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    • 3. 发明授权
    • Shaped articles
    • 形状文章
    • US5061556A
    • 1991-10-29
    • US482986
    • 1990-02-22
    • Bernhard DotzauerWilhelm F. BeckerleHans-Juergen DenuKurt WendelManfred Schwartz
    • Bernhard DotzauerWilhelm F. BeckerleHans-Juergen DenuKurt WendelManfred Schwartz
    • C04B41/48C04B41/63
    • C04B41/009C04B41/483C04B41/63
    • A shaped article is obtainable by impregnating or coating a preform composed in the main of mineral fibers, nonfibrous mineral fillers and starch with a composition which contains a binder comprising a copolymer composed ofa) 60-95% by weight of methyl methacrylate (monomer I),b) 5-40% by weight of acrylic or methacrylic acid (monomer II)c) 0-35% by weight of one or more acrylic esters of a C.sub.1 -C.sub.8 -alkanol (monomer III),d) 0-5% by weight of a copolymerizable olefinically polyunsaturated monomer (monomer IV), ande) 0-5% by weight of another copolymerizable monomer (monomer V)in polymerized form, the weight percentages of monomers I, II, III and V having been selected within the stated limits in such a way that a polymer composed of these monomers only would have a glass transition temperature of from 60.degree. to 125.degree. C.
    • 可以通过浸渍或涂覆以矿物纤维,非纤维矿物填料和淀粉为主成分的预型体,其中含有包含由以下组成的共聚物的组合物的组合物可获得成型制品:a)60-95重量%的甲基丙烯酸甲酯(单体I ),b)5-40重量%的丙烯酸或甲基丙烯酸(单体II)c)0-35重量%的一种或多种C1-C8-链烷醇(单体III)的丙烯酸酯,d)0-5 可共聚的烯属多不饱和单体(单体IV)的重量%,以及e)0-5重量%的聚合形式的其它可共聚单体(单体V),已经选择了单体I,II,III和V的重量百分数 在所述限度内,使得由这些单体组成的聚合物仅具有60至125℃的玻璃化转变温度。
    • 4. 发明授权
    • Paper-coating compositions
    • 纸涂层组合物
    • US4384069A
    • 1983-05-17
    • US298162
    • 1981-08-31
    • Kurt WendelGunter Hirsch
    • Kurt WendelGunter Hirsch
    • C09D133/02C09D133/04D21H19/00D21H19/44D21H19/58D21H19/60C08L33/20C08L31/02C08L31/04C08L33/02
    • D21H19/58D21H19/60
    • An improved paper-coating composition which contains, per 100 parts by weight of a finely divided pigment, from 5 to 25 parts by weight of a copolymer A, in the form of an aqueous dispersion, as a binder, and from 0.5 to 10 parts by weight of a copolymer B, containing(a) from 20 to 70% by weight of copolymerized units of hydroxy-C.sub.2 -C.sub.4 -alkyl acrylates or hydroxy-C.sub.2 -C.sub.4 -alkyl methacrylates,(b) from 10 to 50% by weight of copolymerized units of acrylic acid, methacrylic acid, maleic acid and/or monoesters of maleic acid and(c) from 5 to 50% by weight of copolymerized units of acrylonitrile, methacrylonitrile, C.sub.1 -C.sub.4 -alkyl acrylates of C.sub.1 -C.sub.4 -alkyl methacrylates, or vinyl esters of saturated C.sub.2 -C.sub.4 -carboxylic acidsas the co-binder, with or without from 0.1 to 2.0 parts by weight of an optical brightener which is activated by the co-binder. The paper-coating composition has high water retention.
    • 一种改进的纸涂层组合物,其包含每100重量份的细分散颜料,5至25重量份的作为粘合剂的水分散体形式的共聚物A和0.5至10重量份 的共聚物B,其包含(a)20至70重量%的丙烯酸羟基-C 2 -C 4烷基酯或甲基丙烯酸羟基-C 2 - C 4烷基酯的共聚单元,(b)10至50重量% 的丙烯酸,甲基丙烯酸,马来酸和/或马来酸的单酯的共聚单元和(c)5-50重量%的丙烯腈,甲基丙烯腈,C 1 -C 4烷基的C 1 -C 4烷基丙烯酸酯的共聚单元 甲基丙烯酸酯或饱和C 2 -C 4羧酸的乙烯基酯作为共粘合剂,具有或不具有0.1至2.0重量份由共粘合剂活化的荧光增白剂。 纸张涂料组合物具有高保水性。