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1. 发明授权

US4491669A Mixed alkoxyaminosilanes, methods of making same and vulcanizing silicons prepared therefrom 失效
标题翻译：混合烷氧基氨基硅烷，其制备方法和硫化由其制备的硅酮
公开(公告)号：US4491669A
公开(公告)日：1985-01-01
申请号：US206236
申请日：1980-11-12
申请人： Barry C. Arkles , William R. Peterson, Jr. , Joseph M. Rokowski
发明人： Barry C. Arkles , William R. Peterson, Jr. , Joseph M. Rokowski
IPC分类号： C07F7/02 , C07F7/18 , C07F7/08 , C07F7/10
CPC分类号： C07F7/025 , C07F7/1868
摘要： The preparation of pure mixed alkoxyaminosilanes is described corresponding to the general formula:R.sub.m Si(OR').sub.n (NR"R'").sub.pwherein:R is hydrogen, short chain alkyl or alkenyl or aryl;R" and R'" are separately either hydrogen, short chain alkyl or aryl, at least one being other than hydrogen;R' is short chain alkyl or aryl; andm, n and p are integers such that m+n+p=4 and n and p are at least one each.The obtained compounds are employed in endcapping of polysiloxanes having terminal silane groups.
摘要翻译：对应于通式R MSi（OR'）n（NR''R“'）p描述纯混合烷氧基氨基硅烷的制备，其中：R是氢，短链烷基或链烯基或芳基; R“和R”'分别是氢，短链烷基或芳基，至少一个不同于氢; R'是短链烷基或芳基; m，n和p是整数，使得m + n + p = 4，n和p各自为至少一个。所得化合物用于封端具有末端硅烷基团的聚硅氧烷。

2. 发明授权

US4336395A Ethylene bridged amine functional silanes, composites using the same, and intermediates therefor 失效
标题翻译：乙烯桥连胺官能硅烷，使用其的复合材料及其中间体
公开(公告)号：US4336395A
公开(公告)日：1982-06-22
申请号：US129766
申请日：1980-03-12
申请人： William R. Peterson, Jr. , Barry C. Arkles
发明人： William R. Peterson, Jr. , Barry C. Arkles
IPC分类号： C07F7/10 , C07F7/18
CPC分类号： C07F7/182 , C07F7/10
摘要： Ethylene bridged benzylamine trifunctional silanes are provided having the general formula:Z--CH.sub.2 --Ph--CH.sub.2 CH.sub.2 --SiX.sub.3wherein Ph is a phenyl group, at least one X is a hydrolyzable group and Z is a non-hydrolyzable amine functional group. At least one X group is that which is displaced by hydrolysis during the well known reactions of silanes with siliceous substrates, and is preferably methoxy, ethoxy or methoxyethoxy. The Z group is intended to react and bond with polymers in the formation of polymer composites reinforced with siliceous substrates such as glass fibers. The Z group is preferably an amine or alkyl diamine group. The silanes of the invention have excellent thermal stability so that they may be used as coupling agents for composites in which the polymers are processed at temperatures in excess of 350.degree. C. and/or are subject to temperatures in excess of 150.degree. C. for extended periods of time.
摘要翻译：提供具有通式Z-CH2-Ph-CH2CH2-SiX3的乙烯桥连的苄胺三官能硅烷，其中Ph是苯基，至少一个X是可水解基团，Z是不可水解的胺官能团。至少一个X基团是在硅烷与硅质底物的公知反应期间通过水解而被置换的，并且优选为甲氧基，乙氧基或甲氧基乙氧基。 Z组旨在与聚合物反应并与聚合物结合，形成用硅质基材如玻璃纤维增强的聚合物复合材料。 Z基优选为胺或烷基二胺基。本发明的硅烷具有优异的热稳定性，因此它们可以用作复合材料的偶联剂，其中聚合物在超过350℃的温度下处理和/或经受超过150℃的温度，以供延长的时间。

3. 发明授权

US4276424A Methods for the production of organic polysilanes 失效
标题翻译：生产有机聚硅烷的方法
公开(公告)号：US4276424A
公开(公告)日：1981-06-30
申请号：US99266
申请日：1979-12-03
申请人： William R. Peterson, Jr. , Barry C. Arkles
发明人： William R. Peterson, Jr. , Barry C. Arkles
IPC分类号： C07F7/08 , C07F7/12
CPC分类号： C07F7/0821
摘要： Organic polysilanes may be produced in a simpler, safer and more economic manner by reacting an organohalosilicon hydride with lithium metal or lithium-alkali metal alloy. According to the reaction the silicon-silicon bonds of the organopolysilane are formed by the removal of halogen and hydrogen from the hydride. Particularly important is the formation of dodecamethylcyclohexasilane by the reaction of dimethyl chlorosilane with lithium metal. Simpler polysilanes may be produced by adding to the reaction mixture endcappers such as trifunctional organohalosilanes without an Si-H bond.
摘要翻译：有机聚硅烷可以通过使有机卤硅化物与锂金属或锂 - 碱金属合金反应，以更简单，更安全和更经济的方式制备。根据反应，通过从氢化物中除去卤素和氢，形成有机聚硅烷的硅 - 硅键。特别重要的是通过二甲基氯硅烷与锂金属的反应形成十二甲基环己硅烷。可以通过向反应混合物中加入没有Si-H键的三官能有机卤代硅烷来制备更简单的聚硅烷。

4. 发明申请

US20100280266A1 Fixed-Bed Hydrosilylation Catalyst Complexes and Related Methods 有权
标题翻译：固定床氢化硅烷化催化剂配合物及相关方法
公开(公告)号：US20100280266A1
公开(公告)日：2010-11-04
申请号：US12770895
申请日：2010-04-30
申请人： Gerald L. Larson , Barry C. Arkles , Rudolph A. Cameron
发明人： Gerald L. Larson , Barry C. Arkles , Rudolph A. Cameron
IPC分类号： C07F7/08 , B01J31/12 , B01J8/02
CPC分类号： C07F15/0086 , B01J31/1616 , B01J31/2273 , B01J31/2291 , B01J2231/32 , B01J2531/828 , Y02P20/588
摘要： The invention includes a fixed-bed catalyst complex that includes (i) a metal carbene catalyst, wherein the metal is platinum, and (ii) a catalyst support that includes one or more of silica, alumina and/or glass. The invention provides a fixed-bed catalyst complex that includes a catalyst complex including a carbene chosen from those represented by at least one of Formulae (I), (II), (III), and (IV): Where the vales of X and R1 to R7 are specifically defined. The complex also includes a catalyst support that comprises silica, related reaction products, and related reaction systems.
摘要翻译：本发明包括固定床催化剂络合物，其包括（i）金属卡宾催化剂，其中金属为铂，和（ii）包含二氧化硅，氧化铝和/或玻璃中的一种或多种的催化剂载体。本发明提供了一种固定床催化剂配合物，其包括催化剂络合物，其包含选自由式（I），（II），（III）和（IV）中的至少一个表示的卡宾）：其中X和 R1至R7被具体定义。该复合物还包括一种催化剂载体，其包括二氧化硅，相关的反应产物和相关的反应体系。

5. 发明申请

US20100105817A1 Silanes with Embedded Hydrophilicity, Dispersible Particles Derived Therefrom and Related Methods 有权
标题翻译：具有嵌入亲水性的硅烷，衍生自其的分散粒子及相关方法
公开(公告)号：US20100105817A1
公开(公告)日：2010-04-29
申请号：US12470901
申请日：2009-05-22
申请人： Barry C. Arkles , Jane C. Hollenberg , Yun Mi Kim , Youlin Pan
发明人： Barry C. Arkles , Jane C. Hollenberg , Yun Mi Kim , Youlin Pan
IPC分类号： C08K5/5419 , C07F7/08 , B05D1/02 , B05D1/28 , C23C16/00 , B32B15/02
CPC分类号： C09C1/32 , C01P2006/22 , C07F7/1804 , C09C1/24 , C09C1/3081 , C09C1/3684 , C09C1/405 , Y10T428/2998
摘要： The invention provides a silane compound that includes a hydrophobic group and a silane ester group linked by a hydrophilic group for use as a surface treatment to an inorganic material, such as a pigment, the silane including a hydrophobic group and a silane ester group linked by a hydrophilic group. The invention includes a coated particle including an inorganic material coated with the silane compound(s) and methods of improving the wettability and/or dispersibility of an inorganic material such as a pigment, wherein the method comprises depositing the silane compounds on the surface of a pigment.
摘要翻译：本发明提供了一种硅烷化合物，其包括疏水基团和通过亲水基团连接的硅烷酯基团，用作对诸如颜料的无机材料的表面处理，包含疏水基团的硅烷和由亲水基团。本发明包括包含涂覆有硅烷化合物的无机材料的涂覆颗粒以及改善诸如颜料的无机材料的润湿性和/或分散性的方法，其中所述方法包括在硅烷化合物的表面上沉积硅烷化合物颜料。

6. 发明授权

US6139922A Tantalum and tantalum-based films formed using fluorine-containing source precursors and methods of making the same 失效
标题翻译：使用含氟源前体形成的钽和钽基膜及其制备方法
公开(公告)号：US6139922A
公开(公告)日：2000-10-31
申请号：US313618
申请日：1999-05-18
申请人： Alain E. Kaloyeros , Barry C. Arkles
发明人： Alain E. Kaloyeros , Barry C. Arkles
IPC分类号： C23C16/14 , C23C16/18 , C23C16/34 , C23C16/42 , H01L21/28 , H01L21/285 , H01L21/768 , C23C16/08 , H01L21/44
CPC分类号： H01L21/76846 , C23C16/14 , C23C16/18 , C23C16/34 , C23C16/42 , H01L21/76843 , H01L21/76855
摘要： A method for chemical vapor deposition of a film comprising tantalum onto a substrate includes introducing into a deposition chamber: (i) a substrate; (ii) a source precursor in the vapor state; and (iii) a reactant gas, and maintaining the temperature of the substrate within the chamber as from about 70.degree. C. to about 675.degree. C. for a period of time sufficient to deposit a film comprising tantalum on the substrate. The source precursor has a formula (I):Ta(F.sub.5-q-p)(X.sub.q-p)(R.sub.p) (I)wherein X is selected from the group consisting of bromine, iodine, chlorine, and combinations thereof; q is an integer from 0 to 4; p is an integer from 0 to 4; and R is selected from the group consisting of hydrogen and lower alkyl.
摘要翻译：将包含钽的薄膜化学气相沉积到基底上的方法包括将沉积室引入沉积室：（i）基底; （ii）蒸气状态的源前体; 和（iii）反应物气体，并且将该室内的衬底的温度保持在约70℃至约675℃，持续足以在衬底上沉积包含钽的膜的时间。源前体具有式（I）：其中X选自溴，碘，氯及其组合的Ta（F5-q-p）（Xq-p）（Rp）（I） q是0〜4的整数; p是0至4的整数; 并且R选自氢和低级烷基。

7. 发明授权

US6066196A Method for the chemical vapor deposition of copper-based films and copper source precursors for the same 有权
标题翻译：铜基膜和铜源前体的化学气相沉积方法
公开(公告)号：US6066196A
公开(公告)日：2000-05-23
申请号：US157901
申请日：1998-09-21
申请人： Alain E. Kaloyeros , Barry C. Arkles
发明人： Alain E. Kaloyeros , Barry C. Arkles
IPC分类号： C07C49/92 , C07F1/08 , C23C16/04 , C23C16/14 , C23C16/18 , H01L21/28 , H01L21/285 , H01L21/768 , H01L23/532 , C09D5/00
CPC分类号： C23C16/045 , C23C16/18 , H01L21/76877 , H01L23/53228 , H01L2924/0002
摘要： A method for depositing copper-based films and a copper source precursor for use in the chemical vapor deposition of copper-based films are provided. The precursor includes a mixture of at least one ligand-stabilized copper (I) .beta.-diketonate precursor; and at least one copper(II) .beta.-diketonate precursor. The method includes introducing into a deposition chamber: (i) a substrate; (ii) a copper source precursor in a vapor state including a mixture of at least one ligand-stabilized copper (I) .beta.-diketonate precursor; and at least one copper(II) .beta.-diketonate precursor; and (iii) at least one transport gas, different than said copper source precursor. The reaction substrate temperature is maintained at from about 50.degree. C. to about 500.degree. C. for a period of time sufficient to deposit a copper-based film on said substrate.
摘要翻译：提供了用于铜基膜的化学气相沉积中用于沉积铜基膜和铜源前体的方法。前体包括至少一种配体稳定的铜（I）β-二酮前体的混合物; 和至少一种β-二酮铜（II）前体。该方法包括引入沉积室：（i）衬底; （ii）蒸气状态的铜源前体，包括至少一种配体稳定的铜（I）β-二酮前体的混合物; 和至少一种β-二酮铜（II）前体; 和（iii）不同于所述铜源前体的至少一种输送气体。将反应基板温度保持在约50℃至约500℃，持续足以在所述基材上沉积铜基膜的时间。

8. 发明授权

US5874603A Branched higher alkylsilanes 失效
标题翻译：支链高级烷基硅烷
公开(公告)号：US5874603A
公开(公告)日：1999-02-23
申请号：US892595
申请日：1997-07-15
申请人： Barry C. Arkles
发明人： Barry C. Arkles
IPC分类号： B01D15/08 , B01J20/32 , C07F7/10 , C07F7/12 , C07F7/18 , C07F7/08
CPC分类号： B01J20/3246 , B01J20/287 , C07F7/10 , C07F7/12 , C07F7/1836 , C07F7/184
摘要： A branched alkylsilane includes a branched hydrocarbon backbone which has a linear or branched alkylsilyl moiety extending asymmetrically from the backbone such that the backbone has a first portion and a second portion extending from the moiety. The second portion has two carbon atoms more than the first portion, and the alkylsilyl moiety includes at least one hydrolyzable group bound to silicon for reacting with a substrate. A method for preparing a branched alkylsilane useful for chromatographic applications includes the steps of preparing a vinylidene olefin by dimerization of an .alpha.-olefin and reacting it with a monomeric silane having a silicon-hydrogen bond in the presence of a metallic catalyst such that the silicon-hydrogen bond is added to the vinylidene double bond of the vinylidene olefin thereby converting the double bond to a single bond and bonding the silicon of the monomeric silane to the vinylidene olefin to form a branched alkylsilane.
摘要翻译：支链烷基硅烷包括具有从主链不对称延伸的直链或支链烷基甲硅烷基部分的支链烃主链，使得主链具有从该部分延伸的第一部分和第二部分。第二部分具有比第一部分多两个碳原子，并且烷基甲硅烷基部分包括与硅键合的至少一个可水解基团以与基底反应。制备可用于色谱应用的支链烷基硅烷的方法包括以下步骤：通过α-烯烃的二聚制备亚乙烯基烯烃，并在金属催化剂存在下使其与具有硅 - 氢键的单体硅烷反应，使得硅将氢键加入亚乙烯基烯烃的亚乙烯基双键，从而将双键转化为单键，并将单体硅烷的硅键合到亚乙烯基烯烃上以形成支链烷基硅烷。

9. 发明授权

US5371262A Hydroxymethyltrialkoxysilanes and methods of making and using the same 失效
标题翻译：羟甲基三烷氧基硅烷及其制备和使用方法
公开(公告)号：US5371262A
公开(公告)日：1994-12-06
申请号：US29217
申请日：1993-03-10
申请人： Barry C. Arkles
发明人： Barry C. Arkles
IPC分类号： C03B8/02 , C03C1/00 , C07F7/18 , C08G77/50 , C08G77/60 , C09D183/14 , C07F7/08
CPC分类号： C08G77/60 , C03C1/008 , C07F7/1836 , C08G77/50 , C09D183/14
摘要： Novel hydroxymethyltrialkoxysilanes of the formula: ##STR1## are produced by transesterifying a carboxylic acid ester of hydroxymethyltrialkoxysilane with an alcohol, and distilling the reaction mixture to remove the carboxylate of the alcohol. The carboxylic acid ester of hydroxymethyltrialkoxysilane is prepared by the reaction of an alkali metal carboxylate with chloromethyltrialkoxysilane, which in turn is prepared by the reaction of a trialkylorthoester with chloromethyltrichlorosilane by heating to reflux with removal of alkylchloride, followed by distillation to remove alkyl ester. The hydroxymethyltrialkoxysilanes and carboxylic acid esters thereof, as well as carboxymethyltrialkoxysilanes, are particularly useful in sol-gel processing by undergoing hydrolysis to yield hydroxymethylsilanetriol, and subsequent hydrolysis and polycondensation products.
摘要翻译：通过羟基甲基三烷氧基硅烷的羧酸酯与醇的酯交换反应产生下式的新型羟甲基三烷氧基硅烷：（I），并蒸馏反应混合物以除去醇的羧酸酯。羟甲基三烷氧基硅烷的羧酸酯是通过碱金属羧酸盐与氯甲基三烷氧基硅烷的反应来制备的，而羧甲基三烷氧基硅烷又通过三氯烷基原料与氯甲基三氯硅烷的反应制备，通过加热回流除去烷基氯，然后蒸馏除去烷基酯。羟甲基三烷氧基硅烷及其羧酸酯以及羧甲基三烷氧基硅烷特别可用于通过水解产生羟甲基硅烷三醇的溶胶 - 凝胶加工，以及随后的水解和缩聚产物。

10. 发明授权

US4699991A Methods of using silacrown ethers as catalysts 失效
标题翻译：使用硅氯醚作为催化剂的方法
公开(公告)号：US4699991A
公开(公告)日：1987-10-13
申请号：US426519
申请日：1982-09-29
申请人： Barry C. Arkles
发明人： Barry C. Arkles
IPC分类号： C07F7/18 , C07C120/02 , C07C120/04 , C07C125/06
CPC分类号： C07F7/184 , C07F7/1836
摘要： Organosilicon compounds referred to as silacrown ethers or "silacrowns" are of the general formula: ##STR1## where R.sup.1 and R.sup.2 are organic radicals or hydrogen and n is an integer between 4 and 10 inclusive. Silacrown ethers are prepared by reacting polyethylene glycol with substituted silanes under conditions promoting cyclization over polymerization. Silacrown ethers may be employed as phase-transfer catalysts in solution or immobilized on siliceous supports.
摘要翻译：被称为硅溶胶醚或“硅藻糖”的有机硅化合物具有以下通式：其中R 1和R 2是有机基团或氢，n是4和10之间的整数。通过在促进聚合反应环化的条件下使聚乙二醇与取代的硅烷反应制备硅烷基醚。硅沙酮醚可用作溶液中的相转移催化剂或固定在硅质载体上。

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