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1. 发明授权

US06875409B1 Catalyst and process for oxidation and removal of nitrogen oxides (NOx) from combustion gases 失效
标题翻译：从燃烧气体氧化和除去氮氧化物（NOx）的催化剂和方法
公开(公告)号：US06875409B1
公开(公告)日：2005-04-05
申请号：US10038120
申请日：2001-11-09
申请人： Bing Zhou , Lap-Keung Lee , Naresh J. Suchak
发明人： Bing Zhou , Lap-Keung Lee , Naresh J. Suchak
IPC分类号： B01J23/00
CPC分类号： B01J23/002 , B01D53/944 , B01D2253/112 , B01D2255/1021 , B01D2255/2073 , B01D2255/20738 , B01D2255/20746 , B01D2255/20761 , B01D2255/91 , B01J23/78 , B01J23/83 , B01J23/894 , B01J23/8986 , B01J37/0201 , B01J37/34 , B01J2523/00 , B01J2523/17 , B01J2523/3706 , B01J2523/72 , B01J2523/25
摘要： A bi-functional oxidation catalyst and process for catalytic oxidation and removal of nitrogen oxides (NOx) from combustion gases derived from combustion of carbonaceous fuels such as coal, oil, or natural gas. The bi-functional catalyst includes adsorption and oxidation function metal oxides provided in adjacent close intimate contact by utilizing a binding agent, such as carboxylic acid and calcining to provide a metal oxide complex having a crystalline form. Such nitrogen oxides (NOx) contained in the combustion gases are initially catalytically oxidized to at least about 50 vol % NO2 and some higher oxides by contact with the bi-functional catalyst at 170-550° F. temperature. The combustion gas containing the partially oxidized NOx is then preferably further chemically oxidized by being mixed with a chemical oxidant such as ozone (O3) in a molar ratio of the chemical oxidant3 to NOx in the range of 0.5:1-1.2:1 to produce higher oxides of nitrogen such as substantially N2O5. The further treated combustion gas containing the N2O5 is next scrubbed with a suitable scrubbing liquid such as water to effectively remove the nitrogen oxides (NOx) and produce a clean treated flue gas stream containing less than about 15 ppm nitrogen oxides and suitable for environmentally safe discharge to the atmosphere.
摘要翻译：一种双功能氧化催化剂和从燃烧碳，燃料如煤，油或天然气的燃烧产生的燃烧气体催化氧化和除去氮氧化物（NOx）的方法。双功能催化剂包括通过利用粘合剂（例如羧酸）和煅烧以提供具有结晶形式的金属氧化物络合物在相邻紧密接触中提供的吸附和氧化功能金属氧化物。包含在燃烧气体中的这种氮氧化物（NOx）在170-550°F温度下与双功能催化剂接触，最初催化氧化至至少约50vol％的NO 2和一些较高的氧化物。含有部分氧化的NOx的燃烧气体然后优选通过与化学氧化剂例如臭氧（O 3）以化学氧化剂3与NOx的摩尔比在0.5：1-1.2:1的范围内混合而进一步化学氧化，以产生较高的氮氧化物，例如基本上是N 2 O 5。接下来用含有N2O5的处理过的燃烧气体用合适的洗涤液如水洗涤以有效去除氮氧化物（NOx）并产生含有小于约15ppm氮氧化物并且适于环境安全排放的清洁处理的烟道气流到大气。

2. 发明授权

US06576214B2 Catalytic direct production of hydrogen peroxide from hydrogen and oxygen feeds 失效
公开(公告)号：US06576214B2
公开(公告)日：2003-06-10
申请号：US09867190
申请日：2001-05-29
申请人： Bing Zhou , Michael A. Rueter , Lap-Keung Lee , Bruce P. Pelrine
发明人： Bing Zhou , Michael A. Rueter , Lap-Keung Lee , Bruce P. Pelrine
IPC分类号： C01B1501
CPC分类号： C01B15/029 , B01J21/18 , B01J23/38 , B01J23/40 , B01J35/0013 , B01J37/0203 , B01J37/0211 , C07D301/12 , Y02P20/52 , Y10S977/775 , Y10S977/777 , Y10S977/779 , Y10S977/836 , Y10S977/895 , Y10S977/926
摘要： A process for catalytically directly producing hydrogen peroxide (H2O2) product from hydrogen and oxygen-containing feeds by contacting them with a supported noble metal phase-controlled catalyst and a suitable organic liquid solvent having a Solvent Selection Parameter (SSP) between 0.14×10−4 and 5.0×10−4 at reaction condition of 0-100° C. temperature and 100-3,000 psig pressure. Unconverted feed gas and organic liquid solvent solution are usually recovered and recycled back to the reactor along with any recovered catalyst. If desired, the hydrogen peroxide product can be fed together with an organic chemical feedstock such as propylene and with the organic liquid solvent solution into a second catalytic reaction step which oxidizes the feedstock to produce a desired crude oxidized organic product such as propylene oxide, which may be purified by distillation steps and recovered from the solvent solution.

3. 发明授权

US06919065B2 Supported noble metal, phase-controlled catalyst and methods for making and using the catalyst 失效
标题翻译：负载型贵金属，相控催化剂和制备和使用催化剂的方法
公开(公告)号：US06919065B2
公开(公告)日：2005-07-19
申请号：US10431693
申请日：2003-05-07
申请人： Bing Zhou , Lap-Keung Lee
发明人： Bing Zhou , Lap-Keung Lee
IPC分类号： B01J21/18 , B01J23/38 , B01J23/40 , B01J35/00 , B01J37/02 , C01B15/029 , C07D301/12 , C01B15/01 , B01J21/08 , B01J21/12 , B01J23/00
CPC分类号： C01B15/029 , B01J21/18 , B01J23/38 , B01J23/40 , B01J35/0013 , B01J37/0203 , B01J37/0211 , C07D301/12 , Y02P20/52 , Y10S977/775 , Y10S977/777 , Y10S977/779 , Y10S977/836 , Y10S977/895 , Y10S977/926
摘要： A particulate supported noble metal phase-controlled catalyst material having 5-1000 μm surface area of 50μ500 m2/gm is provided for use in direct catalytic production of hydrogen peroxide (H2O2) product from hydrogen and oxygen-containing feedstreams. The catalyst is made by depositing phase controlled crystals of a noble metal such as palladium on a suitable particulate support material such as carbon black, by utilizing a precursor solution of the metal and a suitable control ionic polymer having molecular weight of 300-8000 such as sodium polyacrylate in a selected metal to polymer molar ratio of 1:0.1 to 1:10, which procedure provides desired phase control of the noble metal atoms to form widely dispersed minute noble metal crystals on the support material. The invention includes methods for making the catalyst, and also a process for utilizing the catalyst to directly produce high yields of hydrogen peroxide (H2O2) product from hydrogen and oxygen-containing gaseous feedstreams.
摘要翻译：提供具有5-1000mum表面积为50mu500m 2 / gm的颗粒状负载的贵金属相控催化剂材料用于直接催化生产过氧化氢（H 2 N 2 产物从氢和含氧进料流中获得。通过使用金属的前体溶液和分子量为300-8000的合适的对照离子聚合物（如分子量为300-8000），将贵金属如钯的相控晶体沉积在合适的颗粒载体材料如炭黑上来制备催化剂，例如聚丙烯酸钠以选择的金属与聚合物的摩尔比为1:0.1至1:10，该方法提供贵金属原子的期望的相位控制，以在载体材料上形成广泛分散的微小贵金属晶体。本发明包括制备催化剂的方法，以及利用催化剂从氢气和氧气直接产生高产率的过氧化氢（H 2 O 2 O 2 H 2）产物的方法。的气态进料流。

4. 发明授权

US06168775A Catalyst and process for direct catalystic production of hydrogen peroxide, (H2O2) 有权
标题翻译：用于直接催化生产过氧化氢（H 2 O 2）的催化剂和方法
公开(公告)号：US06168775A
公开(公告)日：2001-01-02
申请号：US09140265
申请日：1998-08-26
申请人： Bing Zhou , Lap-Keung Lee
发明人： Bing Zhou , Lap-Keung Lee
IPC分类号： B01J2118
CPC分类号： B01J37/0203 , B01J21/18 , B01J23/38 , B01J23/40 , B01J35/0013 , B01J37/0211 , C01B15/029
摘要： A particulate supported noble metal phase-controlled catalyst material having 5-1000 &mgr;m surface area of 50&mgr;500 m2/gm is provided for use in direct catalytic production of hydrogen peroxide (H2O2) product from hydrogen and oxygen-containing feedstreams. The catalyst is made by depositing phase controlled crystals of a noble metal such as palladium on a suitable particulate support material such as carbon black, by utilizing a precursor solution of the metal and a suitable control ionic polymer having molecular weight of 300-8000 such as sodium polyacrylate in a selected metal to polymer molar ratio of 1:0.1 to 1:10, which procedure provides desired phase control of the noble metal atoms to form widely dispersed minute noble metal crystals on the support material. The invention includes methods for making the catalyst, and also a process for utilizing the catalyst to directly produce high yields of hydrogen peroxide (H2O2) product from hydrogen and oxygen-containing gaseous feedstreams.
摘要翻译：提供具有5-500m 2 / gm的5-1000mum表面积的颗粒状负载的贵金属相控催化剂材料，用于从氢气和含氧进料流直接催化生产过氧化氢（H 2 O 2）产物。通过使用金属的前体溶液和分子量为300-8000的合适的对照离子聚合物（如分子量为300-8000），将贵金属如钯的相控晶体沉积在合适的颗粒载体材料如炭黑上来制备催化剂，例如聚丙烯酸钠以选择的金属与聚合物的摩尔比为1:0.1至1:10，该方法提供贵金属原子的期望的相位控制，以在载体材料上形成广泛分散的微小贵金属晶体。本发明包括制备催化剂的方法，以及利用催化剂从氢气和含氧气态进料流直接产生高产率的过氧化氢（H 2 O 2）产物的方法。

5. 发明公开

US20240094824A1 FINGER GESTURE RECOGNITION VIA ACOUSTIC-OPTIC SENSOR FUSION 审中-公开
公开(公告)号：US20240094824A1
公开(公告)日：2024-03-21
申请号：US18368358
申请日：2023-09-14
申请人： Gurunandan Krishnan Gorumkonda , Shree K. Nayar , Chenhan Xu , Bing Zhou
发明人： Gurunandan Krishnan Gorumkonda , Shree K. Nayar , Chenhan Xu , Bing Zhou
IPC分类号： G06F3/01 , G06F3/16 , G06V40/10 , G06V40/20
CPC分类号： G06F3/017 , G06F3/16 , G06V40/10 , G06V40/28
摘要： A finger gesture recognition system is provided. The finger gesture recognition system includes one or more audio sensors and one or more optic sensors. The finger gesture recognition system captures, using the one or more audio sensors, audio signal data of a finger gesture being made by a user, and captures, using the one or more optic sensors, optic signal data of the finger gesture. The finger gesture recognition system recognizes the finger gesture based on the audio signal data and the optic signal data and communicates finger gesture data of the recognized finger gesture to an Augmented Reality/Combined Reality/Virtual Reality (XR) application.

6. 发明申请

US20120286217A1 METHODS FOR MITIGATING AGGLOMERATION OF CARBON NANOSPHERES USING EXTRACTION 审中-公开
标题翻译：使用萃取法减少碳纳米微粒的方法
公开(公告)号：US20120286217A1
公开(公告)日：2012-11-15
申请号：US13106496
申请日：2011-05-12
申请人： Cheng Zhang , Bing Zhou
发明人： Cheng Zhang , Bing Zhou
IPC分类号： H01B1/24 , C01B31/02 , C01B31/00 , B82Y99/00 , B82Y40/00
CPC分类号： H01B1/24 , B82Y30/00 , B82Y40/00 , C01B32/15 , C01P2004/32 , C01P2004/34
摘要： Novel methods for manufacturing carbon nanostructures (e.g., carbon nanospheres) that are highly dispersed include forming a precursor composition, polymerizing the precursor composition, extracting water from the polymerized carbon material using an organic solvent, and carbonizing the polymerized material (e.g., through pyrolysis) to form the carbon nanostructures. The extraction-treated polymerized carbon material forms carbon nanostructures that are less agglomerated than carbon nanostructures manufactured using a similar technique without solvent extraction of water.
摘要翻译：用于制造高度分散的碳纳米结构（例如，碳纳米球）的新方法包括形成前体组合物，聚合前体组合物，使用有机溶剂从聚合碳材料中提取水，以及将聚合材料碳化（例如通过热解）以形成碳纳米结构。萃取处理的聚合碳材料形成碳纳米结构，其比使用类似技术制造的碳纳米结构少而没有溶剂萃取水。

7. 发明申请

US20120286216A1 METHODS FOR MITIGATING AGGLOMERATION OF CARBON NANOSPHERES USING A LONG CHAIN HYDROCARBON SURFACTANT 审中-公开
标题翻译：使用长链烃油表面活性剂减缓碳纳米管聚集的方法
公开(公告)号：US20120286216A1
公开(公告)日：2012-11-15
申请号：US13106469
申请日：2011-05-12
申请人： Cheng Zhang , Bing Zhou
发明人： Cheng Zhang , Bing Zhou
IPC分类号： H01B1/24 , C01B31/02 , C01B31/00 , B82Y40/00 , B82Y99/00
CPC分类号： H01B1/24 , B82Y40/00 , C01B32/05
摘要： Novel methods for manufacturing carbon nanostructures (e.g., carbon nanospheres) that are highly dispersed include forming a precursor composition, polymerizing the precursor composition, applying a long chain hydrocarbon surfactant to the polymerized carbon material, and carbonizing the polymerized material (e.g., through pyrolysis) to form the carbon nanostructures. The long chain hydrocarbon surfactant facilitates the formation of dispersed carbon nanostructures during the carbonization step.
摘要翻译：用于制造高度分散的碳纳米结构（例如，碳纳米球）的新方法包括形成前体组合物，聚合前体组合物，向聚合的碳材料施加长链烃表面活性剂，并将聚合的材料碳化（例如通过热解）以形成碳纳米结构。长链烃表面活性剂促进了碳化步骤期间分散的碳纳米结构的形成。

8. 发明授权

US08225641B2 Nanofibers and methods of making same and using same in humidity sensors 失效
标题翻译：纳米纤维及其制作方法，并在湿度传感器中使用相同的方法
公开(公告)号：US08225641B2
公开(公告)日：2012-07-24
申请号：US12544989
申请日：2009-08-20
申请人： Ce Wang , Hongnan Zhang , Zhenyu Li , Wei Zheng , Wei Wang , Changkun Liu , Bing Zhou
发明人： Ce Wang , Hongnan Zhang , Zhenyu Li , Wei Zheng , Wei Wang , Changkun Liu , Bing Zhou
IPC分类号： G01N19/10
CPC分类号： G01N27/125 , Y10S977/84 , Y10S977/902
摘要： A self-cleaning humidity sensor based on Mg2+/Na+-doped TiO2 nanofiber mats is provided. Examples show the response and recovery characteristic curves for ten circles with the RH changing from 11% to 95%. The nanofibers are manufactured by mixing together a metal salt comprising titanium, a magnesium compound, a sodium compound, and a high molecular weight material to form a mixture, electrospinning the mixture to form composite nanofibers, and calcining the composite nanofibers to yield a TiO2 nanofiber material doped with magnesium and sodium.
摘要翻译：提供了基于Mg2 + / Na +掺杂的TiO2纳米纤维垫的自洁湿度传感器。示例显示了10个圆的响应和恢复特性曲线，RH从11％变化到95％。纳米纤维通过将包含钛，镁化合物，钠化合物和高分子量材料的金属盐混合在一起而制备，以形成混合物，静电纺混合物以形成复合纳米纤维，并煅烧复合纳米纤维以产生TiO 2纳米纤维掺杂镁和钠的材料。

9. 发明申请

US20100196246A1 METHODS FOR MITIGATING AGGLOMERATION OF CARBON NANOSPHERES USING A CRYSTALLIZING DISPERSANT 审中-公开
标题翻译：使用结晶分散剂减缓碳纳米管聚集的方法
公开(公告)号：US20100196246A1
公开(公告)日：2010-08-05
申请号：US12757813
申请日：2010-04-09
申请人： Cheng Zhang , Bing Zhou
发明人： Cheng Zhang , Bing Zhou
IPC分类号： C01B31/02
CPC分类号： B82Y40/00 , B82Y30/00 , C01B32/15
摘要： Novel methods for manufacturing carbon nanostructures (e.g., carbon nanospheres) that are highly dispersed include forming a precursor composition, polymerizing the precursor composition, and carbonizing the polymerized material (e.g., through pyrolysis) to form the carbon nanostructures. The precursor composition includes catalytic metals and a crystallizing dispersant. The crystallizing dispersant forms a crystalline phase in the polymerized precursor material which facilitates the formation of dispersed carbon nanostructures during the carbonation step.
摘要翻译：用于制造高度分散的碳纳米结构（例如，碳纳米球）的新方法包括形成前体组合物，聚合前体组合物，以及将聚合的材料碳化（例如通过热解）形成碳纳米结构。前体组合物包括催化金属和结晶分散剂。结晶分散剂在聚合的前体材料中形成结晶相，其有助于碳酸化步骤期间分散的碳纳米结构的形成。

10. 发明授权

US07718156B2 Method for manufacturing carbon nanostructures having minimal surface functional groups 失效
标题翻译：具有最小表面官能团的碳纳米结构的制造方法
公开(公告)号：US07718156B2
公开(公告)日：2010-05-18
申请号：US11614011
申请日：2006-12-20
申请人： Cheng Zhang , Martin Fransson , Bing Zhou
发明人： Cheng Zhang , Martin Fransson , Bing Zhou
IPC分类号： C01B31/00 , C01B31/04 , C09C1/44 , C09C1/46 , B01J21/18
CPC分类号： B82Y30/00 , B82Y40/00 , C01B32/18 , C01B32/20 , C01P2002/72 , C01P2002/82 , C01P2004/03 , C01P2004/04 , C01P2004/32 , C01P2004/62 , C01P2004/64 , C01P2006/12 , C09C1/44
摘要： Carbon nanostructures are formed from a carbon precursor and catalytic templating nanoparticles. Methods for manufacturing carbon nanostructures generally include (1) forming a precursor mixture that includes a carbon precursor and a plurality of catalytic templating particles, (2) carbonizing the precursor mixture to form an intermediate carbon material including carbon nanostructures, amorphous carbon, and catalytic metal, (3) purifying the intermediate carbon material by removing at least a portion of the amorphous carbon and optionally at least a portion of the catalytic metal, and (4) heat treating the purified intermediate carbon material and/or treating the purified intermediate carbon material with a base to remove functional groups on the surface thereof. The removal of functional groups increases the graphitic content of the carbon nanomaterial and decreases its hydrophilicity.
摘要翻译：碳纳米结构由碳前体和催化模板纳米颗粒形成。制造碳纳米结构的方法通常包括（1）形成包含碳前体和多个催化模板颗粒的前体混合物，（2）将前体混合物碳化以形成包括碳纳米结构，无定形碳和催化金属的中间碳材料（3）通过除去至少一部分无定形碳和任选的至少一部分催化金属来纯化中间碳材料，和（4）对纯化的中间碳材料进行热处理和/或处理纯化的中间碳材料具有用于除去其表面上的官能团的碱。官能团的去除增加了碳纳米材料的石墨含量，降低了其亲水性。

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