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1. 发明申请

US20090318645A1 METHOD FOR THE PRODUCTION OF OXETANE GROUP-CONTAINING (METH)ACRYLATES 审中-公开
标题翻译：含甲基丙烯酸（甲基）丙烯酸酯的制备方法
公开(公告)号：US20090318645A1
公开(公告)日：2009-12-24
申请号：US12375418
申请日：2007-06-14
申请人： Bardo Schmitt , Joachim Knebel , Silvia Beyer
发明人： Bardo Schmitt , Joachim Knebel , Silvia Beyer
IPC分类号： C08F4/72 , C08F120/18
CPC分类号： C07D305/06
摘要： The invention relates to a process for preparing oxetane-containing (meth)acrylates.
摘要翻译：本发明涉及一种制备含氧杂环丁烷（甲基）丙烯酸酯的方法。

2. 发明申请

US20110313195A1 METHOD FOR CONTINUOUSLY PRODUCING ALKYLAMINO(METH)ACRYLAMIDES 失效
标题翻译：连续生产烷基胺（甲基）丙烯酰胺的方法
公开(公告)号：US20110313195A1
公开(公告)日：2011-12-22
申请号：US13254280
申请日：2010-03-03
申请人： Bardo Schmitt , Wolfgang Klesse , Martina Ebert , Dirk Broell , Guido Protzmann , Joachim Knebel , Thomas Kehr , Hans-Gerhard Stadler , Gerhard Koelbl , Benedikt Laux
发明人： Bardo Schmitt , Wolfgang Klesse , Martina Ebert , Dirk Broell , Guido Protzmann , Joachim Knebel , Thomas Kehr , Hans-Gerhard Stadler , Gerhard Koelbl , Benedikt Laux
IPC分类号： C07C231/02
CPC分类号： C07C231/02 , Y02P20/582 , Y02P20/584 , C07C233/38
摘要： The invention relates to a process for continuously preparing N-alkyl(meth)acrylamides by reacting alkyl (meth)acrylates with high-boiling amines. A catalyst activation and specific workup technique achieve product qualities which have not been achieved to date. In addition, very high space-time yields and overall yields can be achieved.
摘要翻译：本发明涉及通过使（甲基）丙烯酸烷基酯与高沸点胺反应来连续制备（甲基）丙烯酰胺的N-烷基酯的方法。催化剂激活和具体的后处理技术实现迄今尚未实现的产品质量。此外，可以实现非常高的时空产量和总产量。

3. 发明申请

US20080300373A1 Method of Purifying (Meth) Acrylates 失效
标题翻译：纯化（甲基）丙烯酸酯的方法
公开(公告)号：US20080300373A1
公开(公告)日：2008-12-04
申请号：US12093744
申请日：2006-10-11
申请人： Bardo Schmitt , Joachim Knebel , Guenther Graeff
发明人： Bardo Schmitt , Joachim Knebel , Guenther Graeff
IPC分类号： C08F4/32 , B01D3/34
CPC分类号： C07C67/54 , C07C69/54
摘要： The invention relates to a process for purifying (meth)acrylates.
摘要翻译：本发明涉及纯化（甲基）丙烯酸酯的方法。

4. 发明授权

US07071351B2 Synthesis of alkylaminoalkyl (meth)acrylate by transesterification 失效
标题翻译：通过酯交换合成（甲基）丙烯酸烷基氨基烷基酯
公开(公告)号：US07071351B2
公开(公告)日：2006-07-04
申请号：US10486351
申请日：2002-08-16
申请人： Bardo Schmitt , Joachim Knebel , Maik Caspari
发明人： Bardo Schmitt , Joachim Knebel , Maik Caspari
IPC分类号： C07C67/03
CPC分类号： C07C213/06 , C07C219/08
摘要： The invention relates to a method for transesterifying methyl methacrylate involving catalysis, particularly zirconium acetylacetonate catalysis. The obtained esters of formula (I) are characterized by having an extremely low content of cross-linking agents.
摘要翻译：本发明涉及甲基丙烯酸甲酯涉及催化，特别是乙酰丙酮酸锆催化的酯交换方法。得到的式（I）酯的特征在于具有极低的交联剂含量。

5. 发明申请

US20050154161A1 Method for producing highly transparent plastics for optical materials 审中-公开
标题翻译：用于制造光学材料的高透明塑料的方法
公开(公告)号：US20050154161A1
公开(公告)日：2005-07-14
申请号：US10509328
申请日：2003-06-13
申请人： Bardo Schmitt , Joachim Knebel , Patrik Hartmann
发明人： Bardo Schmitt , Joachim Knebel , Patrik Hartmann
IPC分类号： G02B1/04 , C07C327/22 , C08F22/10 , C08F220/38 , C08F2/00
CPC分类号： C08F22/105
摘要： The present invention relates to a process for preparing a highly transparent plastic obtainable by free-radical copolymerization of a mixture containing compounds of the formula (I) and (II) where R1 is independently at each instance hydrogen or a methyl radical, R2 is independently at each instance a linear or branched, aliphatic or cycloaliphatic radical or a substituted or unsubstituted aromatic or heteroaromatic radical and m and n are each independently an integer of not less than 0 subject to the proviso that m+n>0, which is characterized in that it is obtainable from a mixture which contains more than 10 mol %, based on the total amount of the compounds of the formula (I) and (II), of compounds of the formula (II) where m+n=2. The present invention also relates to the mixture of the compounds (I) and (II), to processes for preparing the mixture and to particular uses for the highly transparent plastics.
摘要翻译：本发明涉及制备通过含有式（I）和（II）化合物的混合物的自由基共聚获得的高透明塑料的方法，其中R 1各自独立地为氢或甲基，R 2在每种情况下独立地为直链或支链的脂族或脂环族基团或取代或未取代的芳族或杂芳族基团，m和n各自独立地为不小于 0，条件是m + n> 0，其特征在于，其可以从基于式（I）和（II）的化合物的总量的含量大于10摩尔％的混合物获得，其中m + n = 2的式（II）化合物。本发明还涉及化合物（I）和（II）的混合物，用于制备混合物的方法和用于高透明塑料的具体用途。

6. 发明授权

US07790908B2 Process for preparing glyceryl carbonate 失效
标题翻译：制备碳酸甘油酯的方法
公开(公告)号：US07790908B2
公开(公告)日：2010-09-07
申请号：US12088093
申请日：2006-10-11
申请人： Bardo Schmitt , Joachim Knebel , Maik Caspari
发明人： Bardo Schmitt , Joachim Knebel , Maik Caspari
IPC分类号： C07D317/34
CPC分类号： C07D317/36
摘要： The present invention relates to a process for preparing highly pure glyceryl carbonate by transesterifying dialkyl carbonates or cyclic carbonates in the presence of a basic catalyst.
摘要翻译：本发明涉及通过在碱性催化剂存在下将碳酸二烷基酯或环状碳酸酯进行酯交换制备高纯度碳酸甘油酯的方法。

7. 发明申请

US20100185009A1 METHOD FOR SYNTHESIZING ALLYL METHACRYLATE 有权
标题翻译：用于合成甲基丙烯酸甲酯的方法
公开(公告)号：US20100185009A1
公开(公告)日：2010-07-22
申请号：US12667604
申请日：2008-05-08
申请人： Bardo Schmitt , Guido Protzmann , Thorben Schuetz , Harald Trauthwein , Reinhold Martin , Joachim Knebel , Ingo Sander , Klaus Gottmann , Thomas Kehr , Dieter Bathen , Christian Maul
发明人： Bardo Schmitt , Guido Protzmann , Thorben Schuetz , Harald Trauthwein , Reinhold Martin , Joachim Knebel , Ingo Sander , Klaus Gottmann , Thomas Kehr , Dieter Bathen , Christian Maul
IPC分类号： C07C69/52
CPC分类号： C07C67/03 , C07C69/54
摘要： The present invention relates to a process for preparing allyl methacrylate, comprising the reaction of allyl alcohol with an ester of methacrylic acid, wherein the reaction is catalysed by zirconium acetylacetonate. The process according to the invention enables particularly favourable preparation of allyl methacrylate with a very high purity.
摘要翻译：本发明涉及一种制备甲基丙烯酸烯丙酯的方法，其包括烯丙醇与甲基丙烯酸的酯的反应，其中该反应由乙酰丙酮锆催化。根据本发明的方法能够特别有利地制备具有非常高纯度的甲基丙烯酸烯丙酯。

8. 发明申请

US20080139771A1 Thio(Meth)Acrylates, Mixtures For Producing Transparent Plastics, Transparent Plastics And Method For Their Production And Use 审中-公开
标题翻译：硫代（甲基）丙烯酸酯，透明塑料混合物，透明塑料及其生产和使用方法
公开(公告)号：US20080139771A1
公开(公告)日：2008-06-12
申请号：US11813216
申请日：2005-12-03
申请人： Bardo Schmitt , Joachim Knebel , Patrik Hartmann
发明人： Bardo Schmitt , Joachim Knebel , Patrik Hartmann
IPC分类号： C08F28/04
CPC分类号： C07C327/22 , C08F222/1006 , C08F222/24 , C08K5/38 , C08L33/04 , C08L33/14 , C08L41/00 , G02B1/04 , C08L2666/04
摘要： The present invention relates to thio(meth)acrylates, obtainable via reaction of compounds of the formula (I) and (II) where each R1, independently of the others, is hydrogen or a methyl radical, each R2, independently of the others is a linear or branched, aliphatic or cycloaliphatic radical, or a substituted or unsubstituted aromatic or heteroaromatic radical, and each of m and n, independently of the others, is whole number greater than or equal to 0, where m+n>0, with thiol compounds which encompass at least two thiol groups.
摘要翻译：本发明涉及通过式（I）和（II）化合物的反应获得的硫代（甲基）丙烯酸酯，其中每个R 1独立地是氢或甲基，每个R 2独立地为直链或支链的脂族或脂环族基团，或取代或未取代的芳族或杂芳族基团，m和n各自独立地为全部大于或等于0，其中m + n> 0，其中硫醇化合物包含至少两个硫醇基团。

9. 发明授权

US07002035B2 Color stabilization of base-stabilized ethylenically modified unsaturated monomers 失效
标题翻译：碱稳定的烯属改性不饱和单体的稳定性
公开(公告)号：US07002035B2
公开(公告)日：2006-02-21
申请号：US10482278
申请日：2002-05-16
申请人： Bardo Schmitt , Joachim Knebel , Marianne Omeis
发明人： Bardo Schmitt , Joachim Knebel , Marianne Omeis
IPC分类号： C07C69/00 , C07C69/52 , C07C69/66
CPC分类号： C07C67/62 , C07C69/54
摘要： The invention relates to the use of at least one compound from the tocopherol group for the color stabilization of ethylenically unsaturated monomers, particularly hydroxyalkyl(meth)acrylates, which already comprise at least one polymerization inhibitor for base stabilization or storage stabilization. Such color-stabilized and polymerization-inhibited monomers are preferably used in clearcoat and high solid paints.
摘要翻译：本发明涉及至少一种来自生育酚基团的化合物用于烯属不饱和单体，特别是羟基烷基（甲基）丙烯酸酯的颜色稳定化的用途，其已包含至少一种用于碱稳定化或储存稳定化的阻聚剂。这种着色稳定和聚合抑制单体优选用于透明涂层和高固体涂料中。

10. 发明授权

US07521578B2 Process for the preparation of (meth)acrylates of tetra- or polyhydric alcohols 失效
标题翻译：制备四元醇或多元醇的（甲基）丙烯酸酯的方法
公开(公告)号：US07521578B2
公开(公告)日：2009-04-21
申请号：US11995406
申请日：2006-08-16
申请人： Bardo Schmitt , Joachim Knebel , Guenther Graeff
发明人： Bardo Schmitt , Joachim Knebel , Guenther Graeff
IPC分类号： C07C67/30
CPC分类号： C07C67/03 , C07C69/54
摘要： Process for the preparation of acrylic and methacrylic acid esters by transesterification of (meth)acrylic acid esters of the formula I: where R1 is H or CH3 and R2 is an alkyl radical having 1 to 40 carbon atoms, with alkanols which have four or more esterifiable hydroxyl groups, characterized in that 0.01 to 10% by weight, based on the total reaction mixture, of lithium amide catalysts are used as transesterification catalyst.
摘要翻译：通过式（I）的（甲基）丙烯酸酯的酯交换反应制备丙烯酸和甲基丙烯酸酯的方法：其中R 1是H或CH 3，R 2是具有1至40个碳原子的烷基，其中烷基醇具有四个或更多个酯化羟基，其特征在于使用基于总反应混合物的0.01至10重量％的氨基化锂催化剂作为酯交换催化剂。

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