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1. 发明授权

US4981617A Process for the preparation of reaction products of epoxidized ricinoleic acid glycerides with sulfur trioxide 失效
标题翻译：环氧化蓖麻油酸甘油酯与三氧化硫的反应产物的制备方法
公开(公告)号：US4981617A
公开(公告)日：1991-01-01
申请号：US240772
申请日：1988-09-02
申请人： Bernd Fabry , Robert Piorr , Frank Clasen , Horst Ritterbex , Hans Bornmann
发明人： Bernd Fabry , Robert Piorr , Frank Clasen , Horst Ritterbex , Hans Bornmann
IPC分类号： C07C303/00 , C07C305/02 , C07C305/04 , C07C305/10 , C07C309/00 , C07C311/00 , C11D1/28
CPC分类号： C07C303/24
摘要： The sulfonation of epoxidized ricinoleic acid glycerides with a dry stream of gaseous sulfur trioxide diluted with a carrier gas, followed by a reaction of the sulfonated reaction product with nucleophiles, leads to salt-free and anhydrous products showing surface-active properties.
摘要翻译：用载气稀释的气态三氧化硫干燥流体，随后将磺化反应产物与亲核试剂反应的环氧化蓖麻油酸甘油酯的磺化产生显示表面活性的无盐和无水产品。

2. 发明授权

US5312932A Process for the continuous production of partial glyceride sulfates 失效
标题翻译：连续生产偏甘油酯硫酸盐的方法
公开(公告)号：US5312932A
公开(公告)日：1994-05-17
申请号：US66170
申请日：1993-08-03
申请人： Ansgar Behler , Uwe Ploog , Bernd Fabry , Frank Clasen
发明人： Ansgar Behler , Uwe Ploog , Bernd Fabry , Frank Clasen
IPC分类号： C07C303/24 , C07C305/10 , C11D1/28
CPC分类号： C07C303/24 , C07C305/10 , Y10S516/03 , Y10S516/913
摘要： Process for the continuous production of partial glyceride sulfates comprising the steps ofA. continuously reacting partial glycerides with gaseous sulfur trioxide,B. subjecting the resulting acidic sulfonation products to ageing, andC. neutralizilng the aged acidic sulfonation products with an aqueous base in the presence of a buffer.
摘要翻译： PCT No.PCT / EP91 / 02208 Sec。 371日期1993年8月3日 102（e）日期1993年8月3日PCT 1991年11月25日PCT PCT。出版物WO92 / 09569 日期：1992年6月11日。连续生产部分甘油酯硫酸盐的方法，包括以下步骤：A.使部分甘油酯与气态三氧化硫连续反应，B.使所得酸性磺化产物老化，和C.中和酸性磺酸在缓冲液存在下具有含水碱的产物。

3. 发明申请

US20050054551A1 Alkyl-and/or alkylene oligoglycoside betaine ester quaternaries 失效
标题翻译：烷基和/或亚烷基低聚糖苷甜菜碱酯季铵盐
公开(公告)号：US20050054551A1
公开(公告)日：2005-03-10
申请号：US10501490
申请日：2003-01-07
申请人： Ansgar Behler , Frank Clasen
发明人： Ansgar Behler , Frank Clasen
IPC分类号： A61K8/00 , A61K8/37 , A61K8/41 , A61K8/60 , A61K8/73 , A61K47/26 , A61K47/36 , A61Q5/00 , A61Q5/12 , A61Q19/10 , B01F17/18 , B01F17/56 , C07H13/04 , C07H15/04 , C11D1/62 , D06M13/342 , C11D1/00
CPC分类号： A61Q19/10 , A61K8/37 , A61K8/416 , A61K8/604 , A61K8/608 , A61Q5/12 , C07H13/04 , C07H15/04
摘要： A composition containing an alk(en)yl oligoglycoside betaine esterquat corresponding to formula I: R1O(G)nOCOCR2R3NR4R5R6 (I) wherein R1 is an alk(en)yl group having from about 4 to about 22 carbon atoms, G is a sugar unit containing 5 or 6 carbon atoms and n is a number from 1 to about 10, R2 is H or a CH3 group, R3 is H or a linear and/or branched alk(en)yl group having from 1 to about 6 carbon atoms, R4, R5 and R6, independently of one another, represent a linear and/or branched alk(en)yl group having from 1 to about 24 carbon atoms or a linear and/or branched hydroxyalk(en)yl group having from 1 to about 24 carbon atoms.
摘要翻译：对应于式I的含有烯（en）基低聚糖苷甜菜碱酯季铵盐的组合物：R 1 O（G）nOCOCR 2 R 3 NR 4 R 5 R 6（I）其中R 1是具有约4至约22个碳原子的烷基（en）基团，G是含有5或6个碳原子的糖单元，n是1至约10的数，R 2是H或 CH 3基，R 3是H或具有1至约6个碳原子的直链和/或支链烷基（烯）基，R 4，R 5和R 6独立地为一个另一个表示具有1至约24个碳原子的直链和/或支链烷基（en）基团或具有1至约24个碳原子的直链和/或支链羟基链烯（en）基团。

4. 发明授权

US5478554A Process for reducing the content of free fromaldehyde and formic acid in nonionic and anionic surfactants 失效
标题翻译：降低非离子表面活性剂和阴离子表面活性剂中游离醛和甲酸含量的方法
公开(公告)号：US5478554A
公开(公告)日：1995-12-26
申请号：US307729
申请日：1994-09-23
申请人： Ansgar Behler , Hermann Hensen , Uwe Ploog , Werner Seipel , Frank Clasen
发明人： Ansgar Behler , Hermann Hensen , Uwe Ploog , Werner Seipel , Frank Clasen
IPC分类号： A61K8/00 , A61K8/37 , A61K8/39 , A61K8/41 , A61K8/44 , A61K8/46 , A61K8/64 , A61Q5/00 , A61Q19/10 , B01F17/00 , B01F17/42 , C11D1/02 , C11D1/74 , C11D3/26 , C11D3/30 , C11D3/33 , C11D3/37 , A61K7/48
CPC分类号： C11D3/3719 , C11D3/30 , C11D3/33 , Y10S514/97
摘要： A process for reducing the content of free formaldehyde and formic acid in nonionic and anionic surfactants is provided. The process comprises adding an amine compound selected from the group consisting of a) alkanolamines, b) aminocarboxylic acids and c) oligopeptides to a surfactant comprised of a member selected from the group consisting of nonionic and anionic surfactants. The amine compound is preferably selected from the group consisting of a) an alkanolamine containing 2 to 15 carbon atoms, b) an aminocarboxylic acid containing 2 to 8 carbon atoms, and c) an oligopeptide with an average molecular weight of 500 to 5000. The nonionic and anionic surfactants preferably contain 1 to 100 ethylene oxide units in the form of at least one polyethylene glycol chain. The amine compound is preferably added in a quantity of 50 to 6000 ppm, based on active substance of said surfactant.
摘要翻译： PCT No.PCT / EP93 / 00657 Sec。 371日期1994年9月23日 102（e）1994年9月23日PCT 1993年3月18日PCT公布。公开号WO93 / 19724 日期：1993年10月14日。提供了一种降低非离子和阴离子表面活性剂中游离甲醛和甲酸含量的方法。该方法包括将选自a）链烷醇胺，b）氨基羧酸的胺化合物和c）寡肽加入到由选自非离子和阴离子表面活性剂的成员组成的表面活性剂中。胺化合物优选选自a）含有2至15个碳原子的链烷醇胺，b）含有2至8个碳原子的氨基羧酸，和c）平均分子量为500至5000的寡肽。非离子和阴离子表面活性剂优选含有至少一种聚乙二醇链形式的1至100个环氧乙烷单元。基于所述表面活性剂的活性物质，胺化合物的添加量优选为50〜6000ppm。

5. 发明申请

US20110247657A1 Rinse Aid, Comprising Fatty Acid Alkanolamide Polyalkylene Glycol Ethers 审中-公开
标题翻译：冲洗助剂，包括脂肪酸烷醇酰胺聚亚烷基二醇醚
公开(公告)号：US20110247657A1
公开(公告)日：2011-10-13
申请号：US13140265
申请日：2009-12-11
申请人： Frederic Bauer , Sabine Both , Teresa Alexandre , Melanie Nagel , Snsgar Behler , Frank Clasen
发明人： Frederic Bauer , Sabine Both , Teresa Alexandre , Melanie Nagel , Snsgar Behler , Frank Clasen
IPC分类号： A47L15/42 , C07C233/05 , C07C233/18 , C11D3/60
CPC分类号： C11D1/526 , C11D1/662 , C11D1/72 , C11D1/835 , C11D3/2086 , C11D3/3418
摘要： Provided for are rinse aids that exhibit improved drying properties during automatic dish washing and thus allow cleaning methods at lower temperatures than customer reference agents. The rinse aids comprise a) at least one surfactant according to the general formula (I), where R1 is a saturated or unsaturated, branched or linear alkyl or alkenyl radical having 6 to 22 carbon atoms, R2 is hydrogen or an alkyl group having 1 to 6 carbon atoms or a group R3, and R3 is a group A-(O—CH2CHR4—)m—OR5 and R4 and R5 independently from each other are a hydrogen atom or an alkyl group having 1 to 4 carbon atoms and A is a (CH2)n— group or a hydroxyl alkyl group having 2 to 6 carbon atoms and n is an integer from 1 to 6 and m is an integer or a fractional number from 1 to 10 and furthermore b) at least one hydrotrope, c) at least one organic hydroxycarboxylic acid and d) water.
摘要翻译：提供用于在自动洗碗过程中表现出改进的干燥性能的漂洗助剂，因此允许在低于客户参考试剂的温度下进行清洁方法。漂洗助剂包括a）至少一种根据通式（I）的表面活性剂，其中R 1是具有6-22个碳原子的饱和或不饱和的，支链或直链的烷基或链烯基，R2是氢或具有1 至6个碳原子或基团R 3，且R 3为A - （O-CH 2 CHR 4 - ）m-OR 5基团，R 4和R 5彼此独立地为氢原子或具有1至4个碳原子的烷基，A为（CH2）n-基或碳原子数2〜6的羟基烷基，n为1〜6的整数，m为1〜10的整数或分数，b）至少1个水溶助长剂c ）至少一种有机羟基羧酸和d）水。

6. 发明申请

US20110039950A1 Alkyl and/or Alkenyl Ethers of Alkyl and/or Alkenyl (Poly)Glycosides and Their Use 审中-公开
标题翻译：烷基和/或烯基（聚）糖苷的烷基和/或烯基醚及其用途
公开(公告)号：US20110039950A1
公开(公告)日：2011-02-17
申请号：US12937821
申请日：2009-04-06
申请人： Ansgar Behler , Achim Ansmann , Catherine Weichold , Frank Clasen , Anja Wick , Eike Ulf Mahnke , Bjoern Klotz , Carsten Neumann , Matthias Hloucha , Rolf Kawa , Petra Schulte
发明人： Ansgar Behler , Achim Ansmann , Catherine Weichold , Frank Clasen , Anja Wick , Eike Ulf Mahnke , Bjoern Klotz , Carsten Neumann , Matthias Hloucha , Rolf Kawa , Petra Schulte
IPC分类号： A61K47/26 , A61K8/92
CPC分类号： C07H15/04 , A61K8/06 , A61K8/604 , A61K2800/21 , A61K2800/413 , A61Q15/00 , A61Q19/00 , B82Y5/00
摘要： The present invention relates to nanoemulsions comprising alkyl and/or alkenyl ethers of alkyl and/or alkenyl (poly)glycosides, to a method for their preparation and also to their use. The present invention further relates to the alkyl and/or alkenyl ethers of alkyl and/or alkenyl (poly)glycosides themselves, and their use.
摘要翻译：本发明涉及包含烷基和/或烯基（多）糖苷的烷基和/或烯基醚的纳米乳剂，其制备方法以及它们的用途。本发明还涉及烷基和/或烯基（多）糖苷本身的烷基和/或烯基醚及其用途。

7. 发明授权

US07585830B2 Method for the alkoxylation of alkyl and/or alkenyl polyglycosides 失效
标题翻译：烷基和/或链烯基多糖苷的烷氧基化方法
公开(公告)号：US07585830B2
公开(公告)日：2009-09-08
申请号：US10598130
申请日：2005-02-11
申请人： Ansgar Behler , Frank Clasen
发明人： Ansgar Behler , Frank Clasen
IPC分类号： C11D3/22 , C07H15/04 , A61K8/73
CPC分类号： C07H15/04 , A01N25/30 , C07H1/00
摘要： A process for the production of alkoxylated alkyl and/or alkenyl polyglycosides including reacting alkylene oxides with alkyl and alkenyl polyglycosides corresponding to formula (I): R1O-[G]p wherein R1 is an alkyl and/or alkenyl group containing 4-22 carbon atoms, G is a sugar unit containing 5 or 6 carbon atoms and p is a number of 1-10, wherein the alkyl and/or alkenyl polyglycosides corresponding to formula (I) are in the form of a water-containing preparation with a water content of more than 5% by weight, based on the weight of the water-containing preparation is provided. The alkoxylated alkyl and/or alkenyl polyglycosides may be incorporated into agrochemical formulations, herbicides, laundry and dishwashing detergents, cleaning preparations, and pharmaceutical and cosmetic formulations.
摘要翻译：一种制备烷氧基化烷基和/或链烯基多糖苷的方法，包括使环氧烷与对应于式（I）的烷基和烯基多糖苷反应：R1O- [G] p，其中R1是含有4-22个碳原子的烷基和/或烯基原子，G是含有5或6个碳原子的糖单元，p是1-10的数，其中对应于式（I）的烷基和/或链烯基多糖苷是具有水的含水制剂的形式提供了基于含水制剂的重量超过5重量％的含量。烷氧基化烷基和/或链烯基多糖苷可以并入农用化学制剂，除草剂，洗衣和餐具洗涤剂，清洁制剂和药物和化妆品制剂中。

8. 发明授权

US07022661B2 Alkyl-and/or alkylene oligoglycoside betaine ester quaternaries 失效
标题翻译：烷基和/或亚烷基低聚糖苷甜菜碱酯季铵盐
公开(公告)号：US07022661B2
公开(公告)日：2006-04-04
申请号：US10501490
申请日：2003-01-07
申请人： Ansgar Behler , Frank Clasen
发明人： Ansgar Behler , Frank Clasen
IPC分类号： C11D1/90 , C11D3/22 , C07H15/00
CPC分类号： A61Q19/10 , A61K8/37 , A61K8/416 , A61K8/604 , A61K8/608 , A61Q5/12 , C07H13/04 , C07H15/04
摘要： A composition containing an alk(en)yl oligoglycoside betaine esterquat corresponding to formula I: R1O(G)nOCOCR2R3NR4R5R6 (I) wherein R1 is an alk(en)yl group having from about 4 to about 22 carbon atoms, G is a sugar unit containing 5 or 6 carbon atoms and n is a number from 1 to about 10, R2 is H or a CH3 group, R3 is H or a linear and/or branched alk(en)yl group having from 1 to about 6 carbon atoms, R4, R5 and R6, independently of one another, represent a linear and/or branched alk(en)yl group having from 1 to about 24 carbon atoms or a linear and/or branched hydroxyalk(en)yl group having from 1 to about 24 carbon atoms.
摘要翻译：含有对应于式I的alk（en）yl oligoglycoside甜菜碱酯季铵盐的组合物：<？in-line-formula description =“In-line formula”end =“lead”？> R＆lt; G）NCO 2 O 3 R 3 O 3 R 3 O 3 R 3 O 3 R 3 （I）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中R 1是具有约4至约22个碳原子，G是含有5或6个碳原子的糖单元，n是1至约10的数，R 2是H或CH 3， R 3是H或具有1至约6个碳原子的直链和/或支链烷基（烯）基，R 4，R 4， > 5和R 6彼此独立地表示具有1至约24个碳原子的直链和/或支链的烷基（烯）基或直链和/或支链的具有1至约24个碳原子的羟基烯烃（烯）基。

9. 发明申请

US20110014148A1 Cationic Surfactants Having Improved Properties 审中-公开
标题翻译：具有改善性能的阳离子表面活性剂
公开(公告)号：US20110014148A1
公开(公告)日：2011-01-20
申请号：US12922239
申请日：2008-08-16
申请人： Ansgar Behler , Frank Clasen , Hans-Martin Haake , Monika Barbenheim
发明人： Ansgar Behler , Frank Clasen , Hans-Martin Haake , Monika Barbenheim
IPC分类号： A61K8/41 , C07C69/24 , A61Q5/12
CPC分类号： A61Q19/10 , A61K8/416 , A61Q5/02 , A61Q5/12
摘要： The invention is directed to cationic surfactants of formula (I), where R1 is a saturated or unsaturated, branched or linear alkyl group having 6 to 22 carbon atoms, R2 and R3 independently are C1-C3 alkyl groups or hydrogen, n is 2 or 3, and X− is an anion selected from the group consisting of halides, deprotonated carboxylic acids and methosulfate. The cationic surfactants are useful, particularly as hair conditioners, for the preparation of cosmetic compositions.
摘要翻译：本发明涉及式（I）的阳离子表面活性剂，其中R 1是具有6至22个碳原子的饱和或不饱和的支链或直链烷基，R 2和R 3独立地是C 1 -C 3烷基或氢，n是2或 3，X-是选自卤化物，去质子化羧酸和甲基硫酸盐的阴离子。阳离子表面活性剂特别用作头发调理剂，用于制备化妆品组合物。

10. 发明申请

US20060047141A1 Method for producing light coloured polyalkylene glycol diethyl ether of fatty acid alcanolamine 审中-公开
标题翻译：脂肪酸乙醇胺的浅色聚亚烷基二醇二乙醚的制备方法
公开(公告)号：US20060047141A1
公开(公告)日：2006-03-02
申请号：US10539737
申请日：2003-12-10
申请人： Ansgar Behler , Frank Clasen
发明人： Ansgar Behler , Frank Clasen
IPC分类号： C07C263/00
CPC分类号： C07C231/12 , C07C233/20
摘要： The invention relates to the production of light-colored polyalkylene glycol diethyl ethers of fatty acid alkanolamines by adding ethylene to the fatty acid alkanolamide in the presence of an alkaline catalyst. The inventive method cossets of alkoxylating in the presence of reducing agents and treating the obtained product by steam in an alkaline medium.
摘要翻译：本发明涉及通过在碱性催化剂的存在下将乙烯加入到脂肪酸烷醇酰胺中来生产脂肪酸链烷醇胺的浅色聚亚烷基二醇二乙醚。本发明方法在还原剂存在下烷氧基化的方法，并在碱性介质中用蒸汽处理所得产物。

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