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1. 发明授权

US07511096B2 Crosslinked polyvinyl acetals 失效
标题翻译：交联聚乙烯醇缩醛
公开(公告)号：US07511096B2
公开(公告)日：2009-03-31
申请号：US10542019
申请日：2003-12-12
申请人： Bernd Papenfuhs , Martin Steuer , Matthias Gutweiler
发明人： Bernd Papenfuhs , Martin Steuer , Matthias Gutweiler
IPC分类号： C08F8/00
CPC分类号： C08F8/28 , C08F8/48 , C08F16/06 , C08F8/12 , C08F118/08
摘要： The invention relates to methods for producing crosslinked polyvinyl acetals, according to which a polyvinyl alcohol (A1) containing carboxyl groups is crosslinked by (i) reacting the polymer (A1) with at least one polyaldehyde of formula R9(CHO)n, and (ii) at least partly esterifying groups of formula (1) and formula (4a) with each other, said steps being performed in any order. The invention further relates to methods for producing crosslinked polyvinyl acetals, according to which a polyvinyl alcohol (A2) is crosslinked by (i) reacting the polymer (A2) with at least one compound of formula (6), (ii) adding at least one compound of formula (4b), (iii) adding a polyaldehyde of formula (5), and (iv) at least partly esterifying groups of formula (1) and structural units derived from the compound of formula (4b) with each other, the radicals R7, R8, R9, R10, and R11, and the index n being defined as indicated in the description. Also disclosed are the crosslinked polyvinyl acetals obtained by means of the inventive method and particularly appropriate areas of application of said polymers.
摘要翻译：本发明涉及交联聚乙烯醇缩醛的制备方法，根据该方法，含有羧基的聚乙烯醇（A1）通过（i）聚合物（A1）与至少一种式R9（CHO）n的多醛和（ ii）至少部分酯化式（1）和式（4a）的基团彼此，所述步骤以任何顺序进行。本发明还涉及生产交联聚乙烯醇缩醛的方法，其中聚乙烯醇（A2）通过（i）使聚合物（A2）与至少一种式（6）化合物反应而交联，（ii）至少加入一种式（4b）的化合物，（iii）加入式（5）的聚醛，和（iv）至少部分酯化式（1）的基团和由式（4b）化合物衍生的结构单元彼此，基团R 7，R 8，R 9，R 10和R 11，并且索引n如描述中所示定义。还公开了通过本发明方法获得的交联的聚乙烯醇缩醛，特别适合所述聚合物的应用领域。

2. 发明申请

US20060052533A1 Crosslinked polyvinyl acetals 失效
标题翻译：交联聚乙烯醇缩醛
公开(公告)号：US20060052533A1
公开(公告)日：2006-03-09
申请号：US10542019
申请日：2003-12-12
申请人： Bernd Papenfuhs , Martin Steuer , Matthias Gutweiler
发明人： Bernd Papenfuhs , Martin Steuer , Matthias Gutweiler
IPC分类号： C08F8/00
CPC分类号： C08F8/28 , C08F8/48 , C08F16/06 , C08F8/12 , C08F118/08
摘要： The invention relates to methods for producing crosslinked polyvinyl acetals, according to which a polyvinyl alcohol (A1) containing carboxyl groups is crosslinked by (i) reacting the polymer (A1) with at least one polyaldehyde of formula R9(CHO)n, and (ii) at least partly esterifying groups of formula (1) and formula (4a) with each other, said steps being performed in any order. The invention further relates to methods for producing crosslinked polyvinyl acetals, according to which a polyvinyl alcohol (A2) is crosslinked by (i) reacting the polymer (A2) with at least one compound of formula (6), (ii) adding at least one compound of formula (4b), (iii) adding a polyaldehyde of formula (5), and (iv) at least partly esterifying groups of formula (1) and structural units derived from the compound of formula (4b) with each other, the radicals R7, R8, R9, R10, and R11, and the index n being defined as indicated in the description. Also disclosed are the crosslinked polyvinyl acetals obtained by means of the inventive method and particularly appropriate areas of application of said polymers.
摘要翻译：本发明涉及交联聚乙烯醇缩醛的制备方法，根据该方法，含有羧基的聚乙烯醇（A1）通过（i）聚合物（A1）与至少一种式R 9的多醛（CHO）n ，和（ii）使式（1）和式（4a）的基团至少部分酯化，所述步骤以任何顺序进行。本发明还涉及生产交联聚乙烯醇缩醛的方法，其中聚乙烯醇（A2）通过（i）使聚合物（A2）与至少一种式（6）化合物反应而交联，（ii）至少加入一种式（4b）的化合物，（iii）加入式（5）的聚醛，和（iv）至少部分酯化式（1）的基团和由式（4b）化合物衍生的结构单元彼此，基团R 7，R 8，R 9，R 10和R 11， SUP>，并且索引n被定义为如说明书中所示。还公开了通过本发明方法获得的交联的聚乙烯醇缩醛，特别适合所述聚合物的应用领域

3. 发明授权

US07528192B2 Crosslinked polyvinyl acetals 失效
标题翻译：交联聚乙烯醇缩醛
公开(公告)号：US07528192B2
公开(公告)日：2009-05-05
申请号：US10542022
申请日：2003-12-12
申请人： Bernd Papenfuhs , Martin Steuer , Matthias Gutweiler
发明人： Bernd Papenfuhs , Martin Steuer , Matthias Gutweiler
IPC分类号： C08F8/00
CPC分类号： B32B17/10761 , C08F8/00 , C08F16/06
摘要： The invention relates to a method for producing crosslinked polyvinyl acetals, according to which a vinyl alcohol copolymer is reacted with at least one polyaldehyde and is partly esterified.
摘要翻译：本发明涉及一种生产交联聚乙烯醇缩醛的方法，根据该方法，乙烯醇共聚物与至少一种多醛反应并部分酯化。

4. 发明申请

US20060205871A1 Crosslinked polyvinyl acetals 失效
公开(公告)号：US20060205871A1
公开(公告)日：2006-09-14
申请号：US10542022
申请日：2003-12-12
申请人： Bernd Papenfuhs , Martin Steuer , Matthias Gutweiler
发明人： Bernd Papenfuhs , Martin Steuer , Matthias Gutweiler
IPC分类号： C08F8/00
CPC分类号： B32B17/10761 , C08F8/00 , C08F16/06
摘要： The invention relates to a method for producing crosslinked polyvinyl acetals, according to which a vinyl alcohol copolymer is reacted with at least one polyaldehyde and is partly esterified.

5. 发明授权

US07312275B2 Cross-linked polyvinyl acetals 失效
标题翻译：交联聚乙烯醇缩醛
公开(公告)号：US07312275B2
公开(公告)日：2007-12-25
申请号：US10519133
申请日：2003-07-01
申请人： Bernd Papenfuhs , Martin Steuer , Simon Jonas
发明人： Bernd Papenfuhs , Martin Steuer , Simon Jonas
IPC分类号： C08F8/00 , C08G64/14
CPC分类号： C08F8/28 , C08F8/48 , C08F16/06
摘要： The invention relates to a cross-linked polyvinyl acetal which is characterized in that it can be obtained from at least one polyvinylacetal (1) which is obtained by reacting at least one polymer (A), which contains a) 1,0 to 99.9 wt. % structural units of formula (1), b.) 0 to 99.0 wt. % structural units of formula (2), c.) 0 to 70.0 wt. % structural formula (3), d.) 0.0001 to 30.0 wt. % structural units of formula (4) respectively in relation to the overall weight of the polymer (A), with at least one compound (B) of formula (5). Furthermore, the present invention relates to methods for the production of the polyvinyl acetal according to the invention as well as its use.
摘要翻译：本发明涉及一种交联聚乙烯醇缩醛，其特征在于可从至少一种聚乙烯醇缩醛（1）获得，所述聚乙烯醇缩醛（1）是通过使至少一种聚合物（A）反应得到的，所述聚合物（A）含有a）。式（1）的％结构单元，b。）0至99.0wt。式（2）的％结构单元，c。）0-70.0wt。％结构式（3），d。）0.0001〜30.0重量％相对于聚合物（A）的总重量，分别为式（4）的％结构单元与至少一种式（5）的化合物（B）。此外，本发明涉及根据本发明的聚乙烯醇缩醛的制备方法及其用途。

6. 发明申请

US20050239960A1 Cross-linked polyvinyl acetals 失效
标题翻译：交联聚乙烯醇缩醛
公开(公告)号：US20050239960A1
公开(公告)日：2005-10-27
申请号：US10519133
申请日：2003-07-01
申请人： Bernd Papenfuhs , Martin Steuer , Simon Jonas
发明人： Bernd Papenfuhs , Martin Steuer , Simon Jonas
IPC分类号： C08F16/38 , C08F8/28 , C08F8/00
CPC分类号： C08F8/28 , C08F8/48 , C08F16/06
摘要： The invention relates to a cross-linked polyvinyl acetal which is characterized in that it can be obtained from at least one polyvinylacetal (1) which is obtained by reacting at least one polymer (A), which contains a) 1,0 to 99.9 wt. % structural units of formula (1), b.) 0 to 99.0 wt. % structural units of formula (2), c.) 0 to 70.0 wt. % structural formula (3), d.) 0.0001 to 30.0 wt. % structural units of formula (4) respectively in relation to the overall weight of the polymer (A), with at least one compound (B) of formula (5). Furthermore, the present invention relates to methods for the production of the polyvinyl acetal according to the invention as well as its use.
摘要翻译：本发明涉及一种交联聚乙烯醇缩醛，其特征在于可从至少一种聚乙烯醇缩醛（1）获得，所述聚乙烯醇缩醛（1）是通过使至少一种聚合物（A）反应得到的，所述聚合物（A）含有a）。式（1）的％结构单元，b。）0至99.0wt。式（2）的％结构单元，c。）0-70.0wt。％结构式（3），d。）0.0001〜30.0重量％相对于聚合物（A）的总重量，分别为式（4）的％结构单元与至少一种式（5）的化合物（B）。此外，本发明涉及根据本发明的聚乙烯醇缩醛的制备方法及其用途。

7. 发明授权

US07358304B2 High-molecular, crosslinked polyvinyl butyrals, method for the production and use thereof 失效
标题翻译：高分子交联聚乙烯醇缩丁醛，其制备方法和用途
公开(公告)号：US07358304B2
公开(公告)日：2008-04-15
申请号：US10488593
申请日：2002-08-31
申请人： Bernd Papenfuhs , Martin Steuer , Simon Jonas
发明人： Bernd Papenfuhs , Martin Steuer , Simon Jonas
IPC分类号： C08F8/00 , C08F8/14
CPC分类号： B32B17/10761 , B32B17/10688 , B32B17/10697 , C08J5/18
摘要： The invention relates to high-molecular, crosslinked polyvinyl butyrals, obtainable by (self-) crosslinking polyvinyl butyrals that contain coacetalated, acid-functionalized aldehydes. The invention also relates to a method for producing the same and to the use thereof.
摘要翻译：本发明涉及通过（自）交联聚乙烯醇缩丁醛得到的高分子交联聚乙烯醇缩丁醛，其含有共缩醛酸官能化醛。本发明还涉及其制备方法及其用途。

8. 发明授权

US08188182B2 Ion-conductive thermoplastic compositions for electrochromic glazing 失效
标题翻译：用于电致变色玻璃的离子导电热塑性组合物
公开(公告)号：US08188182B2
公开(公告)日：2012-05-29
申请号：US10560902
申请日：2004-06-17
申请人： Holger Stenzel , Alexander Kraft , Karl-Heinz Heckner , Matthias Rottmann , Bernd Papenfuhs , Martin Steuer
发明人： Holger Stenzel , Alexander Kraft , Karl-Heinz Heckner , Matthias Rottmann , Bernd Papenfuhs , Martin Steuer
IPC分类号： C08G18/08 , C08G63/48 , C08G63/91 , C08K3/00 , C08F8/00
CPC分类号： H01B1/122 , B32B17/10577 , B32B17/10761 , C09K9/02 , G02F1/1525 , G02F2001/1502 , G02F2001/1519
摘要： The invention relates to ion-conductive thermoplastic compositions consisting of a partially acetalated polyvinyl alcohol, at least one support electrolyte and at least one softener, the partially acetalated polyvinyl alcohol containing two different acetal units. The invention also relates to electrochromic laminated glass systems produced using the ion-conductive compositions and to a method for producing said systems.
摘要翻译：本发明涉及由部分缩醛化的聚乙烯醇，至少一种支持电解质和至少一种软化剂组成的离子导电热塑性组合物，该部分缩醛化的聚乙烯醇含有两个不同的缩醛单元。本发明还涉及使用离子传导性组合物制造的电致变色夹层玻璃系统及其制造方法。

9. 发明授权

US06984679B2 Plasticizer-containing polyvinylbutyrals, method for producing the same and the use thereof, especially for producing films for use in laminated safety glasses 失效
标题翻译：含增塑剂的聚乙烯醇缩丁醛，其制备方法及其用途，特别是用于制备用于层压安全眼镜的膜
公开(公告)号：US06984679B2
公开(公告)日：2006-01-10
申请号：US10451372
申请日：2001-12-22
申请人： Bernd Papenfuhs , Martin Steuer
发明人： Bernd Papenfuhs , Martin Steuer
IPC分类号： C08K5/09
CPC分类号： B32B17/10761 , B32B17/10605 , C08K5/103 , Y10T428/252 , C08L29/14
摘要： The invention relates to plasticizer-containing polyvinylbutyrals that are characterized by containing as the plasticizer at least one dibenzoate of alkylene and polyalkylene glycols. The invention further relates to a method for producing said compounds, and to their use in molding compounds of all types, especially for producing films that can for example be used as an intermediate layer in laminated safety glasses.
摘要翻译：本发明涉及含增塑剂的聚乙烯醇缩丁醛，其特征在于含有至少一种亚烷基和聚亚烷基二醇的二苯甲酸酯作为增塑剂。本发明还涉及一种生产所述化合物的方法，以及它们在模塑所有类型的化合物中的用途，特别是用于生产可用作层压安全眼镜中的中间层的膜。

10. 发明授权

US09034984B2 Ion-conductive thermoplastic composition, electrochromic composite system and process for producing ion-conductive foil 有权
标题翻译：离子导电热塑性组合物，电致变色复合体系和离子导电箔生产工艺
公开(公告)号：US09034984B2
公开(公告)日：2015-05-19
申请号：US13472820
申请日：2012-05-16
申请人： Holger Stenzel , Alexander Kraft , Karl-Heinz Heckner , Matthias Rottmann , Bernd Papenfuhs , Martin Steuer
发明人： Holger Stenzel , Alexander Kraft , Karl-Heinz Heckner , Matthias Rottmann , Bernd Papenfuhs , Martin Steuer
IPC分类号： C08G18/08 , C08G63/48 , C08G63/91 , C08K3/00 , C08F8/00 , H01B1/12 , B32B17/10 , C09K9/02
CPC分类号： H01B1/122 , B32B17/10577 , B32B17/10761 , C09K9/02 , G02F1/1525 , G02F2001/1502 , G02F2001/1519
摘要： An ion-conductive thermoplastic compositions contains a partially acetalated polyvinyl alcohol, at least one support electrolyte and at least one plasticizer. The partially acetalated polyvinyl alcohol contains two different acetal units. Electrochromic laminated glass systems produced using the ion-conductive compositions and a method for producing the systems are also provided.
摘要翻译：离子导电热塑性组合物含有部分缩醛化的聚乙烯醇，至少一种载体电解质和至少一种增塑剂。部分缩醛化的聚乙烯醇含有两个不同的缩醛单元。还提供了使用离子导电组合物制备的电致变色夹层玻璃系统和用于生产该系统的方法。

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