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1. 发明申请

WO2004050722A1 ZIEGLER NATTA CATALYST SYSTEM AND POLYMERISATION PROCESS USING SAID ZN CATALYST SYSTEM FOR PRODUCING ETHYLENE COPOLYMERS HAVING A BROAD MOLECULAR WEIGHT DISTRIBUTION 审中-公开
标题翻译： ZIEGLER NATTA催化剂体系和聚合工艺使用ZNA催化剂系统生产具有宽带分子量分布的乙烯共聚物
公开(公告)号：WO2004050722A1
公开(公告)日：2004-06-17
申请号：PCT/EP2002/013505
申请日：2002-11-29
申请人： BOREALIS TECHNOLOGY OY , CHU, Kyung-Jun , GAROFF, Thomas , WALDVOGEL, Päivi
发明人： CHU, Kyung-Jun , GAROFF, Thomas , WALDVOGEL, Päivi
IPC分类号： C08F10/00
CPC分类号： C08F10/02 , C08F110/02 , C08F4/642 , C08F4/6567 , C08F4/6555 , C08F2/001 , C08F2500/12 , C08F2500/19
摘要： The application relates to a catalyst system for the polymerisation of ethylene with C 3 -C 10 olefins and to a polymerisation process making use of said catalyst system for producing ethylene polymers having a broad molecular weight distribution as well as to the polymers obtained by such process.
摘要翻译：本申请涉及乙烯与C 3 -C 10烯烃聚合的催化剂体系，以及利用所述催化剂体系生产具有宽分子量分布的乙烯聚合物的聚合方法以及通过这种方法得到的聚合物。

2. 发明申请

WO2009027379A1 SOLID VANADIUM-CONTAINING ZIEGLER-NATTA CATALYST SYSTEM 审中-公开
标题翻译：固体含钒的齐格勒 - 纳塔尔催化剂体系
公开(公告)号：WO2009027379A1
公开(公告)日：2009-03-05
申请号：PCT/EP2008/061101
申请日：2008-08-26
申请人： BOREALIS TECHNOLOGY OY , GAROFF, Thomas , WALDVOGEL, Päivi , KALLIO, Kalle , GUSTAFSSON, Bill
发明人： GAROFF, Thomas , WALDVOGEL, Päivi , KALLIO, Kalle , GUSTAFSSON, Bill
IPC分类号： C08F4/68 , C08F4/685 , C08F210/16
CPC分类号： C08F10/00 , C08F210/16 , C08F4/685 , C08F4/68 , C08F210/14 , C08F2500/08 , C08F2500/03 , C08F2500/20 , C08F210/08
摘要： Solid Ziegler-Natta catalyst system for the (co)polymerisation of ethylene, said catalyst system comprising 1 ) a solid procatalyst formed by contacting at least: a) a Mg-alcoholate complex of the formula (I): Mg(OR 1 ) 2 -n (R 1 ) n , wherein each R 1 independently represents a C 1 -C 20 hydrocarbyl group and 0 1 ) m X 3-m , wherein each R 1 independently represents an alkyl of up to 6 carbon atoms; each X is independently a halogen; 0 1 -C 20 -alkyl group, 0
摘要翻译：用于乙烯（共）聚合的固体齐格勒 - 纳塔催化剂体系，所述催化剂体系包括1）通过使至少与下列物质接触形成的固体前催化剂：a）式（I）的Mg-醇盐络合物：Mg（OR 1）2 - n（R1）n，其中每个R1独立地表示C1-C20烃基和0,1 ... mX3-m，其中每个R1独立地表示至多6个碳原子的烷基; 每个X独立地是卤素; 0

3. 发明申请

WO2004055069A1 METHOD FOR THE PREPARATION OF OLEFIN POLYMERISATION CATALYST SUPPORT AND AN OLEFIN POLYMERISATION CATALYST 审中-公开
标题翻译：烯烃聚合催化剂支持和烯烃聚合催化剂的制备方法
公开(公告)号：WO2004055069A1
公开(公告)日：2004-07-01
申请号：PCT/FI2003/000687
申请日：2003-09-19
申请人： BOREALIS TECHNOLOGY OY , GAROFF, Thomas , WALDVOGEL, Päivi , PESONEN, Kari
发明人： GAROFF, Thomas , WALDVOGEL, Päivi , PESONEN, Kari
IPC分类号： C08F110/02
CPC分类号： C08F10/00 , B01J31/0212 , B01J2231/122 , B01J2531/22 , C08F110/02 , C08F210/16 , C08F4/6548 , C08F4/6555 , C08F4/6546 , C08F2500/24 , C08F2500/18 , C08F2500/12 , C08F2500/04 , C08F210/14
摘要： The invention is directed to a process for producing a particulate support for an olefin polymerisation catalyst wherein a solution of a magnesium compound is contacted with a solution of an element of Group 13 or 14 of the Periodic Table (IUPAC) to obtain a solid reaction product. In the process of the invention the solid reaction product is formed by (i) contacting (a) a solution of a magnesium hydrocarbyloxy compound with (b) a solution of a halogencontaining compound of an element of Group 13 or 14 of the Periodic Table (IUPAC) at an elevated temperature; and (ii) recovering the solidified reaction product from the reaction mixture.
摘要翻译：本发明涉及一种用于生产烯烃聚合催化剂的颗粒载体的方法，其中将镁化合物的溶液与元素周期表（IUPAC）的第13或14族元素的溶液接触以获得固体反应产物。在本发明的方法中，固体反应产物通过以下步骤形成：（a）将（a）镁烃氧基化合物的溶液与（b）元素周期表第13或14族元素的含卤素化合物 IUPAC）; 和（ii）从反应混合物中回收固化的反应产物。

4. 发明申请

WO2004055068A1 METHOD FOR THE PREPARATION OF OLEFIN POLYMERISATION CATALYST SUPPORT AND AN OLEFIN POLYMERISATION CATALYST 审中-公开
标题翻译：烯烃聚合催化剂支持和烯烃聚合催化剂的制备方法
公开(公告)号：WO2004055068A1
公开(公告)日：2004-07-01
申请号：PCT/EP2002/014463
申请日：2002-12-18
申请人： BOREALIS TECHNOLOGY OY , GAROFF, Thomas , WALDVOGEL, Päivi , PESONEN, Kari
发明人： GAROFF, Thomas , WALDVOGEL, Päivi , PESONEN, Kari
IPC分类号： C08F110/02
CPC分类号： C08F10/00 , B01J31/0212 , B01J2231/122 , B01J2531/22 , C08F110/02 , C08F210/16 , C08F4/6548 , C08F4/6555 , C08F4/6546 , C08F2500/24 , C08F2500/18 , C08F2500/12 , C08F2500/04 , C08F210/14
摘要： The invention is directed to a process for producing a particulate support for an olefin polymerisation catalyst wherein a solution of a magnesium compound is contacted with a solution of an element of Group (13 or 14) of the Periodic Table (IUPAC) to obtain a solid reaction product. In the process of the invention the solid reaction product is formed by: i) contacting (a) a solution of a magnesium hydrocarbyloxy compound with (b) a solution of a halogen-containing compound of an element of Group (13 or 14) of the Periodic Table (IUPAC); and ii) recovering the solidified reaction product from the reaction mixture.
摘要翻译：本发明涉及一种用于生产烯烃聚合催化剂的颗粒载体的方法，其中将镁化合物的溶液与元素周期表（IUPAC）的第（13或14）族元素的溶液接触以获得固体反应产物。在本发明的方法中，固体反应产物通过以下步骤形成：i）使（a）镁烃氧基化合物的溶液与（b）（13）或（14）的元素的含卤化合物的溶液周期表（IUPAC）; 和ii）从反应混合物中回收固化的反应产物。

5. 发明申请

WO2009071324A1 POLYMER 审中-公开
标题翻译：聚合物
公开(公告)号：WO2009071324A1
公开(公告)日：2009-06-11
申请号：PCT/EP2008/010359
申请日：2008-12-05
申请人： BOREALIS TECHNOLOGY OY , ERIKSSON, Virginie , VAHTERI, Markku , VÄÄNÄNEN, Marjo , GAROFF, Thomas , HÄTÖNEN, Jari , REKONEN, Petri , FREDRIKSEN, Siw, Bodil , NORD-VARHAUG, Katrin , SEIM, Marit , NILSEN, Jorunn , HELLAND, Irene
发明人： ERIKSSON, Virginie , VAHTERI, Markku , VÄÄNÄNEN, Marjo , GAROFF, Thomas , HÄTÖNEN, Jari , REKONEN, Petri , FREDRIKSEN, Siw, Bodil , NORD-VARHAUG, Katrin , SEIM, Marit , NILSEN, Jorunn , HELLAND, Irene
IPC分类号： C08F210/16 , C08F2/00 , C08F297/08
CPC分类号： C08L23/0815 , C08F210/16 , C08F297/08 , C08F297/083 , C08L53/00 , C08L2205/02 , C08F2/001 , C08L2666/06 , C08L2666/02 , C08F210/08 , C08F210/14 , C08F2500/12 , C08F2500/05 , C08F2500/26 , C08F2500/07
摘要： A multimodal linear low density polyethylene polymer having a final density of 900 to 940 kg/m 3 , and containing at least one α-olefin comonomer in addition to ethylene comprising: (A) 30 to 60 wt% of a lower molecular weight component being an ethylene homopolymer or a copolymer of ethylene and at least one α-olefin; and (B) 70 to 40 wt% of a higher molecular weight component being a copolymer of ethylene and at least one α-olefin, said α-olefin being the same or different from any α-olefin used in component (A) but with the proviso that both components (A) and (B) are not polymers of ethylene and butene alone; wherein the multimodal LLDPE has a dart drop of at least 700 g; and wherein components (A) and (B) are obtainable using a Ziegler-Natta catalyst.
摘要翻译：一种多峰线型低密度聚乙烯聚合物，其最终密度为900至940kg / m 3，并且除乙烯外还包含至少一种α-烯烃共聚单体，其包含：（A）30至60重量％的较低分子量组分为乙烯均聚物或乙烯与至少一种α-烯烃的共聚物; 和（B）70至40重量％的较高分子量组分是乙烯和至少一种α-烯烃的共聚物，所述α-烯烃与组分（A）中使用的任何α-烯烃相同或不同，但与条件是组分（A）和（B）都不是单独的乙烯和丁烯的聚合物; 其中所述多峰LLDPE具有至少700g的滴滴; 并且其中组分（A）和（B）可以使用齐格勒 - 纳塔催化剂获得。

6. 发明申请

WO2009087036A1 USE OF AN IMPROVED SOLID VANADIUM-CONTAINING ZIEGLER-NATTA CATALYST SYSTEM FOR PRODUCING ETHYLENE POLYMER COMPOSITIONS IN A MULTISTAGE PROCESS 审中-公开
标题翻译：在多级过程中使用用于生产乙烯聚合物组合物的改进的含固体含钒纳米粒子催化剂体系
公开(公告)号：WO2009087036A1
公开(公告)日：2009-07-16
申请号：PCT/EP2008/067821
申请日：2008-12-18
申请人： Borealis Technology OY , GAROFF, Thomas , WALDVOGEL, Päivi , KALLIO, Kalle
发明人： GAROFF, Thomas , WALDVOGEL, Päivi , KALLIO, Kalle
IPC分类号： C08F210/16 , C08F4/685 , C08F2/00 , C08F297/08 , C08J5/18 , F16L9/12
CPC分类号： C08F210/16 , C08F110/02 , C08F4/685 , C08F2/001 , C08F210/14 , C08F2500/12 , C08F2500/18 , C08F2500/05 , C08F2500/26 , C08F2500/20
摘要： Improved method for tailoring the molecular weight distribution and comonomer incorporation of a multimodal ethylene polymer having a lower molecular weight component and a higher molecular weight component comprising polymerizing ethylene and optionally at least one further alpha-olefin in at least two stages, wherein at least one stage is carried out in a slurry phase in the presence of an improved solid Ziegler-Natta catalyst system, said catalyst system comprising 1) a solid procatalyst formed by contacting at least: a) a Mg-alcoholate complex of the formula (I): Mg(OR 1 ) 2-n (R 1 ) n , wherein each R 1 independently represents a C 1 -C 20 hydrocarbyl group; and 0 ≤ n 2 ) m X 3-m , wherein each R 2 independently represents an alkyl of up to 6 carbon atoms; each X is independently a halogen; 0 ≤ m 1 -C 20 -alkyl group, 0 ≤ x ≤ 2; 1 ≤ y ≤ 3; 0 ≤ z ≤ 2 and x + y + z = 3, x, y and z may or may not be an integer; a polymer obtainable by this method and use of such a polymer for the manufacture of pipes and films.
摘要翻译：用于定制具有较低分子量组分和较高分子量组分的多峰乙烯聚合物的分子量分布和共聚单体掺入的改进方法，包括在至少两个阶段聚合乙烯和任选的至少一种其它α-烯烃，其中至少一个在改进的固体齐格勒 - 纳塔催化剂体系的存在下，在淤浆相中进行阶段，所述催化剂体系包含1）通过使至少与下列物质接触而形成的固体前催化剂：a）式（I）的Mg-醇合物络合物： Mg（OR1）2-n（R1）n，其中每个R1独立地表示C1-C20烃基; 和0 = n 2）mX 3-m，其中每个R 2独立地表示至多6个碳原子的烷基; 每个X独立地是卤素; 0 = m <3和m，并且可以是或不是整数c）钒化合物和钛化合物，以提供V:Ti的摩尔比为99:1至1:99，以及d）任选的一个或更多的有机配体化合物，其选自包含环戊二烯基阴离子主链的有机化合物，以产生固体前催化剂和2）式（III）的一种或多种有机金属助催化剂，其中每个R为独立地为C 1 -C 20烷基，0 = x = 2; 1 = y = 3; 0 = z = 2，x + y + z = 3，x，y和z可以是整数; 可通过该方法获得的聚合物和这种聚合物用于制造管和膜的用途。

7. 发明申请

WO2007051607A1 ZIEGLER-NATTA CATALYST AND ITS USE TO PREPARE MULTIMODAL POLYOLEFIN 审中-公开
标题翻译： ZIEGLER-NATTA催化剂及其用于制备多组分聚氧乙烯
公开(公告)号：WO2007051607A1
公开(公告)日：2007-05-10
申请号：PCT/EP2006/010495
申请日：2006-11-01
申请人： BOREALIS TECHNOLOGY OY , LINDROOS, Jarmo , BACKMAN, Mats , GAROFF, Thomas , IDELMANN, Peter , JOHANSONN, Solveig , KO SOO, Young , STALHAMMAR, Minna , WALDVOGEL, Paivi
发明人： LINDROOS, Jarmo , BACKMAN, Mats , GAROFF, Thomas , IDELMANN, Peter , JOHANSONN, Solveig , KO SOO, Young , STALHAMMAR, Minna , WALDVOGEL, Paivi
IPC分类号： C08F4/649 , C08F4/651 , C08F2/00
CPC分类号： C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C08F4/651 , C08F2/001 , C08F2500/05 , C08F2500/12 , C08F2500/17 , C08F210/08
摘要： The present invention provides a method for tailoring the molecular weight distribution of a multimodal (e.g. bimodal) ethylene polymer having a lower molecular weight component and a higher molecular weight component comprising polymerising ethylene and optionally at least one further alpha olefin in at least two stages, wherein at least one stage is carried out in a slurry phase in the presence of a Ziegler Natta catalyst comprising an electron donor which is an ether.
摘要翻译：本发明提供了一种用于定制具有较低分子量组分和较高分子量组分的多峰（例如双峰））乙烯聚合物的分子量分布的方法，其包括在至少两个阶段聚合乙烯和任选的至少一种另外的α-烯烃，其中至少一个阶段在包含电子给体（即醚）的齐格勒纳塔催化剂存在下在淤浆相中进行。

8. 发明申请

WO2005118655A1 METHOD FOR THE PREPARATION OF OLEFIN POLYMERISATION CATALYST 审中-公开
标题翻译：烯烃聚合催化剂的制备方法
公开(公告)号：WO2005118655A1
公开(公告)日：2005-12-15
申请号：PCT/FI2005/000255
申请日：2005-06-02
申请人： BOREALIS TECHNOLOGY OY , GAROFF, Thomas , WALDVOGEL, Päivi
发明人： GAROFF, Thomas , WALDVOGEL, Päivi
IPC分类号： C08F10/00
CPC分类号： C08F10/00 , C08F4/6548 , C08F4/6546 , C08F4/6555
摘要： The invention is directed to a process for producing an olefin polymerisation catalyst wherein a solution of a soluble magnesium complex containing an element of is Group 13 or 14 of the Periodic Table (IUPAC) is contacted with a halogen containing transition metal compound of Group 3 to 10 of the Periodic Table (IUPAC) to obtain a solid catalyst complex comprising as essential components Mg, said element of is Group 13 or 14 of the Periodic Table (IUPAC) and said transition metal compound.
摘要翻译：本发明涉及一种生产烯烃聚合催化剂的方法，其中将含有元素周期表（IUPAC）的第13或14族的可溶性镁络合物的溶液与第3族的含卤素的过渡金属化合物接触， 10的元素周期表（IUPAC），以获得包含作为必需组分Mg的固体催化剂络合物，所述元素是元素周期表（IUPAC）的第13或14族和所述过渡金属化合物。

9. 发明申请

WO2003051934A3 PRODUCTION OF OLEFIN POLYMERISATION CATALYSTS 审中-公开
公开(公告)号：WO2003051934A3
公开(公告)日：2003-06-26
申请号：PCT/EP2002/014461
申请日：2002-12-18
申请人： BOREALIS TECHNOLOGY OY , DENIFL, Peter , VAN PRAET, Erik , BARTKE, Michael , OKSMAN, Marita , MUSTONEN, Marja , GAROFF, Thomas , PESONEN, Kari
发明人： DENIFL, Peter , VAN PRAET, Erik , BARTKE, Michael , OKSMAN, Marita , MUSTONEN, Marja , GAROFF, Thomas , PESONEN, Kari
IPC分类号： C08F10/00
摘要： The invention provides a process for producing an olefin polymerisation catalyst, comprising an organometallic compound of a transition metal or of an actinide or lanthanide, in the form of solid catalyst particles, comprising forming a liquid/liquid emulsion system which comprises a solution of one or more catalyst components dispersed in a solvent immiscible therewith; and solidifying said dispersed phase to convert said droplets to solid particles comprising the catalyst and optionally recovering said particles.

10. 发明授权

EP1397395B1 OLEFIN POLYMERISATION CATALYST AND METHODS FOR PREPARING THE SAME 有权
标题翻译：用于生产烯烃聚合催化剂和方法
公开(公告)号：EP1397395B1
公开(公告)日：2015-07-29
申请号：EP02760186.3
申请日：2002-06-18
申请人： Borealis Technology Oy
发明人： DENIFL, Peter , LEINONEN, Timo , VAN PRAET, Erik c/o Borealis Polymers Oy , GAROFF, Thomas , PESONEN, Kari
IPC分类号： C08F4/654 , C08F10/00
CPC分类号： C08F110/06 , C08F4/6546 , C08F4/651 , C08F2500/12 , C08F2500/18 , C08F2500/24

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