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1. 发明申请

WO2010009955A1 1-BUTENE COPOLYMERS 审中-公开
标题翻译： 1-BOTENE共聚物
公开(公告)号：WO2010009955A1
公开(公告)日：2010-01-28
申请号：PCT/EP2009/058108
申请日：2009-06-29
申请人： BASELL POLIOLEFINE ITALIA S.R.L. , RESCONI, Luigi , BALBONI, Davide , MOSCARDI, Gilberto , ESPOSITO, Simona
发明人： RESCONI, Luigi , BALBONI, Davide , MOSCARDI, Gilberto , ESPOSITO, Simona
IPC分类号： C08F210/08 , C08F4/6592
CPC分类号： C08F210/08 , C08F4/65912 , C08F4/65927 , C08F2420/05 , C08F210/14 , C08F2500/15 , C08F2500/17 , C08F2500/20
摘要： A crosslinked copolymer of 1-butene and 1-octene or 1-decene; containing from 3.0% to 20.0% by mole of 1-octene or 1-decene derived units;
摘要翻译： 1-丁烯和1-辛烯或1-癸烯的交联共聚物; 含有3.0％至20.0％摩尔的1-辛烯或1-癸烯衍生的单元;

2. 发明申请

WO2009115402A1 1-BUTENE TERPOLYMERS 审中-公开
标题翻译： 1-BOTENE TERPOLYMERS
公开(公告)号：WO2009115402A1
公开(公告)日：2009-09-24
申请号：PCT/EP2009/052364
申请日：2009-02-27
申请人： BASELL POLIOLEFINE ITALIA S.R.L. , RESCONI, Luigi , BALBONI, Davide , ESPOSITO, Simona
发明人： RESCONI, Luigi , BALBONI, Davide , ESPOSITO, Simona
IPC分类号： C08F210/08 , C08F210/14 , C08F210/16
CPC分类号： C08F210/16 , C08F4/65912 , C08F210/08 , C08F210/14 , C08F2420/05 , C08F4/65927 , C08F2500/15 , C08F2500/17 , C08F2500/20
摘要： A terpolymer of 1-butene, ethylene and a at least a C 8 -C 12 alpha-olefin derived units, containing from 0.1 % to 5 % by mole of ethylene derived units and from 1 from 20% by mol of C 8 -C 12 alpha-olefin derived units, endowed with the following properties : i) isotactic pentad mmmm higher than or equal to 90%; pentads (mmrr+mrrm) lower than 4 and pentad rmmr not detectable by 13 C NMR. ii) intrinsic viscosity (IV) measured in tetrahydronaphthalene at 135°C comprised between 0.8 and 5.0 dL/g; iii) the melting point measured by DSC (TmI) and the C 8 -C 12 alpha-olefin content fulfil the following relationship: TmI -0.3 wherein C is the molar content of C 8 -C 12 alpha-olefin derived units and TmI is the highest melting peak in the first melting transition measured by DSC otherwise the melting point TmI is not detectable.
摘要翻译： 1-丁烯，乙烯和至少一种C 8 -C 12α-烯烃衍生单元的三元共聚物，其含有0.1％至5％（摩尔）的乙烯衍生单元，和1％为20％（摩尔）的C 8 -C 12α-烯烃具有以下性质：i）等于或等于90％的全同立构五单元mmmm; 低于4的五元组（mmrr + mrrm）和13C NMR不能检测到的五元组。 ii）在135℃的四氢化萘中测得的特性粘度（Ⅳ）为0.8至5.0dL / g; iii）通过DSC（TmI）和C8-C12α-烯烃含量测量的熔点满足以下关系：TmI -0.3其中C是C8-C12α-烯烃衍生单元的摩尔含量，TmI是最高的熔融峰在通过DSC测量的第一熔融转变中，不能检测到熔点Tm1。

3. 发明申请

WO2007065816A2 CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS 审中-公开
标题翻译：用于烯烃聚合的催化组分
公开(公告)号：WO2007065816A2
公开(公告)日：2007-06-14
申请号：PCT/EP2006/069031
申请日：2006-11-29
申请人： BASELL POLIOLEFINE ITALIA S.R.L. , LIGUORI, Dario , FOCANTE, Francesca , MORINI, Giampiero , RESCONI, Luigi , VITALE, Gianni
发明人： LIGUORI, Dario , FOCANTE, Francesca , MORINI, Giampiero , RESCONI, Luigi , VITALE, Gianni
IPC分类号： C08F10/00 , C08F4/651
CPC分类号： C08F10/00 , C08F110/02 , C08F210/16 , C08F4/6543 , C08F4/651 , C08F4/6493 , C08F2500/12 , C08F2500/18 , C08F210/14
摘要： A catalyst component for the polymerization of olefins CH 2 =CHR, wherein R is hydrogen or a hydrocarbon radical having 1-12 carbon atoms. In particular, the present invention relates to catalyst components comprising Mg, Ti, halogen and a compound selected from phosphorous derivatives, boron derivatives and aromatic heterocyclic nitrogen derivatives. Said catalyst components are particularly suitable for the preparation of homo and copolymers of ethylene with α-olefins.
摘要翻译：用于烯烃CH 2 = CHR聚合的催化剂组分，其中R是氢或具有1-12个碳原子的烃基。特别地，本发明涉及包含Mg，Ti，卤素和选自磷衍生物，硼衍生物和芳族杂环氮衍生物的化合物的催化剂组分。所述催化剂组分特别适用于制备乙烯与α-烯烃的均聚物和共聚物。

4. 发明公开

EP1957545A2 CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS 审中-公开
标题翻译：用于烯烃聚合的催化剂组分
公开(公告)号：EP1957545A2
公开(公告)日：2008-08-20
申请号：EP06830180.3
申请日：2006-11-29
申请人： Basell Poliolefine Italia S.r.l.
发明人： LIGUORI, Dario , FOCANTE, Francesca , MORINI, Giampiero , RESCONI, Luigi , VITALE, Gianni
IPC分类号： C08F10/00 , C08F4/651
CPC分类号： C08F10/00 , C08F110/02 , C08F210/16 , C08F4/6543 , C08F4/651 , C08F4/6493 , C08F2500/12 , C08F2500/18 , C08F210/14
摘要： A catalyst component for the polymerization of olefins CH2=CHR, wherein R is hydrogen or a hydrocarbon radical having 1-12 carbon atoms. In particular, the present invention relates to catalyst components comprising Mg, Ti, halogen and a compound selected from phosphorous derivatives, boron derivatives and aromatic heterocyclic nitrogen derivatives. Said catalyst components are particularly suitable for the preparation of homo and copolymers of ethylene with α-olefins.
摘要翻译：用于烯烃CH 2 = CHR聚合的催化剂组分，其中R是氢或具有1-12个碳原子的烃基。特别地，本发明涉及包含Mg，Ti，卤素和选自磷衍生物，硼衍生物和芳族杂环氮衍生物的化合物的催化剂组分。所述催化剂组分特别适用于制备乙烯与α-烯烃的均聚物和共聚物。

5. 发明授权

EP1879959B1 POLYMERIZATION PROCESS FOR PREPARING POLYOLEFIN BLENDS 有权
标题翻译：聚合用于生产聚烯烃共混物
公开(公告)号：EP1879959B1
公开(公告)日：2011-07-06
申请号：EP06763094.7
申请日：2006-05-08
申请人： Basell Poliolefine Italia S.r.l.
发明人： RESCONI, Luigi , BIGIAVI, Daniele
IPC分类号： C08L23/00 , C08F10/00
CPC分类号： C08L23/12 , C08L23/10 , C08L23/14 , C08L23/18 , C08L23/20 , C08L2308/00 , C08L2666/06
摘要： A process for preparing polyolefin blends comprising: a) polymerizing in a solution phase propylene or 1-butene to prepare a polymeric solution containing a semicrystalline polymer component; b) polymerizing in a solution phase 1 -hexene or 1-octene to prepare a polymeric solution containing an amorphous polymer component; c) mixing the polymeric solutions obtained from steps a) and b); d) subjecting the mixture of step c) to a devolatilization step to separate a polyolefin blend comprising a semicrystalline component and an amorphous component; the polymerization steps a) and b) being carried out in two polymerization reactors connected in parallel.

6. 发明公开

EP2254946A1 COMPOSITIONS OF 1-BUTENE BASED POLYMERS 有权
标题翻译：组成的聚合物1-丁烯BASE
公开(公告)号：EP2254946A1
公开(公告)日：2010-12-01
申请号：EP09721344.1
申请日：2009-02-26
申请人： Basell Poliolefine Italia S.R.L.
发明人： RESCONI, Luigi , BALBONI, Davide
IPC分类号： C08L23/20
CPC分类号： C08L23/20 , C08L2205/02 , C08L2666/06
摘要： A 1-butene polymer composition comprising: a) from 10% to 90% by weight of an isotactic 1-butene polymer having the following features: i) isotactic pentad (mmmm) measured by
13 C-NMR, higher than 90%; ii) melting point (TmII) higher than 90°C; and iii) intrinsic viscosity (IV) measured in tetrahydronaphthalene (THN) at 135°C comprised between 0.5 dl/g and 5.0 dl/g. b) from 90% to 10% by weight of a copolymer of 1-butene and at least a C
8 -C
12 alpha- olefin derived units, containing from 0% to 10% by mole of propylene or pentene derived units, and/or containing from 0% to 5% by mole of ethylene derived units having a content of C
8 -C
12 alpha-olefin derived units higher than 4.0% by mol and lower than 20.0% by mol; endowed with the following features: i) isotactic pentad mmmm higher than or equal to 90 %; pentads (mmrr+mrrm) lower than 4 and pentad rmmr not detectable by C NMR. ii) intrinsic viscosity (IV) measured in tetrahydronaphthalene at 135°C comprised between 0.8 and 5.0 dL/g; iii) the melting point measured by DSC (TmI) and the C
8 -C
12 alpha-olefin content fulfil the following relationship: TmI -0.3 wherein C is the molar content of C
8 -C
12 alpha-olefin derived units and TmI is the highest melting peak in the first melting transition; otherwise the melting point TmI is not detectable;

7. 发明授权

EP2254946B1 COMPOSITIONS OF 1-BUTENE BASED POLYMERS 有权
标题翻译：组成的聚合物1-丁烯BASE
公开(公告)号：EP2254946B1
公开(公告)日：2012-02-01
申请号：EP09721344.1
申请日：2009-02-26
申请人： Basell Poliolefine Italia S.r.l.
发明人： RESCONI, Luigi , BALBONI, Davide
IPC分类号： C08L23/20
CPC分类号： C08L23/20 , C08L2205/02 , C08L2666/06
摘要： A 1-butene polymer composition comprising: a) from 10% to 90% by weight of an isotactic 1-butene polymer having the following features: i) isotactic pentad (mmmm) measured by
13 C-NMR, higher than 90%; ii) melting point (TmII) higher than 90°C; and iii) intrinsic viscosity (IV) measured in tetrahydronaphthalene (THN) at 135°C comprised between 0.5 dl/g and 5.0 dl/g. b) from 90% to 10% by weight of a copolymer of 1-butene and at least a C
8 -C
12 alpha- olefin derived units, containing from 0% to 10% by mole of propylene or pentene derived units, and/or containing from 0% to 5% by mole of ethylene derived units having a content of C
8 -C
12 alpha-olefin derived units higher than 4.0% by mol and lower than 20.0% by mol; endowed with the following features: i) isotactic pentad mmmm higher than or equal to 90 %; pentads (mmrr+mrrm) lower than 4 and pentad rmmr not detectable by C NMR. ii) intrinsic viscosity (IV) measured in tetrahydronaphthalene at 135°C comprised between 0.8 and 5.0 dL/g; iii) the melting point measured by DSC (TmI) and the C
8 -C
12 alpha-olefin content fulfil the following relationship: TmI -0.3 wherein C is the molar content of C
8 -C
12 alpha-olefin derived units and TmI is the highest melting peak in the first melting transition; otherwise the melting point TmI is not detectable;

8. 发明公开

EP2254918A1 1-BUTENE TERPOLYMERS 审中-公开
公开(公告)号：EP2254918A1
公开(公告)日：2010-12-01
申请号：EP09722405.9
申请日：2009-02-27
申请人： Basell Poliolefine Italia S.R.L.
发明人： RESCONI, Luigi , BALBONI, Davide , ESPOSITO, Simona
IPC分类号： C08F210/08 , C08F210/14 , C08F210/16
CPC分类号： C08F210/16 , C08F4/65912 , C08F210/08 , C08F210/14 , C08F2420/05 , C08F4/65927 , C08F2500/15 , C08F2500/17 , C08F2500/20
摘要： A terpolymer of 1-butene, ethylene and a at least a C
8 -C
12 alpha-olefin derived units, containing from 0.1 % to 5 % by mole of ethylene derived units and from 1 from 20% by mol of C
8 -C
12 alpha-olefin derived units, endowed with the following properties : i) isotactic pentad mmmm higher than or equal to 90%; pentads (mmrr+mrrm) lower than 4 and pentad rmmr not detectable by
13 C NMR. ii) intrinsic viscosity (IV) measured in tetrahydronaphthalene at 135°C comprised between 0.8 and 5.0 dL/g; iii) the melting point measured by DSC (TmI) and the C
8 -C
12 alpha-olefin content fulfil the following relationship: TmI -0.3 wherein C is the molar content of C
8 -C
12 alpha-olefin derived units and TmI is the highest melting peak in the first melting transition measured by DSC otherwise the melting point TmI is not detectable.
摘要翻译： 1-丁烯，乙烯和至少一种C 8 -C 12α-烯烃衍生单元的三元共聚物，含有0.1-5％（摩尔）乙烯衍生单元和1-20％（摩尔）C 8 -C 12α-烯烃衍生单元，具有以下性质：i）全同立构五元组mmmm高于或等于90％; 五元组（mmrr + mrrm）低于4，五元组rmmr不能通过13C NMR检测。 ii）在135℃下在四氢萘中测量的特性粘度（IV）为0.8-5.0dL / g; iii）通过DSC测量的熔点（TmI）和C 8 -C 12α-烯烃含量满足以下关系：T m1 <130×C -0.3其中C是C 8 -C 12α-烯烃衍生的单元的摩尔含量和 TmI是通过DSC测量的第一次熔融转变中的最高熔融峰，否则熔点TmI不可检测。

9. 发明公开

EP1879959A2 POLYMERIZATION PROCESS FOR PREPARING POLYOLEFIN BLENDS 有权
标题翻译：聚合用于生产聚烯烃共混物
公开(公告)号：EP1879959A2
公开(公告)日：2008-01-23
申请号：EP06763094.7
申请日：2006-05-08
申请人： Basell Poliolefine Italia S.r.l.
发明人： RESCONI, Luigi , BIGIAVI, Daniele
IPC分类号： C08L23/00 , C08F10/00
CPC分类号： C08L23/12 , C08L23/10 , C08L23/14 , C08L23/18 , C08L23/20 , C08L2308/00 , C08L2666/06
摘要： A process for preparing polyolefin blends comprising: a) polymerizing in a solution phase propylene or 1-butene to prepare a polymeric solution containing a semicrystalline polymer component; b) polymerizing in a solution phase 1 -hexene or 1-octene to prepare a polymeric solution containing an amorphous polymer component; c) mixing the polymeric solutions obtained from steps a) and b); d) subjecting the mixture of step c) to a devolatilization step to separate a polyolefin blend comprising a semicrystalline component and an amorphous component; the polymerization steps a) and b) being carried out in two polymerization reactors connected in parallel.

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