Kimberley , Peter Maddox , Roger Uhrhammer
发明人： Simon Green , Hoyt Griffin , Brian Kimberley , Peter Maddox , Roger Uhrhammer
IPC分类号： C07C215/50 , C07F7/00 , C07F7/28 , C08F4/642 , C08F4/645 , C08F4/649 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/06 , C08F210/16 , B01J31/00
CPC分类号： C07F7/28 , C07C215/50 , C07C2603/24 , C07F7/00 , C08F4/65908 , C08F4/65912 , C08F10/00 , C08F110/06 , C08F210/16 , C08F4/659 , C08F2500/04 , C08F2500/09 , C08F210/14 , C08F4/64189
摘要： A catalyst for polymerising 1-olefins, comprising (a) a tetradentate ligand I and II as illustrated in the specification wherein; D and D′ are phosphorus or nitrogen; Q and Q are bridging groups forming part of a ring; B is a bridging group between D and D′; R1 and R9 are each independently a polar group or phenyl, naphthyl, anthryl, phenanthryl, triptycyl or a heteroaromatic ring; R5 to R8 are selected from hydrogen, halogen, hydrocarbyl, heterohydrocarbyl, NR′2, PR′2, OR′, SR′ or SiR′3 where each R′ is independently selected from hydrogen, halogen, hydrocarbyl, heterohydrocarbyl, and any adjacent groups may be joined together to form a ring; in the case I, A and A′ are independently OH, 0−, SH, S−, NR″H, R″N−, PR″H or R″P−; and in the case II A and A′ are independently NH, N−, PH or P−, where R″ is defined as for groups R5 to R9 above; and R5 and R5′, R6 and R6′, or R7 and R8 may be joined together to form a ring; (b) a source of Group 3 to 10 transition metal or a lanthanide metal and optionally (c) an activator. Also claimed are transition metal complexes of the ligands and a process for (co)polymerising 1-olefins.
摘要翻译：用于聚合1-烯烃的催化剂，其包含（a）如本说明书中所述的四齿配体I和II，其中： D和D'是磷或氮; Q和Q是形成环的一部分的桥连基团; B是D和D'之间的桥接组; R 1和R 9各自独立地是极性基团或苯基，萘基，蒽基，菲基，三庚基或杂芳族环; R 5至R 8选自氢，卤素，烃基，杂烃基，NR'2，PR 2，/ SUB >，OR'，SR'或SiR'3，其中每个R'独立地选自氢，卤素，烃基，杂烃基和任何相邻基团可以连接在一起形成环; 在I，A和A'独立地为OH的情况下，O - ， - SO - ， - SO - ， - SO - SUP>，PR''H或R''P ; 并且在IIA和A'独立地为NH，N - ， - PH或P - ，其中R“定义为基团R 5， / SUP>至R 9以上; 和R 5和R 5'，R 6和R 6'或R 7' / SUP>和R＆lt; 8＆gt;可以连接在一起形成环; （b）3至10族过渡金属或镧系元素金属的源和任选的（c）活化剂。还要求的是配体的过渡金属络合物和（共）聚合1-烯烃的方法。

3. 发明申请

US20070135296A1 Supported polymerisation catalysts 失效
标题翻译：负载型聚合催化剂
公开(公告)号：US20070135296A1
公开(公告)日：2007-06-14
申请号：US10568822
申请日：2004-08-04
申请人： Grant Jacobsen , Brian Kimberley , Sergio Mastroianni
发明人： Grant Jacobsen , Brian Kimberley , Sergio Mastroianni
IPC分类号： B01J31/00 , C08F4/44
CPC分类号： C08F210/16 , C08F4/65908 , C08F4/65916 , C08F4/6592 , C08F2420/02 , C08F4/65912 , C08F210/14
摘要： A supported polymerisation catalyst system comprises a porous support, a polymerisation catalyst and a cocatalyst wherein the support has been treated with an inert material such as polyisobutene. The support is preferably silica and is preferably treated with the inert material prior to contact with the other components. Preferably the polymerisation catalyst is a metallocene and the polymerisation catalyst system reduces the initial peak isotherm allowing for a smoother activity increase in particular for polymerisations carried out in the gas phase.
摘要翻译：负载型聚合催化剂体系包括多孔载体，聚合催化剂和助催化剂，其中载体已用惰性材料如聚异丁烯处理。载体优选为二氧化硅，并且优选在与其它组分接触之前用惰性材料处理。优选地，聚合催化剂是茂金属，并且聚合催化剂体系降低了初始峰值等温线，从而允许更平滑的活性增加，特别是对于在气相中进行的聚合反应。

4. 发明申请

US20060094838A1 Enhanced polyolefin catalyst 有权
标题翻译：增强聚烯烃催化剂
公开(公告)号：US20060094838A1
公开(公告)日：2006-05-04
申请号：US10977949
申请日：2004-10-29
申请人： Mark Kelly , Shivendra Goyal , Victoria Ker , Perry de Wit , Brian Kimberley
发明人： Mark Kelly , Shivendra Goyal , Victoria Ker , Perry de Wit , Brian Kimberley
IPC分类号： C08F4/44 , B01J31/00
CPC分类号： C08F10/00 , C08F210/16 , C08F4/651 , C08F4/6555 , C08F4/025 , C08F210/14 , C08F2500/12
摘要： The present invention provides a novel process for preparing a catalyst useful in gas phase polymerization of olefins wherein the physical properties of the polymer and the productivity of the catalyst can be altered depending on the sequence of addition of the catalyst components. The catalyst consists of compounds of Ti, Mg, Al and optionally an electron donor supported on an amorphous support.
摘要翻译：本发明提供了一种制备可用于烯烃气相聚合的催化剂的新方法，其中聚合物的物理性质和催化剂的生产率可以根据催化剂组分的添加顺序而改变。催化剂由Ti，Mg，Al的化合物和任选的负载在非晶形载体上的电子给体组成。

5. 发明申请

US20060154808A1 Supported polymerisation catalysts 失效
标题翻译：负载型聚合催化剂
公开(公告)号：US20060154808A1
公开(公告)日：2006-07-13
申请号：US10523828
申请日：2003-08-14
申请人： Grant Jacobsen , Brian Kimberley , Sergio Mastroianni , Michael Taylor
发明人： Grant Jacobsen , Brian Kimberley , Sergio Mastroianni , Michael Taylor
IPC分类号： B01J31/00 , C08F4/02 , C08F4/44
CPC分类号： C08F210/16 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F4/65916 , C08F210/14 , C08F2500/12 , C08F2500/11
摘要： A method for the preparation of a supported transition metal catalyst system which includes the steps of: (i) mixing together in a suitable solvent (a) an aluminoxane and (b) an ionic activator containing a cation and an anion, wherein the anion has at least one substituent containing a moiety having an active hydrogen, (ii) addition of the mixture from step (i) to a support material, and (iii) addition of a transition metal compound in a suitable solvent. The use of tetraisobutylaluminoxane as the aluminoxane results in a more stable activity profile and improved polymer properties in particular melt strength.
摘要翻译：一种制备负载型过渡金属催化剂体系的方法，其包括以下步骤：（i）在合适的溶剂（a）铝氧烷和（b）含有阳离子和阴离子的离子活化剂中混合在一起，其中阴离子具有至少一个含有具有活性氢的部分的取代基，（ii）将步骤（i）的混合物加入到载体材料中，和（iii）在合适的溶剂中加入过渡金属化合物。使用四异丁基铝氧烷作为铝氧烷导致更稳定的活性分布和改进的聚合物性质，特别是熔体强度。

6. 发明申请

US20060100402A1 Supported olefin polymerization catalyst 失效
标题翻译：负载型烯烃聚合催化剂
公开(公告)号：US20060100402A1
公开(公告)日：2006-05-11
申请号：US10539557
申请日：2003-12-03
申请人： Grant Jacobsen , Brian Kimberley , Claudine Lalanne-Magne , Sergio Mastroianni
发明人： Grant Jacobsen , Brian Kimberley , Claudine Lalanne-Magne , Sergio Mastroianni
IPC分类号： C08F4/44 , B01J31/00
CPC分类号： C08F10/02 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F210/16 , C08F4/025 , C08F4/65916 , C08F210/14 , C08F2500/12
摘要： Supported catalyst systems are provided comprising (a) a transition metal compound, (b) an activator comprising (iii) an aluminoxane or (iv) a Group IIIA metal or metalloid compound, and (c) a support material comprising an inorganic metal oxide, inorganic metal halide or polymeric material or mixtures thereof characterised in that the support material has been pretreated with a source of a transition metal atom. The preferred transition metal compounds are metallocenes and the source of the transition metal atom is typically a ferrous or cupric metal salt. The supported catalyst systems show improved activity and also may reduce fouling in gas phase fluidised bed processes.
摘要翻译：提供了负载催化剂体系，其包括（a）过渡金属化合物，（b）活化剂，其包含（iii）铝氧烷或（iv）IIIA族金属或准金属化合物，和（c）包含无机金属氧化物的载体材料，无机金属卤化物或聚合物材料或其混合物，其特征在于支撑材料已用过渡金属原子源预处理。优选的过渡金属化合物是金属茂，过渡金属原子的来源通常是亚铁或二价金属盐。负载型催化剂体系显示出改善的活性，并且还可以减少气相流化床方法中的结垢。

7. 发明申请

US20060247397A1 Supported olefin polymerization catalyst 审中-公开
标题翻译：负载型烯烃聚合催化剂
公开(公告)号：US20060247397A1
公开(公告)日：2006-11-02
申请号：US10539573
申请日：2003-12-03
申请人： Grant Jacobsen , Brian Kimberley , Sergio Mastroianni
发明人： Grant Jacobsen , Brian Kimberley , Sergio Mastroianni
IPC分类号： C08F4/44
CPC分类号： C08F210/16 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F4/65916 , C08F210/14 , C08F2500/12 , C08F2500/04
摘要： A supported catalyst system comprises (a) a dehydrated support material, (b) a transition metal compound, and (c) an activator and is characterised in that the support material has been pretreated with at least two different organoaluminum compounds prior to contact with either or both the transition metal compound or the activator. The preferr transition metal compound is a metallocene and the supported catalyst systems are suitable for the preparation of polymers having broad molecular weight distributions and improved melt strength.
摘要翻译：负载的催化剂体系包括（a）脱水的载体材料，（b）过渡金属化合物和（c）活化剂，其特征在于，在与二种不同的有机铝化合物接触之前，用至少两种不同的有机铝化合物预处理或过渡金属化合物或活化剂两者。优选的过渡金属化合物是茂金属，并且负载的催化剂体系适用于制备具有宽分子量分布和改善的熔体强度的聚合物。

8. 发明申请

US20060223695A1 Supported polymerisation catalysts 有权
标题翻译：负载型聚合催化剂
公开(公告)号：US20060223695A1
公开(公告)日：2006-10-05
申请号：US10568954
申请日：2004-08-04
申请人： Grant Jacobsen , Brian Kimberley , Sergio Mastroianni
发明人： Grant Jacobsen , Brian Kimberley , Sergio Mastroianni
IPC分类号： B01J31/00
CPC分类号： C08F210/16 , C08F4/65908 , C08F4/65916 , C08F4/6592 , C08F2420/02 , C08F4/65912 , C08F210/14
摘要： A supported polymerization catalyst system is prepared by a method comprising the following steps: (i) addition of a cocatalyst to a porous support, (ii) mixing a polymerisation catalyst with a polymerisable monomer, and (iii) contacting together the components resulting from steps (i) and (ii). The porous support is preferably silica and the polymerisation catalyst is preferably a metallocene. The polymerisable monomer is typically 1-hexene and the supported catalyst system provides advantages a slowly decaying activity profile particularly when operating in the gas phase.
摘要翻译：通过包括以下步骤的方法制备负载型聚合催化剂体系：（i）向多孔载体中加入助催化剂，（ii）将聚合催化剂与可聚合单体混合，和（iii）将由步骤（i）和（ii）。多孔载体优选为二氧化硅，聚合催化剂优选为金属茂。可聚合单体通常是1-己烯，并且负载的催化剂体系特别是当在气相中操作时，具有缓慢衰变的活性分布的优点。

9. 发明申请

US20060100091A1 Supported olefin polymerization catalyst 失效
标题翻译：负载型烯烃聚合催化剂
公开(公告)号：US20060100091A1
公开(公告)日：2006-05-11
申请号：US10539518
申请日：2003-12-03
申请人： Grant Jacobsen , Brian Kimberley , Claudine Lalanne-Magne , Sergio Mastroianni
发明人： Grant Jacobsen , Brian Kimberley , Claudine Lalanne-Magne , Sergio Mastroianni
IPC分类号： B01J31/00
CPC分类号： C08F210/16 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F4/65916 , C08F210/14 , C08F2500/12
摘要： Supported catalyst systems are provided comprising (a) a transition metal compound, (b) a non aluminoxane activator comprising, and (c) a support material comprising an inorganic metal oxide, inorganic metal halide or polymeric material or mixtures thereof characterised in that the support material has been pretreated with an SO4 contianing compound. The preferred transition metal compounds are metallocenes and the SO4 containing compound is typically sulphuric acid. The supported catalyst systems show improved activity and also may reduce fouling in gas phase fluidised bed processes.
摘要翻译：提供了负载型催化剂体系，其包括（a）过渡金属化合物，（b）非铝氧烷活化剂，其包含和（c）包含无机金属氧化物，无机金属卤化物或聚合物材料或其混合物的载体材料或其混合物，其特征在于，材料已经用SO 4 SO 4化合物预处理。优选的过渡金属化合物是金属茂，含SO 4的化合物通常是硫酸。负载型催化剂体系显示出改善的活性，并且还可以减少气相流化床方法中的结垢。

10. 发明申请

US20050245699A1 Olefin polymerisation process 失效
标题翻译：烯烃聚合方法
公开(公告)号：US20050245699A1
公开(公告)日：2005-11-03
申请号：US10525730
申请日：2003-08-06
申请人： Grant Jacobsen , Brian Kimberley , Sergio Mastroianni
发明人： Grant Jacobsen , Brian Kimberley , Sergio Mastroianni
IPC分类号： C08F210/00 , C08F2/34 , C08F4/658 , C08F4/659 , C08F4/6592 , C08F10/02 , C08F210/16 , C08F4/44
CPC分类号： C08F210/16 , C08F4/65916 , C08F4/6592 , C08F110/06 , C08F4/65908 , C08F4/65912 , C08F210/14
摘要： A process for the homopolymerisation of ethylene or the copolymerisation of ethylene and (a-olefins in a polymeristation reactor, said process carried out in the presence of a catalyst system comprising (a) a polymerisation catalyst and (b) an ionic activator is characterised in that an organometallic compound of a Group IIIB metal having at least one unit of formula: Mç0çR or Mç0çM where M is the Group IIIB metal and R is a hydrocarbyl group is added to the reactor. Preferred organometallic compounds include aluminoxanes and the process results in improved poison scavenging as well as advantages in activity profiles, catalyst activity and product characteristics. The process is particularly suitable for use with supported metallocene catalyst systems in the slurry or gas phase.
摘要翻译：乙烯均聚或乙烯与聚合反应器中的（α-烯烃）共聚合的方法，所述方法是在包含（a）聚合催化剂和（b）离子活化剂的催化剂体系存在的情况下进行的，其特征在于具有至少一个式：Mç0çR或Mç0çM的单元的IIIB族金属的有机金属化合物，其中M是IIIB族金属，R是烃基，优选的有机金属化合物包括铝氧烷，并且该方法得到改进毒物清除以及活性特性，催化剂活性和产品特性的优点，该方法特别适用于在浆液或气相中负载的茂金属催化剂体系。

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