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    • 3. 发明专利
    • Aqueous coating composition
    • 水性涂​​料组合物
    • JP2005113140A
    • 2005-04-28
    • JP2004289797
    • 2004-10-01
    • Bayer Materialscience Agバイエル・マテリアルサイエンス・アクチェンゲゼルシャフトBayer MaterialScience AG
    • WAMPRECHT CHRISTIANBAUMBACH BEATEKUETTNER WOLFRAM
    • C09D131/02C09D5/00C09D7/12C09D161/06C09D161/20C09D161/24C09D161/26C09D167/00
    • C09D167/00C08L2666/16
    • PROBLEM TO BE SOLVED: To provide an aqueous coating composition satisfying an FDA regulation, containing only ≤20 mass.% of organic solvent, and a crosslinked film obtained from the composition manifests excellent physical properties and high resistance to thermal stress, and free from diglycidyl ether of bisphenol A.
      SOLUTION: The aqueous coating composition contains (A) one or more water-dilutable polyester polyols having an OH number of 20-300 mg KOH/g and an acid number of 20-80 mg KOH/g, obtained by reacting (a) 49-40 mol% of a carboxylic acid component containing an aliphatic, alicyclic, araliphatic and/or aromatic carboxylic acids with two or more COOH functionality and (b) 51-60 mol% of an alcohol component containing one or more aliphatic, alicyclic and/or araliphatic polyols with number average molecular weight of 62-272 g/mol and two or more average OH functionality, (B) one or more OH-reactive crosslinkers selected from the group consisting of phenolic resins, amino resins, benzoguanidine resins and urea resins each having a functionality (based on OH-reactive groups) of ≥2, (C) water, and (D) neutralizing agents.
      COPYRIGHT: (C)2005,JPO&NCIPI
    • 要解决的问题:为了提供满足FDA规定的仅含有≤20质量%有机溶剂的水性涂料组合物,并且由该组合物获得的交联膜显示出优异的物理性能和高的耐热应力性,以及 不含双酚A的二缩水甘油醚。解决方案:水性涂料组合物含有(A)一种或多种水可稀释的聚酯多元醇,其OH值为20-300mg KOH / g,酸值为20-80mg 通过使(a)49-40摩尔%的含有脂族,脂环族,芳脂族和/或芳族羧酸的羧酸组分与两种或更多种COOH官能团反应获得的KOH / g,和(b)51-60摩尔% 醇组分,其含有一种或多种数均分子量为62-272g / mol且两个或多个平均OH官能团的脂族,脂环族和/或芳脂族多元醇,(B)一种或多种选自以下的OH-反应性交联剂: 酚醛树脂,氨基 树脂,苯并胍类树脂和各自具有≥2,(C)水和(D)中和剂的官能度(基于OH反应性基团)的脲树脂。 版权所有(C)2005,JPO&NCIPI