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1. 发明申请

WO0170395A3 POLYMERIZATION CATALYSTS COMPRISING AN OPEN ETA-5 LIGAND 审中-公开
标题翻译：包含开放式ETA-5配体的聚合催化剂
公开(公告)号：WO0170395A3
公开(公告)日：2002-04-11
申请号：PCT/GB0101280
申请日：2001-03-22
申请人： BOREALIS TECH OY , ANDELL OVE , MAARANEN JANNE , KETOLA LASSE
发明人： ANDELL OVE , MAARANEN JANNE , KETOLA LASSE
IPC分类号： B01J31/18 , B01J31/22 , B01J31/38 , C07F7/00 , C07F7/28 , C07F17/00 , C08F4/54 , C08F4/659 , C08F10/00 , C08F110/02 , C08F210/16 , B01J31/14 , C07D213/06 , C07F5/06 , C08F4/60
CPC分类号： B01J31/1815 , B01J31/18 , B01J31/2282 , B01J31/2295 , B01J31/38 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C07F7/00 , C07F7/28 , C07F17/00 , C08F4/65908 , C08F10/00 , C08F110/02 , C08F210/16 , C08F4/659 , C08F4/64013 , C08F2500/07 , C08F2500/04
摘要： A procatalyst complex for the polymerisation of olefins comprising a group III element or a group 3 to 8 transition metal n-bonded by an open n -ligand at least two heteroatoms in the five atom n chain and having an unsaturated ring fused to the first and second atoms of the n chain and a further unsaturated ring fused to the fourth and fifth atoms of the n chain, i.e. (IV) where (a) is an optionally substituted 5 to 12 membered ring; each X independently is C, N, P, B or Si, at least two X's being heteroatoms; a is 0 or 1; R is a C1-16 hydrocarbyl, a tri C1-8 hydrocarbylsilyl or a tri C1-8 hydrocarbylsiloxy group or a group R R where R is a 1 to 4 atom bridge and R is a group capable of o-bonding or n-bonding a transition metal; q is 1, 2 or 3; M is a group III element or a group 3 to 8 transition metal; L is a n-ligand; r is zero, 1 or 2; Z is a o-ligand; and s is zero or a positive integer having a value of up to 3.
摘要翻译：用于烯烃聚合的前催化剂络合物，其包含III族元素或3至8族过渡金属，其通过在5个原子n5链中具有至少两个杂原子并且具有不饱和键环与n 5链的第一和第二个原子融合，另一个不饱和环与n 5链的第四和第五个原子稠合，即（IV），其中（a）是任选取代的5至12个元环每个X独立地是C，N，P，B或Si，至少两个X是杂原子; a是0或1; R是C1-16烃基，三C1-8烃基甲硅烷基或三C1-8烃基甲硅烷氧基或基团R a R b，其中R a是1至4个原子桥，R b，是能够使过渡金属O键合或n键合的基团; q为1,2或3; M是III族元素或3至8族过渡金属; L是n-配体; r为零，1或2; Z是O-配体; 并且s为零或具有高达3的值的正整数。

2. 发明申请

WO0050170A3 A NEW TRANSITION METAL COMPLEX, ITS PREPARATION AS WELL AS A CATALYST SYSTEM BASED THEREUPON AND ITS USE FOR THE POLYMERIZATION OF OLEFINS 审中-公开
标题翻译：一种全新的过渡金属络合物，其制备方法也是基于催化剂体系的基础及其用于烯烃聚合反应
公开(公告)号：WO0050170A3
公开(公告)日：2000-12-07
申请号：PCT/FI0000136
申请日：2000-02-22
申请人： BOREALIS AS , ANDELL OVE , MAARANEN JANNE , KETOLA LASSE
发明人： ANDELL OVE , MAARANEN JANNE , KETOLA LASSE
IPC分类号： B01J31/18 , C07F7/00 , C07F11/00 , C08F10/00 , C07D487/18 , C08F4/602
CPC分类号： B01J31/182 , B01J31/1805 , B01J2531/46 , B01J2531/48 , B01J2531/62 , B01J2531/842 , C07F7/006 , C07F11/005 , C08F10/00 , C08F110/02 , C08F210/16 , C08F4/64089 , C08F4/69224
摘要： The invention relates to new triaza transition metal complexes and their use as polymerization catalysts. They have the formula (1): LnMXm-n, wherein each L is independently a ligand which is multidentate by adjacent cooordinating atoms, M is the central atom which is a metal selected from Groups 4-8 of the Periodic Table of the Elements (IUPAC 1990), each X is independently a unidentate organic or halogen ligand, m is the coordination number or number of coordination sites on the central atom M, and n is the number of the ligands L which is an integer from 1 to m. At least one of the ligands L has formula (2), wherein each of R1-R6 is independently selected from hydrogen and organic groups having from 1 to 10 carbon atoms and the ligand L is coordinated to the central atom M by one to four of the three nitrogen atoms and/or the carbon atom of the ligand L according to formula (2).
摘要翻译：本发明涉及新的三氮杂过渡金属络合物及其作为聚合催化剂的用途。它们具有式（1）：LnMXm-n，其中每个L独立地是由相邻共配原子多齿的配体，M是选自元素周期表第4-8族的金属的中心原子（ IUPAC 1990），每个X独立地是单齿有机或卤素配体，m是中心原子M上的配位点的配位数或数目，n是1至m的整数的配体L的数目。配体L中的至少一个具有式（2），其中R 1 -R 6各自独立地选自氢和具有1至10个碳原子的有机基团，并且配体L与中心原子M配位1至4个根据式（2）的配体L的三个氮原子和/或碳原子。

3. 发明申请

WO0044795A8 A HIGH ACTIVITY OLEFIN POLYMERIZATION PROCATALYST, ITS PREPARATION, CATALYST SYSTEM AND USE 审中-公开
标题翻译：高活性烯烃聚合催化剂及其制备，催化体系和用途
公开(公告)号：WO0044795A8
公开(公告)日：2000-11-02
申请号：PCT/FI0000048
申请日：2000-01-25
申请人： BOREALIS POLYMERS OY , PALMQVIST ULF , JOHANSSON SOLVEIG , LINDGREN DANIEL , ANDELL OVE , LINDROOS JARMO
发明人： PALMQVIST ULF , JOHANSSON SOLVEIG , LINDGREN DANIEL , ANDELL OVE , LINDROOS JARMO
IPC分类号： C08F4/646 , C08F10/00 , C08F110/02 , C08F210/16
CPC分类号： C08F10/00 , C08F110/02 , C08F210/16 , C08F4/651 , C08F4/6576 , C08F4/025 , C08F4/6555 , C08F10/02 , C08F2/001 , C08F210/08 , C08F2500/12 , C08F2500/07 , C08F2500/04 , C08F2500/17
摘要： The invention relates to a high activity procatalyst for the polymerization of C2-C10 olefins, as well as a process for the preparation of this catalyst. The procatalyst has low hydrogen sensitivity and high polymerization activity and give homogenous C2-C10 olefin polymers. The procatalyst is prepared by contacting (a) an inorganic support, (b) an aluminium compound containing both an organic group and chlorine, (c) a compound or mixture containing hydrocarbyl and hydrocarbyl oxide linked to magnesium, (d) a titanium compound, typically a titanium chloride, and (e) a chlorine compound, which is either the same or different from the organic aluminum chloride compound.
摘要翻译：本发明涉及用于C2-C10烯烃聚合的高活性前催化剂，以及制备该催化剂的方法。主催化剂具有低氢敏感性和高聚合活性并且产生均匀的C2-C10烯烃聚合物。（a）无机载体，（b）含有有机基团和氯的铝化合物，（c）含有与镁连接的烃基和烃基氧化物的化合物或混合物，（d）钛化合物，通常是氯化钛，和（e）与有机氯化铝化合物相同或不同的氯化合物。

4. 发明申请

WO0034341A2 PROCESS 审中-公开
标题翻译：处理
公开(公告)号：WO0034341A2
公开(公告)日：2000-06-15
申请号：PCT/GB9904124
申请日：1999-12-07
申请人： BOREALIS AS , PEROXID CHEMIE GMBH , COCKBAIN JULIAN , ANDELL OVE , KALLIO KALLE , KNUUTTILA HILKKA
发明人： ANDELL OVE , KALLIO KALLE , KNUUTTILA HILKKA
IPC分类号： C08F4/64 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16
CPC分类号： C08F10/02 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F110/02 , C08F210/16 , Y10S526/943 , C08F4/65927 , C08F4/65925 , C08F2500/03 , C08F2500/18 , C08F210/14 , C08F2500/12
摘要： Olefin polymerisation may be catalysed by a wide range of catalytic materials. Described herein is a heterogeneous olefin polymerization catalyst comprising a porous particulate support material having impregnated therein a metallocene catalyst the metal atom whereof is bound to an amide group which is not bound to an eta -ligand of the metallocene, or the reaction product of a said metallocene catalyst and a co-catalyst.
摘要翻译：烯烃聚合可以由各种催化材料催化。本文描述的是一种非均相烯烃聚合催化剂，其包含多孔颗粒载体材料，其中浸渍有茂金属催化剂，其金属原子结合到不与金属茂的等离子体结合的酰胺基或所述茂金属催化剂的反应产物茂金属催化剂和助催化剂。

5. 发明申请

WO9525130A8 PROCESS FOR SELECTIVE HYDROGENATION OF UNSATURATED POLYMERS 审中-公开
标题翻译：选择性加氢不饱和聚合物的方法
公开(公告)号：WO9525130A8
公开(公告)日：2000-02-17
申请号：PCT/FI9500120
申请日：1995-03-03
申请人： NESTE OY , REKONEN PETRI , KOPOLA NINA , KOSKIMIES SALME , ANDELL OVE , MAEKELAE MARITA
发明人： REKONEN PETRI , KOPOLA NINA , KOSKIMIES SALME , ANDELL OVE , MAEKELAE MARITA
IPC分类号： C08C19/02 , C08F8/04
CPC分类号： C08C19/02 , C08F8/04
摘要： The invention relates to the selective hydrogenation of unsaturated polymers, in particular elastomeric polymers which contain aromatic rings and carbon-carbon double rings, for example polymers prepared from styrene and butadiene. In this case, the polymer molecule contains internal and terminal-group double bonds, as well as unsaturated bonds in aromatic rings. According to the invention, only the unsaturated terminal and internal bonds are hydrogenated, whereby the thermal and weather resistance properties of the product are improved. Conventionally, hydrogenation has been performed by means of nickel or cobalt catalysts, but now it has been observed that a metallocene/alumoxane catalyst complex not only catalyzes the polymerization reaction of various olefinic compounds but also catalyzes the selective hydrogenation of unsaturated polymers, preferably styrene-butadiene-styrene block polymers.
摘要翻译：本发明涉及不饱和聚合物的选择性氢化，特别是包含芳香环和碳 - 碳双环的弹性体聚合物，例如由苯乙烯和丁二烯制备的聚合物。在这种情况下，聚合物分子含有内部和末端基团双键以及芳环中的不饱和键。根据本发明，只有不饱和端和内键被氢化，从而提高了产品的耐热和耐候性。通常，通过镍或钴催化剂进行氢化，但现在观察到茂金属/铝氧烷催化剂络合物不仅催化各种烯烃化合物的聚合反应，而且还催化不饱和聚合物的选择性氢化，优选苯乙烯 - 丁二烯 - 苯乙烯嵌段聚合物。

6. 发明专利

DE69811512T2 未知
公开(公告)号：DE69811512T2
公开(公告)日：2003-11-13
申请号：DE69811512
申请日：1998-08-21
申请人： BOREALIS TECH OY
发明人： ANDELL OVE , MAARANEN JANNE
IPC分类号： C07D487/04 , C07F7/00 , C07F7/28 , C07F11/00 , C08F4/42 , C08F4/64 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/02 , C08F210/16
摘要： The invention relates to an organometallic compound comprising a central transition metal atom and a ligand coordinated thereto having a heteroatomic ring structure, characterized in that the ligand includes at least three nitrogen atoms, three of them being bonded to the same carbon atom.

7. 发明专利

DE69826130T2 未知
公开(公告)号：DE69826130T2
公开(公告)日：2005-09-22
申请号：DE69826130
申请日：1998-07-17
申请人： BOREALIS TECH OY
发明人： FOLLESTAD ARILD , HOKKANEN HARRI , KALLIO KALLE , ANDELL OVE , PALMQVIST ULF
IPC分类号： C08F2/38 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16

8. 发明专利

AT275586T 未知
公开(公告)号：AT275586T
公开(公告)日：2004-09-15
申请号：AT98935058
申请日：1998-07-17
申请人： BOREALIS TECH OY
发明人： FOLLESTAD ARILD , HOKKANEN HARRI , KALLIO KALLE , ANDELL OVE , PALMQVIST ULF
IPC分类号： C08F2/38 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16

9. 发明专利

DE602005013376D1 未知
公开(公告)号：DE602005013376D1
公开(公告)日：2009-04-30
申请号：DE602005013376
申请日：2005-08-09
申请人： BOREALIS TECH OY
发明人： ANDELL OVE , PENNINKANGAS ANTTI , GE SHAOZHONG , PAAVOLA SARI
IPC分类号： C07F7/08

10. 发明专利

DE60106277T2 未知
公开(公告)号：DE60106277T2
公开(公告)日：2005-02-24
申请号：DE60106277
申请日：2001-08-21
申请人： BOREALIS TECH OY
发明人： ANDELL OVE , MAARANEN JANNE , HOIKKA JOUNI , VANNE TIINA , RAUTIO SOILE
IPC分类号： C07F7/18 , C07F17/00 , C08F4/639 , C08F4/69 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/16
摘要： The invention describes ligands of formula (I), wherein LIG represents an eta -ligand substituted by a group R1 and a group (R'')m; X represents a 1 to 3 atom bridge; Y represents a nitrogen or phosphorus atom; Z represents a carbon, nitrogen or phosphorus atom.

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