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1. 发明申请

WO2002096836A2 FISCHER-TROPSCH PROCESS 审中-公开
标题翻译： FISCHER-TROPSCH过程
公开(公告)号：WO2002096836A2
公开(公告)日：2002-12-05
申请号：PCT/GB2002/002321
申请日：2002-05-17
申请人： BP EXPLORATION OPERATING COMPANY LIMITED , DAVY PROCESS TECHNOLOGY LIMITED , HUFF, George, Albert , NAY, Barry
发明人： HUFF, George, Albert , NAY, Barry
IPC分类号： C07C1/00
CPC分类号： C10G2/331 , C10G2/342
摘要： A process for converting synthesis gas to higher hydrocarbons, at an elevated temperature and pressure, comprising continuously introducing a synthesis gas feed stream comprising 0.1 to 50 % by volume of carbon dioxide into a continuous stirred reactor system comprising a reactor vessel containing a suspension of a solid particulate Fischer-Tropsch catalyst suspended in a liquid medium wherein the solid particulate Fischer-Tropsch catalyst is stable in the presence of carbon dioxide.
摘要翻译：一种在高温和高压下将合成气转化为高级烃的方法，包括将包含0.1至50体积％二氧化碳的合成气进料流连续引入连续搅拌的反应器系统中，该反应器系统包含含有悬浮液悬浮在液体介质中的固体微量费 - 托催化剂，其中固体颗粒费 - 托催化剂在二氧化碳存在下是稳定的。

2. 发明申请

WO2002097010A2 FISCHER-TROPSCH PROCESS 审中-公开
标题翻译： FISCHER-TROPSCH过程
公开(公告)号：WO2002097010A2
公开(公告)日：2002-12-05
申请号：PCT/GB2002/002326
申请日：2002-05-17
申请人： BP EXPLORATION OPERATING COMPANY LIMITED , DAVY PROCESS TECHNOLOGY LIMITED , NAY, Barry , SHARP, Christopher
发明人： NAY, Barry , SHARP, Christopher
IPC分类号： C10G2/00
CPC分类号： C10G2/342
摘要： A process for the conversion of synthesis gas to hydrocarbons, at least a portion of which are liquid at ambient temperature and pressure, by contacting the synthesis gas at an elevated temperature and pressure with a suspension comprising a solid particulate Fischer-Tropsch catalyst suspended in a liquid medium, which contacting takes place in a reactor system comprising at least one high shear mixing zone and a reactor vessel wherein the volume of suspension present in the high shear mixing zone(s) is substantially less than the volume of suspension present in the reactor vessel, which process comprises: mixing the suspension with synthesis gas in the high shear mixing zone(s) and dissipating kinetic energy to the suspension present in the high shear mixing zone(s) at a rate of at least 0.5kW/m 3 relative to the total volume of suspension present in the reactor system; discharging the resulting mixture of synthesis gas and suspension from the high shear mixing zone(s) into the reactor vessel; withdrawing suspension from the reactor vessel and, at least in part, recycling the suspension to the high shear mixing zone(s); wherein the suspension which is recycled to the high shear mixing zone(s) is cooled to a temperature which is not more than 100°C below the temperature of the suspension in the reactor vessel with the proviso that the temperature of the cooled suspension is at least 150°C.
摘要翻译：一种将合成气转化为烃的方法，其中至少一部分在环境温度和压力下为液态，通过使合成气在升高的温度和压力下与悬浮在一种固体颗粒状费托催化剂中的悬浮液液体介质，其在包括至少一个高剪切混合区和反应器容器的反应器系统中进行，其中存在于高剪切混合区中的悬浮体的体积基本上小于存在于反应器中的悬浮液的体积容器，该方法包括：将混合物与合成气混合在高剪切混合区中，并以至少0.5kW / m 3的速率向存在于高剪切混合区域中的悬浮液释放动能 >相对于存在于反应器系统中的悬浮体的总体积; 将所得的合成气和悬浮液的混合物从高剪切混合区排出到反应器容器中; 从反应器容器中取出悬浮液，并且至少部分地将悬浮液再循环到高剪切混合区域; 其中循环到高剪切混合区的悬浮液被冷却到低于反应器容器中悬浮液温度不超过100℃的温度，条件是冷却的悬浮液的温度在至少150℃

3. 发明申请

WO2002097011A2 FISCHER-TROPSCH PROCESS 审中-公开
标题翻译： FISCHER-TROPSCH过程
公开(公告)号：WO2002097011A2
公开(公告)日：2002-12-05
申请号：PCT/GB2002/002328
申请日：2002-05-17
申请人： BP EXPLORATION OPERATING COMPANY LIMITED , DAVY PROCESS TECHNOLOGY LIMITED , FONT FREIDE, Josephus, Johannes, Helena, Maria , NAY, Barry , SHARP, Christopher
发明人： FONT FREIDE, Josephus, Johannes, Helena, Maria , NAY, Barry , SHARP, Christopher
IPC分类号： C10G2/00
CPC分类号： C10G2/332 , C10G2/342
摘要： A process which comprises contacting a gaseous reactant stream comprising synthesis gas at elevated temperature and pressure with a suspension of a particulate Fischer-Tropsch catalyst comprising cobalt in a liquid medium in a reactor system comprising at least one high shear mixing zone and a reactor vessel wherein the process comprises the steps of: a) contacting the particulate Fischer-Tropsch catalyst with a reducing gas at elevated temperature and pressure outside of the high shear mixing zone(s) and the reactor vessel and subsequently suspending the particulate Fischer-Tropsch catalyst in the liquid medium; b) passing the suspension from step a) through the high shear mixing zone(s) where the gaseous reactant stream comprising synthesis gas is mixed with the suspension; c) discharging a mixture comprising the synthesis gas and the suspension from the high shear mixing zone(s) into the reactor vessel; and d) converting the synthesis gas to liquid hydrocarbons in the reactor vessel to form a product suspension comprising the particulate Fischer-Tropsch catalyst suspended in the liquid medium and liquid hydrocarbons.
摘要翻译：一种方法，其包括使包含合成气体的气态反应物流在升高的温度和压力下与包含钴的微粒费 - 托催化剂的悬浮液在包含至少一个高剪切混合区和反应器容器的反应器系统中的液体介质中接触，该方法包括以下步骤：a）在高剪切混合区和反应器容器外的升高的温度和压力下使微量费 - 托催化剂与还原气体接触，随后将颗粒状费 - 托催化剂悬浮在液体介质; b）将来自步骤a）的悬浮液通过高剪切混合区，其中包含合成气的气态反应物流与悬浮液混合; c）将包含合成气和悬浮液的混合物从高剪切混合区排出到反应器容器中; 和d）将合成气转化为反应器容器中的液体烃，以形成悬浮在液体介质中的包含微量费 - 托催化剂和液体烃的产物悬浮液。

4. 发明申请

WO2002096840A1 PROCESS FOR SEPARATING LIQUID HYDROCARBONS FROM A PARTICULATE FISCHER-TROPSCH CATALYST 审中-公开
标题翻译：从颗粒状载体催化剂中分离液体烃的方法
公开(公告)号：WO2002096840A1
公开(公告)日：2002-12-05
申请号：PCT/GB2002/002337
申请日：2002-05-17
申请人： BP EXPLORATION OPERATING COMPANY LIMITED , DAVY PROCESS TECHNOLOGY LIMITED , GAMLIN, Timothy, Douglas , GRAHAM, Carole , HENSMAN, John, Richard , NAY, Barry , NEWTON, David
发明人： GAMLIN, Timothy, Douglas , GRAHAM, Carole , HENSMAN, John, Richard , NAY, Barry , NEWTON, David
IPC分类号： C07C1/06
CPC分类号： C10G2/32 , B03C1/288 , B03C2201/18 , C10G31/09
摘要： A process for filtering a suspension comprising a particulate Fischer-Tropsch catalyst suspended in liquid hydrocarbons and having synthesis gas dispersed therein in the form of gas bubbles and/or irregularly shaped gas voids which process comprises passing the suspension through a filtration unit via a mechanical pumping means under turbulent flow conditions. The filtration unit may comprise a conventional filter element or a T-piece magnetic separator.
摘要翻译：一种用于过滤包含悬浮在液体烃中的微粒费 - 托催化剂并以气泡和/或不规则形状的气体空隙形式分散在其中的合成气的悬浮液的方法，该方法包括使悬浮液通过机械泵送过滤单元意味着在湍流条件下。过滤单元可以包括常规的过滤元件或T形磁选机。

5. 发明公开

EP1328607A2 FISCHER-TROPSCH SYNTHESIS PROCESS 审中-公开
标题翻译： FISCHER-TROPSCH SYNTHESEVERFAHREN
公开(公告)号：EP1328607A2
公开(公告)日：2003-07-23
申请号：EP01974463.0
申请日：2001-10-09
申请人： BP EXPLORATION OPERATING COMPANY LIMITED , Davy Process Technology Limited
发明人： FONT-FREIDE, Josephus, Johannes, Helena, Maria , FORTUNE, Stephen , NAY, Barry , NEWTON, David
IPC分类号： C10G2/00
CPC分类号： C10G2/342
摘要： A process for the conversion of synthesis gas to liquid hydrocarbon products comprising contacting, in a slurry reactor, synthesis gas at an elevated temperature and pressure with a suspension of catalyst in a liquid medium, introducing a low boiling solvent into the slurry reactor, vaporising at least a portion of the low boiling solvent in the slurry reactor, withdrawing from the slurry reactor, a gaseous stream comprising unreacted synthesis gas and vaporised low boiling solvent, cooling at least a portion of the gaseous stream to a temperature at which liquid condenses out so as to form a two phase mixture of gas and condensed liquid, and recycling at least a portion of the gas and at least a portion of the condensed liquid to the slurry reactor.

6. 发明公开

EP1392625A1 PROCESS FOR SEPARATING LIQUID HYDROCARBONS FROM A PARTICULATE FISCHER-TROPSCH CATALYST 有权
标题翻译：方法分离液体碳氢化合物微粒费 - 托催化剂
公开(公告)号：EP1392625A1
公开(公告)日：2004-03-03
申请号：EP02738322.3
申请日：2002-05-17
申请人： BP EXPLORATION OPERATING COMPANY LIMITED , Davy Process Technology Limited
发明人： GAMLIN, Timothy, Douglas , GRAHAM, Carole , HENSMAN, John Richard , NAY, Barry , NEWTON, David
IPC分类号： C07C1/06 , C07C1/04 , B01D35/06 , B03C5/02 , B03C1/023
CPC分类号： C10G2/32 , B03C1/288 , B03C2201/18 , C10G31/09
摘要： A process for filtering a suspension comprising a particulate Fischer-Tropsch catalyst suspended in liquid hydrocarbons and having synthesis gas dispersed therein in the form of gas bubbles and/or irregularly shaped gas voids which process comprises passing the suspension through a filtration unit via a mechanical pumping means under turbulent flow conditions. The filtration unit may comprise a conventional filter element or a T-piece magnetic separator.
摘要翻译：过程用于合成气转化为烃类，其包括在升高的温度和压力下接触的气态物流包含合成气，在与悬浮液，其包括具有在范围内的颗粒大小为5微米至500微米的颗粒的费 - 托催化剂，悬浮在在包括至少一个高剪切混合区和一个反应容器的系统的液体介质。将该悬浮液和气体物流通过高剪切混合区（一个或多个）worin气态流被分解成的气泡通过。分散在其中的悬浮液具有的气泡被从高剪切混合区（一个或多个）到反应容器中排出，并且悬浮液包含所述颗粒的费 - 托催化剂悬浮在液体介质和液态烃生成物从反应器容器中，并至少取出该悬浮液的一部分被经由外部管道在至少万米^{3 每小时悬浮液的流速循环到高剪切混合区（一个或多个）。从流过外部管道悬挂甲，取侧流，并直接传递到过滤单元。}

7. 发明授权

EP1392625B1 PROCESS FOR SEPARATING LIQUID HYDROCARBONS FROM A PARTICULATE FISCHER-TROPSCH CATALYST 有权
标题翻译：方法分离液体碳氢化合物微粒费 - 托催化剂
公开(公告)号：EP1392625B1
公开(公告)日：2010-05-05
申请号：EP02738322.3
申请日：2002-05-17
申请人： BP EXPLORATION OPERATING COMPANY LIMITED , Davy Process Technology Limited
发明人： GAMLIN, Timothy, Douglas , GRAHAM, Carole , HENSMAN, John Richard , NAY, Barry , NEWTON, David
IPC分类号： C07C1/06 , C07C1/04 , B01D35/06 , B03C5/02 , B03C1/023
CPC分类号： C10G2/32 , B03C1/288 , B03C2201/18 , C10G31/09

8. 发明公开

EP1392795A2 FISCHER-TROPSCH PROCESS 审中-公开
标题翻译： FISCHER-TROPSCH过程
公开(公告)号：EP1392795A2
公开(公告)日：2004-03-03
申请号：EP02730430.2
申请日：2002-05-17
申请人： BP EXPLORATION OPERATING COMPANY LIMITED , Davy Process Technology Limited
发明人： NAY, Barry , SHARP, Christopher
IPC分类号： C10G2/00
CPC分类号： C10G2/342
摘要： A process for the conversion of synthesis gas to hydrocarbons, at least a portion of which are liquid at ambient temperature and pressure, by contacting the synthesis gas at an elevated temperature and pressure with a suspension comprising a solid particulate Fischer-Tropsch catalyst suspended in a liquid medium, which contacting takes place in a reactor system comprising at least one high shear mixing zone and a reactor vessel wherein the volume of suspension present in the high shear mixing zone(s) is substantially less than the volume of suspension present in the reactor vessel, which process comprises: mixing the suspension with synthesis gas in the high shear mixing zone(s) and dissipating kinetic energy to the suspension present in the high shear mixing zone(s) at a rate of at least 0.5kW/m3 relative to the total volume of suspension present in the reactor system; discharging the resulting mixture of synthesis gas and suspension from the high shear mixing zone(s) into the reactor vessel; withdrawing suspension from the reactor vessel and, at least in part, recycling the suspension to the high shear mixing zone(s); wherein the suspension which is recycled to the high shear mixing zone(s) is cooled to a temperature which is not more than 100°C below the temperature of the suspension in the reactor vessel with the proviso that the temperature of the cooled suspension is at least 150°C.
摘要翻译：通过使合成气在升高的温度和压力下与包含固体颗粒费 - 托催化剂的悬浮液接触将合成气转化成烃的方法，所述烃的至少一部分在环境温度和压力下为液体，所述悬浮液包含悬浮于所述液体介质发生在包含至少一个高剪切混合区和反应器容器的反应器系统中，其中存在于所述高剪切混合区中的悬浮液的体积显着小于反应器中存在的悬浮液的体积该方法包括：将悬浮液与合成气在高剪切混合区中混合，并将动能以相对于高剪切混合区中存在的悬浮液以至少0.5kW / m 3的速率消散存在于反应器系统中的总悬浮体积; 将所得到的合成气和悬浮液的混合物从高剪切混合区排出到反应器容器中; 从反应器容器中取出悬浮液，并且至少部分地将悬浮液再循环至高剪切混合区; 其中再循环至高剪切混合区的悬浮液冷却至低于反应器容器中悬浮液温度100℃的温度，条件是冷却悬浮液的温度为至少150°C。

9. 发明公开

EP1390325A2 FISCHER-TROPSCH PROCESS 审中-公开
标题翻译： FISCHER-TROPSCH过程
公开(公告)号：EP1390325A2
公开(公告)日：2004-02-25
申请号：EP02738318.1
申请日：2002-05-17
申请人： BP EXPLORATION OPERATING COMPANY LIMITED , Davy Process Technology Limited
发明人： HUFF, George, Albert , NAY, Barry
IPC分类号： C07C1/00
CPC分类号： C10G2/331 , C10G2/342
摘要： A process for converting synthesis gas to higher hydrocarbons, at an elevated temperature and pressure, comprising continuously introducing a synthesis gas feed stream comprising 0.1 to 50 % by volume of carbon dioxide into a continuous stirred reactor system comprising a reactor vessel containing a suspension of a solid particulate Fischer-Tropsch catalyst suspended in a liquid medium wherein the solid particulate Fischer-Tropsch catalyst is stable in the presence of carbon dioxide.
摘要翻译：在升高的温度和压力下将合成气转化成高级烃的方法，包括将包含0.1-50体积％二氧化碳的合成气进料流连续地引入到连续搅拌的反应器系统中，该反应器系统包括含有悬浮在液体介质中的固体颗粒费 - 托催化剂，其中固体颗粒费 - 托催化剂在二氧化碳存在下是稳定的。

10. 发明授权

EP1232132B1 PROCESS FOR CONVERTING SYNTHESIS GAS INTO HIGHER HYDROCARBONS 有权
标题翻译：程序合成气的更高级烃实施
公开(公告)号：EP1232132B1
公开(公告)日：2004-12-29
申请号：EP00977686.5
申请日：2000-11-22
申请人： BP EXPLORATION OPERATING COMPANY LIMITED
发明人： KETLEY, Graham Walter , NAY, Barry , NEWTON, David
IPC分类号： C07C1/06 , B01J19/26
CPC分类号： B01J8/1818 , B01J8/228 , B01J19/26 , B01J2208/00256 , B01J2208/00274 , B01J2208/003 , B01J2208/0053 , C07C1/0455 , C07C1/066 , Y02P20/582
摘要： A process for the conversion of synthesis gas into higher hydrocarbon products in a system comprising a high shear mixing zone and a post mixing zone wherein the process comprises: a) passing a suspension of catalyst in a liquid medium through the high shear mixing zone where the suspension is mixed with synthesis gas; b) discharging a mixture of synthesis gas and suspension from the high shear mixing zone into the post mixing zone; c) converting at least a portion of the synthesis gas to higher hydrocarbons in the post mixing zone to form a product suspension comprising catalyst suspended in the liquid medium and the higher hydrocarbons; d) separating a gaseous stream comprising uncoverted synthesis gas from the product suspension; e) recycling the separated gaseous stream to the high shear mixing zone; and f) recycling at least a portion of the product suspension to the high shear mixing zone.

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