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1. 发明授权

EP2383299B1 SOLID PARTICULATE CATALYSTS COMPRISING BRIDGED METALLOCENES 有权
标题翻译：包含桥式金属化合物的固体颗粒催化剂
公开(公告)号：EP2383299B1
公开(公告)日：2017-12-20
申请号：EP11163925.8
申请日：2011-04-27
申请人： Borealis AG
发明人： Resconi, Luigi , Castro, Pascal , Huhtanen, Lauri
IPC分类号： C08F10/00 , C08F4/6592
CPC分类号： C08F4/65927 , C08F4/65912 , C08F10/00 , C08F110/06 , Y10S526/943 , C08F2500/12 , C08F2500/15 , C08F2500/17
摘要： A solid, particulate catalyst comprising: (i) a complex of formula (I): wherein M is zirconium or hafnium; each X is a sigma ligand; L is a divalent bridge selected from -R' 2 C-, -R' 2 C-CR' 2 -, -R' 2 Si-, -R' 2 Si-SiR' 2 -, -R' 2 Ge-, wherein each R' is independently a hydrogen atom, C1-C20-alkyl, tri(C1-C20-alkyl)silyl, C6-C20-aryl, C7-C20-arylalkyl or C7-C20-alkylaryl; each R 1 independently is a linear or branched C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms from groups 14-16; T 1 and T 4 , which can be the same or different, are an OR 2 , a SR 2 , CH(R 18 ) 2 , CH 2 R 18 , aryl or heteroaryl group; each R 2 , which can be the same or different, is a C1-C20 hydrocarbyl radical; each R 18 , which can be the same or different, is a C1-C20 hydrocarbyl radical or two R 18 groups together with the carbon atom to which they are attached may form a cyclic C4-C20 hydrocarbyl group; T 2 and T 3 , which may be the same or different, are a C(R 18 ) 3 group; W 1 and W 2 , which may be the same or different, are a 5 or 6 membered aryl or heteroaryl ring wherein each atom of said ring is optionally substituted with an R 5 group; each R 5 , which can be the same or different, is a C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms belonging to groups 14-16; and optionally two adjacent R 5 groups taken together can form a further mono or multicyclic ring condensed to W 1 or W 2 , optionally substituted by one or two groups R 5 ; and (ii) a cocatalyst.

2. 发明授权

EP2402354B1 Process for olefin polymerisation using group 4 metallocene as catalysts 有权
标题翻译：一种用于使用第4族的金属茂Katalisatoren聚合烯烃的方法
公开(公告)号：EP2402354B1
公开(公告)日：2016-03-02
申请号：EP10168152.6
申请日：2010-07-01
申请人： Borealis AG
发明人： Castro, Pascal , Resconi, Luigi , Huhtanen, Lauri
IPC分类号： C07F17/00 , C08F4/64 , C08F10/06
CPC分类号： C08F4/6592 , C08F4/65912 , C08F210/06 , C08F210/16 , Y10S526/943 , C08F2500/12 , C08F2500/03 , C08F4/65927

3. 发明公开

EP2829556A1 Process 有权
标题翻译：处理
公开(公告)号：EP2829556A1
公开(公告)日：2015-01-28
申请号：EP13177881.3
申请日：2013-07-24
申请人： Borealis AG
发明人： Resconi, Luigi , Töltsch, Wilfried , Ajellal, Noureddine , Virkkunen, Ville , Lehtiniemi, Ismo
IPC分类号： C08F110/06 , C08F4/657 , C08F4/6592
CPC分类号： C08F110/06 , C08F4/65908 , C08F4/65912 , C08F2410/01 , C08F2/001 , C08F2500/12 , C08F10/00 , C08F4/65927
摘要： A process for the preparation of a propylene homopolymer in a multistage polymerisation process in the presence of a single site catalyst, said process comprising:
(I) in a slurry polymerisation step, polymerising propylene in the presence of said single site catalyst; and subsequently
(II) in a gas polymerisation step polymerising propylene in the presence of catalyst and polymer from step (I) so as to form a propylene homopolymer;
wherein said catalyst comprises
(i) a metallocene complex of a Group 4 metal, said metallocene comprising at least two cyclopentadienyl type ligands;
(ii) a boron based cocatalyst; and
(iii) an aluminoxane cocatalyst;
said catalyst being in solid form, preferably in solid particulate form, and being free from an external carrier.
摘要翻译：一种在单一位点催化剂存在下在多段聚合方法中制备丙烯均聚物的方法，所述方法包括：（I）在淤浆聚合步骤中，在所述单中心催化剂存在下聚合丙烯; （II）在气体聚合步骤中在来自步骤（I）的催化剂和聚合物存在下聚合丙烯以形成丙烯均聚物; 其中所述催化剂包含（i）第4族金属的茂金属配合物，所述茂金属包含至少两个环戊二烯基型配体; （ii）硼基助催化剂; 和（iii）铝氧烷助催化剂; 所述催化剂为固体形式，优选为固体颗粒形式，并且不含外部载体。

4. 发明公开

EP2824142A1 Heterophasic copolymer 有权
标题翻译：异种共聚物
公开(公告)号：EP2824142A1
公开(公告)日：2015-01-14
申请号：EP13176366.6
申请日：2013-07-12
申请人： Borealis AG
发明人： Resconi, Luigi , Töltsch, Wilfried
IPC分类号： C08L23/10 , C08L23/14 , C08L23/16
CPC分类号： C08L23/10 , C08F4/65912 , C08L23/14 , C08L23/16 , C08L2207/02 , C08F10/00 , C08F4/65927 , C08F210/06 , C08F2/001 , C08F2500/12
摘要： A heterophasic propylene ethylene copolymer having an MFR 2 of 0.5 to 100 g/10min and obtained using single site catalysis comprising:
(i) at least 40 wt% of a propylene homopolymer or propylene ethylene copolymer matrix having up to 4 wt% comonomer;
(ii) at least 10 wt% of an ethylene propylene rubber dispersed in the matrix,
said heterophasic propylene ethylene copolymer having a xylene cold soluble content (XS) of 12 to 60 %;
wherein the ethylene content of the xylene cold soluble fraction of said heterophasic propylene ethylene copolymer is between 18 and 70 wt.%; and
wherein the intrinsic viscosity of the XS fraction of said heterophasic propylene ethylene copolymer is greater than the intrinsic viscosity of the matrix fraction of said copolymer.
摘要翻译： MFR 2为0.5-100g / 10min且使用单点催化得到的多相丙烯乙烯共聚物，包括：（i）至少40wt％的具有至多4wt％共聚单体的丙烯均聚物或丙烯乙烯共聚物基体; （ii）至少10重量％的分散在基质中的乙丙橡胶，所述多相丙烯乙烯共聚物具有12至60％的二甲苯冷可溶物含量（XS）; 其中所述多相丙烯乙烯共聚物的二甲苯冷可溶部分的乙烯含量为18至70重量％; 并且其中所述多相丙烯乙烯共聚物的XS部分的特性粘度大于所述共聚物的基体部分的特性粘度。

5. 发明公开

EP2746301A1 Catalyst 有权
标题翻译：催化剂
公开(公告)号：EP2746301A1
公开(公告)日：2014-06-25
申请号：EP12199255.6
申请日：2012-12-21
申请人： Borealis AG
发明人： Resconi, Luigi , Castro, Pascal , Virkkunen, Ville , Izmer, Vyatcheslav V , Kononovich, Dimitry S. , Kulyabin, Pavel Sergeevich , Voskoboynikov, Alexander Z.
IPC分类号： C08F10/06 , C08F4/6592 , C07F17/00 , C07F7/08
CPC分类号： C08F110/06 , C07C1/326 , C07C2531/18 , C07F7/0818 , C07F17/00 , C08F4/65912 , C08F4/65927 , C08F10/06 , C08F4/02 , C08F2500/03 , C08F2500/12 , C08F2500/15 , C08F210/06 , C08F210/16
摘要： A catalyst comprising
(i) an asymmetric complex of formula (I)

wherein
M is zirconium or hafnium;
each X is a sigma ligand;
L is a divalent bridge selected from -R' 2 C-, -R' 2 C-CR' 2 -, -R' 2 Si-, -R' 2 Si-SiR' 2 -, -R' 2 Ge-, wherein each R' is independently a hydrogen atom, C1-C20-alkyl, tri(C1-C20-alkyl)silyl, C6-C20-aryl, C7-C20-arylalkyl or C7-C20-alkylaryl;
R 2 and R 2' are each independently linear C 1-10 hydrocarbyl;
R 5 and R 5' are each independently hydrogen or a C 1-20 hydrocarbyl group;
R 6 and R 6' are each independently hydrogen or a C1-20 hydrocarbyl group;
R 7 is hydrogen or a C1-20 hydrocarbyl group or is ZR 3 ;
Z is O or S, preferably O;
R 3 is a C1-10 hydrocarbyl group;
Ar is an aryl or heteroaryl group having up to 20 carbon atoms optionally substituted by one or more groups R 8 ;
Ar' is an aryl or heteroaryl group having up to 20 carbon atoms optionally substituted by one or more groups R 8' ;
R 8 and R 8' are each independently is a C1-20 hydrocarbyl group;
with the proviso that at least one of R 6 or R 7 is not H;
and (ii) a cocatalyst comprising a compound of a group 13 metal, e.g. boron.
摘要翻译：一种催化剂，其包含（i）其中M为锆或铪的式（I）的不对称配合物; 每个X是σ配体; L是选自-R'2C - ， - R'2C-CR'2 - ， - R'2Si-，-R'2Si-SiR'2-，-R'2Ge-的二价桥，其中每个R'是独立地为氢原子，C 1 -C 20烷基，三（C 1 -C 20烷基）甲硅烷基，C 6 -C 20芳基，C 7 -C 20芳烷基或C 7 -C 20烷芳基; R2和R2'各自独立地为直链C1-10烃基; R5和R5'各自独立地为氢或C 1-20烃基; R6和R6'各自独立地为氢或C1-20烃基; R7是氢或C1-20烃基或是ZR3; Z是O或S，优选O; R3是C1-10烃基; Ar是任选地被一个或多个基团R8取代的具有至多20个碳原子的芳基或杂芳基; Ar'是具有至多20个碳原子的芳基或杂芳基，其任选地被一个或多个基团R8'取代; R8和R8'各自独立地为C1-20烃基; 条件是R6或R7中的至少一个不是H; 和（ii）包含13族金属化合物的助催化剂，例如，硼。

6. 发明授权

EP2540499B1 Multi-layer biaxially oriented polymer film 有权
标题翻译：一种多层双轴取向聚合物薄膜
公开(公告)号：EP2540499B1
公开(公告)日：2014-02-26
申请号：EP11171474.7
申请日：2011-06-27
申请人： Borealis AG
发明人： Resconi, Luigi , Ackermans, Nina , Fiebig, Joachim , Reichelt, Kristin
IPC分类号： B32B27/32 , B32B27/08 , C08L23/10 , C08L23/14
CPC分类号： B32B27/08 , B32B7/02 , B32B27/304 , B32B27/308 , B32B27/32 , B32B27/34 , B32B27/36 , B32B2250/03 , B32B2250/24 , B32B2250/40 , B32B2439/70 , C08L23/14 , C08L23/142 , C08L2203/16 , C08L2205/025 , Y10T428/24975 , Y10T428/263 , Y10T428/265 , Y10T428/2826 , C08F210/06 , C08F4/65925 , C08F210/16 , C08F210/14 , C08F2500/03 , C08F2500/12 , C08F2500/15 , C08F2500/26
摘要： A multi-layer biaxially oriented polymer film comprising a core layer (CL) and at least one sealing layer (SL), €¢ said sealing layer(s) (SL) comprise(s) a propylene copolymer composition (P) having a comonomer content in the range of 3.0 to 8.0 wt.-%, the comonomers are C 5 to C 12 ±-olefins, €¢ said propylene copolymer composition (P) comprises a polypropylene (A) and a polypropylene (B) in the weight ratio [(A)/(B)] of 20/80 to 80/20, wherein €¢ said polypropylene (A) has a comonomer content of equal or below 4.0 wt.-%, the comonomers are C 5 to C 12 ±-olefins, and €¢ said propylene copolymer (B) has a comonomer content of 4.0 to 20.0 wt.-%, the comonomers are C 5 to C 12 ±-olefins.

7. 发明授权

EP2487203B2 Sealing propylene copolymer 有权
公开(公告)号：EP2487203B2
公开(公告)日：2020-11-25
申请号：EP11154317.9
申请日：2011-02-14
申请人： Borealis AG
发明人： Reichelt, Kristin , Resconi, Luigi , Paavilainen, Juha
IPC分类号： C08L23/14 , C09D123/14 , C08F2/00

8. 发明授权

EP2947118B1 Polypropylene composition for automotive interior applications 有权
标题翻译：用于汽车内饰应用的聚丙烯组合物
公开(公告)号：EP2947118B1
公开(公告)日：2017-11-29
申请号：EP14169074.3
申请日：2014-05-20
申请人： Borealis AG
发明人： Wang, Jingbo , Resconi, Luigi , Doshev, Petar , Gahleitner, Markus
IPC分类号： C08L23/12 , C08L23/14
CPC分类号： C08L23/14 , C08K3/34 , C08L23/06 , C08L23/0815 , C08L23/12 , C08L23/16 , C08L2205/025 , C08L2205/03 , C08L2207/02 , C08L2207/04 , C08L2207/062
摘要： Polypropylene composition comprising a heterophasic propylene copolymer and a mineral filler, wherein said heterophasic propylene copolymer has a melting temperature in the range of 140 to 155 °C, a xylene cold soluble content in the range of 20 to 35 wt.-% and a comonomer content of the xylene cold soluble fraction in the range of 18 to 95 wt.-%, wherein further the weight ratio between heterophasic propylene copolymer and the mineral filler is in the range of 2/1 to 4/1.

9. 发明授权

EP2829558B1 PROCESS 有权
标题翻译： VERFAHREN
公开(公告)号：EP2829558B1
公开(公告)日：2016-12-14
申请号：EP13177883.9
申请日：2013-07-24
申请人： Borealis AG
发明人： Resconi, Luigi , Töltsch, Wilfried , Wang, Jingbo
IPC分类号： C08F210/06 , C08F4/657 , C08F4/6592
CPC分类号： C08F210/16 , C08F4/65908 , C08F4/65912 , C08F210/06 , C08F2410/01 , C08F2/001 , C08F2500/12 , C08F2500/17 , C08F2500/18 , C08F10/00 , C08F4/65927

10. 发明授权

EP2829556B1 PROCESS 有权
公开(公告)号：EP2829556B1
公开(公告)日：2016-11-16
申请号：EP13177881.3
申请日：2013-07-24
申请人： Borealis AG
发明人： Resconi, Luigi , Töltsch, Wilfried , Ajellal, Noureddine , Virkkunen, Ville , Lehtiniemi, Ismo
IPC分类号： C08F110/06 , C08F4/657 , C08F4/6592
CPC分类号： C08F110/06 , C08F4/65908 , C08F4/65912 , C08F2410/01 , C08F2/001 , C08F2500/12 , C08F10/00 , C08F4/65927

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