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1. 发明申请

WO2005044911A1 POLYPROPYLENE COMPOSITION 审中-公开
标题翻译：聚丙烯组合物
公开(公告)号：WO2005044911A1
公开(公告)日：2005-05-19
申请号：PCT/IB2004/003584
申请日：2004-11-03
申请人： BASELL POLIOLEFINE ITALIA S.p.A. , BERTA, Dominic, A. , PELLEGATTI, Giampaolo
发明人： BERTA, Dominic, A. , PELLEGATTI, Giampaolo
IPC分类号： C08L23/10
CPC分类号： C08L23/10 , C08L23/0815 , C08L23/14 , C08L23/16 , C08L2205/02 , C08L2205/03 , C08L2666/04 , C08L2666/02
摘要： A propylene polymer composition comprising the following components: a) from 50% to 90% by weight of a propylene homopolymer or a propylene copolymer containing up to 5% by mol of derived units of C2-C20 alpha-olefins, having the following features: (i) a polydispersity index PI>3; (ii) melt flow rate (MFR), as measured at 230°C under a load of 2.16 kg, MFR>1 dg/min; and (iii) fraction soluble in xylene at 25°C (XSRT)>1% b) from 5% to 25% by weight a copolymer of ethylene and one or more derived units of C4-C20 alpha-olefins having the following features: (i) content of ethylene derived units higher than 50% by mol and lower than 92% by mol; (ii) intrinsic viscosity (IV) higher than 1.2 dL/g and lower than 6 dL/g; (iii) density ranging from 0.850 to 0.890 g/cm 3 ; and (iv) a crystallinity content, expressed as the enthalpy of fusion, lower than 62 J/g c) from 5% to 25% by weight of a copolymer of propylene and ethylene having the following features: (i) content of propylene derived units higher than 50% by mol and lower than 92% by mol; (ii) intrinsic viscosity (IV) higher than 2 dL/g and lower than 6 dL/g; (iii) density ranging from 0.850 to 0.890 g/cm3; (iv) the value of the product of reactivity ratios rlxr2 lower than 2; and (v) a crystallinity content, expressed as the enthalpy of fusion, lower than 45 J/g wherein the weight ratio between the ethylene copolymer (component b) and the sum of component b) and component c) is equal to or higher than 0.5 and less than or equal to 0.9.
摘要翻译：包含以下组分的丙烯聚合物组合物：a）50重量％至90重量％的丙烯均聚物或含有至多5摩尔％的C2-C20α-烯烃衍生单元的丙烯共聚物，具有以下特征：（i）多分散指数PI> 3; （ii）熔体流动速率（MFR），在230℃，2.16kg负荷下测量，MFR> 1dg / min; 和（iii）25℃下可溶于二甲苯的馏分（XSRT）> 1％b）5重量％至25重量％的乙烯与一种或多种C4-C20α-烯烃衍生单元的共聚物具有以下特征：（i）乙烯衍生单元含量高于50摩尔％且低于92摩尔％（ii）高于1.2dL / g且小于6dL / g的特性粘度（Ⅳ）; （iii）密度范围为0.850至0.890g / cm 3; 丙烯和乙烯的共聚物的重量比为5％至25％，具有以下特征：（i）丙烯衍生单元的含量高于50摩尔％，低于92摩尔％（ii）高于2dL / g且低于6dL / g的特性粘度（IV）; （iii）密度范围为0.850至0.890g / cm3; （iv）反应性比率rlxr2的值低于2的值; 和（v）以熔融焓表示的结晶度含量低于45J / g，其中乙烯共聚物（组分b）与组分b）和组分c）之和的重量比等于或高于 0.5且小于或等于0.9。

2. 发明申请

WO2004026956A1 POLYOLEFIN COMPOSITION WITH IMPROVED ABRASION RESISTANCE 审中-公开
标题翻译：具有改善耐磨性的聚烯烃组合物
公开(公告)号：WO2004026956A1
公开(公告)日：2004-04-01
申请号：PCT/IB2003/004144
申请日：2003-09-15
申请人： BASELL POLIOLEFINE ITALIA S.P.A. , BERTA, Dominic, A.
发明人： BERTA, Dominic, A.
IPC分类号： C08L23/10
CPC分类号： C08L23/04 , C08L23/0815 , C08L23/10 , C08L23/12 , C08L23/142 , C08L23/16 , C08L23/30 , C08L25/10 , C08L53/02 , C08L91/00 , C08L91/06 , C08L2205/02 , C08L2205/035 , C08L2207/02 , C08L2666/02 , C08L2666/06
摘要： A composition comprising: (I) 55 to 95% by weight of an heterophasic polyolefin composition comprising 8 to 50% by weight of a crystalline propylene polymer fraction and 50 to 92% by weight of an elastomeric propylene fraction; (II) 2 to 20% by weight of an oxidized polyethylene wax having an acid number of 5 to 35 mg KOHIg, a molecular weight Mn of 1,000 to 100,000, and a melting point comprised between 92°C and 140°C; and (III) 3 to 25% by weight of a styrene block copolymer.
摘要翻译：包含：（I）55至95重量％的包含8至50重量％的结晶丙烯聚合物部分和50至92重量％的弹性体丙烯部分的多相聚烯烃组合物; （II）2〜20重量％的酸值为5〜35mg KOHIg，分子量Mn为1,000〜100,000，熔点为92〜140℃的氧化聚乙烯蜡; 和（III）3〜25重量％的苯乙烯嵌段共聚物。

3. 发明公开

EP1325077A1 DIRECTLY PAINTABLE POLYPROPYLENE GRAFT COPOLYMERS 审中-公开
标题翻译： DIREKTLACKBARE接枝聚丙烯共聚物
公开(公告)号：EP1325077A1
公开(公告)日：2003-07-09
申请号：EP01972397.2
申请日：2001-10-05
申请人： Basell Poliolefine Italia S.p.A.
发明人： BERTA, Dominic, A.
IPC分类号： C08L51/06 , C08L23/10 , C08G81/02 , C08F255/02
CPC分类号： C08L51/06 , C08F255/02 , C08L2666/02 , C08L2666/14 , C08L2666/24
摘要： A directly paintable polyolefin composition contains (1) a graft copolymer composition containing (a) a graft copolymer having a backbone of propylene polymer material having graft polymerized thereto at least one vinyl monomer capable of being polymerized by free radicals, (b) a rubber component, and, optionally, (c) a broad molecular weight distribution propylene polymer material, (2) an oxidized polyethylene wax, (3) a propylene homopolymer or copolymer grafted with an anhydride of an aliphatic α,β-unsaturated dicarboxylic acid, (4) a functionalized polymer that is reactive with the anhydride groups of the grafted polymers, (5) optionally, a polyolefin rubber grafted with an anhydride of an aliphatic α,β-unsaturated dicarboxylic acid, and (6) optionally, an ethylene polymer grafted with an anhydride of an aliphatic α,β-unsaturated dicarboxylic acid. The compositions are particularly useful for making injection molded automobile parts and exhibit excellent paint adhesion and durability.

4. 发明公开

EP1539879A1 POLYOLEFIN COMPOSITION WITH IMPROVED ABRASION RESISTANCE 审中-公开
标题翻译：的聚烯烃与提高耐磨性
公开(公告)号：EP1539879A1
公开(公告)日：2005-06-15
申请号：EP03797488.8
申请日：2003-09-15
申请人： Basell Poliolefine Italia S.P.A.
发明人： BERTA, Dominic, A.
IPC分类号： C08L23/10
CPC分类号： C08L23/04 , C08L23/0815 , C08L23/10 , C08L23/12 , C08L23/142 , C08L23/16 , C08L23/30 , C08L25/10 , C08L53/02 , C08L91/00 , C08L91/06 , C08L2205/02 , C08L2205/035 , C08L2207/02 , C08L2666/02 , C08L2666/06
摘要： A composition comprising: (I) 55 to 95% by weight of an heterophasic polyolefin composition comprising 8 to 50% by weight of a crystalline propylene polymer fraction and 50 to 92% by weight of an elastomeric propylene fraction; (II) 2 to 20% by weight of an oxidized polyethylene wax having an acid number of 5 to 35 mg KOHIg, a molecular weight Mn of 1,000 to 100,000, and a melting point comprised between 92°C and 140°C; and (III) 3 to 25% by weight of a styrene block copolymer.

5. 发明授权

EP1056807B1 POLYPROPYLENE GRAFT COPOLYMERS WITH IMPROVED SCRATCH AND MAR RESISTANCE 有权
标题翻译：具有改进的抗划伤性和损害安全POLYPROPYLENEPFROPFCOPOLYMERE
公开(公告)号：EP1056807B1
公开(公告)日：2005-01-26
申请号：EP99973412.2
申请日：1999-12-08
申请人： Basell Poliolefine Italia S.p.A.
发明人： SMITH, Jeanine, A. , BERTA, Dominic, A. , KHASAT, Nitya, P. , ROSENTHAL, Jay, S.
IPC分类号： C08L51/06 , C08L23/10 , C08L23/06
CPC分类号： C08L51/06 , C08L23/06 , C08L2207/02
摘要： A polymer composition with improved scratch and mar resistance contains (1) a graft copolymer comprising a backbone of a propylene polymer material having graft polymerized thereto at least one vinyl monomer capable of being polymerized by free radicals, and (2) an additive selected from the group consisting of (a) about 0.5 % to about 10 % of at least one low molecular weight ethylene polymer or a functionalized derivative thereof, and (b) a combination of (i) about 0.5 % to about 10 % of at least one of the low molecular weight ethylene polymers in (a) and (ii) about 0.5 % to about 10 % of inorganic microspheres, based on the total weight of the composition. Optionally the composition can also contain a compatibilizing agent such as an unsaturated carboxylic acid-functionalized propylene polymer material. The composition can optionally contain about 2 % to about 30 % of one or more rubber components, about 15 % to about 50 % of a broad molecular weight distribution propylene polymer material, or a combination of the two.

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