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1. 发明公开

EP2532687A3 Bridged Metallocene Catalysts 审中-公开
标题翻译：桥联茂金属催化剂
公开(公告)号：EP2532687A3
公开(公告)日：2013-04-10
申请号：EP11169600.1
申请日：2011-06-10
申请人： Borealis AG
发明人： Rieger, Bernhard , Schöbel, Alexander , Reichelt, Norbert
IPC分类号： C08F10/00 , C08F4/6592 , C07F17/00
CPC分类号： C08F10/00 , C07F17/00 , C08F4/65908 , C08F4/65912 , C08F110/06 , C08F4/65927 , C08F2500/01 , C08F2500/03
摘要： A catalyst comprising a complex of formula (I)

wherein
M is zirconium or hafnium;
each X is a sigma ligand;
L is a divalent bridge selected from -R' 2 C-, -R' 2 C-CR' 2 -, -R' 2 Si-, -R' 2 Si-SiR' 2 -, -R' 2 Ge-, wherein each R' is independently a hydrogen atom, C1-C20-hydrocarbyl, tri(C1-C20-alkyl)silyl, C6-C20-aryl, C7-C20-arylalkyl or C7-C20-alkylaryl;
each R 2 is independently a C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms from groups 14-16;
each R 5 is independently hydrogen or an aliphatic C1-20 hydrocarbyl group optionally containing one or more heteroatoms from groups 14-16;
each R 6 is independently hydrogen or an aliphatic C1-20 hydrocarbyl group optionally containing one or more heteroatoms from groups 14-16; or
an R 5 and R 6 group on adjacent carbon atoms can be taken together to form a 5 membered saturated carbon ring which is optionally substituted by a group R 4 ;
each R 7 is independently an aliphatic C1-20 hydrocarbyl group optionally containing one or more heteroatoms from groups 14-16 with at least 2 non-H atoms;
each Ar group is independently an aryl or heteroaryl group having up to 20 carbon atoms optionally substituted by one or more groups R 1 ;
each R 1 is a C1-20 hydrocarbyl group or two R 1 groups on adjacent carbon atoms taken together can form a fused 5 or 6 membered non aromatic ring with the Ar group, said ring being itself optionally substituted with one or more groups R 4 ;
each R 4 is a C1-20 hydrocarbyl group;
and (ii) a cocatalyst comprising a compound of a group 13 metal, e.g. boron.

2. 发明公开

EP3872121A1 EXPANDED POLYPROPYLENE BEADS, A PROCESS FOR PRODUCING EXPANDING POLYPROPYLENE BEADS, MOLDED ARTICLES FORMED FROM EXPANDED POLYPROPYLENE BEADS, AND A PROCESS FOR FORMING SUCH MOLDED ARTICLES 审中-公开
公开(公告)号：EP3872121A1
公开(公告)日：2021-09-01
申请号：EP20160024.4
申请日：2020-02-28
申请人： Borealis AG
发明人： Reichelt, Norbert , Trommsdorff, Ulla , Tammaro, Daniele
IPC分类号： C08J9/00 , C08K3/26 , C08K5/00
摘要： Expanded polypropylene beads comprising a polypropylene composition (C) having:
a) a melt flow rate (MFR 2 ) in the range from 1.5 to 15.0 g/10 min;
b) a melting temperature (Tm) in the range from 135 to 158 °C; and
c) a loss tangent (tan δ) in the range of 2.00 to 4.00
wherein the polypropylene composition (C) comprises more than 90.0 wt.-%, of a long chain branched copolymer of propylene (c-PP) comprising up to 8.0 wt.-% of comonomer(s) selected from ethylene and C 4 to C 10 alpha olefins,
a method for the preparation of said beads, in addition to a method of forming molded articles from said beads, and the molded articles obtained thereby.

3. 发明公开

EP2532687A2 Bridged Metallocene Catalysts 审中-公开
标题翻译： VerbrückteMetallocen-Katalysatoren
公开(公告)号：EP2532687A2
公开(公告)日：2012-12-12
申请号：EP11169600.1
申请日：2011-06-10
申请人： Borealis AG
发明人： Rieger, Bernhard , Schöbel, Alexander , Reichelt, Norbert
IPC分类号： C08F10/00 , C08F4/6592 , C07F17/00
CPC分类号： C08F10/00 , C07F17/00 , C08F4/65908 , C08F4/65912 , C08F110/06 , C08F4/65927 , C08F2500/01 , C08F2500/03
摘要： A catalyst comprising a complex of formula (I)

wherein
M is zirconium or hafnium;
each X is a sigma ligand;
L is a divalent bridge selected from -R' 2 C-, -R' 2 C-CR' 2 -, -R' 2 Si-, -R' 2 Si-SiR' 2 -, -R' 2 Ge-, wherein each R' is independently a hydrogen atom, C1-C20-hydrocarbyl, tri(C1-C20-alkyl)silyl, C6-C20-aryl, C7-C20-arylalkyl or C7-C20-alkylaryl;
each R 2 is independently a C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms from groups 14-16;
each R 5 is independently hydrogen or an aliphatic C1-20 hydrocarbyl group optionally containing one or more heteroatoms from groups 14-16;
each R 6 is independently hydrogen or an aliphatic C1-20 hydrocarbyl group optionally containing one or more heteroatoms from groups 14-16; or
an R 5 and R 6 group on adjacent carbon atoms can be taken together to form a 5 membered saturated carbon ring which is optionally substituted by a group R 4 ;
each R 7 is independently an aliphatic C1-20 hydrocarbyl group optionally containing one or more heteroatoms from groups 14-16 with at least 2 non-H atoms;
each Ar group is independently an aryl or heteroaryl group having up to 20 carbon atoms optionally substituted by one or more groups R 1 ;
each R 1 is a C1-20 hydrocarbyl group or two R 1 groups on adjacent carbon atoms taken together can form a fused 5 or 6 membered non aromatic ring with the Ar group, said ring being itself optionally substituted with one or more groups R 4 ;
each R 4 is a C1-20 hydrocarbyl group;
and (ii) a cocatalyst comprising a compound of a group 13 metal, e.g. boron.
摘要翻译：一种催化剂，其包含式（I）的络合物，其中M为锆或铪; 每个X是σ配体; L是选自-R'2 C-，-R'2 C-CR'2 - ，-R'2 Si-，-R'2 Si-SiR'2 - ，-R'2 Ge-，其中每个R'独立地是氢原子，C 1 -C 20烃基，三（C 1 -C 20烷基）甲硅烷基，C 6 -C 20 - 芳基，C 7 -C 20 - 芳基烷基或C 7 -C 20烷基芳基; 每个R 2独立地为任选地含有一个或多个第14-16族的杂原子的C 1 -C 20烃基; 每个R 5独立地为氢或任选含有一个或多个第14-16族的杂原子的脂族C 1-20烃基; 每个R 6独立地是氢或任选地含有一个或多个第14-16族的杂原子的脂族C 1-20烃基; 或相邻碳原子上的R 5和R 6基团可以一起形成任选被基团R 4取代的5元饱和碳环; 每个R 7独立地是任选地含有一个或多个具有至少2个非H原子的基团14-16的杂原子的脂族C 1-20烃基; 每个Ar基团独立地是具有至多20个碳原子的芳基或杂芳基，任选被一个或多个R 1基团取代; 每个R 1是C 1-20烃基或相邻碳原子上的两个R 1基团可以一起形成与Ar基团稠合的5或6元非芳香环，所述环本身任选被一个或多个R 4基团取代 ; 每个R 4是C 1-20烃基; 和（ii）包含第13族金属的化合物的助催化剂，例如硼。

4. 发明公开

EP3124567A1 POLYPROPYLENE BASED HOT-MELT ADHESIVE COMPOSITION 审中-公开
标题翻译：聚丙烯酸乙二醇酯
公开(公告)号：EP3124567A1
公开(公告)日：2017-02-01
申请号：EP15179158.9
申请日：2015-07-30
申请人： Borealis AG
发明人： Wang, Jingbo , Ek, Carl-Gustav , Sönmez, Anil , Bernreitner, Klaus , Reichelt, Norbert
IPC分类号： C09J123/14
CPC分类号： C09J123/14 , C08F10/04 , C08F10/06 , C08K3/36 , C08K5/0016 , C08K5/0025 , C08K5/0033 , C08K5/005 , C08K5/0066 , C08L23/04 , C08L23/0853 , C08L23/0869 , C08L23/16 , C08L91/06 , C08L2023/42 , C08L2205/02 , C08L2207/02 , C08L2308/00 , C08L2314/02 , C09D191/08 , C09J123/142 , C09J2201/61 , C09J2203/10
摘要： The invention relates to an adhesive composition wherein such composition comprises at least one polypropylene copolymer and wherein such adhesive composition has improved overall bond performance. It further relates to an article comprising said adhesive composition, as well as to a process for producing such article. It even further relates to the use of the adhesive composition in the preparation of an article.
摘要翻译：本发明涉及粘合剂组合物，其中这种组合物包含至少一种聚丙烯共聚物，并且其中这种粘合剂组合物具有改进的整体粘合性能。它还涉及包含所述粘合剂组合物的制品以及用于生产这种制品的方法。它进一步涉及在制备制品中使用粘合剂组合物。

5. 发明授权

EP2275485B1 Heterophasic polypropylene copolymer composition 有权
标题翻译：异丙基聚丙烯共聚物
公开(公告)号：EP2275485B1
公开(公告)日：2011-06-08
申请号：EP09163353.7
申请日：2009-06-22
申请人： Borealis AG
发明人： Posch, Werner , Tranninger, Michael , Leskinen, Pauli , Malm, Bo , Frank, Sybille , Reichelt, Norbert
IPC分类号： C08L23/10 , C08F297/08 , B29C45/00
CPC分类号： C08L23/10 , B29C45/0001 , C08F110/06 , C08F210/06 , C08F297/08 , C08L23/0815 , C08L23/16 , C08L2205/02 , C08L2207/02 , C08L2314/02 , C08F2/001 , C08L2666/06 , C08F210/16 , C08F2500/12 , C08F2500/17 , C08F2500/11

6. 发明公开

EP2275485A1 Heterophasic polypropylene copolymer composition 有权
标题翻译：异丙基聚丙烯共聚物
公开(公告)号：EP2275485A1
公开(公告)日：2011-01-19
申请号：EP09163353.7
申请日：2009-06-22
申请人： Borealis AG
发明人： Posch, Werner , Tranninger, Michael , Leskinen, Pauli , Malm, Bo , Frank, Sybille , Reichelt, Norbert
IPC分类号： C08L23/10 , C08F297/08 , B29C45/00
CPC分类号： C08L23/10 , B29C45/0001 , C08F110/06 , C08F210/06 , C08F297/08 , C08L23/0815 , C08L23/16 , C08L2205/02 , C08L2207/02 , C08L2314/02 , C08F2/001 , C08L2666/06 , C08F210/16 , C08F2500/12 , C08F2500/17 , C08F2500/11
摘要： Heterophasic polypropylene composition comprising
(A) 45 to 70 wt% of a propylene homo- or copolymer matrix with an MFR 2 in accordance with ISO 1133 (230°C, 2.16 kg load) of ≥ 80 g/10 min and
(B) 25 to 40 wt% of an elastomeric propylene-ethylene copolymer, having an intrinsic viscosity IV (ISO 1628, with decalin as solvent) of ≥ 3.3 dl/g and an ethylene content of 20 to 50 wt%,
(C) 0-15 wt% of an elastomeric ethylene/alpha-olefin random copolymer
(D) 3 - 25 parts per weight of inorganic filler,

the heterophasic polypropylene compositions having a total MFR 2 (230°C/2.16 kg) in accordance with ISO 1133 of ≥ 5 g/10 min, a Charpy notched impact strength according to ISO 179/1eA at +23°C of ≥ 15.0 kJ/m 2 , preferably ≥ 25.0 kJ/m 2 , a minimum value for the Charpy notched impact strength according to ISO 179/1 eA at -20°C of ≥ 7.0 kJ/m 2 , preferably ≥ 10.0 kJ/m 2 and a tensile modulus according to ISO 527-3 of ≥1200 MPa; their preparation and use for producing injection moulded articles being free of flow marks.
摘要翻译：多相聚丙烯组合物，其包含（A）45-70重量％的丙烯均聚物或共聚物基体，其MFR 2为符合ISO 1133（230℃，2.16kg负载）为80g / 10min，（B） 25〜40重量％的特性粘度IV（ISO 1628，作为溶剂的十氢化萘）为‰¥3.3dl / g，乙烯含量为20〜50重量％的弹性体丙烯 - 乙烯共聚物，（C） 15重量％的弹性体乙烯/α-烯烃无规共聚物（D）3-25重量份无机填料，根据ISO 1133的总体MFR 2（230℃/ 2.16kg）的多相聚丙烯组合物 ¥5g / 10分钟，根据ISO 179 / 1eA在+ 23℃下的夏比缺口冲击强度‰¥15.0kJ / m 2，优选‰25.0kJ / m 2，夏比缺口冲击强度的最小值根据ISO 179/1 eA在-20°C‰¥7.0 kJ / m 2，优选‰¥10.0 kJ / m 2，根据ISO 527-3的拉伸模量‰¥1200 MPa; 它们的制备和用于生产没有流痕的注塑制品。

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