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    • 5. 发明申请
    • PROCESS FOR OXYGENATION OF COMPONENTS FOR REFINERY BLENDING OF TRANSPORTATION FUELS
    • 氧化运输燃料精炼混合组分的方法
    • WO02097006A3
    • 2003-10-16
    • PCT/US0201158
    • 2002-01-16
    • BP CORP NORTH AMERICA INC
    • HAGEN GARY PHUFF GEORGE A JRGONG WILLIAM HREGALBUTO MONICA CRISTINA
    • B01J23/26B01J23/652B01J23/88C10G27/04C10G27/12C10G53/14C10G67/12C10G67/14
    • C10G27/04C10G27/12C10G53/14C10G67/12
    • Economical processes are disclosed for production of components for refinery blending of transportation fuels which are liquid at ambient conditions by selective oxygenation of refinery feedstocks comprising a mixture of organic compounds. The organic compounds are oxygenated in a liquid reaction medium with an oxidizing agent and heterogenous oxygenation catalyst system which exhibits a capability to enhance the incorporation of oxygen into a mixture of liquid organic compounds to form a mixture comprising hydrocarbons, oxygenated organic compounds, water of reaction, and acidic co-products. The mixture is separated to recover at least a first organic liquid of low density and at least a portion of the catalyst metal, water of reaction and acidic co-products. Advantageously, the organic liquid is washed with an aqueous solution of sodium bicarbonate solution, or other soluble chemical base capable to neutralize and/or remove acidic co-products of oxidation, and recover oxygenated product.
    • 公开了经济方法,用于生产用于在环境条件下通过选择性氧化含有有机化合物的混合物的炼油原料的运输燃料的炼油厂混合的组分。 有机化合物在具有氧化剂和异质氧化催化剂体系的液体反应介质中进行氧化,其表现出增强氧气进入液体有机化合物的混合物以形成包含烃,含氧有机化合物,反应水的混合物的能力 ,和酸性副产物。 分离混合物以回收至少第一低密度有机液体和至少一部分催化剂金属,反应水和酸性副产物。 有利地,有机液体用碳酸氢钠溶液的水溶液或能够中和和/或除去酸性氧化副产物的其它可溶性化学碱洗涤,并回收氧合产物。
    • 6. 发明申请
    • PREPARATION OF COMPONENTS FOR TRANSPORTATION FUELS
    • 运输燃料组分的准备
    • WO02062927A3
    • 2002-11-14
    • PCT/US0201439
    • 2002-01-17
    • BP CORP NORTH AMERICA INC
    • MORRIS GEORGE ELUCY ANDREW RGONG WILLIAM HREGALBUTO MONICA CRISTINAHUFF GEORGE A JR
    • C10G67/12C10G27/12
    • C10G67/12
    • Economical processes are disclosed for the production of component for refinery blending of transportation fuels by selective oxidation of feedstocks comprising a mixture of hydrocarbons, sulfur-containing and nitrogen-containing organic compounds. Oxidation feedstock is contacted with a soluble quaternary ammonium salt containing halogen, suflate, or bisulfate anion, and an immiscible aqueous phase comprising a source of hydrogen peroxide, and at least one member of the group consisting of phosphomolybdic acid and phosphotungstic acid, in a liquid reaction mixture under conditions suitable for reaction of one or more of the sulfur-containing and/or nitrogen-containing organic compounds. Blending components containing less sulfur and/or less nitrogen than the oxidation feedstock are recovered from the reaction mixture. Advantageously, at least a portion of the immiscible acid-containing phase is recycled to the oxidation.
    • 公开了用于通过选择性氧化包含烃,含硫和含氮有机化合物的混合物的原料来生产用于炼油厂混合运输燃料的组件的经济过程。 氧化原料与含有卤素,磺酸盐或硫酸氢根阴离子的可溶性季铵盐和含有过氧化氢源的不混溶性水相以及磷钼酸和磷钨酸中的至少一员在液体中接触 反应混合物在适合于一种或多种含硫和/或含氮有机化合物的反应的条件下反应。 从反应混合物中回收含有比氧化原料少的硫和/或少于氮的组分。 有利地,至少一部分不混溶的含酸相被循环至氧化。