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    • 3. 发明授权
    • Process for benzene reduction and sulfur removal from FCC naphthas
    • FCC石脑油中苯还原和除硫工艺
    • US07837861B2
    • 2010-11-23
    • US11898674
    • 2007-09-14
    • Benjamin S. UmanskyJames F. StanleyTomas R. MelliSean C. SmythEugene M. Roundtree
    • Benjamin S. UmanskyJames F. StanleyTomas R. MelliSean C. SmythEugene M. Roundtree
    • C10G17/00C07C2/58
    • C10G29/205B01J29/40B01J29/70B01J29/90B01J2229/42C10G21/00C10G27/00C10G45/12C10G61/10Y02P20/52
    • A process for the removal of sulfur compounds and benzene of a catalytically cracked petroleum naphtha comprising benzene, organic sulfur compounds and olefins, by fractionating the cracked naphtha into a relatively low boiling range, olefinic, light catalytic naphtha (LCN) and an olefinic heavy catalytic naphtha (HCN) which boils above the range of the LCN the boiling ranges of the LCN and the HCN being defined by a cut point selected to maintain most of the benzene in the cracked naphtha in the LCN together with olefins in the boiling range of the LCN. The LCN is subjected to an optional non-hydrogenative desulfurization step followed by a fixed bed alkylation step in which the benzene in the LCN is alkylated with the olefins contained in this fraction. The HCN is treated by a similar an alkylation step using the olefins contained in this fraction to alkylate the sulfur compounds, forming alkylated products which boil above the gasoline boiling range. The LCN and HCN are then fractionated to remove light ends and higher boiling sulfur reaction products (disulfides, alkylated thiophenes) boiling above the gasoline boiling range.
    • 烯烃,轻质催化石脑油(LCN)和烯烃重催化作用,通过将裂解石脑油分馏成相对低沸点的方法,除去含有苯,有机硫化合物和烯烃的催化裂化石脑油的硫化合物和苯的方法 石脑油(HCN)沸点高于LCN的范围,LCN和HCN的沸点范围由选择为将LCN中的裂解石脑油中的大部分苯保持在沸点范围内的烯烃所限定的切割点 LCN。 对LCN进行任选的非氢化脱硫步骤,然后进行固定床烷基化步骤,其中LCN中的苯用该馏分中所含的烯烃烷基化。 通过类似的烷基化步骤处理HCN,使用该级分中所含的烯烃烷基化硫化合物,形成沸点高于汽油沸程的烷基化产物。 然后将LCN和HCN分馏以除去沸点高于汽油沸程的轻馏分和较高沸点硫反应产物(二硫化物,烷基化噻吩)。
    • 4. 发明申请
    • Process for benzene reduction and sulfur removal from FCC naphthas
    • FCC石脑油中苯还原和除硫工艺
    • US20080116112A1
    • 2008-05-22
    • US11898674
    • 2007-09-14
    • Benjamin S. UmanskyJames F. StanleyTomas R. MelliSean C. SmythEugene M. Roundtree
    • Benjamin S. UmanskyJames F. StanleyTomas R. MelliSean C. SmythEugene M. Roundtree
    • C10G17/00
    • C10G29/205B01J29/40B01J29/70B01J29/90B01J2229/42C10G21/00C10G27/00C10G45/12C10G61/10Y02P20/52
    • A process for the removal of sulfur compounds and benzene of a catalytically cracked petroleum naphtha comprising benzene, organic sulfur compounds and olefins, by fractionating the cracked naphtha into a relatively low boiling range, olefinic, light catalytic naphtha (LCN) and an olefinic heavy catalytic naphtha (HCN) which boils above the range of the LCN the boiling ranges of the LCN and the HCN being defined by a cut point selected to maintain most of the benzene in the cracked naphtha in the LCN together with olefins in the boiling range of the LCN. The LCN is subjected to an optional non-hydrogenative desulfurization step followed by a fixed bed alkylation step in which the benzene in the LCN is alkylated with the olefins contained in this fraction. The HCN is treated by a similar an alkylation step using the olefins contained in this fraction to alkylate the sulfur compounds, forming alkylated products which boil above the gasoline boiling range. The LCN and HCN are then fractionated to remove light ends and higher boiling sulfur reaction products (disulfides, alkylated thiophenes) boiling above the gasoline boiling range.
    • 烯烃,轻质催化石脑油(LCN)和烯烃重催化作用,通过将裂解石脑油分馏成相对低沸点的方法,除去含有苯,有机硫化合物和烯烃的催化裂化石脑油的硫化合物和苯的方法 石脑油(HCN)沸点高于LCN的范围,LCN和HCN的沸点范围由选择为将LCN中的裂解石脑油中的大部分苯保持在沸点范围内的烯烃所限定的切割点 LCN。 对LCN进行任选的非氢化脱硫步骤,然后进行固定床烷基化步骤,其中LCN中的苯用该馏分中所含的烯烃烷基化。 通过类似的烷基化步骤处理HCN,使用该级分中所含的烯烃烷基化硫化合物,形成沸点高于汽油沸程的烷基化产物。 然后将LCN和HCN分馏以除去沸点高于汽油沸程的轻馏分和较高沸点硫反应产物(二硫化物,烷基化噻吩)。
    • 5. 发明授权
    • Gasoline production by olefin polymerization with aromatics alkylation
    • 汽油生产通过烯烃聚合与芳烃烷基化
    • US07525002B2
    • 2009-04-28
    • US11362128
    • 2006-02-27
    • Benjamin S. UmanskyMichael C. ClarkAjit B. Dandekar
    • Benjamin S. UmanskyMichael C. ClarkAjit B. Dandekar
    • C07C2/12C07C2/66
    • C10L1/06C10G2400/02
    • A process for the production of high octane number gasoline from light refinery olefins, typically from the catalytic cracking unit, and benzene-containing aromatic streams such as reformate. A portion of the light olefins including ethylene and propylene is polymerized to form a gasoline boiling range product and another portion is used to alkylate the light aromatic stream. The alkylation step may be carried out in successive stages with an initial low temperature stage using a catalyst comprising an MWW zeolite followed by a higher temperature stage using a catalyst comprising an intermediate pore size zeolite such as ZSM-5. Using this staged approach, the alkylation may be carried out in the vapor phase. Alternatively, the alkylation may be carried out in the liquid phase using the heavier olefins (propylene, butene) dissolved into the aromatic stream by selective countercurrent extraction; a separate alkylation step using the ethylene not taken up in the extraction is carried out at a higher temperature.
    • 一种从轻质炼油烯烃(通常来自催化裂化装置)和含苯芳族物流如重整产物生产高辛烷值汽油的方法。 一部分轻质烯烃(包括乙烯和丙烯)聚合形成汽油沸程产物,另一部分用于烷基化轻芳烃流。 烷基化步骤可以在初始低温阶段中使用包含MWW沸石的催化剂,随后使用包含中等孔径沸石如ZSM-5的催化剂进行更高温度阶段的连续阶段进行。 使用这种分级方法,烷基化可以在气相中进行。 或者,烷基化可以使用通过选择性逆流萃取溶解到芳族物流中的较重烯烃(丙烯,丁烯)在液相中进行; 在较高温度下进行使用在萃取中未溶解的乙烯的单独的烷基化步骤。
    • 6. 发明授权
    • Vapor phase aromatics alkylation process
    • 气相芳烃烷基化方法
    • US07498474B2
    • 2009-03-03
    • US11362255
    • 2006-02-27
    • Benjamin S. UmanskyMichael C. ClarkAjit B. DandekarChristine N. Elia
    • Benjamin S. UmanskyMichael C. ClarkAjit B. DandekarChristine N. Elia
    • C07C2/66
    • C10G29/205
    • A process for the production of high octane number gasoline from light refinery olefins and benzene-containing aromatic streams such as reformate. The process achieves good utilization of both the ethylene and the propylene present in the mixed olefin feed from the unsaturated gas plant while reducing gasoline benzene levels. The light olefins including ethylene and propylene are reacted with the light aromatic stream containing benzene and other single ring aromatic compounds to form a gasoline boiling range product containing akylaromatics. The reaction is carried out with a two-catalyst system which comprises a member of the MWW family of zeolites and an intermediate pore size zeolite such as ZSM-5 using a fixed catalyst bed in both stages. Use of the two catalyst system enables the conversion of the ethylene and propylene components of the olefin feed to be converted to alkylaromatics under favorable conditions.
    • 一种从轻质炼油烯烃和含苯芳族物流如重整油生产高辛烷值汽油的方法。 该方法可以很好地利用来自不饱和气体装置的混合烯烃进料中存在的乙烯和丙烯,同时降低汽油苯的含量。 包括乙烯和丙烯的轻质烯烃与含有苯和其它单环芳族化合物的轻芳烃物流反应,形成含烷基芳族化合物的汽油沸程产品。 该反应用两催化剂体系进行,该双催化剂体系包括MWW沸石族的成员和中等孔径的沸石如ZSM-5,其使用两个阶段的固定催化剂床。 使用这两种催化剂体系可使烯烃进料的乙烯和丙烯成分转化成有利条件下的烷基芳族化合物。
    • 7. 发明申请
    • METHOD AND SYSTEM FOR DETERMINING FLOW DISTRIBUTION THROUGH A COMPONENT
    • 通过组件确定流量分布的方法和系统
    • US20140294041A1
    • 2014-10-02
    • US14226997
    • 2014-03-27
    • Yibing ZhangLimin SongGeoff KeiserMichael L. HergenrotherBerne K. StoberPatricia H. KalamarasBenjamin S. Umansky
    • Yibing ZhangLimin SongGeoff KeiserMichael L. HergenrotherBerne K. StoberPatricia H. KalamarasBenjamin S. Umansky
    • G01N25/00G01F1/684
    • G01N25/18G01F1/661G01F1/684G01F1/6884G01F1/74G01K11/3206G01N25/00
    • Systems and methods for determining the flow distribution of a fluid through a component with a sensing cable including an optical fiber sensor array aligned with a heating element disposed in the component. An excitation source is configured to propagate at least one heat pulse through the heating element along at least a portion of the sensing cable to affect an exchange of thermal energy between the heating element and the fluid exposed to the sensing cable. An optical signal is adapted to receive a signal from each of a plurality of sensor locations and measure a temperature profile corresponding to the heat pulse at the sensor locations. A control unit is configured to determine a flow of the fluid by determining one or more properties of the fluid exposed to the sensing cable at each of the plurality of sensor locations based on the temperature profile corresponding thereto. The present invention can be effective in accurate and high spatial resolution of flow distributions through vessel components, such as a particulate bed (such as a reactor catalyst bed), a wash bed including packing material, an absorbent bed, a structured bed, a filter, or the like.
    • 用于通过传感电缆确定流体通过部件的流动分布的系统和方法,所述传感电缆包括与设置在所述部件中的加热元件对准的光纤传感器阵列。 激励源被配置为沿着感测电缆的至少一部分传播至少一个热脉冲通过加热元件,以影响加热元件和暴露于感测电缆的流体之间的热能交换。 光信号适于接收来自多个传感器位置中的每一个的信号,并且测量对应于传感器位置处的加热脉冲的温度分布。 控制单元被配置为基于与其对应的温度分布,通过确定在多个传感器位置中的每一个处暴露于感测电缆的流体的一个或多个属性来确定流体的流动。 本发明可以有效地准确和高空间地分辨通过容器部件的流动分布,例如颗粒床(例如反应器催化剂床),包括填充材料的洗涤床,吸收床,结构化床,过滤器 ,等等。