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1. 发明授权

US07022811B2 3,4-Alkylenedioxythiophene compounds and polymers thereof 失效
标题翻译： 3,4-亚烷基二氧噻吩化合物及其聚合物
公开(公告)号：US07022811B2
公开(公告)日：2006-04-04
申请号：US10680546
申请日：2003-10-07
申请人： Bert Groenendaal , John R. Reynolds , Carleton L. Gaupp , Irina Schwendeman
发明人： Bert Groenendaal , John R. Reynolds , Carleton L. Gaupp , Irina Schwendeman
IPC分类号： C08G75/00 , C08L41/00
CPC分类号： C07D495/04 , C08G61/12 , C08G61/123 , C08G61/126 , H01G11/48 , H01G11/56 , Y02E60/13
摘要： A thiophene compound represented by formula (I): wherein A represents a C1-5-alkylene bridge substituted with at least one fluorine atom and/or at least one alkyl group substituted with a fluorine-containing-group; polymers containing monomeric units of a thiophene compound represented by formula (I); a process for preparing polymers containing monomeric units of a thiophene compound represented by formula (I), optionally chemically or electrochemically; and solutions, dispersions, pastes and layers containing such polymers.
摘要翻译：由式（I）表示的噻吩化合物：其中A表示被至少一个氟原子取代的C 1-5 - 亚烷基桥和/或至少一个被含氟 - 组; 含有由式（I）表示的噻吩化合物的单体单元的聚合物; 化学或电化学制备由式（I）表示的噻吩化合物的单体单元的聚合物的方法; 以及含有这种聚合物的溶液，分散体，糊剂和层。

2. 发明授权

US06791738B2 Electrochromic polymers and polymer electrochromic devices 有权
标题翻译：电致变色聚合物和聚合物电致变色器件
公开(公告)号：US06791738B2
公开(公告)日：2004-09-14
申请号：US10302164
申请日：2002-11-21
申请人： John R. Reynolds , Kyukwan Zong , Irina Schwendeman , Gursel Sonmez , Philippe Schottland , Avni A. Argun , Pierre-Henri Aubert
发明人： John R. Reynolds , Kyukwan Zong , Irina Schwendeman , Gursel Sonmez , Philippe Schottland , Avni A. Argun , Pierre-Henri Aubert
IPC分类号： G02F115
CPC分类号： C09K9/02 , C08G61/123 , C08G61/124 , C08G61/126 , G02F2001/1502
摘要： The subject invention pertains to electrochromic polymers and polymer electrochromic devices. In a specific embodiment, two complementary polymers can be matched and incorporated into dual polymer electrochromic devices. The anodically coloring polymers in accordance with the subject invention can allow control over the color, brightness, and environmental stability of an electrochromic window. In addition, high device contrast ratios, high transmittance changes, and high luminance changes can be achieved, along with half-second switching times for full color change. Also provided are electrochromic devices such as advertising signage, video monitors, stadium scoreboards, computers, announcement boards, warning systems for cell phones, warning/information systems for automobiles, greeting cards, electrochromic windows, billboards, electronic books, and electrical wiring. The subject invention also provides for the use of complementary electrochromic polymers in the manufacture of electrochromic devices. In some embodiments, the devices of the invention can be prepared using metal vapor deposition or line patterning.
摘要翻译：本发明涉及电致变色聚合物和聚合物电致变色装置。在一个具体的实施方案中，两个互补的聚合物可以匹配并结合到双聚合物电致变色装置中。根据本发明的阳极着色聚合物可以控制电致变色窗的颜色，亮度和环境稳定性。此外，可以实现高器件对比度，高透射率变化和高亮度变化，以及全色变化的半秒切换时间。还提供了诸如广告标牌，视频监视器，体育场记分牌，计算机，公告板，手机警告系统，汽车警告/信息系统，贺卡，电致变色窗，广告牌，电子书和电线的电致变色装置。本发明还提供了互补电致变色聚合物在制造电致变色器件中的应用。在一些实施例中，可以使用金属气相沉积或线图案化来制备本发明的装置。

3. 发明授权

US06734312B2 Process for preparing a compound containing a heteroaromatic group with one or more ether substituents 失效
标题翻译：制备含有一个或多个醚取代基的杂芳族基团的化合物的方法
公开(公告)号：US06734312B2
公开(公告)日：2004-05-11
申请号：US10325424
申请日：2002-12-20
申请人： John R. Reynolds , Bert Groenendaal , Kyukwan Zong , Luis Madrigal
发明人： John R. Reynolds , Bert Groenendaal , Kyukwan Zong , Luis Madrigal
IPC分类号： C07D49502
CPC分类号： C07D491/04 , C07D495/04
摘要： A process for preparing a heteroaromatic compound having a heteroaromatic nucleus substituted with one or more ether groups comprising the step of: condensing at least one hydroxy-group of a compound having said heteroaromatic nucleus, said at least one hydroxy group (—OH) being substituted at &agr;- or &bgr;-positions with respect to a heteroatom of said heteroaromatic nucleus, with an alcohol containing one or more primary or secondary alcohol groups, optionally substituted with nitro, amide, ester, halogen, cyano or (hetero)aromatic groups, using the redox couple of a triaryl- or trialkylphosphine and an azodioxo-compound at a temperature between −40° C. and 160° C.
摘要翻译：一种制备具有被一个或多个醚基取代的杂芳族核的杂芳族化合物的方法，包括以下步骤：将具有所述杂芳族核的化合物的至少一个羟基缩合，所述至少一个羟基（-OH）被取代含有一个或多个伯或仲醇基的醇，任选被硝基，酰胺，酯，卤素，氰基或（杂）芳族基团取代的醇，使用在所述杂芳族核的杂原子的α位或β位上，使用在-40℃至160℃的温度下，三芳基 - 或三烷基膦和偶氮二氧化合物的氧化还原对。

4. 发明授权

US09775241B2 Nanotube dispersants and dispersant free nanotube films therefrom 有权
公开(公告)号：US09775241B2
公开(公告)日：2017-09-26
申请号：US14009922
申请日：2012-04-03
申请人： Ryan M. Walczak , John R. Reynolds , Andrew Gabriel Rinzler , Andrew M. Spring , Svetlana V. Vasilyeva , Pooja Wadhwa
发明人： Ryan M. Walczak , John R. Reynolds , Andrew Gabriel Rinzler , Andrew M. Spring , Svetlana V. Vasilyeva , Pooja Wadhwa
IPC分类号： C09D147/00 , C09D101/02 , C09D11/00 , H05K1/09 , C08J3/02 , C09D5/02 , C09D7/12 , C01B31/02 , C01B31/04 , C09D11/30 , C09D11/52 , B82Y30/00 , B82Y40/00 , B05D1/04 , B05D1/18 , B05D1/28 , B05D3/00 , C08K7/24
CPC分类号： H05K1/092 , B05D1/04 , B05D1/18 , B05D1/28 , B05D3/007 , B82Y30/00 , B82Y40/00 , C01B32/168 , C01B32/174 , C01B32/194 , C08J3/02 , C08J2300/10 , C08K3/041 , C08K7/24 , C09D5/027 , C09D7/70 , C09D11/30 , C09D11/52 , C09D101/02 , C09D147/00 , H05K2201/0323 , C08L1/284 , C08L101/02
摘要： A degradable polymeric nanotube (NT) dispersant comprises a multiplicity of NT associative groups that are connected to a polymer backbone by a linking group where there are cleavable groups within the polymer backbone and/or the linking groups such that on a directed change of conditions, bond breaking of the cleavable groups results in residues from the degradable polymeric NT dispersant in a manner where the associative groups are uncoupled from other associative groups, rendering the associative groups monomelic in nature. The degradable polymeric nanotube (NT) dispersant can be combined with carbon NTs to form a NT dispersion that can be deposited to form a NT film, or other structure, by air brushing, electrostatic spraying, ultrasonic spraying, ink-jet printing, roll-to-roll coating, or dip coating. The deposition can render a NT film that is of a uniform thickness or is patterned with various thicknesses. Upon deposition of the film, the degradable polymeric nanotube (NT) dispersant can be cleaved and the cleavage residues removed from the film to yield a film where contact between NTs is unencumbered by dispersants, resulting in highly conductive NT films.

5. 发明授权

US08961830B2 Electroactive polymers containing pendant pi-interacting/binding substituents, their carbon nanotube composites, and processes to form the same 有权
标题翻译：含有π-相互作用/结合取代基的电活性聚合物，它们的碳纳米管复合材料以及其形成方法
公开(公告)号：US08961830B2
公开(公告)日：2015-02-24
申请号：US12445429
申请日：2007-10-11
申请人： John R. Reynolds , Ryan M. Walczak , Andrew G. Rinzler
发明人： John R. Reynolds , Ryan M. Walczak , Andrew G. Rinzler
IPC分类号： H01B1/00 , C09D5/24 , H01B1/24 , H01L51/00 , G02F1/15
CPC分类号： C09D5/24 , G02F2001/1515 , H01B1/24 , H01L51/0039 , H01L51/0043 , H01L51/0054
摘要： A composition of matter comprises a polymer with a fully conjugated backbone or a conjugated block with a plurality of binding groups connected to the backbone by a linking moiety. The binding groups permit a non-covalent binding to a graphitic surface such as a carbon nanotube. A composition of matter where an electroactive polymer with binding groups connected to a conjugated backbone through a linking moiety is bound to carbon nanotubes. Such compositions can be used for a variety of applications using electroactive materials.
摘要翻译：物质组合物包含具有完全共轭骨架的聚合物或具有多个通过连接部分连接至主链的结合基团的共轭嵌段。结合基团允许与石墨表面如碳纳米管非共价结合。其中具有通过连接部分与共轭骨架连接的结合基团的电活性聚合物与碳纳米管结合的物质组合物。这种组合物可用于使用电活性材料的各种应用。

6. 发明授权

US08519088B2 Earth-toned photovoltaic devices 有权
标题翻译：土质光伏器件
公开(公告)号：US08519088B2
公开(公告)日：2013-08-27
申请号：US13321875
申请日：2010-05-26
申请人： Pierre Marc Beaujuge , John R. Reynolds , Franky So , Jegadesan Subbiah
发明人： Pierre Marc Beaujuge , John R. Reynolds , Franky So , Jegadesan Subbiah
IPC分类号： C08G75/00
CPC分类号： H01L31/042 , H01L27/301 , H01L31/02 , H01L51/0036 , H01L51/0037 , H01L51/0043 , H01L51/0094 , H01L51/4253 , H01L2251/308 , Y02E10/549
摘要： The invention is directed to an assembly of photovoltaic cells having at least two different earth-toned colors, where different colors are situated in different cells, the cells color being defined by the donor-acceptor (DA) π-conjugated polymer and an acceptor moiety combination comprising the photoactive layer of the cell, and where the different colored solar cells are coupled into an assembly. The assembly can be flexible and can have colors specifically arranged in a camouflage or other pattern.
摘要翻译：本发明涉及一种具有至少两种不同颜色的不同颜色的光电池组件，其中不同的颜色位于不同的细胞中，细胞颜色由供体 - 受体（DA）π共轭聚合物和受体部分定义组合，其包含电池的光敏层，并且其中不同的有色太阳能电池耦合到组件中。该组件可以是柔性的并且可以具有以伪装或其他图案特别布置的颜色。

7. 发明申请

US20120115049A1 SINGLE WALL CARBON NANOTUBE BASED AIR CATHODES 审中-公开
标题翻译：单壁碳纳米管空气阴极
公开(公告)号：US20120115049A1
公开(公告)日：2012-05-10
申请号：US13265976
申请日：2010-04-22
申请人： Andrew Gabriel Rinzler , Rajib Kumar Das , John R. Reynolds , Ryan M. Walczak
发明人： Andrew Gabriel Rinzler , Rajib Kumar Das , John R. Reynolds , Ryan M. Walczak
IPC分类号： H01M4/90 , H05K3/00 , H01M4/88 , B29C39/22 , B82Y30/00
CPC分类号： H01M4/8673 , H01M4/8605 , H01M4/8657 , H01M4/8668 , H01M8/1007 , H01M8/1011 , H01M12/06 , H01M2008/1095 , Y02E60/523 , Y10T29/49124
摘要： An embodiment of the invention is an air cathode having a porous membrane with at least one hydrophobic surface that contacts a conductive catalytic film that comprises single walled carbon nanotubes (SWNTs) where the nanotubes are in intimate electrical contact. The conductive film can include fullerenes, metals, metal alloys, metal oxides, or electroactive polymers in addition to the SWNTs. In other embodiments of the invention the air cathode is a component of a metal-air battery or a fuel cell.
摘要翻译：本发明的一个实施方案是具有多孔膜的空气阴极，该多孔膜具有至少一个疏水表面，该疏水性表面与包含纳米管紧密电接触的单壁碳纳米管（SWNT）的导电催化膜相接触。除了SWNT之外，导电膜可以包括富勒烯，金属，金属合金，金属氧化物或电活性聚合物。在本发明的其它实施例中，空气阴极是金属 - 空气电池或燃料电池的组件。

8. 发明申请

US20120032104A1 PROCESSING METHOD FOR WATER SOLUBLE POLYMERIC MATERIALS 有权
标题翻译：水溶性聚合材料的加工方法
公开(公告)号：US20120032104A1
公开(公告)日：2012-02-09
申请号：US13196412
申请日：2011-08-02
申请人： Chad Martin Amb , Pierre Marc Beaujuge , John R. Reynolds
发明人： Chad Martin Amb , Pierre Marc Beaujuge , John R. Reynolds
IPC分类号： H01G9/035 , C09K3/16 , B05D1/02 , B05D3/00 , B05D3/10 , H01B1/12 , B05D5/12
CPC分类号： H01B1/122 , C08G2261/3223 , H01G9/022 , Y02E60/13
摘要： Embodiments of the invention are directed to a method of forming a film of an insoluble conjugated polymer (CP) by deposition of an ionic CP from aqueous solution and converting the ionic CP to the insoluble CP. The ionic CP can be the salt of a carboxylic acid, sulfonic acid, phosphonic acid, boronic acid, amine, imine, phosphine, thioether, or complexed bidentate or polydentate ligand. The insoluble CP film can be used with an aqueous electrolyte solution for use as: an electrochromic film; charge injection layer for a solar cell, LED, and FET; conventional paints; supercapacitor; battery; electronic paper; anti-static coating; transparent conductor; sensors; anti-microbial coating; adhesive; RFID; or memory system.
摘要翻译：本发明的实施方案涉及通过从水溶液中沉积离子CP并将离子CP转化为不溶性CP来形成不溶性共轭聚合物（CP）的膜的方法。离子CP可以是羧酸，磺酸，膦酸，硼酸，胺，亚胺，膦，硫醚或络合的二齿或多齿配体的盐。不溶性CP膜可以与电解质溶液一起使用，用作电致变色膜; 用于太阳能电池，LED和FET的电荷注入层; 常规油漆; 超级电容器电池; 电子纸; 防静电涂料; 透明导体传感器; 抗微生物涂层; 胶粘剂; RFID; 或内存系统。

9. 发明授权

US07333257B2 Device for contacting patterned electrodes on porous substrates 有权
标题翻译：用于在多孔基材上接触图案化电极的装置
公开(公告)号：US07333257B2
公开(公告)日：2008-02-19
申请号：US10992827
申请日：2004-11-19
申请人： John R. Reynolds , Avni A. Argun , Pierre Henri Aubert , Mathieu Berard
发明人： John R. Reynolds , Avni A. Argun , Pierre Henri Aubert , Mathieu Berard
IPC分类号： G02F1/153
CPC分类号： H01L27/3248 , G02F1/155 , G02F2001/1555 , G02F2201/42 , H01L21/76898 , H01L33/62 , H01L51/0096 , H01L2224/32225 , H01L2924/12041 , Y02E10/549 , Y10T29/435 , Y10T29/49126
摘要： A method for contacting patterned electrode devices includes the steps of providing a porous substrate, depositing electrically conductive material to form at least one electrode on a front-side of the porous substrate and depositing at least one electrically conductive back-side contact trace on the back-side of the substrate. A portion of the electrically conductive material penetrates into the substrate. A device is formed including the electrode on the front side of the substrate, wherein the electrode is electrically coupled by a conducting channel including the electrically conductive material through the substrate to the back-side contact trace.
摘要翻译：用于接触图案化电极器件的方法包括以下步骤：提供多孔基底，沉积导电材料以在多孔基底的正面上形成至少一个电极，并在背面沉积至少一个导电背面接触迹线的基底。导电材料的一部分渗透到基底中。形成包括在基板的正面上的电极的器件，其中电极通过包括导电材料的导电沟道通过衬底电耦合到背面接触迹线。

10. 发明授权

US07331764B1 High-strength low-weight fan blade assembly 有权
标题翻译：高强度低重量风扇叶片总成
公开(公告)号：US07331764B1
公开(公告)日：2008-02-19
申请号：US10827601
申请日：2004-04-19
申请人： John R. Reynolds , Jay S. Porter
发明人： John R. Reynolds , Jay S. Porter
IPC分类号： F04D29/34
CPC分类号： F04D29/329 , F04D29/023 , F04D29/388 , F05D2300/43 , F05D2300/603
摘要： An engine cooling fan system including a hub disc about which first and/or second pluralities of elongated fan blades characterized by a first and second respective pitch angles may be fastened. Each respective fan blade further comprises a hub-engaging portion, a twisted transition portion and an air-engaging portion. Each fan blade is formed from a composite material having a thermoset resin matrix phase and an evenly dispersed continuous fiber reinforcement phase.
摘要翻译：一种发动机冷却风扇系统，其包括轮毂盘，围绕所述轮毂盘可以紧固以第一和第二相应俯仰角为特征的第一和/或多个细长风扇叶片。每个风扇叶片还包括轮毂接合部分，扭转过渡部分和空气接合部分。每个风扇叶片由具有热固性树脂基体相和均匀分散的连续纤维增强相的复合材料形成。

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