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    • 5. 发明申请
    • CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS
    • 用于烯烃聚合的催化组分
    • WO2009080497A2
    • 2009-07-02
    • PCT/EP2008/067118
    • 2008-12-09
    • BASELL POLIOLEFINE ITALIA S.R.L.PATRONCINI, GiovanniVINCENZI, Paolo
    • VINCENZI, Paolo
    • C08F10/00C08F4/651
    • C08F10/00C08F110/06C08F4/651C08F2500/18C08F2500/24
    • Catalyst component having average particle size equal to or lower than 40 μm comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two electron donor compounds one of which being present in an amount from 15 to 50% by mol with respect to the total amount of donors and selected from succinates of formula (I) below (I) in which the radicals R 1 and R 2 , equal to, or different from, each other are a C 1 -C 20 linear or branched alkyl, alkenyl, cycloalkyl, aryl, arylalkyl or alkylaryl group, optionally containing heteroatoms; and the radicals R 3 and R 4 equal to, or different from, each other, are C 1 -C 20 alkyl, C3-C20 cycloalkyl, C5-C20 aryl, arylalkyl or alkylaryl group with the proviso that at least one of them is a branched alkyl; said compounds being, with respect to the two asymmetric carbon atoms identified in the structure of formula (I), stereoisomers of the type (S, R) or (R, S) and at least another electron donor compound which is extractable, under the test of extractability disclosed in the characterization section, for more than 30% by mol.
    • 平均粒度等于或小于40μm的催化剂组分包括卤化镁,至少具有Ti-卤素键的钛化合物和至少两种电子给体化合物,其中一种以15-50%的量存在,其量为15-50% 相对于供体的总量,选自下列式(I)的琥珀酸酯(I),其中基团R 1和R 2彼此相同或不同,为C 1 -C 20直链或支链烷基,烯基 ,环烷基,芳基,芳烷基或烷基芳基,任选地含有杂原子; 并且彼此相同或不同的基团R 3和R 4是C 1 -C 20烷基,C 3 -C 20环烷基,C 5 -C 20芳基,芳基烷基或烷基芳基,条件是它们中的至少一个是支链烷基; 所述化合物相对于在式(I)结构中鉴定的两个不对称碳原子,是可以提取的(S,R)或(R,S)型的至少另一种电子给体化合物的立体异构体 在表征部分中公开的可萃取性试验,超过30%(摩尔)。