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    • 3. 发明申请
    • THERMOPLASTIC POLYOLEFINS WITH HIGH FLOWABILITY AND EXCELLENT SURFACE QUALITY PRODUCED BY A MULTISTAGE PROCESS
    • 具有高流动性和优异表面质量的热塑性聚烯烃由多种工艺生产
    • WO2009153213A1
    • 2009-12-23
    • PCT/EP2009/057256
    • 2009-06-12
    • Borealis AGGREIN, ChristelleBERNREITER, Klaus
    • GREIN, ChristelleBERNREITER, Klaus
    • C08L23/12C08F2/00C08F4/646C08F210/06C08F210/16
    • C08L23/12C08F110/02C08F210/06C08F210/16C08F297/08C08F297/083C08L23/10C08L23/16C08L2205/02Y02P20/52C08F2/001C08F4/6465C08L2666/06C08L2666/02C08F2500/12C08F2500/17C08F2500/21
    • Reactor grade thermoplastic polyolefins with high flowability and excellent surface quality comprising (A) 40 - 90 wt% of a propylene homo- or copolymer matrix with an MFR in accordance with ISO 1 133 (230°C, 2.16 kg load) of ≥ 200 g/10 min and (B) 2 - 30 wt% of an elastomeric ethylene-propylene copolymer having an intrinsic viscosity IV (according to ISO 1628 with decalin as solvent) of ≤ 2.8 dl/g and an ethylene content of > 50 to 80 wt% and (C) 8 - 30 wt% of an elastomeric ethylene-propylene copolymer having an intrinsic viscosity IV (according to ISO 1628 with decalin as solvent) of 3.0 - 6.5 dl/g and an propylene content of 50 to 80 wt%, the reactor grade thermoplastic polyolefins being obtainable by a multistage polymerization process with at least 3 polymerization steps in the presence of a catalyst system comprising (i) a Ziegler-Natta procatalyst which contains a trans-esterification product of a lower alcohol and a phthalic ester and (ii) an organometallic cocatalyst and (iii) external donor represented by formula (I) Si(OCH 2 CH 3 ) 3 (NR 1 R 2 ) wherein R 1 and R 2 can be the same or different a represent a hydrocarbon group having 1 to 12 carbon atoms, as well as the use of these reactor grade thermoplastic polyolefins and molded articles produced from them.
    • 具有高流动性和优异表面质量的反应器级热塑性聚烯烃,其包含(A)40-90重量%的丙烯均聚物或共聚物基质,其具有根据ISO 1 133(230℃,2.16kg负荷)的MFR为= 200g / 10分钟,和(B)2-30重量%的特性粘度IV(根据ISO 1628,以萘烷作为溶剂)= 2.8dl / g,乙烯含量> 50-80重量%的弹性乙烯 - 丙烯共聚物 %和(C)8-30重量%的具有3.0-6.5dl / g的特性粘度IV(根据ISO 1628和十氢化萘作为溶剂)的弹性体乙烯 - 丙烯共聚物,丙烯含量为50-80重量% 反应器级热塑性聚烯烃可通过多级聚合方法获得,在催化剂体系存在下至少具有3个聚合步骤,所述催化剂体系包含(i)含有低级醇和邻苯二甲酸酯的酯交换反应产物的齐格勒 - 纳塔前催化剂和 (ii)有机金属助催化剂和(ii i)由式(I)Si(OCH 2 CH 3)3(NR 1 R 2)表示的外给体,其中R 1和R 2可以相同或不同,a表示具有1至12个碳原子的烃基,以及使用这些反应器级热塑性 聚烯烃和由它们生产的模塑制品。
    • 4. 发明申请
    • IMPROVED PROCESS FOR PRODUCING HETEROPHASIC PROPYLENE COPOLYMERS
    • 用于生产异构丙烯共聚物的改进方法
    • WO2012062738A1
    • 2012-05-18
    • PCT/EP2011/069618
    • 2011-11-08
    • BOREALIS AGLESKINEN, PauliGREIN, Christelle
    • LESKINEN, PauliGREIN, Christelle
    • C08F10/06C08F2/00C08F4/646
    • C08F10/06C08F110/06C08F210/06C08L23/12C08L23/142C08L23/16C08L2205/025C08L2205/03C08L2205/035C08L2308/00C08L2314/02C08F2/001C08F2500/02C08F210/16C08F2500/01C08F2500/17C08F110/14C08F4/6492
    • Process for producing high flow heterophasic propylene copolymers; said process comprises the steps of - polymerising propylene and optionally an ethylene and/or C 4 -C 12 alpha-olefin comonomer in a slurry reactor in the presence of hydrogen and a polymerisation catalyst system, obtaining as slurry reactor product first propylene polymer fraction (PP1) of the polypropylene matrix, - transferring the slurry reactor product into a 1 st gas phase reactor, - further polymerising propylene and optionally an ethylene and/or C 4 -C 12 α-olefin comonomer in the presence of said slurry reactor product, the polymerisation catalyst system and additional hydrogen, obtaining as 1 st gas phase reactor product a mixture of the first propylene polymer fraction (PP1) and a second propylene polymer fraction (PP2), being the polypropylene matrix of the heterophasic propylene copolymer having an MFR 2 in accordance with ISO 1133 (230°C, 2.16 kg) equal to or above 200 g/10min, - transferring said 1 st gas phase reactor product into a 2 nd gas phase reactor - producing a first elastomeric propylene copolymer fraction (EPR1), in the presence of said 1 st gas phase reactor product and at least one ethylene and/or C 4 to C 12 α-olefin, the comonomer/propylene ratio being in the range of 150 to 300 mol/kmol transferring the 2 nd gas phase reactor product into a 3 rd gas phase reactor, - producing a second elastomeric propylene copolymer fraction (EPR2) in the presence of said 2 nd gas phase reactor product and at least one ethylene and/or C 4 to C 12 α- olefin, the comonomer/propylene ratio being in the range of 300 to 1000 mol/kmol and, - recovering the heterophasic propylene copolymer for further processing said polymerisation catalyst system comprising (i) a Ziegler-Natta procatalyst and (ii) an organometallic cocatalyst and (iii) an external donor represented by formula (I) Si(OCH 2 CH 3 ) 3 (NR 1 R 2 ) (I) wherein R 1 and R 2 can be the same or different and represent a hydrocarbon group having 1 to 12 carbon atoms.
    • 生产高流量异相丙烯共聚物的方法; 所述方法包括在氢气和聚合催化剂体系的存在下,在淤浆反应器中聚合丙烯和任选的乙烯和/或C 4 -C 12α-烯烃共聚单体的步骤,获得作为浆料反应器产物的第一丙烯聚合物部分(PP1) 的聚丙烯基质, - 将淤浆反应器产物转移到第一气相反应器中, - 在所述淤浆反应器产物存在下,进一步聚合丙烯和任选的乙烯和/或C 4 -C 12α-烯烃共聚单体,聚合催化剂体系和 获得作为第一气相反应器产物的第一丙烯聚合物级分(PP1)和第二丙烯聚合物级分(PP2)的混合物,其是异相丙烯共聚物的聚丙烯基体,其具有根据ISO 1133的MFR 2(230 ℃,2.16kg)等于或高于200g / 10min, - 将所述第一气相反应器产物转移到第二气相反应器中 - 产生第一埃拉 聚丙烯共聚物部分(EPR1),在所述第一气相反应器产物和至少一种乙烯和/或C 4至C 12α-烯烃的存在下,共聚单体/丙烯比为150-300mol / 将第二气相反应器产物转化成第三气相反应器, - 在所述第二气相反应器产物和至少一种乙烯和/或C 4 -C 12α-烯烃的存在下生产第二弹性体丙烯共聚物部分(EPR2), 共聚单体/丙烯比在300至1000mol / kmol的范围内,和 - 回收多相丙烯共聚物,用于进一步处理所述聚合催化剂体系,其包含(i)齐格勒 - 纳塔前催化剂和(ii)有机金属助催化剂和(iii) 由式(I)Si(OCH 2 CH 3)3(NR 1 R 2)(I)表示的外给体,其中R 1和R 2可以相同或不同,表示具有1至12个碳原子的烃基。
    • 5. 发明申请
    • IMPROVED PROCESS FOR POLYMERISING PROPYLENE
    • 改进丙烯聚合方法
    • WO2012062735A1
    • 2012-05-18
    • PCT/EP2011/069614
    • 2011-11-08
    • BOREALIS AGPAAVILAINEN, JuhaLESKINEN, PauliHAKOLA, SameliSANDHOLZER, DanielGREIN, Christelle
    • PAAVILAINEN, JuhaLESKINEN, PauliHAKOLA, SameliSANDHOLZER, DanielGREIN, Christelle
    • C08F10/06C08F2/00C08F4/646
    • C08F2/04C08F2/34C08F10/06C08F110/06C08F210/06C08L23/12C08L2308/00C08L2314/02C08F2/001C08F2500/02C08F210/16C08F2500/01C08F2500/17C08L23/142
    • Process for producing a propylene homopolymer, a propylene random copolymer or a heterophasic propylene polymer, which process comprises the steps of (a) prepolymerisation, (b) slurry phase polymerisation (c) gas phase polymerisation and optionally (d) one or two further gas phase polymerisation(s), whereby the process is performed in the presence of a catalyst system comprising (x) a Ziegler-Natta procatalyst and (y) an organometallic cocatalyst and (z) an external donor represented by formula (II) and/or (III) Si(OCH 2 CH 3 ) 3 (NR 1 R 2 ) (II) or R 3 nR 4 mSi(OR 5 )z (III) wherein R 1 and R 2 can be the same or different and represent a hydrocarbon group having 1 to 12 carbon atoms and R 3 and R 4 can be the same or different and represent a hydrocarbon group having 1 to 12 carbon atoms, R 5 is methyl or ethyl, z is 2 or 3, preferably 2, m is 0 or 1, n is 0 or 1, with the proviso that n + m +z = 4, the external donor being added in an amount of 3 to 30 wt%, based on the total amount of external donor added, to the prepolymerisation step and in an amount of 70 to 97 wt%, based on the total amount of external donor added, to the slurry polymerisation step.
    • 制备丙烯均聚物,丙烯无规共聚物或多相丙烯聚合物的方法,该方法包括以下步骤:(a)预聚合,(b)淤浆相聚合(c)气相聚合和任选地(d)一种或两种另外的气体 其中该方法在催化剂体系存在下进行,所述催化剂体系包括(x)齐格勒 - 纳塔前催化剂和(y)有机金属助催化剂和(z)由式(II)表示的外给体和/或 (III)Si(OCH 2 CH 3)3(NR 1 R 2)(II)或R 3 n R 4 m Si(OR 5)z(III)其中R 1和R 2可以相同或不同,表示具有1至12个碳原子的烃基,且R 3和R 4可以 相同或不同,表示具有1至12个碳原子的烃基,R 5是甲基或乙基,z是2或3,优选2,m是0或1,n是0或1,条件是n + + z = 4,外给体的添加量为3〜30重量%,基于外给体ad的总量 给予预聚合步骤,并且以浆料聚合步骤为基础,将加入的外用供体的总量计为70-97重量%。