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    • 1. 发明专利
    • Catalyst for production of hydrogen
    • 催化剂生产氢
    • JP2005262070A
    • 2005-09-29
    • JP2004077603
    • 2004-03-18
    • Babcock Hitachi KkHitachi Ltdバブコック日立株式会社株式会社日立製作所
    • YOSHII YASUOYOSHIDA NORIKONAGAYAMA KOUSEIYATABE HIROSHIMIYATA TERUFUMI
    • B01J23/76B01J21/04B01J32/00C01B3/40
    • Y02P20/52
    • PROBLEM TO BE SOLVED: To improve the initial performance and durability of the catalyst in a PEFC fuel cell system equipped with a hydrogen production apparatus by optimizing the amount of an Ni ingredient and that of rare earth elements carried by an inorganic oxide support. SOLUTION: The catalyst contains Ni element and at least one rare earth ingredient, carried in an inorganic oxide support. The Ni to rare earth atomic mole ratio is 0.05-0.3, and the ratio of the mole of rare earth atoms to that of molecules in the oxide support is 0.015-0.07. Preferably, the content of the Ni ingredient is 5-50 wt.%, based on the content of the metal oxide, and that of rare earth ingredients is 1-25 wt.%, based on the metal oxides. The catalyst is available in fuel cell systems equipped with a fuel-modifying device having a catalyst for hydrogen production, e.g. domestic and business PEFC systems, permits reduction of the starting time and can maintain a high performance over a long period. COPYRIGHT: (C)2005,JPO&NCIPI
    • 要解决的问题:通过优化Ni成分的量和由无机氧化物载体承载的稀土元素的量,来提高配备有氢制造装置的PEFC燃料电池系统中的催化剂的初始性能和耐久性 。 解决方案:催化剂含有Ni元素和至少一种稀土成分,载于无机氧化物载体中。 Ni与稀土原子摩尔比为0.05-0.3,稀土元素的摩尔数与氧化物载体中的分子的摩尔比为0.015-0.07。 优选地,基于金属氧化物的含量,Ni成分的含量为5-50重量%,稀土成分的含量为基于金属氧化物的1-25重量%。 催化剂可用于配备有具有用于制氢的催化剂的燃料改性装置的燃料电池系统,例如, 国内和国际PEFC系统,允许减少启动时间,并能长期保持高性能。 版权所有(C)2005,JPO&NCIPI