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1. 发明申请

US20120016071A1 POLYFUNCTIONAL (METH)ACRYLIC POLYMER, COATING COMPOSITION, PROCESS FOR PRODUCING A COATING AND COATED ARTICLE 审中-公开
标题翻译：多官能（甲基）丙烯酸聚合物，涂料组合物，制备涂料和涂料的方法
公开(公告)号：US20120016071A1
公开(公告)日：2012-01-19
申请号：US13259184
申请日：2010-03-03
申请人： Bardo Schmitt , Wolfgang Klesse , Martina Ebert , Thorben Schuetz , Mario Gomez Andreu
发明人： Bardo Schmitt , Wolfgang Klesse , Martina Ebert , Thorben Schuetz , Mario Gomez Andreu
IPC分类号： C09D135/06 , B05D3/00 , B05D7/14 , C08F222/38 , B05D7/24
CPC分类号： C09D133/066 , C08F212/08 , C08F220/18 , C08G18/6266 , C08G18/73 , C09D125/14 , C09D133/14 , C09D135/06 , C09D175/04 , C08F220/26 , C08F220/36
摘要： The present invention relates to a (meth)acrylate polymer for preparing a coating composition, where the (meth)acrylate polymer comprises 0.5% to 20% by weight of units derived from (meth)acrylic monomers which in the alkyl radical have at least one double bond and 8 to 40 carbon atoms, 0.1% to 60% by weight of units derived from hydroxyl-containing monomers which have up to 9 carbon atoms, 0.1% to 95% by weight of units derived from (meth)acrylates having 1 to 12 carbon atoms in the alkyl radical, and 0.1% to 60% by weight of units derived from styrene monomers, based in each case on the weight of the (meth)acrylate polymer, and the (meth)acrylate polymer has a weight-average molecular weight in the range from 2000 to 60 000 g/mol. The present invention further relates to a coating composition and to a method of producing a coating. The present invention describes, furthermore, a coated article comprising a coating obtainable by the method.
摘要翻译：本发明涉及一种用于制备涂料组合物的（甲基）丙烯酸酯聚合物，其中（甲基）丙烯酸酯聚合物包含0.5重量％至20重量％的衍生自（甲基）丙烯酸单体的单元，其在烷基中具有至少一个双键和8至40个碳原子，0.1至60重量％的衍生自具有至多9个碳原子的含羟基单体的单元，0.1重量％至95重量％的衍生自（甲基）丙烯酸酯的单元，其具有1至（甲基）丙烯酸酯聚合物的重量，基于（甲基）丙烯酸酯聚合物的重量，基于（甲基）丙烯酸酯聚合物的重量百分数为0.1〜60重量％的苯乙烯单体衍生的单元，分子量在2000〜60000g / mol的范围内。本发明还涉及一种涂料组合物和一种制备涂料的方法。此外，本发明还描述了包含可通过该方法获得的涂层的涂覆制品。

2. 发明申请

US20110313195A1 METHOD FOR CONTINUOUSLY PRODUCING ALKYLAMINO(METH)ACRYLAMIDES 失效
标题翻译：连续生产烷基胺（甲基）丙烯酰胺的方法
公开(公告)号：US20110313195A1
公开(公告)日：2011-12-22
申请号：US13254280
申请日：2010-03-03
申请人： Bardo Schmitt , Wolfgang Klesse , Martina Ebert , Dirk Broell , Guido Protzmann , Joachim Knebel , Thomas Kehr , Hans-Gerhard Stadler , Gerhard Koelbl , Benedikt Laux
发明人： Bardo Schmitt , Wolfgang Klesse , Martina Ebert , Dirk Broell , Guido Protzmann , Joachim Knebel , Thomas Kehr , Hans-Gerhard Stadler , Gerhard Koelbl , Benedikt Laux
IPC分类号： C07C231/02
CPC分类号： C07C231/02 , Y02P20/582 , Y02P20/584 , C07C233/38
摘要： The invention relates to a process for continuously preparing N-alkyl(meth)acrylamides by reacting alkyl (meth)acrylates with high-boiling amines. A catalyst activation and specific workup technique achieve product qualities which have not been achieved to date. In addition, very high space-time yields and overall yields can be achieved.
摘要翻译：本发明涉及通过使（甲基）丙烯酸烷基酯与高沸点胺反应来连续制备（甲基）丙烯酰胺的N-烷基酯的方法。催化剂激活和具体的后处理技术实现迄今尚未实现的产品质量。此外，可以实现非常高的时空产量和总产量。

3. 发明授权

US08674133B2 Method for continuously producing alkylamino(meth)acrylamides 失效
标题翻译：连续生产烷基氨基（甲基）丙烯酰胺的方法
公开(公告)号：US08674133B2
公开(公告)日：2014-03-18
申请号：US13254280
申请日：2010-03-03
申请人： Bardo Schmitt , Wolfgang Klesse , Martina Ebert , Dirk Broell , Guido Protzmann , Joachim Knebel , Thomas Kehr , Hans-Gerhard Stadler , Gerhard Koelbl , Benedikt Laux
发明人： Bardo Schmitt , Wolfgang Klesse , Martina Ebert , Dirk Broell , Guido Protzmann , Joachim Knebel , Thomas Kehr , Hans-Gerhard Stadler , Gerhard Koelbl , Benedikt Laux
IPC分类号： C07C231/02
CPC分类号： C07C231/02 , Y02P20/582 , Y02P20/584 , C07C233/38
摘要： The invention relates to a process for continuously preparing N-alkyl(meth)acrylamides by reacting alkyl(meth)acrylates with high-boiling amines. A catalyst activation and specific workup technique achieve product qualities which have not been achieved to date. In addition, very high space-time yields and overall yields can be achieved.
摘要翻译：本发明涉及通过使（甲基）丙烯酸烷基酯与高沸点胺反应来连续制备（甲基）丙烯酰胺的N-烷基酯的方法。催化剂激活和具体的后处理技术实现迄今尚未实现的产品质量。此外，可以实现非常高的时空产量和总产量。

4. 发明授权

US08669328B2 Composition comprising as the aqueous dispersion preferably (meth)acrylate polymers containing benzophenone in a mixture with (meth)acrylate polymers different therefrom and the use of said composition 失效
标题翻译：包含作为水分散体的组合物优选含有与（甲基）丙烯酸酯聚合物不同的混合物中的二苯甲酮的（甲基）丙烯酸酯聚合物，以及所述组合物
公开(公告)号：US08669328B2
公开(公告)日：2014-03-11
申请号：US13201889
申请日：2010-03-02
申请人： Christine Maria Breiner , Mario Gomez Andreu , Gerold Schmitt , Wolfgang Klesse
发明人： Christine Maria Breiner , Mario Gomez Andreu , Gerold Schmitt , Wolfgang Klesse
IPC分类号： C08L33/04 , C09D133/04 , C04B41/48 , C08L33/12 , C09D133/12 , C08F2/22 , C08F2/48
CPC分类号： C04B41/009 , C04B41/483 , C04B41/63 , C04B2111/60 , C08L33/12 , C08L2205/02 , C09D133/12 , C04B28/02 , C08L2666/04
摘要： The invention describes a composition comprising, in the form of aqueous dispersion, A) for every 100 parts by weight of a, or of a plurality of, (meth)acrylate polymer(s); B) from 1-400 parts by weight of a, or of a plurality of, (meth)acrylate polymer(s), which contain(s) a compound of the formula (I) copolymerized, where the (meth)acrylate polymer(s) B) differ from the (meth)acrylate polymers specified in A), where these are obtainable by emulsion polymerization of a mixture comprising a) from 0.1 to 99.9 percent by weight of at least one compound of the formula (I), preferably of a benzophenone (meth)acrylate, in which the definitions of the moieties are those given in the description; and b) from 99.9 to 0.1% by weight of a, or of a plurality of, ethylenically unsaturated monomer(s) which differ(s) from a) and which is/are copolymerizable with a), where components a) and b) together give 100% by weight of the polymerizable constituents of the mixture; and where the parts by weight of A) and B) are based on the solids content of the polymers A) or B) in the aqueous dispersion. Dispersions of this type are UV-curable and have excellent suitability for the production of coatings of any type, in particular for coating of mineral substrates, such as concrete. The dispersions of the invention are also advantageous for blending with known dispersions and improve their properties, in particular in respect of their curing profile.
摘要翻译：本发明描述了一种组合物，其包含水分散体的形式，A）每100重量份的一种或多种（甲基）丙烯酸酯聚合物; B）1-400重量份的一种或多种（甲基）丙烯酸酯聚合物，其含有（s）共聚的式（I）化合物，其中（甲基）丙烯酸酯聚合物（ s）B）与A）中规定的（甲基）丙烯酸酯聚合物不同，其中这些可通过将混合物乳液聚合而获得，所述混合物包含a）0.1至99.9重量％的至少一种式（I）化合物，优选的二苯甲酮（甲基）丙烯酸酯，其中部分的定义是在说明书中给出的那些; 和b）99.9重量％至0.1重量％的a）或多个不同于a）的烯键式不饱和单体，并且其可与a）共聚，其中组分a）和b）一起提供100重量％的混合物的可聚合组分; 并且其中A）和B）的重量份数基于水分散体中聚合物A）或B）的固体含量。这种类型的分散体是可UV固化的，并且对于任何类型的涂料的生产具有优异的适用性，特别是用于矿物基材例如混凝土的涂层。本发明的分散体也有利于与已知的分散体共混并改进其性能，特别是在其固化分布方面。

5. 发明申请

US20110136975A1 MONOMER MIXTURE, POLYMER, COATING MEANS AND METHOD FOR PRODUCING A COATING 审中-公开
标题翻译：单体混合物，聚合物，涂料方法和制造涂料的方法
公开(公告)号：US20110136975A1
公开(公告)日：2011-06-09
申请号：US13055624
申请日：2009-08-31
申请人： Christine Maria Breiner , Gerold Schmitt , Wolfgang Klesse , Mario Gomez Andreu
发明人： Christine Maria Breiner , Gerold Schmitt , Wolfgang Klesse , Mario Gomez Andreu
IPC分类号： C08L29/00 , B05D3/10 , C08L33/02 , C08F26/02 , C08F12/28 , C08F216/34
CPC分类号： C07C67/293 , C07C69/54 , C08F8/00 , C08F220/06 , C08F220/14 , C08F220/18 , C08F220/26 , C08F220/28 , C08L33/14 , C09D133/14
摘要： The present invention relates to a monomer mixture comprising at least 30% by weight of one or more alkyl (meth)acrylates having 1 to 10 carbon atoms in the alkyl radical, whose alkyl radical contains no double bonds or heteroatoms, and 0.1% to 40% by weight of one or more (meth)acrylates having at least one aldehyde group in the alkyl radical. The present invention further relates to polymers obtainable from this monomer mixture and also to coating materials which comprise the stated polymers.
摘要翻译：本发明涉及一种单体混合物，其包含至少30重量％的烷基中具有1-10个碳原子的（甲基）丙烯酸烷基酯（其烷基不含双键或杂原子）和0.1％至40％重量％的一种或多种在烷基中具有至少一个醛基的（甲基）丙烯酸酯。本发明还涉及可从该单体混合物获得的聚合物，还涉及包含所述聚合物的涂料。

6. 发明申请

US20110319514A1 COMPOSITION COMPRISING AS THE AQUEOUS DISPERSION PREFERABLY (METH)ACRYLATE POLYMERS CONTAINING BENZOPHENONE IN A MIXTURE WITH (METH)ACRYLATE POLYMERS DIFFERENT THEREFROM AND THE USE OF SAID COMPOSITION 失效
标题翻译：作为含有（甲基）丙烯酸酯聚合物的混合物中含有苯甲酸酯（甲基）丙烯酸酯聚合物的优选（甲基）丙烯酸酯聚合物的组合物和不同组合物的使用
公开(公告)号：US20110319514A1
公开(公告)日：2011-12-29
申请号：US13201889
申请日：2010-03-02
申请人： Christine Maria Breiner , Mario Gomez Andreu , Gerold Schmitt , Wolfgang Klesse
发明人： Christine Maria Breiner , Mario Gomez Andreu , Gerold Schmitt , Wolfgang Klesse
IPC分类号： C09D129/12 , C08J3/28
CPC分类号： C04B41/009 , C04B41/483 , C04B41/63 , C04B2111/60 , C08L33/12 , C08L2205/02 , C09D133/12 , C04B28/02 , C08L2666/04
摘要： The invention describes a composition comprising, in the form of aqueous dispersion, A) for every 100 parts by weight of a, or of a plurality of, (meth)acrylate polymer(s); B) from 1-400 parts by weight of a, or of a plurality of, (meth)acrylate polymer(s), which contain(s) a compound of the formula (I) copolymerized, where the (meth)acrylate polymer(s) B) differ from the (meth)acrylate polymers specified in A), where these are obtainable by emulsion polymerization of a mixture comprising a) from 0.1 to 99.9 percent by weight of at least one compound of the formula (I), preferably of a benzophenone (meth)acrylate, in which the definitions of the moieties are those given in the description; and b) from 99.9 to 0.1% by weight of a, or of a plurality of, ethylenically unsaturated monomer(s) which differ(s) from a) and which is/are copolymerizable with a), where components a) and b) together give 100% by weight of the polymerizable constituents of the mixture; and where the parts by weight of A) and B) are based on the solids content of the polymers A) or B) in the aqueous dispersion. Dispersions of this type are UV-curable and have excellent suitability for the production of coatings of any type, in particular for coating of mineral substrates, such as concrete. The dispersions of the invention are also advantageous for blending with known dispersions and improve their properties, in particular in respect of their curing profile.
摘要翻译：本发明描述了一种组合物，其包含水分散体的形式，A）每100重量份的一种或多种（甲基）丙烯酸酯聚合物; B）1-400重量份的一种或多种（甲基）丙烯酸酯聚合物，其含有（s）共聚的式（I）化合物，其中（甲基）丙烯酸酯聚合物（ s）B）与A）中规定的（甲基）丙烯酸酯聚合物不同，其中这些可通过将混合物乳液聚合而获得，所述混合物包含a）0.1至99.9重量％的至少一种式（I）化合物，优选的二苯甲酮（甲基）丙烯酸酯，其中部分的定义是在说明书中给出的那些; 和b）99.9重量％至0.1重量％的a）或多个不同于a）的烯键式不饱和单体，并且其可与a）共聚，其中组分a）和b）一起提供100重量％的混合物的可聚合组分; 并且其中A）和B）的重量份数基于水分散体中聚合物A）或B）的固体含量。这种类型的分散体是可UV固化的，并且对于任何类型的涂料的生产具有优异的适用性，特别是用于矿物基材例如混凝土的涂层。本发明的分散体也有利于与已知的分散体共混并改进其性能，特别是在其固化分布方面。

7. 发明授权

US07144954B2 Highly transparent plastic for optical materials 失效
标题翻译：用于光学材料的高透明塑料
公开(公告)号：US07144954B2
公开(公告)日：2006-12-05
申请号：US10529478
申请日：2003-09-13
申请人： Bardo Schmitt , Wolfgang Klesse , Volker Kerscher , Patrik Hartmann
发明人： Bardo Schmitt , Wolfgang Klesse , Volker Kerscher , Patrik Hartmann
IPC分类号： C08J3/00 , C08K3/20 , C08L75/00 , C08F18/08 , C08G8/30
CPC分类号： C08G18/8175 , C08F222/1006 , C08G18/3876 , C08G18/73
摘要： The present invention relates to mixtures containing A) compounds of the formula (I) and (II) where R1 is independently at each instance hydrogen or a methyl radical, R2 is independently at each instance a linear or branched, aliphatic or cycloaliphatic radical or a substituted or unsubstituted aromatic or heteroaromatic radical and m and n are each independently an integer of not less than 0 subject to the proviso that m+n>0, and B) at least one ethylenically unsaturated monomer (A) which is different from the compounds of the formula (I) and (II). The present invention further relates to processes for polymerizing these mixtures, the highly transparent polymers thus obtainable and to their use.
摘要翻译：本发明涉及含有A）式（I）和（II）化合物的混合物，其中R 1各自独立地为氢或甲基，R 2，在每种情况下独立地为直链或支链的脂族或脂环族基团或取代或未取代的芳族或杂芳族基团，m和n各自独立地为不小于0的整数，条件是m + n> 0，B ）与式（I）和（II）的化合物不同的至少一种烯属不饱和单体（A）。本发明还涉及使这些混合物聚合的方法，由此获得的高度透明的聚合物及其用途。

8. 发明申请

US20070225398A1 Concentrated Aqueous Methacrylamide Solution Comprising Methacrylic Acid 审中-公开
标题翻译：包含甲基丙烯酸的浓甲基丙烯酰胺溶液
公开(公告)号：US20070225398A1
公开(公告)日：2007-09-27
申请号：US11587389
申请日：2005-05-20
申请人： Joachim Knebel , Wolfgang Klesse , Bardo Schmitt
发明人： Joachim Knebel , Wolfgang Klesse , Bardo Schmitt
IPC分类号： C08F20/56 , C08F220/56 , C08L53/00
CPC分类号： C07C231/22 , C07C233/09
摘要： The invention relates to a liquid, concentrated formulation containing methacrylamide.
摘要翻译：本发明涉及含有甲基丙烯酰胺的液体浓缩制剂。

9. 发明授权

US06936734B2 Process for manufacturing unsaturated carboxylic acid anhydrides 失效
标题翻译：制备不饱和羧酸酐的方法
公开(公告)号：US06936734B2
公开(公告)日：2005-08-30
申请号：US10068849
申请日：2002-02-11
申请人： Bardo Schmitt , Joachim Knebel , Wolfgang Klesse , Andrea Wittkowski , Benedikt Laux
发明人： Bardo Schmitt , Joachim Knebel , Wolfgang Klesse , Andrea Wittkowski , Benedikt Laux
IPC分类号： C07B61/00 , C07C51/56 , C07C51/573 , C07C57/04 , C07C65/00
CPC分类号： C07C51/56 , C07C57/04
摘要： The present invention relates to a process for preparing an unsaturated carboxylic acid anhydride by reacting an unsaturated carboxylic acid and a lower aliphatic carboxylic acid anhydride in the presence of a stabilizer and catalyst that contains a metal salt of an anionic organic compound which has at least one carboxyl group.
摘要翻译：本发明涉及一种在稳定剂和含有阴离子有机化合物的金属盐的催化剂存在下使不饱和羧酸和低级脂族羧酸酐反应制备不饱和羧酸酐的方法，所述阴离子有机化合物的金属盐具有至少一个羧基。

10. 发明申请

US20050261421A1 Highly transparent plastic for optical materials 失效
标题翻译：用于光学材料的高透明塑料
公开(公告)号：US20050261421A1
公开(公告)日：2005-11-24
申请号：US10529478
申请日：2003-09-13
申请人： Bardo Schmitt , Wolfgang Klesse , Volker Kerscher , Patrik Hartmann
发明人： Bardo Schmitt , Wolfgang Klesse , Volker Kerscher , Patrik Hartmann
IPC分类号： C08F222/10 , C08G18/38 , C08G18/73 , C08G18/81 , C08K3/00
CPC分类号： C08G18/8175 , C08F222/1006 , C08G18/3876 , C08G18/73
摘要： The present invention relates to mixtures containing A) compounds of the formula (I) and (II) where R1 is independently at each instance hydrogen or a methyl radical, R2 is independently at each instance a linear or branched, aliphatic or cycloaliphatic radical or a substituted or unsubstituted aromatic or heteroaromatic radical and m and n are each independently an integer of not less than 0 subject to the proviso that m+n>0, and B) at least one ethylenically unsaturated monomer (A) which is different from the compounds of the formula (I) and (II). The present invention further relates to processes for polymerizing these mixtures, the highly transparent polymers thus obtainable and to their use.
摘要翻译：本发明涉及含有A）式（I）和（II）化合物的混合物，其中R 1各自独立地为氢或甲基，R 2，在每种情况下独立地为直链或支链的脂族或脂环族基团或取代或未取代的芳族或杂芳族基团，m和n各自独立地为不小于0的整数，条件是m + n> 0，B ）与式（I）和（II）的化合物不同的至少一种烯属不饱和单体（A）。本发明还涉及使这些混合物聚合的方法，由此获得的高度透明的聚合物及其用途。

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