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1. 发明授权

US6166248A Process for the separation of acrylic acid 失效
标题翻译：丙烯酸分离方法
公开(公告)号：US6166248A
公开(公告)日：2000-12-26
申请号：US147628
申请日：1999-02-04
申请人： Bernd Heida , Fritz Thiessen , Ulrich Hammon , Albrecht Dams
发明人： Bernd Heida , Fritz Thiessen , Ulrich Hammon , Albrecht Dams
IPC分类号： C07C51/25 , C07C51/48 , C07C57/05 , C07C57/07 , C07C51/16 , C07C241/00
CPC分类号： C07C51/48 , C07C57/04
摘要： A process for isolating acrylic acid forward during catalytic gas phase oxidation of propene, which entails separating acrylic acid from the gas phase oxidation reaction using an absorbent containing biphenyl, diphenyl ether or dimethyl phthalate; and extracting acrylic acid from acid water of the gas phase reaction with a solvent containing biphenyl, diphenyl ether or dimethyl phthalate.
摘要翻译： PCT No.PCT / EP97 / 04214 Sec。 371日期1999年2月4日 102（e）1999年2月4日PCT PCT 1997年8月1日PCT公布。第WO98 / 05622号公报日期1998年2月12日在丙烯的催化气相氧化中丙烯酸向前分离的方法，其需要使用含有联苯，二苯基醚或邻苯二甲酸二甲酯的吸收剂从丙烯酸与气相氧化反应分离; 并与含有联苯，二苯基醚或邻苯二甲酸二甲酯的溶剂从气相反应的酸性水中萃取丙烯酸。

2. 发明授权

US5173468A Compositions of the formula MO.sub.12 P.sub.a V.sub.b X.sup.1.sub.c X.sup.2.sub.d X.sup.3.sub.e Sb.sub.f Re.sub.g S.sub.h O.sub.n 失效
标题翻译：公式MO12PAVBX1CX2DX3ESBFREGSHON的组合物
公开(公告)号：US5173468A
公开(公告)日：1992-12-22
申请号：US729169
申请日：1991-07-12
申请人： Karl-Heinz Boehning , Gerd Duembgen , Ulrich Hammon , Richard Krabetz , Franz Merger , Matthias Schwarzmann , Fritz Thiessen , Herbert Vogel
发明人： Karl-Heinz Boehning , Gerd Duembgen , Ulrich Hammon , Richard Krabetz , Franz Merger , Matthias Schwarzmann , Fritz Thiessen , Herbert Vogel
IPC分类号： B01J27/19 , B01J27/199 , C07B61/00 , C07C57/055
CPC分类号： B01J23/002 , B01J27/199 , B01J2523/00
摘要： Compositions of the formula IMO.sub.12 P.sub.a V.sub.b X.sup.1.sub.c X.sup.2.sub.d X.sup.3.sub.e Sb.sub.f Re.sub.g S.sub.h O.sub.n (I)whereX.sup.1 is potassium, rubidium and/or cesium,X.sup.2 is copper and/or silver,X.sup.3 is cerium, boron, zirconium, manganese and/or bismuth,a is from 0.5 to 3.0,b is from 0.01 to 3.0,c is from 0.2 to 3.0,d is from 0.01 to 2.0,e is from 0 to 2.0,f is from 0.01 to 2.0,g is from 0 to 1.0,h is from 0.001 to 0.5 andn is a number determined by the valency and content ofthe elements different from oxygen in I, are used as catalysts for preparing methacrylic acid by gas-phase oxidation of methacrolein.
摘要翻译：式I MO12PaVbX1cX2dX3eSbfRegShOn（I）的组成，其中X1是钾，铷和/或铯，X2是铜和/或银，X3是铈，硼，锆，锰和/或铋，a是0.5-3.0，b 为0.01〜3.0，c为0.2〜3.0，d为0.01〜2.0，e为0〜2.0，f为0.01〜2.0，g为0〜1.0，h为0.001〜0.5，n为由I中不同于氧的元素的化合价和含量确定的数字被用作通过甲基丙烯醛的气相氧化制备甲基丙烯酸的催化剂。

3. 发明授权

US5221767A Compositions of the formula Mo.sub.12 P.sub.a V.sub.b X.sup.1 c X.sup.2 d X.sup.3 e Sb.sub.f Re.sub.g S.sub.h O.sub.n 失效
标题翻译：式组成Mo12 Pa Vb X1c X2d X3e Sbf Reg Sh On
公开(公告)号：US5221767A
公开(公告)日：1993-06-22
申请号：US928334
申请日：1992-08-12
申请人： Karl-Heinz Boehning , Gerd Duembgen , Ulrich Hammon , Richard Krabetz , Franz Merger , Matthias Schwarzmann , Fritz Thiessen , Herbert Vogel
发明人： Karl-Heinz Boehning , Gerd Duembgen , Ulrich Hammon , Richard Krabetz , Franz Merger , Matthias Schwarzmann , Fritz Thiessen , Herbert Vogel
IPC分类号： B01J27/199
CPC分类号： B01J23/002 , B01J27/199 , B01J2523/00
摘要： Compositions of the formula IMo.sub.12 P.sub.a V.sub.b X.sub.c.sup.1 X.sub.d.sup.2 X.sub.e.sup.3 Sb.sub.f Re.sub.g S.sub.h O.sub.n (I),whereX.sup.1 is potassium, rubidium and/or cesium,X.sup.2 is copper and/or silver,X.sup.3 is cerium, boron, zirconium, manganese and/or bismuth,a is from 0.5 to 3.0,b is from 0.01 to 3.0,c is from 0.2 to 3.0,d is from 0.01 to 2.0,e is from 0 to 2.0,f is from 0.01 to 2.0,g is from 0 to 1.0,h is from 0.001 to 0.5 andn is a number determined by the valency and content of the elements different from oxygen in I, are used as catalysts for preparing methacrylic acid by gas-phase oxidation of methacrolein.
摘要翻译：式I Mo12Pa VbXc1Xd2Xe3SbfRegShOn（I）的组成，其中X1是钾，铷和/或铯，X2是铜和/或银，X3是铈，硼，锆，锰和/或铋，a是0.5-3.0 ，b为0.01〜3.0，c为0.2〜3.0，d为0.01〜2.0，e为0〜2.0，f为0.01〜2.0，g为0〜1.0，h为0.001〜0.5， n是由I中不同于氧的元素的化合价和含量确定的数，用作通过甲基丙烯醛的气相氧化制备甲基丙烯酸的催化剂。

4. 发明授权

US5087744A Preparation of methacrylic acid 失效
标题翻译：甲基丙烯酸的制备
公开(公告)号：US5087744A
公开(公告)日：1992-02-11
申请号：US213837
申请日：1988-06-30
申请人： Richard Krabetz , Gerd Duembgen , Franz Merger , Michael Jaeger , Fritz Thiessen , Herbert Vogal
发明人： Richard Krabetz , Gerd Duembgen , Franz Merger , Michael Jaeger , Fritz Thiessen , Herbert Vogal
IPC分类号： B01J27/19 , C07B63/04 , C07C51/00 , C07C51/235 , C07C51/25 , C07C57/055 , C07C57/07 , C07C67/00
CPC分类号： C07C51/252
摘要： Methacrylic acid can be prepared with advantage by gas phase oxidation of methacrolein or isobutyraldehyde over Mo- and P-containing catalysts at from 250.degree. to 400.degree. C. with cooling of the hot reaction gas to below 100.degree. C., absorption of the methacrylic acid in a water-operated absorption column, at below 100.degree. C. and partial recycling into the oxidation reactor after admixture of methacrolein or isobutyraldehyde and oxygen by feeding a quantity of methacrolein or isobutyraldehyde equal to the quantity of methacrolein or isobutyraldehyde consumed in the reaction in liquid form together with a polymerization inhibitor into the reactor gas in the lower two-thirds of the absorber column and upstream of the feed point for the fresh methacrolein or isobutyraldehyde or down-stream of the absorption column splitting off the reactor off-gas a side stream which is washed in a wash column operated with water at
摘要翻译：甲基丙烯酸可以通过在250℃至400℃的含Mo和P的催化剂上甲基丙烯醛或异丁醛的气相氧化来制备，同时将热反应气体冷却至低于100℃，吸收甲基丙烯酸酸在水性吸收塔中，低于100℃，并通过加入与反应中消耗的甲基丙烯醛或异丁醛的量相等的量的异丁烯醛或异丁醛，将甲基丙烯醛或异丁醛和氧气混合后，部分再循环进入氧化反应器液体形式与聚合抑制剂一起在吸收塔的下三分之二的反应器气体中，在新鲜的甲基丙烯醛或异丁醛的进料点的上游或吸收塔的下游分离反应器废气a 侧流在洗涤塔中用水在<10℃下洗涤以除去未转化的异丁烯醛或异丁醛，其为f 作为吸收塔顶部的水溶液。

5. 发明授权

US4031135A Manufacture of acrylic acid by oxidation of propylene with oxygen-containing gases in two separate catalyst stages 失效
标题翻译：通过在两个独立的催化剂阶段用含氧气体氧化丙烯来制造丙烯酸
公开(公告)号：US4031135A
公开(公告)日：1977-06-21
申请号：US595321
申请日：1975-07-11
申请人： Heinz Engelbach , Richard Krabetz , Gerd Duembgen , Carl-Heinz Willersinn , Ulrich Lebert , Fritz Thiessen
发明人： Heinz Engelbach , Richard Krabetz , Gerd Duembgen , Carl-Heinz Willersinn , Ulrich Lebert , Fritz Thiessen
IPC分类号： C07C57/05 , C07C45/35 , C07C51/00 , C07C51/25 , C07C57/055 , C07C67/00 , C07C51/32
CPC分类号： C07C45/35 , C07C51/252
摘要： In the oxidation of propylene to acrylic acid in the gas phase in two spatially separate oxidation stages, a part of the off-gas, which has been freed from condensable products, is fed to the oxidation stages in addition to freshly charged propylene and air, under the following conditions:A. The recycled off-gas and air are in part fed to the first oxidation stage and in part to the second oxidation stage,B. The molar ratio of propylene : oxygen : residual gases fed to the first stage is 1 : 1.5-2.3 : 11-19,C. The molar ratio of the total propylene fed in, to the total oxygen fed in, in the form of air or off-gas, before and after the first stage, and to the total residual gases fed in is 1 : 1.9-2.5 : 13-25, with the proviso thatD. The air and the recycled off-gas are divided between the two feed points in such a way that from 10 to 50% by volume of the total quantity of air and off-gas fed in are added after the first stage andE. The air and off-gas are admixed to the reaction gas mixture after the first stage, immediately after it leaves the catalyst zone, so that the mixture is rapidly cooled to a temperature of from 150.degree. to 320.degree. C.
摘要翻译：在两个空间分离的氧化阶段中，在气相中将丙烯氧化成丙烯酸，除了新鲜电荷的丙烯和空气之外，将一部分已经脱除可冷凝产物的废气进料到氧化阶段，在以下条件下：

6. 发明授权

US4259211A Catalyst for the oxidation of acrolein and methacrolein to acrylic acid and methacrylic acid, respectively 失效
标题翻译：分别将丙烯醛和甲基丙烯醛氧化成丙烯酸和甲基丙烯酸的催化剂
公开(公告)号：US4259211A
公开(公告)日：1981-03-31
申请号：US963203
申请日：1978-11-24
申请人： Richard Krabetz , Walter Herrmann , Norbert Scholz , Heinz Engelbach , Gerd-Juergen Engert , Carl-Heinz Willersinn , Gerd Duembgen , Fritz Thiessen
发明人： Richard Krabetz , Walter Herrmann , Norbert Scholz , Heinz Engelbach , Gerd-Juergen Engert , Carl-Heinz Willersinn , Gerd Duembgen , Fritz Thiessen
IPC分类号： B01J23/00 , B01J23/24 , B01J23/28 , B01J23/30 , B01J23/31 , B01J23/34 , B01J23/88 , B01J23/89 , B01J37/02 , C07B61/00 , C07C51/00 , C07C51/25 , C07C57/055 , C07C67/00 , B01J23/22 , B01J23/72
CPC分类号： B01J23/887 , B01J23/002 , B01J23/24 , B01J23/34 , B01J37/0221 , B01J37/0236 , C07C51/252 , B01J2523/00
摘要： Catalysts which consist of a molded carrier, the surface of which is coated with an active catalyst composition of the general formula Mo.sub.12 A.sub.a B.sub.b C.sub.c D.sub.d O.sub.x, where A is V and/or W, B is Cu and/or Fe and/or Mn and/or Ni and/or Cr, C is Nb and/or Ta and/or Bi and/or Sb and/or Sn and/or Th and/or Ce and/or U, D is Li and/or Na and/or K and/or Rb and/or Cs and/or Tl and a is from 0.1 to 18, b is from 0 to 8, c is from 0 to 10, d is from 0 to 2 and x is from 36 to 135, which are particularly active and selective for the oxidation of acrolein and methacrolein with oxygen-containing gases to give acrylic acid and methacrylic acid, respectively, are obtained by first manufacturing the catalyst composition, before applying it to the carrier, from thermally easily decomposed salts of the components by mixing aqueous solutions, slurries or moist solid masses of the salts of the components, drying the mixture and calcining the dried composition at from 140.degree. to 600.degree. C., then milling it to a particle size of less than 150 .mu.m and thereafter applying it, as a mixture with water, as a layer from 10 to 1,500 .mu.m thick, to the premolded carrier, which has a rough surface.
摘要翻译：催化剂由模制载体组成，其表面涂覆有通式为Mo12AaBbCcDdOx的活性催化剂组合物，其中A为V和/或W，B为Cu和/或Fe和/或Mn和/或Ni，和 /或Cr，C是Nb和/或Ta和/或Bi和/或Sb和/或Sn和/或Th和/或Ce和/或U，D是Li和/或Na和/或K和/或 Rb和/或Cs和/或T1和a为0.1至18，b为0至8，c为0至10，d为0至2，x为36至135，特别有活性，选择性地分别用含氧气体氧化丙烯醛和甲基丙烯醛以产生丙烯酸和甲基丙烯酸，这是通过首先在将催化剂组合物施加到载体上之前通过将组分的热容易分解的盐混合溶液，浆液或湿固体组分的盐的组分，干燥混合物并在140℃至600℃下煅烧干燥的组合物，然后将其研磨成颗粒尺寸小于150μm，然后将其作为与水混合的10至1,500μm厚的层涂于具有粗糙表面的预成型载体上。

7. 发明授权

US5788895A Mass transfer in plate columns and apparatus for this purpose 失效
标题翻译：用于此目的的板柱和装置中的质量传递
公开(公告)号：US5788895A
公开(公告)日：1998-08-04
申请号：US692189
申请日：1996-08-05
申请人： Gerhard Altinger , Horst Egly , Rudolf Kaiser , Fritz Thiessen
发明人： Gerhard Altinger , Horst Egly , Rudolf Kaiser , Fritz Thiessen
IPC分类号： B01D3/22 , B01D3/32 , B01J19/32 , C07C51/42 , C07C57/04 , B01F3/04
CPC分类号： B01D3/324 , C07C51/42
摘要： Column tray for a mass transfer column, in particular one provided with a support ring at the circumference, which tray has support elements and tray plates arranged side by side on the support elements and having passages, in particular holes, valves or bubble caps, wherein the majority, preferably the total number, of tray plates are connected liquid-tight, preferably welded, to the support elements or the support ring, in particular in discrete area elements; the majority, preferably the total number, of support elements are connected liquid-tight, preferably welded, to one another and to the column wall or the support ring, in particular in discrete area elements; and in addition the majority, preferably the total number, of adjacent tray plates and support elements are separated from one another and from the column wall or the support ring by gaps having a width of from 1 to 15 mm, preferably from 1 to 7 mm.
摘要翻译：用于传质柱的塔盘，特别是在圆周上设置有支撑环的托盘，托盘具有支撑元件和托盘板，该支撑元件和托盘板并排布置在支撑元件上，并且具有通道，特别是孔，阀或气泡盖，其中托盘板的大部分，优选总数优选地被焊接到支撑元件或支撑环上，特别是在离散区域元件中; 支撑元件的大部分，优选地，总数量液体密封，优选地焊接到彼此，并且连接到柱壁或支撑环，特别是在离散区域元件中; 此外，相邻的托盘板和支撑元件的大部分，优选地，总数彼此分离，并且从柱壁或支撑环分离出宽度为1至15mm，优选为1至7mm的间隙。

8. 发明授权

US4110370A Method of separating high-boiling or non-volatile materials 失效
标题翻译：分离高沸点或非挥发性物质的方法
公开(公告)号：US4110370A
公开(公告)日：1978-08-29
申请号：US620252
申请日：1975-10-07
申请人： Heinz Engelbach , Richard Krabetz , Gerd Duembgen , Carl-Heinz Willersinn , Walter Frey , Ulrich Lebert , Fritz Thiessen
发明人： Heinz Engelbach , Richard Krabetz , Gerd Duembgen , Carl-Heinz Willersinn , Walter Frey , Ulrich Lebert , Fritz Thiessen
IPC分类号： C07C51/00 , C07C51/44 , C07C51/48 , C07C57/07 , C07C67/00 , C07C57/04 , B01D1/14
CPC分类号： C07C51/48 , Y10S203/22
摘要： In the oxidation of propylene and/or acrolein, high-boiling or non-volatile byproducts are separated from the solvents used for absorbing the acrylic acid by treating the said solvents laden with byproducts with the hot reaction gases in such amounts that the major portion of the solvents evaporates, the residual solvent containing a high percentage of said byproducts then being discarded or worked up.
摘要翻译：在丙烯和/或丙烯醛的氧化中，将高沸点或非挥发性副产物与用于吸收丙烯酸的溶剂分离，通过用热反应气体处理含有副产物的所述溶剂，使得主要部分溶剂蒸发，含有高百分比的所述副产物的残留溶剂然后被丢弃或处理。

9. 发明授权

US4052450A Catalytic oxidation of .alpha.-olefins 失效
标题翻译： '烯烃的催化氧化
公开(公告)号：US4052450A
公开(公告)日：1977-10-04
申请号：US405152
申请日：1973-10-10
申请人： Richard Krabetz , Heinz Engelbach , Ulrich Lebert , Walter Frey , Gerd Duembgen , Fritz Thiessen , Carl-Heinz Willersinn
发明人： Richard Krabetz , Heinz Engelbach , Ulrich Lebert , Walter Frey , Gerd Duembgen , Fritz Thiessen , Carl-Heinz Willersinn
IPC分类号： C07C47/22 , B01J21/00 , B01J23/00 , B01J23/28 , B01J23/31 , B01J23/88 , B01J23/887 , B01J23/888 , C07B61/00 , C07C45/00 , C07C45/34 , C07C45/35 , C07C51/25 , C07C67/00 , C07C255/08 , C07C51/32
CPC分类号： B01J23/31 , B01J23/8876 , B01J23/8885 , C07C45/34 , C07C45/35 , C07C51/252 , B01J2523/00
摘要： In the oxidation of .alpha.-olefins in the gas phase to .alpha.,.beta.-olefinically unsaturated aldehydes and carboxylic acids with molecular oxygen in the presence of an inert gas using a catalyst containing molybdenum and bismuth with elements as oxides or mixed oxides at from 280.degree. to 450.degree. C a content of indium and/or aluminum and/or lanthanum and/or gallium as oxide or mixed oxide results in an improvement in the conversion and/or activity and/or life of the catalyst.

10. 发明授权

US3932500A Recovering anhydrous acrylic acid 失效
标题翻译：回收无水丙烯酸
公开(公告)号：US3932500A
公开(公告)日：1976-01-13
申请号：US272551
申请日：1972-07-17
申请人： Gerd Duembgen , Heinz Engelbach , Walter Frey , Richard Krabetz , Ulrich Lebert , Hermann Spitzl , Fritz Thiessen , Carl-Heinz Willersinn
发明人： Gerd Duembgen , Heinz Engelbach , Walter Frey , Richard Krabetz , Ulrich Lebert , Hermann Spitzl , Fritz Thiessen , Carl-Heinz Willersinn
IPC分类号： C07C51/25 , C07C51/48 , C07C57/07 , C07C53/00 , C07C55/00 , C07C57/00 , C07C59/00
CPC分类号： C07C51/252 , C07C51/48
摘要： Acrylic acid practically devoid of water, acrolein, formaldehyde and acetic acid is obtained at particularly low cost by countercurrent scrubbing and quenching of the reaction gas formed in the catalytic oxidation of propylene and/or acrolein with a high-boiling, extremely hydrophobic solvent followed by processing of the extract.
摘要翻译：丙烯酸，甲醛和乙酸实际上不含水，丙烯醛，甲醛和乙酸通过逆流洗涤和猝灭丙烯和/或丙烯醛在高沸点，极疏水溶剂的催化氧化中形成的反应气体而得到，处理提取物。

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