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    • 2. 发明申请
    • IMPROVING CUMENE OXIDATION
    • 改善阳离子氧化
    • WO2010069586A1
    • 2010-06-24
    • PCT/EP2009/009122
    • 2009-12-17
    • BOREALIS AGPUROLA, Veli-MattiMANNERLA, Anja
    • PUROLA, Veli-MattiMANNERLA, Anja
    • C07C409/10C07C407/00
    • C07C409/10C07C407/00C07C407/003
    • A process for oxidizing cumene to cumene hydroperoxide using an oxygen containing gas, which process composes - conducting a cumene feed and an oxygen containing gas feed to at least the first oxidation reactor in a series of 3-8 reactors, thereby forming an oxidation mixture, and - conducting the oxidation mixture from one oxidation reactor to at least one subsequent reactor, wherein - the reactors are operated with reducing liquid levels; - the oxidation is operated as a dry oxidation, whereby the only gaseous feeds conducted to the oxidation reactors are the cumene feed and the oxygen containing gas feed; - the oxygen containing gas feed is washed with caustic and then with water to remove all acidic or caustic traces before conducting it into an oxidation reactor; - the pressure within each oxidation reactor is in the range of 0-10 barg; - the off-gases from the top section of each oxidation reactor are separated and cooled, whereby a condensate containing unreacted cumene is formed, and - washing the condensate and recycling at least a part of it to at least the first oxidation reactor; - the non-condensed off-gases are treated in a thermal oxidizer; and - the first reactor in the series of oxidation reactors has a liquid inventory of 30- 300% larger than in the remaining reactors, preferably 50-100%, or the first two reactors in the series of oxidation reactors have a liquid inventory of 30— 300% larger than in the remaining reactors, preferably 50—100%.
    • 使用含氧气体将异丙基苯氧化为氢过氧化枯烯的方法,该方法构成 - 在一系列3-8反应器中至少将第一氧化反应器进行枯烯进料和含氧气体进料,从而形成氧化混合物, 以及 - 将氧化混合物从一个氧化反应器导入至少一个随后的反应器,其中 - 所述反应器以降低的液面进行操作; - 氧化作为干氧化操作,由此仅向氧化反应器输送的气态进料是枯烯进料和含氧气体进料; - 含氧气体进料用苛性碱洗涤,然后用水洗涤,以便在将其进入氧化反应器之前去除所有的酸性或碱性痕迹; - 每个氧化反应器内的压力在0-10巴的范围内; - 将每个氧化反应器的顶部的废气分离并冷却,由此形成含有未反应的枯烯的冷凝物, - 洗涤冷凝物并将其至少一部分再循环至至少第一氧化反应器; - 未冷凝的废气在热氧化器中处理; 并且 - 该系列氧化反应器中的第一反应器的液体存量比剩余的反应器中的液体存量大30-100%,优选为50-100%,或者该系列氧化反应器中的前两个反应器的液体存量为30 - 比剩余的反应器大300%,优选为50-100%。