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    • 4. 发明专利
    • BRPI0401661A
    • 2004-11-30
    • BRPI0401661
    • 2004-04-27
    • BAYER MATERIALSCIENCE AG
    • GRIMM WOLFGANGMICHELS ERHARDSCHUETZE MARC
    • C08G18/65C08G18/10C08G18/79C08G101/00C08J9/04C08J9/12C08G18/32C08J9/00
    • Flexible foamed polyurethane moldings of density below 500 kg/m 3>and DIN ISO 02769 maximum shrinkage 1.5% are obtained from mixtures of (a) organic isocyanates; (b) specified polyols; (c) crosslinkers/chain extenders; (d) blowing gents comprising nitrogen, air and/or carbon dioxide together with a chemical and/or physical blowing agent of boiling point -30 to +75[deg]C; and optionally also (e) emulsifiers; (f) additives or auxiliaries; and (g) catalysts : Flexible foamed polyurethane moldings of density below 500 kg/m 3>and DIN ISO 02769 maximum shrinkage 1.5% are obtained from mixtures with ratio molar NCO groups : NCO-reactive end groups = 0.95 : 1.15 comprising (a) organic isocyanates of 2-4 NCO groups per molecule and NCO content 6-49 wt.%; (b) polyols comprising (i) polyetheresterpolyols of number average molecular weight (M n) 800-6000, number average functionality 1.7-4 and ether : ester group weight ratio 0.05 : 0.95-0.48 : 0.52 obtained by polycondensation of (i.1) dicarboxylic acids or derivatives of up to 12C, (i.2) polyether polyols of M n1000-8000, average functionality 1.7-4 and ethyleneoxide content 10-40 wt.% and/or ether-based polymerpolyols of OH number 10-149 and average functionality 1.7-4, which contain 1-50 wt.% filler based on the polymerpolyol weight, (i.3) one or more polyols of M n62-750 and average functionality 2-8 which contain >=2 OH end groups per molecule and optionally (i.4) ester-based polymerpolyols of OH number 10-149 and average functionality 1.7-4 which contain 1-50 wt.% filler based on the polymerpolyol weight; and/or (ii) mixtures of (ii.1) polyesterpolyols consisting of polyesterpolyols of M n1000-4000 and functionality 1.4-7 and/or ester-based polymerpolyols as per (i.4) and (ii.2) 5-48 wt.% (based on (ii.1)) of polyetherpolyols consisting of ethyleneoxide-containing polyetherpolyols of M n900-18000, functionality 1.7-4 and ethyleneoxide content 10-40 wt.% and/or ether-based polymerpolyols OH number 10-149 and average functionality 1.7-4, which contain 1- 50 wt.% filler based on the polymerpolyol weight; (c) 5-25 wt.%, based on weight of (b) + (c), of crosslinkers/chain extenders; (d) blowing agents comprising nitrogen, air and/or carbon dioxide together with a chemical and/or physical blowing agent of boiling point -30 to +75[deg]C; and optionally also (e) emulsifiers; (f) additives or auxiliaries; and (g) catalysts An independent claim is also included for preparation of the polyurethane foam.
    • 6. 发明专利
    • DK1473313T3
    • 2006-10-02
    • DK04009184
    • 2004-04-17
    • BAYER MATERIALSCIENCE AG
    • GRIMM WOLFGANGMICHELS ERHARD DRSCHUETZE MARC DR
    • C08G18/10C08G18/42C08G18/40C08G18/65C08G18/79C08G101/00C08J9/04C08J9/12
    • Flexible foamed polyurethane moldings of density below 500 kg/m 3>and DIN ISO 02769 maximum shrinkage 1.5% are obtained from mixtures of (a) organic isocyanates; (b) specified polyols; (c) crosslinkers/chain extenders; (d) blowing gents comprising nitrogen, air and/or carbon dioxide together with a chemical and/or physical blowing agent of boiling point -30 to +75[deg]C; and optionally also (e) emulsifiers; (f) additives or auxiliaries; and (g) catalysts : Flexible foamed polyurethane moldings of density below 500 kg/m 3>and DIN ISO 02769 maximum shrinkage 1.5% are obtained from mixtures with ratio molar NCO groups : NCO-reactive end groups = 0.95 : 1.15 comprising (a) organic isocyanates of 2-4 NCO groups per molecule and NCO content 6-49 wt.%; (b) polyols comprising (i) polyetheresterpolyols of number average molecular weight (M n) 800-6000, number average functionality 1.7-4 and ether : ester group weight ratio 0.05 : 0.95-0.48 : 0.52 obtained by polycondensation of (i.1) dicarboxylic acids or derivatives of up to 12C, (i.2) polyether polyols of M n1000-8000, average functionality 1.7-4 and ethyleneoxide content 10-40 wt.% and/or ether-based polymerpolyols of OH number 10-149 and average functionality 1.7-4, which contain 1-50 wt.% filler based on the polymerpolyol weight, (i.3) one or more polyols of M n62-750 and average functionality 2-8 which contain >=2 OH end groups per molecule and optionally (i.4) ester-based polymerpolyols of OH number 10-149 and average functionality 1.7-4 which contain 1-50 wt.% filler based on the polymerpolyol weight; and/or (ii) mixtures of (ii.1) polyesterpolyols consisting of polyesterpolyols of M n1000-4000 and functionality 1.4-7 and/or ester-based polymerpolyols as per (i.4) and (ii.2) 5-48 wt.% (based on (ii.1)) of polyetherpolyols consisting of ethyleneoxide-containing polyetherpolyols of M n900-18000, functionality 1.7-4 and ethyleneoxide content 10-40 wt.% and/or ether-based polymerpolyols OH number 10-149 and average functionality 1.7-4, which contain 1- 50 wt.% filler based on the polymerpolyol weight; (c) 5-25 wt.%, based on weight of (b) + (c), of crosslinkers/chain extenders; (d) blowing agents comprising nitrogen, air and/or carbon dioxide together with a chemical and/or physical blowing agent of boiling point -30 to +75[deg]C; and optionally also (e) emulsifiers; (f) additives or auxiliaries; and (g) catalysts An independent claim is also included for preparation of the polyurethane foam.
    • 7. 发明专利
    • PROCEDIMIENTO PARA LA PREPARACION DE ELASTOMEROS DE POLIURETANO Y SU USO.
    • ES2295447T3
    • 2008-04-16
    • ES02797592
    • 2002-08-19
    • BAYER MATERIALSCIENCE AG
    • BRECHT KLAUSGRIMM WOLFGANGSCHLEIERMACHER STEPHANSCHUTZE MARC
    • A43B13/04C08G18/16C08G18/22C08G18/48
    • Procedimiento para la preparación de elastómeros de poliuretano, caracterizado porque se hacen reaccionar (a) di- y/o poliisocianatos orgánicos con (b) al menos un polioléter con un peso molecular numérico medio de 800 g/mol a 25.000 g/mol y con una funcionalidad media de 1, 6 a 2, 4, (c) dado el caso otros polioléteres distintos de b) con un peso molecular numérico medio de 800 g/mol a 25.000 g/mol y con funcionalidades medias de 2, 4 a 8, (d) dado el caso polimeropolioles con 1 a 50% en peso, preferiblemente 1 a 45% en peso de carga, referido al polimeropoliol, y con índices de OH de 10 a 149 y funcionalidades medias de 1, 8 a 8, (e) dado el caso alargadores de cadena de bajo peso molecular con funcionalidades medias de 1, 8 a 2, 1 y con pesos moleculares de 750 g/mol y menores y/o reticulantes con funcionalidades medias de 3 a 4 y con pesos moleculares de hasta 750 g/mol en presencia de (f) catalizadores amina y una mezcla de catalizadores compuesta por (g) al menos un compuesto orgánicode titanio y/o circonio (h) y al menos un carboxilato de litio orgánico (i) y dado el caso adicionalmente al menos un carboxilato de bismuto orgánico (j) dado el caso agentes de expansión y (k) dado el caso aditivos, en el que la relación entre la cantidad de substancia etaTi de los iones de titanio y/o etaZr de los iones de circonio del componente g) y la cantidad de substancia etaLi de los iones de litio del componente h) asciende a 0, 2 a 4, y cuando se utiliza el componente i) la relación entre la cantidad de substancia etaBi de los iones de bismuto del componente i) y la suma de las cantidades de substancia etaTi y/o etaZr y etaLi asciende a 0, 0001 a 0, 53.