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1. 发明申请

WO2012084961A1 BRIDGED METALLOCENE CATALYSTS 审中-公开
标题翻译： BRIDGED METALLOCENE催化剂
公开(公告)号：WO2012084961A1
公开(公告)日：2012-06-28
申请号：PCT/EP2011/073426
申请日：2011-12-20
申请人： BOREALIS AG , RESCONI, Luigi , CASTRO, Pascal , VOSKOBOYNIKOV, Alexander Z , IZMER, Vyatcheslav V , KONOVICH, Dmitry S
发明人： RESCONI, Luigi , CASTRO, Pascal , VOSKOBOYNIKOV, Alexander Z , IZMER, Vyatcheslav V , KONOVICH, Dmitry S
IPC分类号： C08F10/00 , C08F4/6592
CPC分类号： C08F4/76 , B01J31/2295 , B01J2231/122 , B01J2531/48 , B01J2531/49 , C07F17/00 , C08F4/52 , C08F4/65908 , C08F4/65927 , C08F10/00 , C08F110/06 , C08F210/06 , C08F4/65912 , C08F2500/03 , C08F2500/12 , C08F210/16
摘要： A solid, particulate catalyst comprising: (i) a complex of formula (I) wherein M is zirconium or hafnium; each X is a sigma ligand; L is a divalent bridge selected from -R '2 C-, -R' 2 C-CR' 2 -, -R' 2 Si-, -R' 2 Si-SiR' 2 -, -R' 2 Ge-, wherein each R' is independently a hydrogen atom, C1-C20-hydrocarbyl, tri(C1-C20-alkyl)silyl, C6-C20-aryl, C7-C20-arylalkyl or C7-C20-alkylaryl; each R 1 is a C4-C20 hydrocarbyl radical branched at the β-atom to the cyclopentadienyl ring, optionally containing one or more heteroatoms belonging to groups 14-16, or is a C3-C20 hydrocarbyl radical branched at the β-atom to the cyclopentadienyl ring where the β-atom is an Si-atom; each R 18 is a C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms belonging to groups 14-16; each R 4 is a hydrogen atom or a C 1-6 -hydrocarbyl radical; each W is a 5 or 6 membered aryl or heteroaryl ring wherein each atom of said ring is optionally substituted with at least one R 5 group; each R 5 is the same or different and is a C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms belonging to groups 14-16; and optionally two adjacent R 5 groups taken together can form a further mono or multicyclic ring condensed to W optionally substituted by one or two groups R 5 ; and each R 7 is a C1-C20 hydrocarbyl radical; and (ii) a cocatalyst, preferably comprising an organometallic compound of a Group 13 metal.
摘要翻译：一种固体颗粒催化剂，其包含：（i）式（I）的络合物，其中M为锆或铪; 每个X是σ配体; L是选自-R'2C-，-R'2C-CR'2-，-R'2Si-，-R'2Si-SiR'2-，-R'2Ge-的二价桥，其中每个R' 独立地为氢原子，C 1 -C 20烃基，三（C 1 -C 20烷基）甲硅烷基，C 6 -C 20 - 芳基，C 7 -C 20 - 芳基烷基或C 7 -C 20 - 烷基芳基; 每个R 1是在β原子处与环戊二烯基环支链的C 4 -C 20烃基，任选地含有一个或多个属于第14-16族的杂原子，或者是在β原子处支化至环戊二烯基的C 3 -C 20烃基其中β原子是Si原子; 每个R18是任选地含有一个或多个属于第14-16族的杂原子的C1-C20烃基; 每个R 4是氢原子或C 1-6烃基; 每个W是5或6元芳基或杂芳基环，其中所述环的每个原子任选被至少一个R 5基团取代; 每个R 5相同或不同，并且是任选地含有一个或多个属于第14-16族的杂原子的C 1 -C 20烃基; 并且任选地两个相邻的R5基团可以形成另外的一个或多个环稠合成可任选地被一个或两个基团R 5取代的W 1; 并且每个R 7是C 1 -C 20烃基; 和（ii）助催化剂，优选包含第13族金属的有机金属化合物。

2. 发明申请

WO2014096166A1 CATALYSTS 审中-公开
标题翻译：催化剂
公开(公告)号：WO2014096166A1
公开(公告)日：2014-06-26
申请号：PCT/EP2013/077339
申请日：2013-12-19
申请人： BOREALIS AG
发明人： RESCONI, Luigi , CASTRO, Pascal , VIRKKUNEN, Ville , IZMER, Vyatcheslav V , KONONOVICH, Dmitry S , KULYABIN, Pavel Sergeevich , VOSKOBOYNIKOV, Alexander Z
IPC分类号： C08F10/06 , C08F4/6592 , C07F17/00 , C07F7/08 , C08F4/02
CPC分类号： C08F110/06 , C07C1/326 , C07C2531/18 , C07F7/0818 , C07F17/00 , C08F4/65912 , C08F4/65927 , C08F10/06 , C08F4/02 , C08F2500/03 , C08F2500/12 , C08F2500/15 , C08F210/06 , C08F210/16
摘要： A catalyst comprising (i) an asymmetric complex of formula (I) wherein M is zirconium or hafnium; each X is a sigma ligand; L is a divalent bridge selected from -R' 2 C-, -R' 2 C-CR' 2 -, -R' 2 Si-, -R' 2 Si-SiR' 2 -, -R' 2 Ge-, wherein each R' is independently a hydrogen atom, Cl-C20-alkyl, tri(Cl- C20-alkyl)silyl, C6-C20-aryl, C7-C20-arylalkyl or C7-C20-alkylaryl; R 2 and R 2' are each independently linear C 1-10 hydrocarbyl; R 5 and R 5' are each independently hydrogen or a CI -20 hydrocarbyl group; R6 and R 6' are each independently hydrogen or a CI -20 hydrocarbyl group; R 7 is hydrogen or a CI -20 hydrocarbyl group or is ZR 3 ; Z is O or S, preferably O; R 3 is a Cl-10 hydrocarbyl group; Ar is an aryl or heteroaryl group having up to 20 carbon atoms optionally substituted by one or more groups R 8 ; Ar' is an aryl or heteroaryl group having up to 20 carbon atoms optionally substituted by one or more groups R 8' ; R 8 and R 8' are each independently is a CI -20 hydrocarbyl group; with the proviso that at least one of R 6 or R 7 is not H; and (ii) a cocatalyst comprising a compound of a group 13 metal, e.g. boron.
摘要翻译：一种催化剂，其包含（i）式（I）的不对称配合物，其中M为锆或铪; 每个X是σ配体; L是选自-R'2C-，-R'2C-CR'2-，-R'2Si-，-R'2Si-SiR'2-，-R'2Ge-的二价桥，其中每个R' 独立地是氢原子，C 1 -C 20 - 烷基，三（C 1 -C 20 - 烷基）甲硅烷基，C 6 -C 20 - 芳基，C 7 -C 20 - 芳基烷基或C 7 -C 20烷基芳基; R2和R2'各自独立地为直链C 1-10烃基; R5和R5'各自独立地为氢或C1〜20烃基; R6和R6'各自独立地为氢或C1〜20烃基; R 7为氢或C 1-20烃基或ZR 3; Z是O或S，优选O; R3是C1-10烃基; Ar是任选被一个或多个基团R 8取代的具有至多20个碳原子的芳基或杂芳基; Ar'是任选被一个或多个R 8'基团取代的具有至多20个碳原子的芳基或杂芳基; R8和R8'各自独立地为C1〜20烃基; 条件是R6或R7中的至少一个不是H; 和（ii）包含第13族金属化合物的助催化剂，例如硼。

3. 发明申请

WO2014096164A1 CATALYSTS 审中-公开
标题翻译：催化剂
公开(公告)号：WO2014096164A1
公开(公告)日：2014-06-26
申请号：PCT/EP2013/077335
申请日：2013-12-19
申请人： BOREALIS AG
发明人： RESCONI, Luigi , CASTRO, Pascal , VIRKKUNEN, Ville , IZMER, Vyatcheslav V , KONONOVICH, Dmitry S , KULYABIN, Pavel Sergeevich , VOSKOBOYNIKOV, Alexander Z
IPC分类号： C07F17/00 , C07F7/08 , C08F10/06 , C08F4/6592
CPC分类号： C08F4/65927 , C07C1/321 , C07C17/16 , C07C45/00 , C07C51/00 , C07F7/0818 , C07F7/082 , C07F17/00 , C08F210/06 , C08F10/06 , C08F4/65912 , C08F210/16 , C08F2500/03 , C08F2500/12
摘要： An asymmetric complex of formula (I) wherein M is zirconium or hafnium; each X is a sigma ligand; L is a divalent bridge selected from -R' 2 C-, -R' 2 C-CR' 2 -, -R' 2 Si-, -R' 2 Si-SiR' 2 -, -R' 2 Ge-, wherein each R' is independently a hydrogen atom, C1-C20-alkyl, tri(C1-C20-alkyl)silyl, C6-C20-aryl, C7-C20-arylalkyl or C7-C20-alkylaryl; R 2 and R 2 ' are each independently a C 1 -C 20 hydrocarbyl radical; R 5' is a C 1-20 hydrocarbyl group; R 5 is hydrogen, or a C 1-20 hydrocarbyl group; R 6 is a non tertiary C 1-10 alkyl group or C6-10-aryl group or C7-10 arylalkyl group or ZR 3 ; R 6' is a tertiary C 4-20 alkyl group; Z is O or S; R 3 is a C1-20 hydrocarbyl group optionally substituted with halo; Ar is an aryl or heteroaryl group having up to 20 carbon atoms optionally substituted by one or more groups R 1 ; Ar' is an aryl or heteroaryl group having up to 20 carbon atoms optionally substituted by one or more groups R 1 ; each R 1 is a C 1-20 hydrocarbyl group or two R 1 groups on adjacent carbon atoms taken together can form a fused 5 or 6 membered ring with the Ar group, said ring being itself optionally substituted with one or more groups R 4 ; and each R 4 is a C 1-20 hydrocarbyl group.
摘要翻译：式（I）的不对称配合物，其中M是锆或铪; 每个X是σ配体; L是选自-R'2C-，-R'2C-CR'2-，-R'2Si-，-R'2Si-SiR'2-，-R'2Ge-的二价桥，其中每个R' 独立地为氢原子，C 1 -C 20烷基，三（C 1 -C 20 - 烷基）甲硅烷基，C 6 -C 20 - 芳基，C 7 -C 20 - 芳基烷基或C 7 -C 20 - 烷基芳基; R2和R2'各自独立地为C1-C20烃基; R5'是C1-20烃基; R5是氢或C1-20烃基; R6是非叔C 1-10烷基或C 6-10 - 芳基或C 7-10芳基烷基或ZR 3; R6'是叔C4-20烷基; Z是O或S; R3是任选被卤素取代的C 1-20烃基; Ar是任选被一个或多个R 1基团取代的具有至多20个碳原子的芳基或杂芳基; Ar'是任选被一个或多个R 1基团取代的具有至多20个碳原子的芳基或杂芳基; 每个R 1是C 1-20烃基或相邻碳原子上的两个R 1基团可以与Ar基团形成稠合的5或6元环，所述环本身任选地被一个或多个基团R 4取代; 并且每个R 4是C 1-20烃基。

4. 发明公开

EP2655431A1 BRIDGED METALLOCENE CATALYSTS 审中-公开
标题翻译： VERBRÜCKTEMETALLOCENKATALYSATOREN
公开(公告)号：EP2655431A1
公开(公告)日：2013-10-30
申请号：EP11802400.9
申请日：2011-12-20
申请人： Borealis AG
发明人： RESCONI, Luigi , CASTRO, Pascal , VOSKOBOYNIKOV, Alexander Z , IZMER, Vyatcheslav V , KONONOVICH, Dmitry S
IPC分类号： C08F10/00 , C08F4/6592
CPC分类号： C08F4/76 , B01J31/2295 , B01J2231/122 , B01J2531/48 , B01J2531/49 , C07F17/00 , C08F4/52 , C08F4/65908 , C08F4/65927 , C08F10/00 , C08F110/06 , C08F210/06 , C08F4/65912 , C08F2500/03 , C08F2500/12 , C08F210/16
摘要： A solid, particulate catalyst comprising: (i) a complex of formula (I) wherein M is zirconium or hafnium; each X is a sigma ligand; L is a divalent bridge selected from -R
'2 C-, -R'
2 C-CR'
2 -, -R'
2 Si-, -R'
2 Si-SiR'
2 -, -R'
2 Ge-, wherein each R' is independently a hydrogen atom, C1-C20-hydrocarbyl, tri(C1-C20-alkyl)silyl, C6-C20-aryl, C7-C20-arylalkyl or C7-C20-alkylaryl; each R
1 is a C4-C20 hydrocarbyl radical branched at the β-atom to the cyclopentadienyl ring, optionally containing one or more heteroatoms belonging to groups 14-16, or is a C3-C20 hydrocarbyl radical branched at the β-atom to the cyclopentadienyl ring where the β-atom is an Si-atom; each R
18 is a C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms belonging to groups 14-16; each R
4 is a hydrogen atom or a C
1-6 -hydrocarbyl radical; each W is a 5 or 6 membered aryl or heteroaryl ring wherein each atom of said ring is optionally substituted with at least one R
5 group; each R
5 is the same or different and is a C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms belonging to groups 14-16; and optionally two adjacent R
5 groups taken together can form a further mono or multicyclic ring condensed to W optionally substituted by one or two groups R
5 ; and each R
7 is a C1-C20 hydrocarbyl radical; and (ii) a cocatalyst, preferably comprising an organometallic compound of a Group 13 metal.

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