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    • 5. 发明授权
    • Washing compositions containing aluminosilicates and nonionics and
method of washing textiles
    • 含有硅铝酸盐和非离子表面活性剂的洗涤组合物和洗涤纺织品的方法
    • US4083793A
    • 1978-04-11
    • US723728
    • 1976-09-16
    • Gunter JakobiPeter KringsMilan Johann SchwugerHeinz Smolka
    • Gunter JakobiPeter KringsMilan Johann SchwugerHeinz Smolka
    • C11D1/83C11D3/08C11D3/12B01J1/04C11D1/825C11D1/831
    • C11D3/08C11D1/8305C11D3/1286
    • A method of washing soiled textiles, wherein the soiled textiles are immersed in an aqueous liquor which contains at least one compound inhibiting alkaline earth metal ion precipitation on said soiled textiles and surface-active compounds comprising using finely-dispersed, water-insoluble silicate compounds having a calcium-binding power of at least 50 mg CaO/gm of anhydrous active substance and having the formula, combined water not shown(M.sub.2/n O).sub.x . Me.sub.2 O.sub.3 . (SiO.sub.2).sub.ywhere M is a cation of the valence n, exchangeable with calcium, x is a number of from 0.7 to 1.5, Me is a member selected from aluminum and boron and y is a number of from 0.8 to 6, as said compound inhibiting alkaline earth metal ion precipitation, together with surface-active compounds including non-ionic surface-active compounds being constituted by a mixture of compounds of different degrees of ethoxylation where one of the ethoxylated compounds has 8 to 20 ethylene oxide units and the other has from 2 to 6 ethylene oxide units; as well as washing compositions containing said silicate compounds and said surface-active compounds.
    • 一种洗涤污染织物的方法,其中将污染的纺织品浸入含有至少一种抑制碱土金属离子沉淀的化合物的水性液体中,所述化合物在所述污染的纺织品和表面活性化合物上包括使用细分散的水不溶性硅酸盐化合物, 具有至少50mg CaO / gm无水活性物质并具有下式的组合水(M2 / nO)x的钙结合力。 Me2O3。 (SiO 2)y其中M是价数为n的阳离子,可与钙交换,x为0.7至1.5的数,Me为选自铝和硼的成员,y为0.8至6的数,如所述 化合物抑制碱土金属离子沉淀,以及包括非离子表面活性化合物在内的表面活性化合物由不同程度乙氧基化的化合物的混合物构成,其中一种乙氧基化合物具有8至20个环氧乙烷单元,另一种 具有2至6个环氧乙烷单元; 以及含有所述硅酸盐化合物和所述表面活性化合物的洗涤组合物。
    • 9. 发明授权
    • Process for the production of powdery washing agents by spray-drying
    • 通过喷雾干燥生产粉末洗涤剂的方法
    • US4169075A
    • 1979-09-25
    • US856244
    • 1977-12-01
    • Dieter KuhlingJosef HuppertzPeter KringsHerbert Reuter
    • Dieter KuhlingJosef HuppertzPeter KringsHerbert Reuter
    • C11D3/12C11D11/02C01B33/28C02B1/44
    • C11D3/1286C11D11/02Y10S159/13
    • A process for the preparation of powdery washing agent compositions by spray-drying compositions containing aqueous suspensions of water-insoluble, calcium-binding aluminosilicates with an improved stability against settling comprising at least 20% by weight of at least one finely-divided, water-insoluble silicate compound having a calcium-binding power of at least 50 mg CaO/gm of anhydrous active substance and having the formula, combined water not shown(M.sub.2/n O).sub.x.multidot. Me.sub.2 O.sub.3.multidot. (SiO.sub.2).sub.ywhere M is a cation of the valence n, exchangeable with calcium, x is a number of from 0.7 to 1.5, Me is aluminum or boron, and y is a number from 0.8 to 6, and at least 0.5% by weight of at least one organic dispersing agent as follows:(1) an organic, macromolecular polymer with carboxyl and/or hydroxyl groups, p1 (2) an organic phosphonic acid with at least one additional phosphonic or carboxylic acid group,(3) an alkyl acid phosphate having 3 to 20 carbon atoms in the alkyl(4) a nonionic surface-active compound with a turbidity point in aqueous butoxyethoxyethanol according to DIN 53917 of below 90.degree. C.(5) a surface-active sulfonate, and the remainder an aqueous liquor. The said suspensions are pumpable and suitable as stock solution in the preparation of washing agent compositions.
    • 一种通过喷雾干燥组合物制备粉末洗涤剂组合物的方法,该组合物含有水不溶性钙结合铝硅酸盐的水性悬浮液,其具有改善的沉降稳定性,其包含至少20重量%的至少一个细分的, 具有至少50mg CaO / gm无水活性物质的钙结合力的不溶性硅酸盐化合物,具有下式,组合水未示出(M2 / nO)x xMe 2 O 3 x(SiO 2)y WHERE M是价数n的阳离子, 可与钙交换,x为0.7至1.5的数,Me为铝或硼,y为0.8至6,至少0.5重量%的至少一种如下有机分散剂:
    • 10. 发明授权
    • Low-foaming liquid washing agent concentrates
    • 低发泡液体洗涤剂浓缩液
    • US4153570A
    • 1979-05-08
    • US873510
    • 1978-01-30
    • Manfred HennemannAlbrecht LohrPeter Krings
    • Manfred HennemannAlbrecht LohrPeter Krings
    • B01F17/04C11D1/14C11D1/22C11D1/29C11D1/72C11D1/83C11D10/04C11D17/00C11D9/32
    • C11D3/0026C11D10/04C11D3/3418C11D1/143C11D1/22C11D1/29C11D1/523C11D1/72
    • Low foaming, liquid, aqueous washing agent concentrate comprising(a) 5 to 12 weight % of a linear sodium alkyl benzene sulfonate with 10-13 carbon atoms in the alkyl chain and/or of a linear secondary sodium alkane sulfonate with 14-18 carbon atoms:(b) 2 to 6 weight % of a linear sodium alkyl polyglycol ether sulfate with 10-16 carbon atoms in the alkyl chain and 1-3 ethylene glycol ether groups;(c) 2 to 6 weight % of a sodium or potassium soap of mainly saturated fatty acids with 12-18 carbon atoms, 50-90 weight % of which have 16-18 carbon atoms;(d) 15 to 28 weight % of a mixture of ethoxylated alcohols, consisting of (i) 30-50 weight % of linear primary ethoxylated alcohols with 16-18 carbon atoms and 8-12 glycol ether groups and (ii) 30-50 weight % of linear primary ethoxylated alcohols with 16-18 carbon atoms and 3-7 glycol ether groups, both of said ethoxylated alcohols having a ratio of saturated to mono-unsaturated hydrocarbon residues of 1:4 to 4:1, and (iii) 10-30 weight % of linear and/or 2-methyl substituted primary saturated ethoxylated alcohols with 10-15 carbon atoms and 4-9 glycol ether groups;(e) 2 to 7 weight % of a fatty acid diethanolamide with 10-16 carbon atoms in the fatty acid residue;(f) 4 to 10 weight % of a toluene, xylene or isopropylbenzene sulfonate in the form of the sodium, potassium or triethanolamine salt; and(g) 2 to 7 weight % of an alkanol with 1-3 carbon atoms;And the remainder water and optionally other conventional ingredients, wherein the total weight of all the anhydrous components of said concentrate amounts to between 40 and 65 weight % thereof.
    • 低发泡,液体,水性洗涤剂浓缩物,其包含(A)5至12重量%的具有10-13个碳原子在烷基链和/或具有14-18个碳原子的直链二次亚烷基硫酸钠的直链烷基苯甲醛磺酸盐的重量% ATOMS: